• Title/Summary/Keyword: Airborne concentration

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A Study on Composition of Solvent Thinners and Evaporation in the Air (일부 신나의 구성성분과 공기중 증발에 관한 연구)

  • Zoh, Kyung Ehi;Paik, Nam Won
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.7 no.2
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    • pp.245-263
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    • 1997
  • For twelve solvent thinners, evaporation rates of components were investigated and models to estimate the actual concentration have been evaluated. Also, the current ACGIH TLVs (Threshold Limit Values) for the concentration of organic mixtures have been adjusted. The results of this study are summarized as follows : 1. Airborne concentrations of solvent thinner components were related to their respective vapor pressure (r=0.96). On the other hand, there was no significant relation between the concentrations in the air of the thinner compounds and the original amount in liquid form. 2. Airborne concentrations of each chemical were estimated by temperature at $8.5{\pm}1$, $16.7{\pm}1$ and $31.5{\pm}2^{\circ}C$ with an air velocity of 1.5 m/s. The concentrations were increased by increasing temperature (p<0.05). The percentage of concentrations were proportionate to their respective percentage of vapor pressure. Among the chemicals studied, n-butyl acetate, n-butyl alcohol, m-xylene, p-xylene and o-xylene showed a clear relationship to temperature. 3. Airborne concentration of each chemical was estimated by air velocity at 0.05, 1.50 and 2.50 m/s, with a constant temperature at $17{\pm}2^{\circ}C$. The concentrations were increased by increasing air velocity (p<0.05). The percentage of concentrations were proportionate to their respective percentage of vapor pressure. Among the chemicals studied, n-butyl alcohol, m-xylene and p-xylene showed a clear relationship to velocity. 4. In estimating the concentrations of solvent thinners by temperature and air velocity, ACGIH TLVs for mixtures tended to be larger than the values obtained by ACGIH exposure index. It shows that ACGIH TLVs for mixtures are not adequate for evaluating the airborne concentration of thinners and other organic mixtures. 5. The evaporation rate of the thinners were compared to the theoretical equations of Hummel, Braun and Mackay. The Hummel and Braun methods were close to exposure index but Makay's showed an underestimated value. In order to see the accuracy of each three models, the SSE (Error Sum of Squares) calculated for Hummel's was 1.73, being the closest to the actual values. 6. Present ACGIH TLVs for mixtures are not appropriate evaluate industrial environments. In this study, a correction of TLVs using vapor pressure of respective components was suggested. In order to evaluate the corrected TLVs a paired t-test was performed. There was no significant difference between the exposure index and the concentration over suggested TLVs (p>0.05). Thus, this corrected TLVs seem appropriate in order to evaluate actual industrial workplaces organic chemical concentration in the air.

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A Study on Factors Affecting Airborne Fume Composition and Concentration in Welding Process (용접공정에서 발생된 공기중 흄의 조성과 농도에 영향을 미치는 요인에 관한 연구)

  • Shin, Yong Chul;Yi, Gwang Yong;Park, Seung Hyun;Lee, Na Roo;Jeong, Jee Yeon;Park, Jung Keun;Oh, Se Min;Moon, Young Hahn
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.7 no.2
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    • pp.181-195
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    • 1997
  • The purpose of this study was to investigate factors affecting the composition and concentrations of fumes generated from various types of welding processes. The results are as follows. 1. Iron(Fe), zinc(Zn) and manganese(Mn) were predominant in Welding fumes. The Fe content in total fumes was 25.5% in coated electrode and 28.2% in $CO_2$ are welding, and the Zn content was 4.5% and 9.1%, respectively, and the Mn was 3.6% and 7.8%, respectively. 2. It was found that the important factors determining composition and concentration of fumes were type of industries, type of welding processes, type and composition of electrodes, composition of base metals, confinement of workplaces or condition of ventilation, work intensity, coated metals such as lead and Zn in paint. 3. The Mn content in airborne fumes was highly correlated with that of electrode(r=0.77, p<0.01) and was about 4 times higher than that in electrodes or base metals. The results lindicate that Mn is well evaporated into air during welding. The higher vapor pressure of Mn may explain this phenomenon. 4. the airborne total fume concentrations were significantly different among types of industries(p<0.001). The airborne total fume concentration was higher in order of sleel-structure manufacturing($GM=15.1mg/m^3$), shipbuilding($GM=13.2mg/m^3$), automobile-component manufacturing ($GM=7.8mg/m^3$) and automobile assembling industry($GM=3.0mg/m^3$) 5. The airbone total fume concentration was 6 times higher in $CO_2$ welding than in coated electrode welding, and approximately 3 times higher in confined area than in open area, in steel-structure manufacturing industry. 6. The concentration of welding fume outside welding helmet was about 2 times higher than that inside it. It is recommened that air sampling be done inside helmet to evaulate worker's exposure accurately, for it has an outstanding effect on reducing worker exposure to fumes and other contaminants.

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Risk Assessment of Airborne Toxic Metals in Thejon Industrial Complex (대전공단지역의 대기중 독성금속에 대한 위해도 평가)

  • Lee, Jin Hong;Yun, Mi Jung;Nam, Byung Hyun;Wang, Chang Keun;Kang, Ho
    • Journal of Environmental Impact Assessment
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    • v.8 no.2
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    • pp.1-8
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    • 1999
  • The research centers on the concentration profile and risk assessment of toxic metals for ambient air in Taejon industrial complex. Airborne concentrations of each toxic metal for risk assessment were obtained from 2-year sampling by high volume air sampler and analysis by ICP-MS and ICP-AES in the complex. The long-term arithmetic mean of human carcinogen, arsenic, hexavalent chromium and nickel subsulfide was 5.53, 2.16 and $3.46ng/m^3$ while the mean of probable human carcinogen, beryllium, cadmium and lead was 0.08, 2.35, $293.29ng/m^3$, respectively. And the long-term arithmetic mean concentration of non-carcinogenic metal, manganese was $55.91ng/m^3$. The point risk estimate for the inhalation of carcinogenic metals was $3.6{\times}10^{-5}$, which was higher than a risk standard of $10^{-5}$. About 75% of the cancer risk was to the inhalation of human carcinogen, arsenic. Thus, it is necessary to properly manage arsenic risk in Taejon industrial complex. The point hazard index by the inhalation of manganese was 1.1. Therefore, an investigation into Taejon industrial complex is needed to obtain more fine long-term concentration data for airborne non-carcinogenic metals including manganese.

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A Study on Airborne Coal Dust Concentration at each Work Site in Coal Briquet Factory (연탄제조 공장의 작업장별 석탄분진의 농도에 관한 연구)

  • 신대윤;오정룡;강공언
    • Journal of Environmental Health Sciences
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    • v.18 no.1
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    • pp.6-11
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    • 1992
  • This study was carried out to investigate exposure level, size distribution, and respirable mass fraction of airborne coal dust and heavy metal concentration of respirable coal dust at each work site in coal briquet factory from July 1991 to September 1991. Geometric mean of total dust concentration was 10.88mg/m$^{3}$ at storage shop, 8.22mg/m$^{3}$ at pulverize shop, and 3.79mg/m$^{3}$ at rotary press shop, respectively, but those at storage and pulverize shop were higher than TLV. Geometric mean of respirable coal dust concentration wat 1.03mg/m$^{3}$ at storage shop, 0.78mg/m$^{3}$ at pulverize shop, and 0.55mg/m$^{3}$ at rotary press shop, respectively, which were lower than TLV Aerodynamic 50% cutoff diameter of the suspended coal dust was 5$\mu$m at rotary press shop and 6.8$\mu$m at storage shop, ranged to thoracic particulate defined by ACGIH, and deposited in the region of repiratory system. The mass fraction rate of respirable dust to the total coal dust was 26.2% at rotary press shop, 18.8% at storage shop, and 13.8% at pulverize shop, respectively. Heavy metal concentrations of the respirable coal dust were 0.028mg/m$^{3}$ ib Fe, 0.0081mg/m$^{3}$ in Cu, and 0.0039mg/m$^{3}$ in Pb.

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Effects of Occupational Chromium Exposure on Plasma Homocysteine, Folate and Vitamin B12 Concentration (직업적인 크롬 노출이 혈중 Homocysteine, Folate와 Vitamin B12 농도에 미치는 영향)

  • Kim, Ki-Woong;Kim, Kyoo Sang;Park, Injeong;Kang, Seong-Kyu;Oh, Sung-Soo;Jeong, Hyo Seok;Chang, Sung Keun
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.16 no.3
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    • pp.245-253
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    • 2006
  • We evaluated the relations among exposure and urinary levels of Cr, folate, vitamin $B_{12}$ and Hcy levels in the workers chronically exposure to Cr. Subjects were 104 male employees, 65 workers exposed to Cr in 9 electroplating plants and 39 office workers who had never been occupationally exposed to hazardous substances including Cr. The geometric mean(GM) of Cr in workplace was $0.069{\pm}0.101mg/m^3$ and urinary Cr was $0.483{\pm}0.394mg/g$ creatinine and airborne Cr concentration was significantly correlated to the urinary concentration of Cr(r=0.900, p=0.000). The geometric mean concentration of urinary Cr in control group was $0.301{\pm}0.255mg/g$ creatinine. In comparing the workers exposed to Cr with controls, significantly higher mean plasma levels were found of Hcy($11.3{\pm}4.9$ vs $9.4{\pm}4.7{\mu}mol/{\ell}$, p=0.05), but vitamin $B_{12}$ levels ($181.8{\pm}68.7$ vs $216.0{\pm}64.3nmol/{\ell}$, p=0.01) was significantly decreased. Hcy concentrations correlated positively with airborne Cr concentrations(r=0.287, p=0.004) and urinary Cr concentrations(r=0.244, p=0.015) but folate concentrations correlated negatively with airborne(r=-0.234, p=0.020) and urinary Cr concentrations(r=-0.640, p=0.090), respectively. No correlations were observed between vitamin $B_{12}$, airborne and urinary Cr concentrations. Also, Hcy concentrations correlated positively with vitamin $B_{12}$(r=0.295, p=0.0020 and negatively with folate concentrations(r=-0.196, p=0.046). The various biological(i.e. age and serum indicates) or lifestyle factors(i.e. medication, smoking, alcohol and coffee intake), also taken into account as potential confounders, did not influence the correlations found. Thus, this study found evidence that Cr might be associated with elevated plasma levels of Hcy. Furthermore, elevated plasma levels of Hcy were significantly associated with folate and vitamin $B_{12}$ concentration.

Distribution Properties of Airborne Chlorides in Korea (우리나라의 비래염분 분포 특성)

  • Lee, Jong-Suk;Ahn, Ki-Hong;Kim, Do-Gyeum;Park, Jung-Jun
    • Journal of the Korea Concrete Institute
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    • v.22 no.6
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    • pp.769-776
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    • 2010
  • Concrete structures immersed in seawater are exposed to uniform chloride concentration. However, seashore concrete structures are subjected to various airborne chlorides concentration depending on areas, distance from seashore, orientation of structures and wind direction etc. Therefore, structures which is not coming into direct contact with seawater are greatly affected by salt attack and those cases have been reported. This study intends to investigate salt attack by airborne chlorides in terms of the distance from the seashore based on the measurements conducted at 73 spots and 27 areas during 3 years in the Eastern, Western and Southern coasts of South Korea. Results revealed large regional variations of the salinity in coastal regions along with significant seasonal effects caused by seasonal winds. Moreover, the salinity is seen to diminish as the distance from the seashore increases at a rate corresponding to the function $y=ax^{-b}$. These results will be helpful to do the durability design and management of seashore structures.

Isolation Effectiveness by Progressive Space Organization in Negative Pressured Isolation Unit (음압격리병실에 있어서 단계별 공간구성의 격리효과)

  • Kwon, Soonjung;Sung, Minki
    • Journal of The Korea Institute of Healthcare Architecture
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    • v.22 no.4
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    • pp.79-86
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    • 2016
  • Purpose: The purpose of this study is to identify the effect of Progressive Space Organization (ante-rooms) in Negative Pressured Isolation Unit(NPIU) such as National and Regional Isolation Units in Korea in order to build basic data for the evidence based design of Airborne Infection Isolation Units which should prepare and respond effectively to the public health crisis due to the hazardous airborne infectious disease. Methods: 1) Gas(SF6) test and analysis on the 23 Korean Isolation Units under operation. 2) Assessment of the isolation level of the space components by checking the Gas concentration. 3) Analysis of the Isolation Effectiveness according to Space Organizational levels. Results: 1) The higher segregation level is, the lower Gas(SF6) concentration is. 2) Too many segregations(anterooms) of Isolation Unit are not efficient for the prevention of infectious bacillus spread. For example, 4 level of segregation has similar segregation effect to the 3 level of segregation. Implications: Many anterooms in front of the isolated patient bedroom will guarantee the safe environment against the danger of hazardous airborne nosocomial infection. On the other hand, too many segregations is inefficient, expensive, inconvenient, narrow(unflexible) and so on. This study can be used as basic data for further development of design guidelines of isolation units.

A study of a thermal energy equipment for controlling airborne microorganisms in indoor laboratory environments (열에너지 활용 부유미생물 제어장치 설계 및 실험실 실내공기를 대상으로 한 성능측정에 관한 연구)

  • Kim, Hyun Geon;Hwang, Gi Byung;Lee, Jun Hyun;Lee, Byung Uk
    • Particle and aerosol research
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    • v.5 no.3
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    • pp.133-138
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    • 2009
  • Airborne microorganisms, termed bioaerosols, are etiological agents of many respiratory and skin diseases. There are high demands of controlling the concentration of bioaerosols, specifically in indoor environments. Here, a new system for controlling indoor bioaerosols is designed and evaluated. An idea of a short time exposure to a thermal energy is used in the design of the equipment. The system was tested in laboratory environments. The experimental results show that the new system can reduce the concentration of viable bioaerosols of indoor laboratory environments.

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Design and Performance Evaluation using Computational Fluid Dynamics (CFD) Analysis of Wetcyclones for the Collection of Airborne Bacteria (공기 중 박테리아 포집을 위한 습식 사이클론의 CFD 해석을 이용한 설계 및 성능 평가)

  • Hyun Sik Ko;Jungwoo Park;Jiwoo Jung;Jungho Hwang
    • Particle and aerosol research
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    • v.19 no.3
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    • pp.77-87
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    • 2023
  • We present the development of a wetcyclone sampler designed for the sampling of airborne bacteria. The wetcyclone design involves a combination of two traditional cyclone shapes and computational fluid dynamics (CFD) analysis to validate its effectiveness in terms of pressure drop and collection efficiency. The wetcyclone exhibits a collection efficiency of over 90% for bacteria, specifically targeting Staphylococcus aureus. Additionally, the wetcyclone enables continuous bioaerosol sampling using a liquid medium (deionized water), demonstrating a concentration ratio exceeding >105 and a stable microbial recovery rate of 81.9%. The application of real-time quantitative polymerase chain reaction (qPCR) and the colony counting method ensures precise measurement of the concentration ratio and microbial recovery rate.

Distribution of Hospital Airborne Microorganisms in Seoul, Korea (서울시내 종합 병원 공기중의 미생물 분포)

  • Hong, Jun-Bai;Chung, Yun-Hee;Yun hee Chang
    • Journal of Environmental Health Sciences
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    • v.29 no.1
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    • pp.1-7
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    • 2003
  • This study was carried out to investigate the airborne microbial pollution in hospital environment. Using a mechanical air sampler, microbiological samples were taken from intensive care unit, general ward room, patients wailing room and outdoor of 20 hospitals in Seoul, Korea. The concentration of airborne bacteria and fungi ranged 97-410 cfu/㎥ and 37-77 cfu/㎥, respectively and patients waiting room had highest bacterial count. 10 genera of molds were identified and the most frequently recovered molds were Aspergillus, followed by Penicillium, Alternaria and Cladosporium. Among Staphylococcus species, S. haemolyticus and S. epidermidis were predominant and 47% of Staphylococcus species were isolated from intensive rare unit.