• Title/Summary/Keyword: Aerosols

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Chemical and Absorption Characteristics of Water-soluble Organic Carbon and Humic-like Substances in Size-segregated Particles from Biomass Burning Emissions

  • Yu, Jaemyeong;Yu, Geun-Hye;Park, Seungshik;Bae, Min-Suk
    • Asian Journal of Atmospheric Environment
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    • v.11 no.2
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    • pp.96-106
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    • 2017
  • In this study, measurements of size-segregated particulate matter (PM) emitted from the combustion of rice straw, pine needles, and sesame stem were conducted in a laboratory chamber. The collected samples were used to analyze amounts of organic and elemental carbon (OC and EC), water-soluble organic carbon (WSOC), humic-like substances (HULIS), and ionic species. The light absorption properties of size-resolved water extracts were measured using ultraviolet-visible spectroscopy. A solid-phase extraction method was first used to separate the size-resolved HULIS fraction, which was then quantified by a total organic carbon analyzer. The results show that regardless of particle cut sizes, the contributions of size-resolved HULIS ($=1.94{\times}HULIS-C$) to PM size fractions ($PM_{0.32}$, $PM_{0.55}$, $PM_{1.0}$, and $PM_{1.8}$) were similar, accounting for 25.2-27.6, 15.2-22.4 and 28.2-28.7% for rice straw, pine needle, and sesame stem smoke samples, respectively. The $PM_{1.8}$ fraction revealed WSOC/OC and HULIS-C/WSOC ratios of 0.51 and 0.60, 0.44 and 0.40, and 0.50 and 0.60 for the rice straw, pine needle, and sesame stem burning emissions, respectively. Strong absorption with decreasing wavelength was found by the water extracts from size-resolved biomass burning aerosols. The absorption ${\AA}ngstr{\ddot{o}}m $ exponent values of the size-resolved water extracts fitted between 300 and 400 nm wavelengths for particle sizes of $0.32-1.0{\mu}m$ were 6.6-7.7 for the rice straw burning samples, and 7.5-8.0 for the sesame stem burning samples. The average mass absorption efficiencies of size-resolved WSOC and HULIS-C at 365 nm were 1.09 (range: 0.89-1.61) and 1.82 (range: 1.33-2.06) $m^2/g{\cdot}C$ for rice straw smoke aerosols, and 1.13 (range: 0.85-1.52) and 1.83 (range: 1.44-2.05) $m^2/g{\cdot}C$ for sesame stem smoke aerosols, respectively. The light absorption of size-resolved water extracts measured at 365 nm showed strong correlations with WSOC and HULIS-C concentrations ($R^2=0.89-0.93$), indicating significant contribution of HULIS component from biomass burning emissions to the light absorption of ambient aerosols.

Size Distributions of Trace Elements in Airborn Particulates Collected using Drum impactor at Gosan, Jeju Island : Measurements in Springtime 2002 (DRUM impactor를 이용한 대기 입자상 물질 중 원소성분의 입경분포 특성 : 제주도 고산지역의 2002년 봄철 (3.29-5.30) 측정 연구)

  • 한진석;문광주;류성윤;안준영;공부주;홍유덕;김영준
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.4
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    • pp.555-569
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    • 2004
  • Size -segregated measurements of aerosol composition using 8-stage DRUM impactor are used to determine the transport of natural and anthropogenic aerosols at Gosan site from 29 March to 30 May in 2002. Separation of ambient aerosols by DRUM impactor offers many Advantages over other standard filtration techniques. Some of the most important advantages are the ability to segregate into details by particle tire, to better preserve chemical integrity since the air stream doesn't pars through the deposit, to collect samples as a function of time, and to have a wide variety of impaction surfaces available to match analytical needs. Although the transport of Yellow sand is a well-known phenomenon in springtime, the result of measurement shows that not only soil dust but also anthropogenic aerosols, including sulfur, enriched trace metals such as Pb, Ni, Zn. Cu, Cr, As, Se, Br, are transported to Gosan in springtime. This study combines the size- and time-resolved aerosol composition measurements with isentropic, backward air-mass trajectories in order to identify some potential source regions of anthropogenic aerosols. As a result, during the NYS period, the average concentration of PM$_{10}$ was 46$\mu\textrm{g}$/㎥, Si, Al. S, Fe, Cl, K, Ca were higher than 1,000 ng/㎥ and Ti was about 100 ng/㎥. The concentrations of Zn, Mn, Cu. Pb, Br, Rb, V, Cr, Ni. At, Se ranged between 1 and 70 ng/㎥. More than 50% typical soil elements, tuck as Al, Si, Fe, Cd. Ti, Cr, Cu, Br. were distributed in a coarse particle range(5.0-12${\mu}{\textrm}{m}$). In other hand, anthropogenic pollutants, luck as S, N, Vi, were mainly distributed in a fine particle range (0.09-0.56${\mu}{\textrm}{m}$). During the YS period, PM$_{10}$ increased about 8 times than NYS period, and main soil elements, such as Al, Si, S, K, V, Mn, Fe also doubled in coarse particle range (1.15-12${\mu}{\textrm}{m}$). But Zn, As, Pb, Cu and Se, which distributed in the time aerosols (0.09-0.56${\mu}{\textrm}{m}$), were on the same level with or decreased than NYS period. Finally. except the YS Period, coarse particles (2.5-12${\mu}{\textrm}{m}$) are inferred to be influenced by soil, coal combustion, waste incineration, ferrous and nonferrous sources through similar pathways with Yellow Sand. But fine particles have different sources, such as coal combustion, gasoline vehicle, biomass burning, oil or coal combustion, nonferrous and ferrous metal sources, which are transported from China, Korea peninsula and local sources.ces.

Acidification and neutralization characteristics of size-fractionated atmospheric aerosols at Gosan site of Jeju Isalnd (제주도 고산지역 대기 에어로졸의 입경별 산성화-중화 특성)

  • Kim, Won-Hyung;Song, Jung-Min;Kim, Hyeon-A;Kang, Chang-Hee;Kim, In-Whan
    • Analytical Science and Technology
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    • v.28 no.1
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    • pp.47-57
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    • 2015
  • The size fractionated atmospheric aerosols have been collected at Gosan site of Jeju Island during 2010~2011, and then their characteristics of acidification and neutralization have been investigated. The anthropogenic $NH_4{^+}$ and nss-$SO_4{^{2-}}$ showed high concentrations mostly at ultra-fine particle mode of $0.7{\sim}1.1{\mu}m$, but they also had a bimodal distribution showing high concentrations at coarse particle mode of $4.7{\sim}5.8{\mu}m$ during Asian Dust periods. The concentrations of nss-$Ca^{2+}$ and $NO_3{^-}$ were relatively high at coarse particle mode of $3.3{\sim}4.7{\mu}m$, especially $NO_3{^-}$ showed high concentrations with a bimodal pattern at both fine and coarse particle modes. The acidification of atmospheric aerosols at Gosan area was contributed mostly by inorganic sulfuric and nitric acids, while the contribution by organic formic and acetic acids was only 1.6~6.4%. Furthermore, the neutralization of acidic species among atmospheric aerosols was performed mostly by $NH_3$, $CaCO_3$ and $MgCO_3$, especially the neutralization by $NH_3$ was high in fine particle mode, while that by $CaCO_3$ was relatively high in coarse particle mode.

Exploiting GOCI-II UV Channel to Observe Absorbing Aerosols (GOCI-II 자외선 채널을 활용한 흡수성 에어로졸 관측)

  • Lee, Seoyoung;Kim, Jhoon;Ahn, Jae-Hyun;Lim, Hyunkwang;Cho, Yeseul
    • Korean Journal of Remote Sensing
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    • v.37 no.6_1
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    • pp.1697-1707
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    • 2021
  • On 19 February 2020, the 2nd Geostationary Ocean Color Imager (GOCI-II), a maritime sensor of GEO-KOMPSAT-2B, was launched. The GOCI-II instrument expands the scope of aerosol retrieval research with its improved performance compared to the former instrument (GOCI). In particular, the newly included UV band at 380 nm plays a significant role in improving the sensitivity of GOCI-II observations to the absorbing aerosols. In this study, we calculated the aerosol index and detected absorbing aerosols from January to June 2021 using GOCI-II 380 and 412 nm channels. Compared to the TROPOMI aerosol index, the GOCI-II aerosol index showed a positive bias, but the dust pixels still could be clearly distinguished from the cloud and clear pixels. The high GOCI-II aerosol index coincided with ground-based observations indicating dust aerosols were detected. We found that 70.5% of dust and 80% of moderately-absorbing fine aerosols detected from the ground had GOCI-II aerosol indices larger than the 75th percentile through the whole study period.

Estimation of the major sources for organic aerosols at the Anmyeon Island GAW station (안면도에서의 초미세먼지 유기성분 주요 영향원 평가)

  • Han, Sanghee;Lee, Ji Yi;Lee, Jongsik;Heo, Jongbae;Jung, Chang Hoon;Kim, Eun-Sill;Kim, Yong Pyo
    • Particle and aerosol research
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    • v.14 no.4
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    • pp.135-144
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    • 2018
  • Based on a two-year measurement data, major sources for the ambient carbonaceous aerosols at the Anmyeon Global Atmosphere Watch (GAW) station were identified by using the Positive Matrix Factorization (PMF) model. The particulate matter less than or equal to $2.5{\mu}m$ in aerodynamic diameter (PM2.5) aerosols were sampled between June 2015 to May 2017 and carbonaceous species including ~80 organic compounds were analyzed. When the number of factors was 5 or 6, the performance evaluation parameters showed the best results, With 6 factor case, the characteristics of transported factors were clearer. The 6 factors were identified with various analyses including chemical characteristics and air parcel movement analysis. The 6 factors with their relative contributions were (1) anthropogenic Secondary Organic Aerosols (SOA) (10.3%), (2) biogenic sources (24.8%), (3) local biomass burning (26.4%), (4) transported biomass burning (7.3%), (5) combustion related sources (12.0%), and (6) transported sources (19.2%). The air parcel movement analysis result and seasonal variation of the contribution of these factors also supported the identification of these factors. Thus, the Anmyeon Island GAW station has been affected by both regional and local sources for the carbonaceous aerosols.