• Title/Summary/Keyword: Al Contents

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Behaviors of Metals in the Settling Particles in the Bransfield Strait, Antarctica (남극 브랜스필드 해협에서 침강입자의 금속원소 특성)

  • Kim, Dong-Seon;Kim, Dong-Yup;Kim, Young-June;Kang, Young-Chul;Shim, Jeong-Hee
    • Ocean and Polar Research
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    • v.25 no.1
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    • pp.41-52
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    • 2003
  • Sediment trap samples were collected to find out characteristic behaviors of metals in the settling particles by using time-series sediment traps at 678m and 1678m water depths in the Bransfield Strait from December 27th, 1999 to December 26th, 2000. Total mass fluxes at the intermediate water depth (678m water depth) were high in the austral summer and low in the austral winter, whereas at the deep water depth (1678m water depth) they showed high values in both the summer and winter. Total mass fluxes were generally higher in the deep water depth than in the intermediate water depth, which indicates that a substantial amount of sediments are laterally transported by strong currents into the deep basin from the shallow water depths. Aluminium contents also showed large seasonal variations with high values in the winter and low values in the summer. On the contrary, organic carbon contents were high in the summer and low in the winter. Al contents were negatively correlated with organic carbon contents, which may be ascribed that detrital particles are diluted by organic matter produced by phytoplankton in the surface waters. Metals measured in this study exhibited three characteristic behaviors; 1) a positive correlation with Al-Ti, Fe, Mn, V, Co, and Ba, 2) a negative correlation with Al-Cd and Zn, 3) no relationship with Al-Sr, Cu, Cr, Ni. Terrestrial materials may act as a major source fer metals that are positively correlated with Al, and organic matter may be a major source for metals that are negatively correlated with Al. Enrichment factor (EF) of Fe, Mn, Ba, Vi Co, Sr, Cr, and Ni ranged from 0.5 to 1.5, whereas EF of Zn, Cu, and Cd showed much higher values than 1.

Using Liquid Aluminum Chloride to Reduce Heavy Metals from Animal Wastes (액상염화알루미늄을 이용한 축산 폐기물 속의 중금속 저감 효과)

  • Kim, Chang-Mann;Choi, Jung-Hoon;Choi, In-Hag
    • Journal of Environmental Science International
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    • v.21 no.3
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    • pp.377-382
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    • 2012
  • Recent research has demonstrated that treating poultry litter with alum (aluminum sulfate) and aluminum chloride can remove environmental threats (ammonia, soluble phosphorus and odor) posed by litter. However, scientific information available on heavy metal in poultry litter with liquid aluminum chloride is still lacked. The purpose of this study was to investigate the effects of applying liquid aluminum chloride to rice hulls on heavy metals and to provide basic information to producers. Six hundred 0-d-old broiler were assigned to 4 treatments (control, 100 g, 200 g and 300 g of liquid $AlCl_3$/kg of rice hulls, respectively) with 3 replicates of 50 birds. The experimental period lasted for 6 weeks. Liquid $AlCl_3$ was sprayed on the rice hulls surface using a small hand pump. Total Al contents increased (P<0.05) with the increasing levels of liquid $AlCl_3$ levels over time in comparison with control groups. Total Cu and Pb were lowered in all liquid $AlCl_3$ treatments compared with the controls during 6 weeks. Significant differences in all treatments were found for total Cu contents at 2, 3 and 5 weeks and total Pb at 0, 1, 2 and 3 weeks. Total Zn contents decreased with time when compared with controls. However, no significant differences in total Zn contents were observed among all treatments. In light of environmental managements, spraying liquid $AlCl_3$ to rice hulls indicated the significant advantages in reducing heavy metals as well as improving poultry industrial competitiveness.

Friction Characteristics of Automotive Friction Materials with Ceramic Powder Contents (자동차용 마찰재에 함유된 세라믹분말의 함량에 따른 마찰특성)

  • Lee, Yong-Jin;Ryu, Jae-Kyung;Kim, Taik-Nam
    • Korean Journal of Materials Research
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    • v.19 no.7
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    • pp.403-406
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    • 2009
  • The friction characteristics of automotive brake friction materials that contained different ceramic content were investigated. Several kinds of raw materials, such as resin-based binder, reinforcing fiber, friction restraint, abrasive, and filling materials were mixed, pressed, and heated in order to make the brake friction materials. The contents of SiC and $BaSO_4$ changed from 5 vol% to 20 vol%, respectively. In addition to this, the content of $Al_2O_3$ adjusted from 1 vol% to 16 vol%. The surface morphology of the SiC containing sample appeared rough while more debris was observed when the contents of SiC increased. This implies that the SiC containing brake composite was not adequate for the automobile. However, the relatively smooth surface was observed in samples that contained the $Al_2O_3$. But the roughness was low with a content of 11 vol% $Al_2O_3$ compared to the other samples. This is consistent with the abrasive properties of the samples. In the case of $BaSO_4$ containing samples, the smoothes surface was observed in the contents of 15 vol% $BaSO_4$. Thus, it was concluded that the 11 vol% $Al_2O_3$ and 15 vol% $BaSO_4$ containing composite would be the optimum content for the brake composite. Similar to the results of the surface morphology, the abrasion resistance consistently decreased when the content of SiC increased. On the contrary, the sample that contained 11 vol% $Al_2O_3$ and 15 vol% $BaSO_4$ showed the highest abrasion resistance compared to the other samples.

Effects of Aluminum Compound on the Brain Histologial Change of Rats (알루미늄 화합물이 흰쥐의 뇌조직에 미치는 영향)

  • Han, Sung-Hee;Kim, Joong-Man;Baek, Seung-Hwa
    • Korean Journal of Food Science and Technology
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    • v.27 no.6
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    • pp.915-920
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    • 1995
  • This study was performed to investigate the effect of aluminum compound on the aluminum contents and histological change in brain tissue of rats. Seventy five male Sprague-Dawley strains were divided into five groups consisting of the control, 250 ppm $AlCl_3$ group, 500 ppm $AlCl_3$ group, 250 ppm $Al_2(SO_4)_3$ group, 500 ppm $Al_2(SO_4)_3$ group and kept on the diet for 2 weeks. The weight gain was increased by administration of $AlCl_3$ but decreased by administration of $Al_2(SO_4)_3$ as compared to control group. The aluminum contents in brain tissue of each group; 250 ppm $AlCl_3$ group, 500 ppm $AlCl_3$ group, 250 ppm $Al_2(SO_4)_3$ group and 500 ppm $Al_2(SO_4)_3$ group were 64.63, 102.21, 132.64 and 180.41 ppm, respectively. Aluminum accumulation in brain tissue was higher with administration of $Al_2(SO_4)_3$ than with administration of $AlCl_3$. In $AlCl_3$ administration group, multiple small intracytoplasmic granules and microvacuole were seen in large pyramidal cells of cortex and granulovacuolar degeneration. In $Al_2(SO_4)_3$ administration group revealed pollagis pallor, cellular pyknosis, microcavitation resulted from edema in deeper cortical layers were observed. Blue-pigmentation which represents the accumulation of aluminum was noted In granulovacuolar degeneration site in $Al_2(SO_4)_3$ administration group.

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Effect of Fe, Mn Content on the Castability in Al-9wt%Si-Mg System Alloys for High Elongation (고신율 금형주조용 Al-9wt%Si-Mg계 합금의 주조특성에 미치는 Fe, Mn함량의 영향)

  • Kim, Heon-Joo;Jeong, Chang-Yeol
    • Journal of Korea Foundry Society
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    • v.33 no.6
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    • pp.233-241
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    • 2013
  • Effect of Fe and Mn contents on the castability of Al-9wt%Si-xMg-yFe-zMn alloy has been studied. The alloy was composed of ${\alpha}$-Al phase, Al+eutectic Si phase, ${\beta}$-Al5FeSi compound and chinese script ${\alpha}$-$Al_{15}(Mn,Fe)_3Si_2$ compound. ${\beta}$-$Al_5FeSi$ and ${\alpha}$-$Al_{15}(Mn,Fe)_3Si_2$ compounds assumed to effect the fluidity and shrinkage behaviors of the alloy during solidification due to the crystallization of ${\alpha}$-$Al_{15}(Fe,Mn)_3Si_2$ and ${\beta}$-$Al_5FeSi$ compounds above eutectic temperature. As Fe and Mn contents of Al-9wt%Si-0.3wt%Mg system alloy increased from 0.15wt% to 0.6wt% and from 0.3wt% to 0.7wt%, fluidity of the alloy decreased by 5.7% and 3.3%, respectively. And as Mg content of Al-9wt%Si-0.45wt%Fe-0.5wt%Mn system alloy increased from 0.3wt% to 0.4wt%, fluidity of the alloy decreased by 8.6%. When Fe content of the alloy increased from 0.15wt% to 0.6wt%, macro shrinkage ratio decreased from 6.1% to 4.1%, and micro shrinkage ratio increased from 0.04% to 0.24%. Similarly, Mn content of the alloy increased from 0.3wt% to 0.7wt%, macro shrinkage ratio decreased from 6.0% to 4.5% and micro shrinkage ratio increased from 0.12% to 0.18%. Judging from the castability of the alloy, Al-9wt%Si-0.3wt%Mg alloy with low content of Fe and Mn, 0.1wt% Fe and 0.3wt% Mn, is recommendable.

Studies on Trace Elements of Polished Rice in Korea (I) (한국산 쌀의 Trace Element에 관한 연구 (제1보))

  • 오성례
    • YAKHAK HOEJI
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    • v.4 no.1
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    • pp.17-20
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    • 1959
  • Recently the attention of the trace elements in arisen to the biochemical importances and the biochemical significances have been discussed and shown by several workers. And also UN-narcotic Committee has shown that geographical difference of Optimum based on the produced area, would be significant on its contents of trace elements. The problem of Rice in Korea is urgently important on the nutritional and agricultural view points for the soil improvement of its production and for the betterment of health program. In order to check the adaptability of cultural problems to the different qualities of the with regards to the kinds of rice spieces and in order to know the comsumption of trace elements through rice, the contents of trace elements on 40 samples of the polished rice sampled from the different areas consisting in 8 kinds of rice species are studied on contents of Al, MN, Ni, Zn, Co, Cu and Fe in this paper. Though the further wide spread studies should be carried out. It seems that Al, Fe and Ni contents show little differences by the kinds of rices species and Cu, Al, Mn, Zn, and Ni contents show geographically little differences. But these differences are not significant statistically. The Co was not detected from the rice samples. It is not clear whether Co content in rice is a undetectable amount or the Co is absent in rice at all.

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A Study on the Hydrogenation Properties of MmNi4.5Al0.5Zrx(X=0.0-0.2) Alloys Containing the Zr by Excess (Zr을 과잉 첨가한 MmNi4.5Al0.5Zrx(X=0.0-0.2) 합금의 수소화 반응특성에 대한 연구)

  • Na, Young-Sang;Lee, Jai-Young
    • Journal of Hydrogen and New Energy
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    • v.4 no.1
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    • pp.31-39
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    • 1993
  • In order to improve the hydrogen storage capacity and the activation property of the $MmNi_{4.5}Al_{0.5}$ alloy, the multiphase alloy system are prepared by adding the excess Zr in $MmNi_{4.5}Al_{0.5}$ alloy. It is estimated from the X-ray diffraction pattern and the energy dispersive X-ray analysis that the 2nd phases in $MmNi_{4.5}Al_{0.5}Zr_x$ alloys are $ZrNi_3$, ${\beta}$-Zr. Their morphology is also examined by the scanning electron microscope, and it shows the needle-like precipitation. As the Zr contents increase, the activation time and the plateau pressure decrease, sloping of the plateau pressure increase. Amount of the 2nd phases increase with Zr contents in $MmNi_44.5Al_{0.5}Zr_x$ alloys. The $MmNi_44.5Al_{0.5}Zr_{0.05}$ alloy, which shows the maximum storage capacity and the strong resistance to intrinsic degradation, is considered as a proper alloy for hydrogen storage.

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Effects of Characterization of Polymeric Al(III) Coagulants on Coagulation of Surface Water (고분자성 Al(III) 응집제의 특성이 상수원수의 응집특성에 미치는 영향)

  • Lee, Sun Gi;Han, Seung Woo;Kang, Lim Seok
    • Journal of Korean Society of Water and Wastewater
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    • v.12 no.2
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    • pp.99-105
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    • 1998
  • This research explored the feasibility of preparing and utilizing a preformed polymeric solution of Al(III) for coagulation in water treatment. Slow base(NaOH) injection into supersaturated aluminum chloride solutions did produce high yields of the type of Al polymers useful to water treatment applications. PACl's characteristic analysis showed that the quantity of polymeric Al produced at value of $r(OH_{added}/Al)=2.2$ was 83% of the total aluminum in solution, as showing maximum contents and precipitate was dramatically increased when r was increased above 2.35. And PACl was stable during sitoring period so aging effect was negligible. Results of the coagulation of Nakdong river waters with three PACls showed that the effectiveness of the three coagulants can be considered as r = 2.2 > r = 2.0 > r = 2.35 which are also the order of higher polymeric aluminum contents. Coagulation results for synthetic water exhibited optimum dose of 0.25mM Al, for three PACls, but above optimum dose, r = 2.0 and 2.2 PACl impaired the coagulation and sedimentation of turbidity and humic acid because of the restabilization of particulate. The effect of pH for on coagulation of Nak Dong River water showed that it had much effect turbidity and TOC removal, especially near pH 7. But pH effect was little for turbidity and TOC removal when r = 2.35 PACl was used for coagulation, that PACl had much more precipitates content.

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Properties of the $\beta$-SiC-$ZrB_2$ Composites with $Al_{2}O_{3}+Y_{2}O_{3}$ additives ($Al_{2}O_{3}+Y_{2}O_{3}$를 첨가한 $\beta$-SiC-$ZrB_2$ 복합체의 특성)

  • Shin, Yong-Deok;Ju, Jin-Young
    • Proceedings of the KIEE Conference
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    • 1998.11c
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    • pp.853-855
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    • 1998
  • The electrical resistivity and mechanical properties of the hot-pressed and annealed ${\beta}$-SiC+39vol.%$ZrB_2$ electroconductive ceramic composites were investigated as a function of the liquid forming additives of $Al_{2}O_{3}+Y_{2}O_{3}$(6:4wt%). In this microstructures. no reactions were observed between $\beta$-SiC and $ZrB_2$, and the relative density is over 97.6% of the theoretical density. Phase analysis of composites by XRD revealed mostly of a $\alpha$-SiC(6H, 4H), $ZrB_2$ and weakly $\beta$-SiC(15R) phase. The fracture toughness decreased with increased $Al_{2}O_{3}+Y_{2}O_{3}$ contents and showed the highest for composite added with 4wt% $Al_{2}O_{3}+Y_{2}O_{3}$ additives. The electrical resistivity increased with increased $Al_{2}O_{3}+Y_{2}O_{3}$ contents because of the increasing tendency of pore formation according to amount of liquid forming additives $Al_{2}O_{3}+Y_{2}O_{3}$. The electrical resistivity of composites is all positive temperature coefficient resistance(PTCR) against temperature up to $700^{\circ}C$.

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Studies on Incombustibility Improvement of EPDM Rubber with $Al(OH)_3$ and $Sb_2O_3$ ($Al(OH)_3$$Sb_2O_3$의 첨가에 따른 EPDM계 고무의 난연성 향상 연구)

  • Kim, Jin-Yong;Lee, Won-Bok;Lim, Dae-Hyun;Suh, Hyuk;Rhee, Young-Woo
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.11a
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    • pp.449-452
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    • 2009
  • In order to improve incombustibility of EPDM(Ethylene propylene diene monomer)-based rubber, inorganic materials as $Al(OH)_3$ and $Sb_2O_3$ were added. The mechanical and thermal properties have been measured for vulcanized rubber loaded with different concentrations of $Al(OH)_3$ and $Sb_2O_3$. As inorganic material contents increases from 5phr to 30phr, the specific gravity and hardness increase while elongation at break decreases. This study performed incombustibility test and thermal analysis through TGA(Thermogravimetric Analyzer). As a results, incombustible and thermal properties of EPDM-based rubber were improved as $Al(OH)_3$ and $Sb_2O_3$ contents increase.

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