• Journal of the Korea Concrete Institute
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• v.20 no.5
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• pp.661-668
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• 2008

It is necessary to develop a new technology for effectively reducing hydration heat and controlling thermal cracking caused increasing construction of large size massive concrete structures such as mat foundation of high-rise building, grandiose bridge, and LNG tank. Therefor, to develop a new technology for reducing hydration heat of large size massive concrete in this study, after developing the latent heat binder for controling hydration heat of concrete by application of latent heat material, it was investigated basic properties and durability such as slump, air content and compressive strength, shrinkage properties, permeability, freezing and thawing resistance, corrosion, and hydration heat generation properties of concrete using latent heat binder. As a test result, it was confirmed that latent heat binder was not affected adversely the basic property and durability of concrete, and was advanced on the reduction of hydration heat and control of thermal crack. It is expected to be applied as the excellent technology on the management of hydration heat and thermal crack in large size mass concrete structures.

• Korean Journal of Soil Science and Fertilizer
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• v.40 no.4
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• pp.255-261
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• 2007

Soil aggregates, resulting from physico-chemical and biological interactions, are important to understand carbon dynamics and material transport in soils. The objective of this study is to investigate stable macro-aggregate (> 0.25mm diameter) in wet sieving (SM) and their relation to soil properties in 15 sites. The clay contents of soils were ranged from 1% to 33%, and their land uses included bare and cultivated lands of annual upland crops, orchard, and grass. Undisturbed 3 inch cores with five replicates were sampled at topsoil (i.e., 0- to 10-cm depth), for analyzing SM and physico-chemical properties, after in situ measurement of air permeability. SM of sandy soils, with clay content less than 2%, was observed as 0%. Except the sandy soils, SM of soils mainly depended on land uses, showing 27%~35% in soils with annual plants such as vegetable and corn, 51% in orchard, and 75% in grass. This sequence of SM is probably due to the different strength of soil disturbance like tillage with different land uses. SM had significant correlation with cation exchange capacity, organic matter content, sand, clay, silt, bulk density, and exchangeable potassium (K) and magnesium (Mg), whereas fluctuating properties with fertilization such as pH, EC, and water soluble phosphorus weren't significantly correlated to the SM. Particularly, exchangeable calcium (Ca) had significant relation with SM, only except soils with oversaturating Ca. This study, therefore, suggested that SM could perceive different land uses and the change of soil properties in soils, necessarily considering soil textures and Ca over-saturation.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.2
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• pp.161-167
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• 2011

Proton conductors have attracted considerable attention for solid oxide fuel cell (SOFC), hydrogen pump, gas sensor, and membrane separators. Doped $SrCeO_3$ exhibits appreciable proton conductivity in hydrogen-containing atmosphere at high temperature. However commercial realization has been hampered due to the reactivity of $SrCeO_3$ with $CO_2$. The chemical stability and proton conductivity are dependent on dopant type. The purpose of this work is to investigate chemical stability of $SrCe_{0.95}Gd_{0.05}O_{3-\alpha}-Ce_{0.9}Gd_{0.1}O_{2-\beta}$ composites in $CO_2$ and $H_2$ gases. Thermogravimetric analysis (TGA) was performed in gaseous $CO_2$ and electrical conductivity of the composites were also measured between 500 and $900^{\circ}C$ in air and $H_2$ atmosphere. $SrCe_{0.95}Gd_{0.05}O_{3-\alpha}-Ce_{0.9}Gd_{0.1}O_{2-\beta}$ composite membranes showed good chemical stability of in $CO_2$ atmosphere and high conductivity at hydrogen condition. The hydrogen permeation of $SrCe_{0.95}Gd_{0.05}O_{3-\alpha}-Ce_{0.9}Gd_{0.1}O_{2-\beta}$ composite membranes was investigated as a function of volumetric content of $SrCe_{0.95}Gd_{0.05}O_{3-\alpha}$. The $SrCe_{0.95}Gd_{0.05}O_{3-\alpha}-Ce_{0.9}Gd_{0.1}O_{2-\beta}$(6:4) membrane with a thickness of 1.0 mm showed the highest hydrogen permeability with the flux reaching of 0.12 $ml/min{\cdot}cm^2$ at $800^{\circ}C$ in 100%$H_2/N_2$ as feed gas.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.7 no.3
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• pp.229-240
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• 1987

Carbonation of concrete is one type of a chemical process. The reaction mechanism is very complex for the case when low-calcium fly ash and blast furnace slag is added. When fly ash and blast furnace slag is used as an admixture in concrete, they improve compressive strength in the long term, permeability and chemical resistance of concrete by a pozzolanic reaction and latent hydraulic property. On the other hand, the pozzolanic reaction of fly ash and latent hydraulic property of the blast furance slag leads to a reduction of the alkalinity of the concrete. It has been pointed out that this will accelerate the carbonation of the concrete and the corrosion of reinforcement steel embedded in the concrete. In order to clarify the effect of fly ash and blast furance slag on the carbonation of concrete, an accelerated carbonation testing of concrete was carried out by varying the conditions of concrete and the initial curing period in water. The test results of accelerated carbonation were compared to the carbonation test results of concrete stored for 15 years in open air, but protected from rain. As a result, the equation for the rate of carbonation based on compressive strength of concrete was proposed.

• Asian Journal of Turfgrass Science
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• v.20 no.1
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• pp.83-91
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• 2006

This research was initiated to enhance the tilth of fine-textured soil for turf growth by incorporation of crumb rubber shredded from used tires. A specific objective was to determine the physical properties of soil mixes amended with different grade and amount of crumb rubber in soils. Two soils and three different grades(3.5, 6.5 and 9.5 mm) of crumb rubber were used. The soils selected were an Arenzville silt loam(coarse-silty, mixed, nonacid, mesic Typic Udifluvents) and a Hosmer silty clay loam(fine-silty, mixed, mesic Typic Fragiudalfs). The amount of crumb rubber mixed in soil ranged from 0 to 0.4 $g{\cdot}g^{-1}$(using 0.05 $g{\cdot}g^{-1}$) increments and 0 as a control. For each treatment, soil cores were constructed following the recommendation by the United States Golf Association Green Section Record. Results indicated that porosity of the mixes decreased as the amount of crumb rubber increased. Regardless of the grade of crumb rubber, mixes with less than 0.15 $g{\cdot}g^{-1}$ of crumb rubber in fine-textured soil could not enhance their macro-porosity and hydraulic conductivity. However, as the amendment increased over 0.15 $g{\cdot}g^{-1}$, the tilth of the mixes had improved significantly macro-porosity, hydraulic conductivity and air permeability, as compared with a control.

• Journal of Adhesion and Interface
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• v.21 no.3
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• pp.81-85
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• 2020

Shaving dust is a collagen fiber that is the leather waste occurred for thickness adjustment during the natural leather manufacturing process, and causes problems such as an environmental contamination because of a chromium (Cr) contained when it comes to reclaiming process. Various studies applying the shaving dust are currently being conducted in many countries across the world with an initiative by the EU. Of those applications, the bonded leather is being highlighted as a substitute for natural leather. Since the bonded leather, however, uses latex as a binder, accordingly it entails a high weight and a poor ventilation, which are deemed as disadvantages due to its dense internal tissues compared to other synthetic leathers. To address such disadvantages, this study employed the thermally expandable micro sphere to improve its air permeability and light weight by alleviating the internal structure. This is a study on the manufacturing of light bonded leather using the shaving dusts. In the study, the shaving dusts were forced to foam under 100~120℃ considering the heat resistance of collagen fiber after applying the thermally expandable micro sphere, and then the tendency was analyzed. In the analysis results, the most excellent foaming rate was exhibited when the shaving dusts were treated under 120℃ for 8 minutes and the variation of internal structure according to a foaming was observed through SEM analysis for the cross-section of the bonded leather.

• Journal of the Korean Wood Science and Technology
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• v.43 no.6
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• pp.730-739
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• 2015

Various cellulose nanofibers (CNF) with different morphology and chemical properties were prepared for the reinforcement of sheet of paper mulberry bast fiber. Lignocellulose nanofiber (LCNF), Holocellulose nanofiber (HCNF), alkali-treated HCNF (AT-HCNF), TEMPO-oxidated nanofiber (TEMPO-NF) and cellulose nanocrystal (CNF) were prepared and their addition effect on the properties of sheet of paper mulberry bast fiber were investigated. Air permeability, surface smoothness, and tensile properties were improved by increasing CNF addition. Its improvement may be due to the CNF deposited between and on paper mulberry bast fibers, which was confirmed by SEM observation.

• Magazine of the Korean Society of Agricultural Engineers
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• v.37 no.3_4
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• pp.61-71
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• 1995

Natural ground is a composite consisted of the three phases of water, air and soil paircies. Among the three components, water as a material is weU understood but soil particles are not in foundation engineering. Especially, weathered granite soil generally shows a large volumetric expansion when they freeze. And, the stability and durability of the soil have shown decreased with repetitive freezing and thawing processes. These unique charcteristics may cause various construction and management problems if the soil is used as a construction material and foundation layers. This project was initiated to investigate the soil's physical and engineering characteristics resulting from freezing and freezing-thawing processes. Research results may be used as a basic data in solving various problems related to the soil's unique characteristics. The following conclusions were obtained: The degree of decomposition of weathered granite soil in Kangwon-do was very different between the West and East sides of the divide of the Dae-Kwan Ryung. Soil particles distributed wide from very coarse to fine particles. Consistency could be predicted with a function of P200 as LL=0.8 P200+20. Permeability ranged from 10-2 to 10-4cm/sec, moisture content from 15 to 20% and maximum dry density from 1.55 to 1.73 g /cmΥ$^3$ By compaction, soil particles easily crushed, D50 of soil particles decreased and specific surface significantly increased. Shear characteristics varied wide depending on the disturbance of soil. Strain characteristics influenced the soil's dynamic behviour. Elastic failure mode was observed if strain was less than 1O-4/s and plastic failure mode was observed if strain was more than 10-2/s. The elastic wave velocity in the soil rapidly increased if dry density became larger than 1.5 g /cm$^3$ and these values were Vp=250, Vg= 150, respectively. Frost heave ratio was the highest around 0 $^{\circ}C$ and the maximum frost heave pressure was observed when deformation ratio was less than 10% which was the stability state of soil freezing. The state had no relation with frost depth. Over freezing process was observed when drainage or suction freezing process was undergone. Drainage freezing process was observed if freezing velocity was high under confined pressure and suction frost process was occurred if the velocity was low under the same confined process.

• Journal of the Korea institute for structural maintenance and inspection
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• v.20 no.1
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• pp.56-63
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• 2016

This experiment was compared and analyzed between the original surface paint through chloride penetration, neutralization, freeze-thaw and chemical corrosion resistance measuring internal structure and volume of voids in order to evaluate the effect of increase in durability of the newly modeled nano synthesized polymer paint painted on concrete surface which results improvement on air permeability to increase the durability of concrete structures. The test result of measuring volume of void and inner structure, concrete, spreaded with nano synthesized polymer paint, showed decreasing trend of pore volume in the range of less than $0.1{\mu}m$ and more than $0.3{\mu}m$. Also, using an electron microscope inside showed tightness of hydration texture. Chloride penetration depth of concrete, painted with nano synthesized polymer paint, was decreased more than 92% compared to non-painted concrete and 70% with water-based epoxy painted concrete. Especially, chemical corrosion resistance test set with aqueous solution of 5% sulfuric acid, non-painted concrete and water-based epoxy painted concrete showed weight loss of 4% after dipping for 12 days. On the other hand, concrete painted with nano synthesized polymer paint showed 1.7% weight loss under the same condition. Also, it showed great result of appearance under the criteria of Tsivilis et al.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.817-820
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• 2008

The river environments of many streams in korea have been deteriorate through the rapid industrialization and urbanization since the 1960s. In korea, on the other hand, much efforts on the research and project have been made for the restoration of the deteriorated streams to close-to-nature. in order to restore the deteriorated streams, therefore, it is necessary to investigate such advanced technologies and materials. In view of this requirement, various research paths are being taken focusing on coarse aggregates to make multi-functional porous concrete having continuous voids so as to improve water and air permeability, acoustic absorption, water purification and applicability to vegetation. The Purpose of this study is to investigate the method for recovery of the environment in the streams area using porous concrete retaining wall block. the multi-P.O.C block applies for test in the Jangduri-cheon have been monitored planting, stability etc. after 6 months, plant grows flourishing and reconstructed in state such as nature rivers.