• Title/Summary/Keyword: Aerosol surface area

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The Study on the Quantitative Dust Index Using Geostationary Satellite (정지기상위성 자료를 이용한 정량적 황사지수 개발 연구)

  • Kim, Mee-Ja;Kim, Yoonjae;Sohn, Eun-Ha;Kim, Kum-Lan;Ahn, Myung-Hwan
    • Atmosphere
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    • v.18 no.4
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    • pp.267-277
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    • 2008
  • The occurrence and strength of the Asian Dust over the Korea Peninsular have been increased by the expansion of the desert area. For the continuous monitoring of the Asian Dust event, the geostationary satellites provide useful information by detecting the outbreak of the event as well as the long-range transportation of dust. The Infrared Optical Depth Index (IODI) derived from the MTSAT-1R data, indicating a quantitative index of the dust intensity, has been produced in real-time at Korea Meteorological Administration (KMA) since spring of 2007 for the forecast of Asian dust. The data processing algorithm for IODI consists of mainly two steps. The first step is to detect dust area by using brightness temperature difference between two thermal window channels which are influenced with different extinction coefficients by dust. Here we use dynamic threshold values based on the change of surface temperature. In the second step, the IODI is calculated using the ratio between current IR1 brightness temperature and the maximum brightness temperature of the last 10 days which we assume the clear sky. Validation with AOD retrieved from MODIS shows a good agreement over the ocean. Comparison of IODI with the ground based PM10 observation network in Korea shows distinct characteristics depending on the altitude of dust layer estimated from the Lidar data. In the case that the altitude of dust layer is relatively high, the intensity of IODI is larger than that of PM10. On the other hand, when the altitude of dust layer is lower, IODI seems to be relatively small comparing with PM10 measurement.

Effect of Film Thickness on the Photocatalytic Performance of TiO2 Film Fabricated by Room Temperature Powder Spray in Vacuum Process (상온 진공 분말 분사공정에 의해 제조된 TiO2 광촉매 막의 두께변화에 따른 광촉매 특성)

  • Kim, Kun-Young;Ryu, Jung-Ho;Hahn, Byung-Dong;Choi, Jong-Jin;Yoon, Woon-Ha;Lee, Byoung-Kuk;Park, Dong-Soo;Park, Chan
    • Journal of the Korean Ceramic Society
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    • v.45 no.12
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    • pp.839-844
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    • 2008
  • $TiO_2$ is an environment-friendly semiconducting material, and it has photocatalytic and hydrophilic effect. There are a lot of reports on the photocatalytic characteristics of $TiO_2$, such as organic pollutants resolving, anti-bacterial, and self-purification material. In this paper, $TiO_2$ micron-sized powders were deposited on the glass by room temperature powder spray in vacuum process, so called aerosol deposition (AD), and nano-grained $TiO_2$ photocatalytic thin films were fabricated. The thickness of the films were controlled by changing the number of deposition cycle. Morphologies and characteristics of the AD-$TiO_2$ thin films were examined by SEM, TEM, XRD, and UV-Visible Spectrophotometer. As the thickness of $TiO_2$ films increased, surface roughness increased. By this increment, the reaction area between film and pollutant was enlarged, resulting in better photocatalytic property.

Surface Ozone Episode Due to Stratosphere-Troposphere Exchange and Free Troposphere-Boundary Layer Exchange in Busan During Asian Dust Events

  • Moon, Y.S.;Kim, Y.K.;K. Strong;Kim, S.H.;Lim, Y.K.;Oh, I.B.;Song, S.K.
    • Journal of Environmental Science International
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    • v.11 no.5
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    • pp.419-436
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    • 2002
  • The current paper reports on the enhancement of O$_3$, CO, NO$_2$, and aerosols during the Asian dust event that occurred over Korea on 1 May 1999. To confirm the origin and net flux of the O$_3$, CO, NO$_2$, and aerosols, the meteorological parameters of the weather conditions were investigated using Mesoscale Meteorological Model 5(MM5) and the TOMS total ozone and aerosol index, the back trajectory was identified using the Hybrid Single-Particle Lagrangian Integrated Trajectory Model(HYSPLIT), and the ozone and ozone precursor concentrations were determined using the Urban Ashed Model(UAM). In the presence of sufficiently large concentrations of NO$\sub$x/, the oxidation of CO led to O$_3$ formation with OH, HO$_2$, NO, and NO$_2$ acting as catalysts. The sudden enhancement of O$_3$, CO, NO$_2$ and aerosols was also found to be associated with a deepening cut-off low connected with a surface cyclone and surface anticyclone located to the south of Korea during the Asian dust event. The wave pattern of the upper trough/cut-off low and total ozone level remained stationary when they came into contact with a surface cyclone during the Asian dust event. A typical example of a stratosphere-troposphere exchange(STE) of ozone was demonstrated by tropopause folding due to the jet stream. As such, the secondary maxima of ozone above 80 ppbv that occurred at night in Busan, Korea on 1 May 2001 were considered to result from vertical mixing and advection from a free troposphere-boundary layer exchange in connection with an STE in the upper troposphere. Whereas the sudden enhancement of ozone above 100 ppbv during the day was explained by the catalytic reaction of ozone precursors and transport of ozone from a slow-moving anticyclone area that included a high level of ozone and its precursors coming from China to the south of Korea. The aerosols identified in the free troposphere over Busan, Korea on 1 May 1999 originated from the Taklamakan and Gobi deserts across the Yellow River. In particular, the 1000m profile indicated that the source of the air parcels was from an anticyclone located to the south of Korea. The net flux due to the first invasion of ozone between 0000 LST and 0600 LST on 1 May 1999 agreed with the observed ground-based background concentration of ozone. From 0600 LST to 1200 LST, the net flux of the second invasion of ozone was twice as much as the day before. In this case, a change in the horizontal wind direction may have been responsible for the ozone increase.

Breakthrough behaviour of NBC canister against carbon tetrachloride: a simulant for chemical warfare agents

  • Srivastava, Avanish Kumar;Shah, D.;Mahato, T.H.;Singh, Beer;Saxena, A.;Verma, A.K.;Shrivastava, S.;Roy, A.;Yadav, S.S.;Shrivastava, A.R.
    • Carbon letters
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    • v.13 no.2
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    • pp.109-114
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    • 2012
  • A nuclear, biological, chemical (NBC) canister was indigenously developed using active carbon impregnated with ammoniacal salts of copper (II), chromium (VI) and silver (I), and high efficiency particulate aerosol filter media. The NBC canister was evaluated against carbon tetra chloride ($CCl_4$) vapours, which were used as a simulant for persistent chemical warfare agents under dynamic conditions for testing breakthrough times of canisters of gas masks in the National Approval Test of Respirators. The effects of $CCl_4$ concentration, test flow rate, temperature, and relative humidity (RH) on the breakthrough time of the NBC canister against $CCl_4$ vapour were also studied. The impregnated carbon that filled the NBC canister was characterized for surface area and pore volume by $N_2$ adsorption-desorption isotherm at liquid nitrogen temperature. The study clearly indicated that the NBC canister provides adequate protection against $CCl_4$ vapours. The breakthrough time decreased with the increase of the $CCl_4$ concentration and flow rate. The variation in temperature and RH did not significantly affect the breakthrough behaviour of the NBC canister at high vapour concentration of $CCl_4$, whereas the breakthrough time of the NBC canister was reduced by an increase of RH at low $CCl_4$ vapour concentration.

Characteristics of Sea Surface Temperature Variation during the High Impact Weather over the Korean Peninsula (한반도에서 위험기상 발생 시 나타나는 해수면온도 변동의 특성)

  • Jung, Eunsil
    • Journal of the Korean earth science society
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    • v.40 no.3
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    • pp.240-258
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    • 2019
  • Typhoons, torrential rainfall, and heavy snowfall cause catastrophic losses each year in the Republic of Korea. Therefore, if we can know the possibility of this phenomenon in advance through regular observations, it will be greatly beneficial to Korean society. Korea is surrounded by sea on its three sides, and the sea surface temperature (SST) directly or indirectly affects the development of typhoons, heavy rainfall, and heavy snowfall. Therefore, the characteristics of SST variability related to the high impact weather are investigated in this paper. The heavy rainfall in Korea was distributed around Seoul, Gyeonggi, and west and southern coast. The heavy snowfall occurred mainly in the eastern coastal (hereafter Youngdong Heavy Snow) and the southwestern region (hereafter Honam-type heavy snow). The SST variability was slightly different depending on the type and major occurrence regions of the high impact weather. When the torrential rain occurred, the SST variability was significantly increased in the regions extending to Jindo-Jeju island-Ieodo-Shanghai in China. When the heavy snow occurred, the SST variability has reduced in the southern sea of Jeju island, regardless of the type of heavy snowfall, whereas the SST variability has increased in the East Sea near $130^{\circ}E$ and $39^{\circ}N$. Areas with high SST variability are anticipated to be used as a basis for studying the atmospheric-oceanic interaction mechanism as well as for determining the background atmospheric aerosol observation area.

An Estimation of Concentration of Asian Dust (PM10) Using WRF-SMOKE-CMAQ (MADRID) During Springtime in the Korean Peninsula (WRF-SMOKE-CMAQ(MADRID)을 이용한 한반도 봄철 황사(PM10)의 농도 추정)

  • Moon, Yun-Seob;Lim, Yun-Kyu;Lee, Kang-Yeol
    • Journal of the Korean earth science society
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    • v.32 no.3
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    • pp.276-293
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    • 2011
  • In this study a modeling system consisting of Weather Research and Forecasting (WRF), Sparse Matrix Operator Kernel Emissions (SMOKE), the Community Multiscale Air Quality (CMAQ) model, and the CMAQ-Model of Aerosol Dynamics, Reaction, Ionization, and Dissolution (MADRID) model has been applied to estimate enhancements of $PM_{10}$ during Asian dust events in Korea. In particular, 5 experimental formulas were applied to the WRF-SMOKE-CMAQ (MADRID) model to estimate Asian dust emissions from source locations for major Asian dust events in China and Mongolia: the US Environmental Protection Agency (EPA) model, the Goddard Global Ozone Chemistry Aerosol Radiation and Transport (GOCART) model, and the Dust Entrainment and Deposition (DEAD) model, as well as formulas by Park and In (2003), and Wang et al. (2000). According to the weather map, backward trajectory and satellite image analyses, Asian dust is generated by a strong downwind associated with the upper trough from a stagnation wave due to development of the upper jet stream, and transport of Asian dust to Korea shows up behind a surface front related to the cut-off low (known as comma type cloud) in satellite images. In the WRF-SMOKE-CMAQ modeling to estimate the PM10 concentration, Wang et al.'s experimental formula was depicted well in the temporal and spatial distribution of Asian dusts, and the GOCART model was low in mean bias errors and root mean square errors. Also, in the vertical profile analysis of Asian dusts using Wang et al's experimental formula, strong Asian dust with a concentration of more than $800\;{\mu}g/m^3$ for the period of March 31 to April 1, 2007 was transported under the boundary layer (about 1 km high), and weak Asian dust with a concentration of less than $400\;{\mu}g/m^3$ for the period of 16-17 March 2009 was transported above the boundary layer (about 1-3 km high). Furthermore, the difference between the CMAQ model and the CMAQ-MADRID model for the period of March 31 to April 1, 2007, in terms of PM10 concentration, was seen to be large in the East Asia area: the CMAQ-MADRID model showed the concentration to be about $25\;{\mu}g/m^3$ higher than the CMAQ model. In addition, the $PM_{10}$ concentration removed by the cloud liquid phase mechanism within the CMAQ-MADRID model was shown in the maximum $15\;{\mu}g/m^3$ in the Eastern Asia area.

Toxico-pathological Study p,p-DDE After Experimental Aerosol Exposed to ICR Mouse (환경호르몬인 p,p-DDE의 흡입 시 ICR 마우스의 폐에 미치는 독성병리학적 연구)

  • Choi Hae-Yun;Jung Tae-Young;Ku Sae-Kwang;Yang Hee-Bog;Lee Hyeung-Sik
    • Toxicological Research
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    • v.21 no.2
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    • pp.151-160
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    • 2005
  • In order to monitor the histological and general profiles of lung after direct expose of p,p-DDE, 1, 5 and 10 mg/ml of p,p-DDE were sprayed to male ICR mouse, and seven days after exposure, changes of body weight, lung weight, clinical signs, histological profiles of lung and total WBC in blood were investigated with changes of total cell number and their differential count in bronchoalveolar lavage fluid (BALF). In the present study, a significant and dosage-dependent decrease of body weight was detected in p,p-DDE exposed groups and body weight gains during observational periods (7 days) were also significantly and dosage-dependently decreased in p,p-DDE exposed groups compared to that of vehicle control group. In addition general depression signs were detected in all p,p-DDE exposed groups with dosage-dependent manners, and lung weights were also increased in p,p-DDE exposed groups. Congestion, hemorrhage and severe exudate were observed in the lung of p,p-DDE exposed groups with sarcomatous changes and these signs were also showed by dosage-dependent manners. In addition, foreign body pneumonia signs were observed in the lung of p,p-DDE exposed groups in histological levels. The percentage of ALSA (Area of luminal surface of alveoli) was also significantly and dosage-dependently decreased in p,p-DDE exposed groups and total blood WBC and BALF cell numbers were significantly and dosage-dependently increased in p,p­DDE exposed groups compared to that of vehicle control group and increase percentage of neutrophil, eosinophil, and lymphocyte in BALF were monitored in p,p-DDE exposed groups compared to that of vehicle control group. In conclusion, severe allergic response and/or foreign body pneumonitic changes were induced by direct exposure of p,p-DDE containing beverage. So it is considered that strong and powerful regulation was need to control production of residence of environmental pollutant especially to p,p-DDE.

The Character of Distribution of Solar Radiation in Mongolia based on Meteorological Satellite Data (위성자료를 이용한 몽골의 일사량 분포 특성)

  • Jee, Joon-Bum;Jeon, Sang-Hee;Choi, Young-Jean;Lee, Seung-Woo;Park, Young-San;Lee, Kyu-Tae
    • Journal of the Korean earth science society
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    • v.33 no.2
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    • pp.139-147
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    • 2012
  • Mongolia's solar-meteorological resources map has been developed using satellite data and reanalysis data. Solar radiation was calculated using solar radiation model, in which the input data were satellite data from SRTM, TERA, AQUA, AURA and MTSAT-1R satellites and the reanalysis data from NCEP/NCAR. The calculated results are validated by the DSWRF (Downward Short-Wave Radiation Flux) from NCEP/NCAR reanalysis. Mongolia is composed of mountainous region in the western area and desert or semi-arid region in middle and southern parts of the country. South-central area comprises inside the continent with a clear day and less rainfall, and irradiation is higher than other regions on the same latitude. The western mountain region is reached a lot of solar energy due to high elevation but the area is covered with snow (high albedo) throughout the year. The snow cover is a cause of false detection from the cloud detection algorithm of satellite data. Eventually clearness index and solar radiation are underestimated. And southern region has high total precipitable water and aerosol optical depth, but high solar radiation reaches the surface as it is located on the relatively lower latitude. When calculated solar radiation is validated by DSWRF from NCEP/NCAR reanalysis, monthly mean solar radiation is 547.59 MJ which is approximately 2.89 MJ higher than DSWRF. The correlation coefficient between calculation and reanalysis data is 0.99 and the RMSE (Root Mean Square Error) is 6.17 MJ. It turned out to be highest correlation (r=0.94) in October, and lowest correlation (r=0.62) in March considering the error of cloud detection with melting and yellow sand.

Analysis of Uncertainty in Ocean Color Products by Water Vapor Vertical Profile (수증기 연직 분포에 의한 GOCI-II 해색 산출물 오차 분석)

  • Kyeong-Sang Lee;Sujung Bae;Eunkyung Lee;Jae-Hyun Ahn
    • Korean Journal of Remote Sensing
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    • v.39 no.6_2
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    • pp.1591-1604
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    • 2023
  • In ocean color remote sensing, atmospheric correction is a vital process for ensuring the accuracy and reliability of ocean color products. Furthermore, in recent years, the remote sensing community has intensified its requirements for understanding errors in satellite data. Accordingly, research is currently addressing errors in remote sensing reflectance (Rrs) resulting from inaccuracies in meteorological variables (total ozone, pressure, wind field, and total precipitable water) used as auxiliary data for atmospheric correction. However, there has been no investigation into the error in Rrs caused by the variability of the water vapor profile, despite it being a recognized error source. In this study, we used the Second Simulation of a Satellite Signal Vector version 2.1 simulation to compute errors in water vapor transmittance arising from variations in the water vapor profile within the GOCI-II observation area. Subsequently, we conducted an analysis of the associated errors in ocean color products. The observed water vapor profile not only exhibited a complex shape but also showed significant variations near the surface, leading to differences of up to 0.007 compared to the US standard 62 water vapor profile used in the GOCI-II atmospheric correction. The resulting variation in water vapor transmittance led to a difference in aerosol reflectance estimation, consequently introducing errors in Rrs across all GOCI-II bands. However, the error of Rrs in the 412-555 nm due to the difference in the water vapor profile band was found to be below 2%, which is lower than the required accuracy. Also, similar errors were shown in other ocean color products such as chlorophyll-a concentration, colored dissolved organic matter, and total suspended matter concentration. The results of this study indicate that the variability in water vapor profiles has minimal impact on the accuracy of atmospheric correction and ocean color products. Therefore, improving the accuracy of the input data related to the water vapor column concentration is even more critical for enhancing the accuracy of ocean color products in terms of water vapor absorption correction.