• Asian Journal of Atmospheric Environment
• /
• v.6 no.1
• /
• pp.53-66
• /
• 2012

A comparison of analytical approaches for Levoglucosan ($C_6H_{10}O_5$, commonly formed from the pyrolysis of carbohydrates such as cellulose) and used for a molecular marker in biomass burning is made between the four different analytical systems. 1) Spectrothermography technique as the evaluation of thermograms of carbon using Elemental Carbon & Organic Carbon Analyzer, 2) mass spectrometry technique using Gas Chromatography/mass spectrometer (GC/MS), 3) Aerosol Mass Spectrometer (AMS) for the identification of the particle size distribution and chemical composition, and 4) two dimensional Gas Chromatography with Time of Flight mass spectrometry (GC${\times}$GC-TOFMS) for defining the signature of Levoglucosan in terms of chemical analytical process. First, a Spectrothermography, which is defined as the graphical representation of the carbon, can be measured as a function of temperature during the thermal separation process and spectrothermographic analysis. GC/MS can detect mass fragment ions of Levoglucosan characterized by its base peak at m/z 60, 73 in mass fragment-grams by methylation and m/z 217, 204 by trimethylsilylderivatives (TMS-derivatives). AMS can be used to analyze the base peak at m/z 60.021, 73.029 in mass fragment-grams with a multiple-peak Gaussian curve fit algorithm. In the analysis of TMS derivatives by GC${\times}$GC-TOFMS, it can detect m/z 73 as the base ion for the identification of Levoglucosan. It can also observe m/z 217 and 204 with existence of m/z 333. Although the ratios of m/z 217 and m/z 204 to the base ion (m/z 73) in the mass spectrum of GC${\times}$GC-TOFMS lower than those of GC/MS, Levoglucosan can be separated and characterized from D (-) +Ribose in the mixture of sugar compounds. At last, the environmental significance of Levoglucosan will be discussed with respect to the health effect to offer important opportunities for clinical and potential epidemiological research for reducing incidence of cardiovascular and respiratory diseases.

• Journal of Environmental Science International
• /
• v.32 no.12
• /
• pp.899-914
• /
• 2023

Various seeding materials for cloud seeding are being used, and sodium chloride powder is one of them, which is commonly used. This study analyzed the experimental results of multi-aircraft cloud seeding in connection with Republic of Korea Air Force (CN235) and KMA/NIMS(Korea Meteorological Administration/National Institute of Meteorological Sciences) Atmospheric Research Aircraft. Powdered sodium chloride was used in CN235 for the first time in South Korea. The analysis of the cloud particle size distributions and radar reflectivity before and after cloud seeding showed that the growth efficiency of powdery seeding material in the cloud is slightly higher than that of hygroscopic flare composition in the distribution of number concentrations by cloud aerosol particle diameter (10 ~ 1000 ㎛). Considering the radar reflectivity, precipitation, and numerical model simulation, the enhanced precipitation due to cloud seeding was calculated to be a maximum of 3.7 mm for 6 hours. The simulated seeding effect area was about 3,695 km², which corresponds to 13,634,550 tons of water. In the precipitation component analysis, as a direct verification method, the ion equivalent concentrations (Na⁺, Cl^-, Ca²⁺) of the seeding material at the Bukgangneung site were found to be about 1000 times higher than those of other non-affected areas between about 1 and 2 hours after seeding. This study suggests the possibility of continuous multi-aircraft cloud seeding experiments to accumulate and increase the amount of precipitation enhancement.

• Journal of Korean Society of Environmental Engineers
• /
• v.33 no.3
• /
• pp.196-201
• /
• 2011

Emission from meat cooking may contribute to the concentration of the Particulate Matters(PM) in the city. This study is to investigate the particle size and the emission characteristics of particulate matters from pork and beef cooking. The chamber was installed for sampling of PM generated from pork belly and beef sirloin cooking including seasoned ones. Cascade Impactor and Portable Aerosol Monitor (PAM) were used to analyse the particle size distribution. At the result of the Cascade Impactor sampling, particulate matters from the pork cooking was higher than that of beef. The gravimetric concentration of PM according to the size was highest at the range of $1.95{\sim}3.2{\mu}m$ and the gravimetric concentration of PM from the non-seasoned meat was higher than that of the seasoned one. The emission factors from pork, pork seasoned, beef and beef seasoned were 1.36 g/kg, 1.03 g/kg, 1.23 g/kg, 0.92 g/kg respectively. To see the result of PAM sampling, the ranges of $1.6{\sim}2.5{\mu}m$ and $2.5{\sim}3.5{\mu}m$ were reveled as highest. The ration of $PM_{2.5}/PM_{10}$ from pork and beef was 0.56~0.58. The emission factors from pork, pork seasoned, beef and beef seasoned measured by PAM were revealed as 3.37 g/kg, 2.76 g/kg, 2.93 g/kg, 2.77 g/kg respectively.

• Journal of Korean Society of Environmental Engineers
• /
• v.31 no.2
• /
• pp.153-160
• /
• 2009

A PM10 (aerodynamic diameter${\leq}$10 ${\mu}m$) sampler is used to quantify the potential human exposure to suspended particulate matter (PM) and to comply with the governmental regulation. This study was conducted to compare and evaluate the same PM10 cutpoint and different slopes between United States Environmental Protection Agency (USEPA) PM10 sampling criterion and American Conference of Governmental Industrial Hygienists/$Comit\acute{e}$ $Europ\acute{e}en$ de Normalization/International Organization for Standardization thoracic PM10 sampling criterion through theory and experiment. Four PM10 samplers according to the USEPA criterion and one RespiCon sampler in accordance with the thoracic PM10 criterion were used in the present study. In addition, one DustTrak monitor was used to measure real time PM10 mass concentrations. All six aerosol samplers were tested in a PM generation chamber using polydisperse fly ash. Theoretical mass concentrations were calculated by applying the measured particle size distribution characteristics (geometric mean = 6.6 ${\mu}m$, geometric standard deviation = 1.9) of fly ash to each sampling criterion. The measured mass concentrations through a chamber experiment were consistent with theoretical mass concentrations in that a RespiCon sampler with the thoracic PM10 criterion collected less PM than a PM10 sampler with the USEPA criterion. The overall chamber experiment results indicated, when a PM10 sampler was used as a reference sampler, that (1) a RespiCon sampler had a normalizing factor of 1.6, meaning that this sampler underestimated an average 60% of PM10 mass sampled from a PM10 sampler, and (2) a DustTrak real-time monitor using a PM10 inlet had a calibration factor of 2.1.