• 대한화학회지
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• 제37권6호
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• pp.549-554
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• 1993

티타늄 금속판을 공기산화와 수증기 산화하여 만든 Ti$O_{2-x}$ 박막을 시료로 사용하여 1M NaOH 용액에서 광전기화학적 성질을 연구하였다. 높은 온도에서 제조된 Ti$O_{2-x}$ 전극들은 낮은 온도에서 제조된 전극들보다 더 음의 값으로 주어지는 flat band potential($V_{fb}$)과 더 높은 donor density($N_D$)를 가졌다. 전극전위의 변화에 따른 광전류 측정과 Mott-Schottky plot로부터 얻은 $V_{fb}$는 -0.95 ∼ -1.1 V 사이에서 비슷한 값으로 주어졌다. 자외부 영역의 광을 완전히 차단하는 TiO2 단결정을 필터로 하여 가시부 영역의 광전류를 측정할 때 분해능이 좋은 slit를 사용한 경우 좋은 sub band gap 광반응을 볼 수 있었다.

• Carbon letters
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• 제12권3호
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• pp.121-130
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• 2011

Public concern has recently increased over the potential risk of toxic elements emitted from anthropogenic sources. Among these, mercury has drawn special attention owing to its increasing level of bioaccumulation in the environment and in the food chain, with potential risks for human health. This paper presents an overview of research related to mercury control technology and identifies areas requiring additional research and development. It critically reviews measured mercury emissions progress in the development of promising control technologies, including catalytic oxidation, sorbent injection, photochemistry oxidation, and air pollution control devices.

• 한국환경과학회지
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• 제2권3호
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• pp.201-206
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• 1993

The concentration of Total Suspended Particulates(T.S.P), size distribution of suspended particulates, and soluble anions of T.S.P in atmosphere of industrial region in Busan were investigated. T.S.P was measured by High-Volume Air Sampler and particle size distribution was measured by Anderson Air Sampler. We analyzed the chemical component of the T.S.P by ion Chromatography and measure4 the shape and size of T.S.P by Scanning Electron Micrography The small size of T.S.P mainly exist in industrial region, but the large size of T.S.P mainly exist in residentail area.

• 한국연소학회지
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• 제4권1호
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• pp.131-139
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• 1999

A Numerical Analysis of NOx production in Hydrogen-Air flame is performed using the quasi-laminar reaction modelling. As results, in low global strain rate region, $U_F/D_F\;{\leq}\;50,000$, the quasi-laminar reaction modelling reproduces the experimentally observed EINOx half power scaling that the ratio of EINOx and flame residence time, $L_f^3(D_F^2U_F)$, is proportional to the square root of global strain rate. Thus, it suggests that turbulence-chemistry interaction has a minor impact on the trend of NOx production in low global strain rate region. However, the quasi-laminar reaction modelling predicts the higher temperature and NOx than experimentally observed. This overprediction may be due to the lack of radiation and quasi-laminar reaction modelling.

• Membrane and Water Treatment
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• 제6권2호
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• pp.95-102
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• 2015

The presented research is about characterization of Cellulose Triacetate (CTA) based Polymer Inclusion Membranes (PIMs) which incorporated the commercial extractant Aliquat 336, Tributylphosphate (TBP) as modifier and 2-Nitro Phenyl Pentyl Ether (NPPE) as plasticizer, for the preparation of the membranes. Chemical and physical characteristics of the synthesized membranes especially membrane thickness and side difference effects were investigated. Different surface structures and membrane thickness affect the extraction efficiency of membranes. Membrane extraction experiments were studied where the glass-facing surface of the membranes placed next to feed phase and the air-facing surface to stripping phase. The membrane was characterized by means of AFM, FT-IR and SEM.

• 한국연소학회:학술대회논문집
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• 한국연소학회 1999년도 제19회 KOSCO SYMPOSIUM 논문집
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• pp.71-79
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• 1999

Numerical analysis on the characteristics of nitrogen oxides (NOx) formation in turbulent nonpremixed hydrogen-air flames was carried out. Lagrange IEM model and Assumed PDF model were applied to consider turbulence-chemistry interaction known to affect the production of NOx. Partial equilibrium assumption was used to predict nonequilibrium effect to which one-half power dependence between EINOx normalized by flame residence time and global strain rate is attributed. As a result. such one-half power dependence could be reproduced only by reaction model including $HO_{2}$and $H_{2}O_{2}$, which means its dependence on Damkohler number; nonequilibrium effect. This dependence was shown better in the region of higher global strain. Besides, the improvement of turbulence model is required to predict mean flow properties quantitatively in the radial direction.

• 전자공학회논문지A
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• 제33A권12호
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• pp.47-52
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• 1996

Cl-based gas chemistry is generally used to etching for al alloy metallization. After the etching of Al alloy with Cl-based gas plasma, residual chlorine on Al alloy reacts with H$_{2}$O due to air exposure and results in Al corrosion. In this study, the corrosion phenomena of Al wer examined with XPS(X-ray photoelectron spectroscopy) and SEM (scanning electorn microscopy). It was confirmed that chlorine mainly existed at the grian boundary of Al alloy after plasma etching of Al alloy with cl-based gas chemistry and Al corrosion was largely generated at the grain boundary of Al alloy. And residual chlorine was passivated by sulfur and fluorine which were generated by SF$_{6}$ plasma. These effects of passivation reduced the Al corrosion due to air exposure.

• Carbon letters
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• 제16권3호
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• pp.219-221
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• 2015

In order to study the impact of atmosphere during electron beam irradiation (EBI) of polyacrylonitrile (PAN) precursor fibers, the latter were stabilized by EBI in both air and oxygen atmospheres. Gel-fraction determination indicated that EBI-stabilization under an oxygen atmosphere leads to an enhanced cyclization in the PAN fibers. In the Fourier-transform infrared spectroscopy analysis, the PAN fibers stabilized by EBI under an oxygen atmosphere exhibited a greater decrease in the peak intensity at 2244 cm⁻¹ (C≡N vibration) and a greater increase in the peak intensity at 1628 cm⁻¹ (C=N absorption) than the corresponding PAN fibers stabilized under an air atmosphere. From the X-ray diffraction analysis it was found that oxygen uptake in PAN fibers leads to an increase in the amorphous region, produced by cyclization.

• 공업화학
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• 제28권1호
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• pp.125-131
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• 2017

본 연구에서는 유기적으로 기능화된 은 나노 입자들은 공기와 물이 형성하는 계면에서 자발적 조립 과정을 통해 새로운 2차원 상부 구조들(superstructures)을 생성하는 것을 발견하였다. 상부 구조의 분석은 금속 나노 입자의 심형과 입자계면에 결합된 유기 분자의 크기를 바꿈으로써 입자 간 특징적 상호 작용(characteristic inter-particle interaction)을 조절할 수 있고 이들 사이의 미묘한 상호 작용(subtle interplay)을 통해 은 나노 입자의 2차원 조립이 발생함을 시사한다. 본 연구를 통해 발견한 새로운 구조들은 기능성 나노 소재, 촉매 및 소자 응용 분야에 매우 중요한 잠재적 용도가 있을 것이라 사료된다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1996년도 추계학술대회 논문집
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• pp.252-255
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• 1996

Cl-based gas chemistry is generally used to etching for Al alloy metallization. After the etching of Al alloy with Cl-based gas plasma, residual chlorine on Al alloy reacts with $H_2O$ due to air exposure and results in Al corrosion. In this study, the corrosion Phenomena of Al were examined with XPS(X-ray photoelectron spectroscopy) and SEF(Scanning electron microscopy). It was confirmed that chlorine mainly existed at the grain boundary of Al alloy after plasma etching of Al alloy with Cl-based gas chemistry and Al corrosion was largely generated at the grain boundary of Al a1loy. And residual chlorine was passivated by sulfur and fluorine which were generated by SF$_{6}$ plasma. These effects of passivation reduced the Al corrosion due to air exposure.e.