• Title/Summary/Keyword: Ag-$TiO_2$

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Dielectric and Pyroelectric Properties for 0.65PbMg1/3Ta2/3)O3-0.35PbTiO3 Solid Solution Modified with Ag2O (Ag2O가 첨가된 0.65PbMg1/3Ta2/3)O3-0.35PbTiO3 고용체의 유전, 초전 특성)

  • Kim, G.B.
    • Journal of the Korean Vacuum Society
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    • v.17 no.5
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    • pp.442-447
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    • 2008
  • Ferroelectric samples of the 0.65Pb$(Mg_{1/3}Ta_{2/3})O_3-0.35PbTiO_3$ modified with $Ag_2O$ were prepared by sintering at $1200^{\circ}C$ for 4 h. The fractured surface of sintered pellets were examined by scanning electron microscopy(SEM). The dielectric constant, loss, and pyroelectric coefficient of the ceramics samples were determined. The dielectric and pyroelectric properties could be improved with the addition of small amount of $Ag_2O$ up to 0.2 mol%. The dielectric and pyroelectirc peak temperatures are continuously shifted to lower temperature with addition of small amounts of $Ag_2O$.

Hydrogen Production from Photocatalytic Splitting of Water/Methanol Solution over a Mixture of P25-TiO2 and AgxO (산화은/이산화티타늄 혼합물을 광촉매로 활용한 물/메탄올 분해 수소제조)

  • Kim, Kang Min;Jeong, Kyung Mi;Park, No-Kuk;Lee, Tae Jin;Kang, Misook
    • Clean Technology
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    • v.21 no.4
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    • pp.271-277
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    • 2015
  • A photocatalyst which mixed by the commercialized P25-TiO2 and a synthesized AgxO was used in an appropriate weight ratio to effectively produce hydrogen gas in this study. The AgxOs were synthesized with the conventional sol-gel method, and tetramethylammonium hydroxides were added at the synthesis process in order to stabilize the solutions, and then the solutions were heat-treated at the temperatures of -5, 25, and 50 ℃, resulted to obtain the three types of silver oxides. Physicochemical properties of the synthesized AgxOs were identified through X-ray diffraction analysis (XRD), scanning emission microscopy (SEM), ultraviolet-visible spectroscopy, and X-ray photoelectron spectroscopy (XPS). In the photolysis results of water/methanol (weight ratio 1:1) solution, the mixture of P25-TiO2/AgxO exhibited a significantly higher hydrogen gases evolution, compared to that of pure P25-TiO2. Additionally, the addition of H2O2 as an supplement oxidant and in AgxO synthesized at 50 ℃ improved the hydrogen production efficiency. In particular, the emitted hydrogen gases reached to 13,000 μmol during 8 hours when a mixed catalyst, AgxO of 0.1 g and P25-TiO2 of 0.9 g, were used.

Optical and Structural Properties of Multi-period Low-emissivity Filters by RE Magnetron Sputtering

  • Lee, J.-H.;Lee, S.-H.;Yoo, K.-L.;Lee, K.-S.;Hwangbo, C.K.
    • Journal of Korean Vacuum Science & Technology
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    • v.6 no.2
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    • pp.67-70
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    • 2002
  • Multi-period low-emissivity (low-e) filters based on [TiO$_2$|Ti|Ag|TiO$_2$] layer structure were designed and fabricated by a RF magnetron sputtering method. Optical, structural, chemical, and electrical properties were investigated with various analytical tools. Interface layers consisting of Ag, Ti, and O were observed next to Ag layers by Rutherford backscattering spectrometry (RBS) analysis. The results show that Ti layers of ~ 1.8 nm protect the Ag layers from oxidation better than those of ~ 1 nm and the optical spectra of the filter with thicker Ti layers are in agreement with the simulated one. The average transmittance of a low-e filter with thicker Ti layers is reduced and the sheet resistance is slightly increased due to the increased Ti thickness.

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The design of the optical film for absorbent ARAS coating (흡수층을 이용한 무반사, 무정전용 광학박막의 설계)

  • Park, M.C.;Son, Y.B.;Jung, B.Y.;Lee, I.S.;Hwangbo, C.K.
    • Journal of Korean Ophthalmic Optics Society
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    • v.5 no.1
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    • pp.7-11
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    • 2000
  • The anti-reflective anti-static (ARAS) optical film is designed using absorbent materials such as ITO, $TiN_xW_y$, Ag by Essential Macleod program. [air ${\mid}TiN_xW_y{\mid}SiO_2{\mid}$ glass] two layer shows wide-band AR coating in the wavelength range of 450~700 nm. The reflectivity, transmittance of this coating are below 0.5%, about 75%, respectively. [air $SiO_2{\mid}TiO_2{\mid}SiO_2{\mid}$, ITO glass] layer can adjust reflectance of below 0.5% with above 97% transmittance. In the [air ${\mid}SiO_2{\mid}TiO_2{\mid}SiO_2{\mid}$ Ag glass] layer, the transmission can be controlled at above 96% with reflectance of 1~2%.

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Effects of Surface Characteristics of TiO2 Nanotublar Composite on Photocatalytic Activity (TiO2 복합 광촉매의 표면 특성과 광촉매 효율)

  • Lee, Jong-Ho;Youn, Jeong-Il;Kim, Young-Jig;Oh, Han-Jun
    • Korean Journal of Materials Research
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    • v.24 no.10
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    • pp.556-564
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    • 2014
  • To synthesize a high-performance photocatalyst, N doped $TiO_2$ nanotubes deposited with Ag nanoparticles were synthesized, and surface characteristics, electrochemical behaviors, and photocatalytic activity were investigated. The $TiO_2$ nanotubular photocatalyst was fabricated by anodization; the Ag nanoparticles on the $TiO_2$ nanotubes were synthesized by a reduction reaction in $AgNO_3$ solution under UV irradiation. The XPS results of the N doped $TiO_2$ nanotubes showed that the incorporated nitrogen ions were located in interstitial sites of the $TiO_2$ crystal structure. The N doped titania nanotubes exhibited a high dye degradation rate, which is effectively attributable to the increase of visible light absorption due to interstitial nitrogen ions in the crystalline $TiO_2$ structure. Moreover, the precipitated Ag particles on the titania nanotubes led to a decrease in the rate of electron-hole recombination; the photocurrent of this electrode was higher than that of the pure titania electrode. From electrochemical and dye degradation results, the photocurrent and photocatalytic efficiency were found to have been significantly affected by N doping and the deposition of Ag particles.

Antibacterial Properties of PU/$TiO_2$ Hybrid membrane Films after Photodepositing of Silver (은(Ag) 광증착에 의한 폴리우레탄/$TiO_2$ 하이브리드 멤브레인 필름의 항균특성)

  • Cho, Seong-Min;Min, Byung-Gil;Ji, Kwang-Hwan
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2012.03a
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    • pp.50-50
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    • 2012
  • 투습방수필름으로 많이 사용되고 있는 폴리우레탄(PU)에 광촉매 기능성을 가지고 있는 나노-$TiO_2$(Degussa P25)를 1~10wt% 복합시킨 후, 은(Ag)이온 수용액에서 자외선 조사에 의한 광증착시키는 과정을 거쳐 은이 도핑된 PU/$TiO_2$/Ag 하이브리드 멤브레인 필름을 제조하였다. (주)비에스지에서 제공받은 PU/DMF/MEK 용액에 $TiO_2$를 초음파로 균일하게 분산배합한 후, 필름캐스팅하여 만든 필름을 AgNO3 수용액에 침지시키고 254nm의 자외선을 30~120초 동안 조사하는 광증착법으로 은을 환원시켜 도핑시켰다. 은 도핑된 하이브리드 필름을 Shaking flask method에서 폐렴간균, 황색포도상구균에 대한 항균성을 측정하고, Clear zone method에서 대장균에 대한 항균성을 측정한 결과, $TiO_2$ 함량이 3wt% 이상이고 UV조사시간이 60초 이상인 경우 99.9% 이상의 항균성을 나타내는 것을 확인하였다.

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