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Study on Formation Mechanism of Iron Oxide Nanoparticles (산화철 나노입자의 형성 메커니즘에 대한 연구)

  • Kim, Dong-Young;Yoon, Seok-Soo;Takahashi, Migaku
    • Journal of the Korean Magnetics Society
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    • v.22 no.5
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    • pp.167-172
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    • 2012
  • In order to analyze the formation mechanism of iron oxide nanoparticles, we measured the heat flow of $Fe(OL)_3$ precursor with temperature, and TEM images and AC susceptibility of aliquots samples sequentially taken from the reaction solution, respectively. The thermal decomposition of two OL-chain from $Fe(OL)_3$ produced the Fe-OL monomer, which were contributed to the formation of iron oxide nanoparticles. In the initial stage of nanoparticles formation, the small iron oxide nanoparticles had ${\gamma}-Fe_2O_3$ structure. However, as the iron oxide nanoparticles were rapidly growth, the iron oxide nanoparticles showed ${\gamma}-Fe_2O_3$-FeO core-shell structure which the FeO layer was formed on the surface of ${\gamma}-Fe_2O_3$ nanoparticles by insufficient oxygen supply from the reaction solution. These nanoparticles were transformed to $Fe_3O_4$ structure by oxidation during long aging time at high temperature. Finally, the $Fe_3O_4$ nanoparticles with high saturation magnetization and stable in the air could be easily synthesized by the thermal decomposition method.

The Effect of Pre and Intra-Operative Warming Therapy on Tympanic Temperature Changes during Perioperative Phase in Receiving Patients with Total Hip Replacement (수술전과 수술중 피부가온요법 적응이 고관절 전치환술 환자의 수술 주기 고막체온 변화에 미치는 영향)

  • Kwon Young-Sook;Kim Eun-Hee
    • Journal of Korean Academy of Fundamentals of Nursing
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    • v.7 no.1
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    • pp.86-96
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    • 2000
  • The purpose of the study was to investigate the effects of Warming Therapy used with patients consistantly before and during surgery to on changes in their body temperatures. The data were collected from patients in a university hospital in Taegu between December 1, 1998 and May 31, 1999. The subjects were selected from patients who were hospitalized for total hip replacement surgery. Thirty participants were assigned to two groups : experimental(Warming Therapy) group and control group. Each group consisted of 15 patients. The research design was a repeated measurement design, using a nonequivalent control group. The Warming Therapy, using a forced-air warming blanket, that is a, 'Bair Hugger' was applied to subjects in the experimental group. The subjects in the group were treated with the 'Bair Hugger' to warm up the whole body for 40 minutes before surgery and upper body and face during the operation. The core temperature was measured using a tympanic thermometer. The body temperature of the patients was measured 13 times every 15 minutes during the surgery. After the operation the body temperature of the patients was measured 4 times every 15 minutes, from the time of arrivial in the recovery room to the time of leaving the recovery room. The SPSS Win 9.0 program was used for data analysis. Specific methods tested were done using ${\chi}^2-test$, t-test, repeated measures ANOVA. The findings of the study are as follows. 1. The first hypothesis, 'The level of tympanic temperature for the experimental group which received Warming Therapy will be higher than that of the control group during the operation', was supported (F=32.16, p=.000). 2. The second hypothesis, 'The level of tympanic temperature for the experimental group which received Warming Therapy will be higher than that of the control group after the operation', was supported.(F=33.36, p=.000) 3. During recovery, shivering was observed one patient in the experimental group and seven patients in the control group. In summary, the findings of the study suggest that the 'Warming Therapy' applied before and during the surgery was a very effective treatment for surgical patients in maintaining the core temperature during surgery

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Effect of Hollow Sphere Size on Heat Shield Properties of hollow TiO2/polyacrylate Composites (중공구의 크기에 의한 hollow TiO2/polyacrylate 복합체의 열차단 특성)

  • Kim, Jong Seok
    • Applied Chemistry for Engineering
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    • v.32 no.6
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    • pp.690-694
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    • 2021
  • Carbon spheres (CS) were fabricated using glucose as a precursor in the hydrothermal method. Hollow TiO2 (H-TiO2) spheres with 200 nm, 500 nm, and 1,200 nm were synthesized by CS/TiO2 core-shell particles via a sol-gel and calcination method. H-TiO2 spheres with nano and micron sizes were characterized using FE-SEM, HR-TEM, and X-ray diffraction. The CIE color coordinate, solar reflectance, and heat shield temperatures of H-TiO2/polyacrylate (PA) composite film were investigated using a UV-Vis-NIR spectrometer and homemade heat insulation temperature measuring device. H-TiO2/PA composites exhibit excellent thermal insulation since the hollow structure filled with dry air has low thermal conductivity and near infrared light reflecting performance. The thermal insulation increased with increasing the hollow sphere (HS) size on H-TiO2/PA composites. The PA composite film mixed with H-TiO2 filled with 1200 nm HS reduced the heat shield temperature by 26 ℃ compared to that of the transparent glass counterpart.

Geoacoustic Model at the YSDP-105 Long-core Site in the Mid-eastern Yellow Sea (황해 중동부 해역 YSDP-105 심부코어 지점의 지음향 모델)

  • Ryang, Woo-Hun;Jin, Jae-Hwa;Hahn, Jooyoung
    • Journal of the Korean earth science society
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    • v.40 no.1
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    • pp.24-36
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    • 2019
  • In the mid-eastern Yellow Sea, glacio-eustatic sea-level fluctuations and a regional tectonic subsidence have combined to represent an aggradational stacking pattern of sedimentary units during late Pleistocene-Holocene. The accumulated sediments are divisible into two-type units of Type-A and Type-B in high-resolution air-gun seismic profiles and the deep-drilled core of YSDP-105. Type-A unit largely comprises clast-rich coarse-grained sediments of non-marine to paralic origin, whereas Type-B unit consists mostly of tidal fine-grained sediments. Based on a bottom model of the sedimentary units, this study suggested a geoacoustic model of long-coring bottom layers at the YSDP-105 drilling site of the mid-eastern Yellow Sea. The geoacoustic model of 64-m depth below the seafloor with four-layer geoacoustic units was reconstructed in continental shelf strata at 45 m in water depth. For actual modeling, the geoacoustic property values of the models were compensated to in situ depth values below the seafloor using the Hamilton modeling method. We suggest that the geoacoustic model will be used for geoacoustic and underwater acoustic experiments of mid- and low-frequency reflecting on the deep bottom layers in the mid-eastern Yellow Sea.

Development of Robot Platform for Autonomous Underwater Intervention (수중 자율작업용 로봇 플랫폼 개발)

  • Yeu, Taekyeong;Choi, Hyun Taek;Lee, Yoongeon;Chae, Junbo;Lee, Yeongjun;Kim, Seong Soon;Park, Sanghyun;Lee, Tae Hee
    • Journal of Ocean Engineering and Technology
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    • v.33 no.2
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    • pp.168-177
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    • 2019
  • KRISO (Korea Research Institute of Ship & Ocean Engineering) started a project to develop the core algorithms for autonomous intervention using an underwater robot in 2017. This paper introduces the development of the robot platform for the core algorithms, which is an ROV (Remotely Operated Vehicle) type with one 7-function manipulator. Before the detailed design of the robot platform, the 7E-MINI arm of the ECA Group was selected as the manipulator. It is an electrical type, with a weight of 51 kg in air (30 kg in water) and a full reach of 1.4 m. To design a platform with a small size and light weight to fit in a water tank, the medium-size manipulator was placed on the center of platform, and the structural analysis of the body frame was conducted by ABAQUS. The robot had an IMU (Inertial Measurement Unit), a DVL (Doppler Velocity Log), and a depth sensor for measuring the underwater position and attitude. To control the robot motion, eight thrusters were installed, four for vertical and the rest for horizontal motion. The operation system was composed of an on-board control station and operation S/W. The former included devices such as a 300 VDC power supplier, Fiber-Optic (F/O) to Ethernet communication converter, and main control PC. The latter was developed using an ROS (Robot Operation System) based on Linux. The basic performance of the manufactured robot platform was verified through a water tank test, where the robot was manually operated using a joystick, and the robot motion and attitude variation that resulted from the manipulator movement were closely observed.

A Study on the Analysis of R&D Trends and the Development Plan of Electronic Attack System (전자공격체계 연구개발 동향 분석과 발전방안에 대한 연구)

  • Sim, Jaeseong;Park, Byoung-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.6
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    • pp.469-476
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    • 2021
  • An electronic attack (EA) system is an essential weapon system for performing electronic warfare missions that contain signal tracking and jamming against multiple threats using electromagnetic waves, such as air defense radars, wireless command and communication networks, and guided missiles. The combat effectiveness can be maximized, and the survivability of militarily protecting combat power can be enhanced through EA mission operations, such as disabling the functions of multiple threats. The EA system can be used as a radio frequency jamming system to respond to drone attacks on the core infrastructure, such as airports, power plants, and communication broadcasting systems, in the civilian field. This study examined the criteria for classification according to the electronic attack missions of foreign EA systems based on an aviation platform. The foreign R&D trends by those criteria were investigated. Moreover, by analyzing the R&D trends of domestic EA systems and future battlefields in the domestic security environments, this paper proposes technological development plans of EA systems suitable for the future battlefield environments compared to the foreign R&D trends.

Analysis on Study Cases of Safety Assessment and Cases for Spent Nuclear Fuel Pool Accident (사용후핵연료 습식저장시설 사고 안전성 평가 연구 현황 및 사고 사례 분석)

  • Shin Dong Lee;Hyeok Jae Kim;Geon Woo Son;Kwang Pyo Kim
    • Journal of Radiation Industry
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    • v.17 no.3
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    • pp.283-292
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    • 2023
  • Spent nuclear fuel corresponds to high-level radioactive waste that has high decay heat and radioactivity. Accordingly, Spent nuclear fuel withdrawn from the reactor core is primarily stored and managed in a spent nuclear fuel pool in the nuclear power plant to reduce decay heat and radioactivity. In Korea, most nuclear power plant store all spent nuclear fuel in a spent nuclear fuel pool. For wet storage, there are no defense in depth different with reactor core. The study related to spent nuclear fuel pool accident should be carried out to ensure safety. Therefore, it is necessary to analyze previous study cases related to safety of spent nuclear fuel pool and accident cases to build foundational knowledge. The Objective of this study is to analyze study cases of safety assessment and cases for spent nuclear fuel pool accident. For analyzing study cases of safety assessment, possible phenomena when spent nuclear fuel pool accident occurring identified, Subsequently, study cases for safety assessment about each phenomena were investigated, and materials & methods and results for each study are analyzed. For analyzing cases for spent nuclear fuel pool accident, we analyzed accident cases caused by loss of cooling and loss of coolant in spent nuclear fuel pool. Subsequently, causes and change of water level and temperature by each accident case are analyzed. As a result of the analysis on study cases of spent nuclear fuel pool accident, the results of the study conducted by each research institute were vary depending on the computer code, materials & methods of experiment and major assumptions used in the study. As a result of analyzing cases for spent nuclear fuel pool accident, it was found that accident cases for loss of cooling is more than cases for loss of coolant accident. Even though the types of accident in spent nuclear fuel pool were similar, the specific causes were different by each accident case. All the accident cases analyzed did not lead to severe accidents, such as nuclear fuel being exposed to the air. The result of this study will be used as fundamental data for study on spent nuclear fuel pool accident that will be conducted in the future.

A Study on Appropriate Military Strength of Unified Korea (Focused on relative balance strategy and conflict scenario) (통일 한국의 적정 군사력에 관한 연구 - 분쟁 시나리오와 상대적 균형전략을 중심으로 -)

  • Hong, Bong-Gi
    • Journal of National Security and Military Science
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    • s.13
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    • pp.687-738
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    • 2016
  • To prepare for the complicated international relationship regarding Korean Peninsula after reunification, this thesis started off with the awareness that Unified Korea should build its international posture and national security at an early stage by determining its appropriate military strength for independent defense and military strategies that Unified Korea should aim. The main theme of this thesis is 'The research on appropriate military strength of the Unified Korean military'. To derive appropriate military strength of Unified Korea, this research focuses on conflict scenario and relative balance strategy based on potential threats posed by neighboring countries, and this is the part that differentiates this research from other researches. First of all, the main objective of the research is to decide appropriate military strength for Unified Korea to secure defense sufficiency. For this, this research will decide efficient military strategy that Unified Korea should aim. Than by presuming the most possible military conflict scenario, this research will judge the most appropriate military strength for Unified Korea to overcome the dispute. Second, after deciding appropriate military strength, this research will suggest how to operate presumed military strength in each armed force. The result of this thesis is as in the following. First, Unified Korea should aim 'relative balance strategy'. 'Relative balance strategy' is a military strategy which Unified Korea can independently secure defense sufficiency by maintaining relative balance when conflicts occur between neighboring countries. This strategy deters conflicts in advance by relative balance of power in certain time and place. Even if conflict occurs inevitably, this strategy secures initiative. Second, when analyzing neighboring countries interest and strategic environment after unification, the possibility of all-out war will be low in the Korean Peninsula because no other nation wants the Korean Peninsula to be subordinated to one single country. Therefore appropriate military strength of the Unified Korean military would be enough when Unified Korea can achieve relative balance in regional war or limited war. Third, Northeast Asia is a region where economic power and military strength is concentrated. Despite increasing mutual cooperation in the region, conflicts and competition to expand each countries influence is inherent. Japan is constantly enhancing their military strength as they aim for normal statehood. China is modernizing their military strength as they aspire to become global central nation. Russia is also enhancing their military strength in order to hold on to their past glory of Soviet Union as a world power. As a result, both in quality and quantity, the gap between military strength of Unified Korea and each neighboring countries is enlarged at an alarming rate. Especially in the field of air-sea power, arms race is occurring between each nation. Therefore Unified Korea should be equipped with appropriate military strength in order to achieve relative balance with each threats posed by neighboring countries. Fourth, the most possible conflicts between Unified Korea and neighboring countries could be summarized into four, which are Dokdo territorial dispute with Japan, Leodo jurisdictional dispute with China, territorial dispute concerning northern part of the Korea Peninsula with China and disputes regarding marine resources and sea routes with Russia. Based on those conflict scenarios, appropriate military strength for Unified Korea is as in the following. When conflict occurs with Japan regarding Dokdo, Japan is expected to put JMSDF Escort Flotilla 3, one out of four of its Japan Maritime Self-Defense Force Escort Fleet, which is based in Maizuru and JMSDF Maizuru District. To counterbalance this military strength, Unified Korea needs one task fleet, comprised with three task flotilla. In case of jurisdictional conflict with China concerning Leodo, China is expected to dispatch its North Sea fleet, one out of three of its naval fleet, which is in charge of the Yellow Sea. To response to this military action, Unified Korea needs one task fleet, comprised with three task flotilla. In case of territorial dispute concerning northern part of the Korean Peninsula with China, it is estimated that out of seven Military Region troops, China will dispatch two Military Region troops, including three Army Groups from Shenyang Military Region, where it faces boarder with the Korean Peninsula. To handle with this military strength, Unified Korea needs six corps size ground force strength, including three corps of ground forces, two operational reserve corps(maneuver corps), and one strategic reserve corps(maneuver corps). When conflict occurs with Russia regarding marine resources and sea routes, Russia is expected to send a warfare group of a size that includes two destroyers, which is part of the Pacific Fleet. In order to balance this strength, Unified Korea naval power requires one warfare group including two destroyers. Fifth, management direction for the Unified Korean military is as in the following. Regarding the ground force management, it would be most efficient to deploy troops in the border area with china for regional and counter-amphibious defense. For the defense except the border line with china, the most efficient form of force management would be maintaining strategic reserve corps. The naval force should achieve relative balance with neighboring countries when there is maritime dispute and build 'task fleet' which can independently handle long-range maritime mission. Of the three 'task fleet', one task fleet should be deployed at Jeju base to prepare for Dokdo territorial dispute and Leodo jurisdictional dispute. Also in case of regional conflict with china, one task fleet should be positioned at Yellow Sea and for regional conflict with Japan and Russia, one task fleet should be deployed at East Sea. Realistically, Unified Korea cannot possess an air force equal to neither Japan nor China in quantity. Therefore, although Unified Korea's air force might be inferior in quantity, they should possess the systematic level which Japan or China has. For this Unified Korea should build air base in island areas like Jeju Island or Ullenong Island to increase combat radius. Also to block off infiltration of enemy attack plane, air force needs to build and manage air bases near coastal areas. For landing operation forces, Marine Corps should be managed in the size of two divisions. For island defense force, which is in charge of Jeju Island, Ulleung Island, Dokdo Island and five northwestern boarder island defenses, it should be in the size of one brigade. Also for standing international peace keeping operation, it requires one brigade. Therefore Marine Corps should be organized into three divisions. The result of the research yields a few policy implications when building appropriate military strength for Unified Korea. First, Unified Korea requires lower number of ground troops compared to that of current ROK(Republic of Korea) force. Second, air-sea forces should be drastically reinforced. Third, appropriate military strength of the Unified Korean military should be based on current ROK military system. Forth, building appropriate military strength for Unified Korea should start from today, not after reunification. Because of this, South Korea should build a military power that can simultaneously prepare for current North Korea's provocations and future threats from neighboring countries after reunification. The core of this research is to decide appropriate military strength for Unified Korea to realize relative balance that will ensure defense sufficiency from neighboring countries threats. In other words, this research should precisely be aware of threats posed by neighboring countries and decide minimum level of military strength that could realize relative balance in conflict situation. Moreover this research will show the path for building appropriate military strength in each armed force.

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THE EFFECTS OF VARIOUS ALL-ETCHING AGENTS AND VARIED ETCHING TIME ON ENAMEL MORPHOLOGY AND BOND STRENGTH (수종의 All-Etching Agent와 산부식시간에 따른 법랑질 산부식형태 및 전단 결합강도에 관한 연구)

  • Kwon, So-Ran;Yoon, Tae-Hyun;Park, Dong-Soo
    • Restorative Dentistry and Endodontics
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    • v.21 no.1
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    • pp.136-149
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    • 1996
  • The effects of various All-Etching Agents (10% phosphoric acid, 10% maleic acid and 10 % citric acid) and 32 % phosphoric acid and varied etching time were evaluated by observing the morphology of the etched enamel surfaces using Scanning electron microscopy and by measuring the shear bond strength of a composite resin to human enamel. A total of 156 extracted premolar and molar teeth free of irregularities were employed in this study. Specimens for the observation of enamel morphology were divided into 12 groups of 3 teeth each, based on the type of etchant used and application time. After exposure to the etching agent specimens were washed air-dried and then glued to aluminum stubs and coated with a layer of gold for examination in the scanning electron microscope. Specimens for the evaluation of bond strength were divided into 12 groups of 10 teeth each also based on the type of etchant used and application time. After exposure to the etching agent the specimens were washed, air-dried and a thin layer of bonding agent was applied using a brush. Z 100 composite resin was light cured to the surface and stored at $37^{\circ}C$, 100% humidity for 7 days. An Instron Universal Testing Machine was used to apply a shearing force at $90^{\circ}$ angle from the enamel surface. It is concluded from this study that commercial All-etching agents can be used with a 15-second etching without adversely affecting retention of dental resin materials. At the same time, the acid concentration is probably a suitable compromise regarding the acid's function as a dentin demineralizing all-etch conditioning agent. The following results were obtained. 1. Specimens etched with 10 % citric acid showed a random superficial etching pattern which could not be related to prism morphology. 2. Specimens etched with 10 % and 32 % phosphoric acid and 10 % maleic acid showed a type I pattern in which core material was preferentially removed leaving the prism peripheries relatively intact or a type II pattern in which prism peripheries were preferentially removed. This delineation became more distinguished as etching time was increased. 3. All-Etching Agents and 32 % phosphoric acid showed a statistically significant higher shear bond strength at 15 seconds etching time.(p<0.05) 4. 10 % maleic acid and 32 % phosphoric acid exhibited a statistically significant higher shear bond strength than 10 % phosphoric and citric acid at 15 seconds etching time.(p<0.05).

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Changes in Means and Extreme Events of Changma-Period Precipitation Since mid-Joseon Dynasty in Seoul, Korea (조선 중기 이후 서울의 장마철 강수 평균과 극한강수현상의 변화)

  • Choi, Gwangyong
    • Journal of the Korean Geographical Society
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    • v.51 no.1
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    • pp.23-40
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    • 2016
  • In this study, long-term changes in means and extreme events of precipitation during summer rainy period called Changma (late June~early September) are examined based on rainfall data observed by Chukwooki during Joseon Dynasty (1777~1907) and by modern rain-gauge onward (1908~2015) in Seoul, Korea. Also, characterizations of the relevant changes in synoptic climate fields in East Asia are made by the examination of the NCEP-NCAR reanalysis I data. Analyses of 239-year time series of precipitation data demonstrate that the total precipitation as well as their inter-annual variability during the entire Changma period (late June~early September) has increased in the late 20th century and onward. Notably, since the early 1990s the means and extreme events during the summer Changma period (late June~mid-July) and Changma break period (late July~early August) has significantly increased, resulting in less clear demarcations of sub-Changma periods. In this regard, comparisons of synoptic climate fields before and after the early 1990s reveal that in recent decades the subtropical high pressure has expanded in the warmer Pacific as the advection of high-latitude air masses toward East Asia was enhanced due to more active northerly wind vector around the high pressure departure core over Mongolia. Consequently, it is suggested that the enhancement of rising motions due to more active confluence of the two different air masses along the northwestern borders of the Pacific might lead to the increases of the means and extreme events of Changma precipitation in Seoul in recent decades.

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