• 제목/요약/키워드: Al and Zn alloys

검색결과 151건 처리시간 0.023초

용체화처리된 주조용 Mg-8%Al-X%Zn 합금의 부식 거동 (Corrosion Behavior of Solution-Treated Mg-8%Al-X%Zn Casting Alloys)

  • 전중환;황인제
    • 열처리공학회지
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    • 제28권3호
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    • pp.126-133
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    • 2015
  • The aim of this study is to investigate the effect of solution treatment on the corrosion behavior of Mg-8%Al-(0-1)%Zn casting alloys in 1M NaCl aqueous solution. After the solution treatment, all alloys showed single ${\alpha}$-(Mg) phase microstructure by dissolution of ${\beta}(Mg_{17}Al_{12})$ phase into the ${\alpha}$-(Mg) matrix. The $H_2$ evolution volume decreased with an increase in Zn content, which indicates that the addition of Zn plays a beneficial role in decreasing corrosion rate of the Mg-Al-Zn alloy in solution-treated state. The microstructural evaluations on the corrosion products and corroded surfaces after the immersion test in 1 M NaCl solution revealed that the incorporation of more $Al_2O_3$ and ZnO into the corrosion product, by which the penetration of $Cl^-$ ions is impeded, are thought to be responsible for the better corrosion resistance in relation with the Zn addition.

분무 Al-Zn-Mg 합금의 기계적 성질 및 미세조직에 미치는 Ag 첨가의 영향 (A Study on the Effects of Ag Addition on the Mechanical Properties and Microstructure in Atomized Al-Zn-Mg Alloys)

  • 신희상;정태호;남태운
    • 한국주조공학회지
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    • 제19권6호
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    • pp.456-465
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    • 1999
  • The overall objective of this study is to investigate the effect of Ag addition on the mechanical properties and microstructure of rapid solidified 7000 Al series alloys. Al-Zn-Mg-Cu alloys with small amounts of Ag was fabricated into the powder by gas atomization. The powder was extruded after the cold compaction and degassing and then followed by T6 heat treatment. Microstructure observation, phase analysis, room and high temperature tensile test and hardness test were pursued. The tensile strength and hardness of Ag-added alloy after heat treatment was increased with increasing Ag contents. However, the elongation of extruded alloys was not increased as much as to be expected. The reason of this result seems to be related to $the{\Omega}$ phase, which contribute to the high temperature strength stability of Al-Cu-Zn alloys through the formation of eutectoid with Ag addition.

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Al-Zn-Mg-(Sc) 합금의 고온가공성에 미치는 Sc 함량의 영향 (Effect of Scancium Content on The Hot Extrusion of Al-Zn-Mg-(Sc) Alloy)

  • 김진호;김정한;염종택;이동근;박노광
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2006년도 춘계학술대회 논문집
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    • pp.184-187
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    • 2006
  • The effects of scandium content and extrusion parameters on Al-Zn-Mg-(Sc) alloys were examined. Three kinds of Al-Zn-Mg-(Sc) alloys with up to 0.30 wt.% Sc were prepared. The compression test was conducted to investigate the microstructure evolution during hot deformation. Despite of microstructural differences in the alloys, deformation behaviors were very similar. After extrusion at $350^{\circ}C$ with the ram speed of 15mm/sec, AA7075 showed a moderate surface quality compared with other Sc containing alloys, which was attributed to low flow stresses. AA7075 showed coarse-grained bands in surface region. With the ram speed of 1.5mm/sec at $350^{\circ}C$, the surface quality of the alloys was sound due to low friction stresses and deformation heating. As the Sc content increased, tensile strengths and elongations at room temperature improved.

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합금원소 Si, Mn, Zn 첨가에 따른 Al-Mg 합금의 유동도 및 기계적 성질 변화 (Variation of Fluidity and Mechanical Properties of Al-Mg Alloys with the Addition of Si, Mn, and Zn)

  • 김정민;성기덕;전중환;김기태;정운재
    • 한국주조공학회지
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    • 제24권3호
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    • pp.138-144
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    • 2004
  • Effects of alloying elements such as Si, Mn, Zn on the fluidity and mechanical properties of high ductility Al-Mg based alloys were investigated. The fluidity of alloys was evaluated using a vacuum suction fluidity test, and Si addition was observed to increase the fluidity of AI-Mg binary alloys substantially while Zn somewhat decreased the fluidity. However, both the strength and ductility were significantly deteriorated by the Si additions. It was observed that a small amount of Mn addition to Al-Mg alloy increased the tensile strength effectively without losing much ductility but the effect of Zn addition on the strength was relatively small.

최대하중조건에 따른 Mg-Al-Zn 합금의 확률변수 잔차를 이용한 확률론적 피로균열전파모델 평가 (Evaluation of Probabilistic Fatigue Crack Propagation Models in Mg-Al-Zn Alloys Under Maximum Load Conditions Using Residual of Random Variable)

  • 최선순
    • 대한기계학회논문집A
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    • 제39권1호
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    • pp.63-69
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    • 2015
  • 본 논문의 주 목적은 최대하중조건을 변화시키면서 확률변수의 잔차를 이용하여 확률론적 피로균열전파모델들을 평가하고, Mg-Al-Zn 합금의 피로균열성장거동의 변동성을 묘사하기에 적합한 확률론적 모델을 제시하는 것이다. 평가에 사용된 모델은 피로균열성장의 변동성을 나타내기 위하여 실험적 피로균열전파모델인 Paris-Erdogan 모델, Walker 모델, Forman 모델과 수정 Forman 모델에 확률변수를 도입한 모델이다. 최대하중조건에 따른 Mg-Al-Zn 합금의 피로균열전파거동의 확률적 변동성을 묘사하기에 적합한 모델은 '확률론적 Paris-Erdogan 모델'과 '확률론적 Walker 모델'임을 밝혔으며, 최대하중조건이 피로균열성장의 확률적 변동성에 미치는 영향 또한 고찰하였다.

확률변수의 잔차를 이용한 Mg-Al-Zn 합금의 시편두께 조건에 따른 확률론적 피로균열전파모델 연구 (A Study of Probabilistic Fatigue Crack Propagation Models in Mg-Al-Zn Alloys Under Different Specimen Thickness Conditions by Using the Residual of a Random Variable)

  • 최선순
    • 대한기계학회논문집A
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    • 제36권4호
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    • pp.379-386
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    • 2012
  • 본 논문의 주 목적은 확률변수의 잔차를 이용하여 제안된 확률론적 피로균열전파모델들을 평가하고 Mg-Al-Zn 합금의 확률론적 피로거동을 묘사하기에 적합한 모델을 제시하는 것이다. 제안된 모델은 '확률론적 Paris-Erdogan 모델', '확률론적 Walker 모델', '확률론적 Forman 모델'과 '확률론적 수정 Forman 모델'이다. 이 모델들은 실험적 피로균열전파모델인 Paris-Erdogan 모델, Walker 모델, Forman 모델과 수정 Forman 모델에 확률변수를 도입하여 준비하였다. Mg-Al-Zn 합금의 피로균열전파거동을 묘사하기에 적합한 모델은 일반적으로 '확률론적 Paris-Erdogan 모델'과 '확률론적 Walker 모델'임을 밝혔으며, 시편두께 9.45mm 에서는 '확률론적 Forman 모델'이 적합하였다.

등온 시효한 Mg-Al-(Zn) 합금에서 불연속 석출물의 경도와 미세조직에 미치는 Zn 첨가의 영향 (Effects of Zn Addition on Hardness and Microstructure of Discontinuous Precipitates in Isothermally Aged Mg-Al-(Zn) Alloys)

  • 전중환
    • 열처리공학회지
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    • 제35권4호
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    • pp.177-184
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    • 2022
  • The present study aims to investigate the influence of Zn addition on hardness and microstructural characteristics of discontinuous precipitates (DPs) formed by isothermal aging in Mg-9%Al and Mg-9%Al-1%Zn alloys. To obtain large DPs volume fractions in the microstructure, the alloy specimens were solution-treated at 688 K for 24 h followed by water quenching, and then aged at 413 K for 48 h. The aged Mg-9%Al-1%Zn alloy had higher DPs content than the Mg-9%Al alloy, indicating that the Zn addition plays a beneficial role in enhancing age-hardening response. The DPs in the Zn-containing alloy possessed the higher hardness than those of the Zn-free alloy. Microstructural examination revealed that the increased hardness of the DPs resulting from the Zn addition is closely associated with the lower α-(Mg)/β(Mg17Al12) interlamellar spacing and the higher volume fraction of β phase layer of the DPs.

희생양극 하에서 알루미늄의 해수 부식 거동 (Corrosion Behavior of Aluminium Coupled to a Sacrificial Anode in Seawater)

  • 김종수;김희산
    • 한국표면공학회지
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    • 제39권1호
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    • pp.25-34
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    • 2006
  • Al-Mg alloy, an open rack vaporizer(ORV) material was reported to be corroded in seawater environments though the ORV material was coupled to thermally sprayed Al-Zn alloy functioning a sacrificial anode. In addition, the corrosion behavior based on the calculated corrosion potential did not match the observed corrosion behavior. Hence, the goal of this study is to get better understanding on Al or Al-Mg alloy coupled to Al-Zn alloy and to provide the calculated corrosion potential representing the corrosion behavior of the ORV material by immersion test, electrochemical tests, and calculation of corrosion and galvanic potential. The corrosion potentials of Al and Al alloys also depended on alloying element as well as surface defects. The corrosion potentials of Al and Al-Mg alloy were changed with time. In the meantime, the corrosion potentials of Al-Zn alloys were not. The corrosion rates of Al-Zn alloys were exponentially increased with zinc contents. The phenomena were explained with the stability of passive film proved by passive current density depending on pH and confirmed by the model proposed by McCafferty. Dissimilar material crevice corrosion (DMCC) test shows that higher content of zinc caused Al-Mg alloy corroded more rapidly, which was due to the fact that higher corrosion rate of Al-Zn makes [$H^+$] and [$Cl^-$] more concentrated within pit solution to corrode Al-Mg alloy. Considering electrochemical reactions within pit as well as bulk in the calculation gives better prediction on the corrosion behavior of Al and Al-Mg alloy as well as the capability of Al-Zn alloy for corrosion protection.

CORROSION BEHAVIOR OF Al-Zn ALLOY AS A SACRIFICIAL ANODE OF ORV TUBES

  • Jin, Huh;Lee, Ho-Kyun;Lee, Jae-Ho
    • 한국표면공학회지
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    • 제32권3호
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    • pp.452-455
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    • 1999
  • ORV which vaporizes LNG to NG is consisted of tube and header whose substrate is aluminum alloy. The corrosion of the tube is very severe because of sea water being used as the heating source. In this research to protect ORV substrate material, the corrosion behavior of aluminum alloys was investigated for the sacrificial role of Al-Zn alloy for ORV tubes. The electrochemical behavior of aluminum alloys in sea water was investigated. The corrosion behavior of thermally-sprayed and cladded samples were compared through salt spray tests. Al-Zn alloy can act as a sacrificial anode and cladded Al-Zn alloy has a better corrosion resistance than that of thermally sprayed one. The galvanic effect of Al-Zn to substrate material was conformed from scratched sample tests.

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비대칭 압연과 시효 시퀀스가 Al-Zn-Mg-Cu합금의 미세조직과 기계적 특성에 미치는 영향 (Effects of Asymmetric Rolling and Aging Sequence on Microstructure and Mechanical Properties of Al-Zn-Mg-Cu Aluminum Alloys)

  • 정민경;이종범;김수현;한준현
    • 열처리공학회지
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    • 제36권5호
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    • pp.285-297
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    • 2023
  • The effects of aging treatment sequence, specifically pre-aging and post-aging, on the microstructure and mechanical properties of Al-Zn-Mg-Cu aluminum alloys has been studied in comparison to symmetrically rolled specimens. In symmetrically rolled specimens, a straight-band precipitation distribution was observed, whereas asymmetrically rolled specimens exhibited a curved-band microstructure of fine precipitates. Notably, the asymmetrically rolled specimens displayed higher strengths. In the case of post-aging, the aging process occurred after rolling, and the dislocations generated during rolling acted as nucleation sites for precipitates during aging. This resulted in the formation of fine precipitates, contributing to improved mechanical properties compared to symmetric rolling. To enhance strength of the Al-Zn-Mg-Cu aluminum alloys, asymmetric rolling proves to be more effective than symmetric rolling, with post-aging showing greater efficacy than pre-aging.