• Korean Journal of Materials Research
• /
• v.29 no.11
• /
• pp.684-689
• /
• 2019

Single crystals, which have complexed composition, are fabricated by solid state grain growth. However, it is hard to achieve stable properties in a single crystal due to trapped pores. Aerosol deposition (AD) is suitable for fabrication of single crystals with stable properties because this process can make a high density coating layer. Because of their unique features (nano sized grains, stress inner site), it is hard to fabricate single crystals, and so studies of grain growth behavior of AD film are essential. In this study, a $BaTiO_3$ coating layer with ${\sim}9{\mu}m$ thickness is fabricated using an aerosol deposition method on (100) and (110) cut $SrTiO_3$ single crystal substrates, which are adopted as seeds for grain growth. Each specimen is heat-treated at various conditions (900, 1,100, and $1,300^{\circ}C$ for 5 h). $BaTiO_3$ layer shows different growth behavior and X-ray diffraction depending on cutting direction of $SrTiO_3$ seed. Rectangular pillars at $SrTiO_3$ (100) and laminating thin plates at $SrTiO_3$ (110), respectively, are observed.

• Particle and aerosol research
• /
• v.8 no.4
• /
• pp.161-172
• /
• 2012

Three-dimensional numerical simulation using a computational fluid dynamics (CFD) was carried out in order to investigate the formation and dispersion of the plume discharged from the stack of a thermal power station. The simulation was based on the standard ${\kappa}{\sim}{\varepsilon}$ turbulence model and a finite-volume method. Warm and moist exhaust from a power plant stack forms a visible plume as entering the cold ambient air. In the simulation, moisture content, emission velocity and temperature of the flue gas, air temperature and wind speed were dealt with the main parameters to analyze the properties of the plume composed mainly of water vapor. As a result of the simulation, the plume could be more apparent in cold winter due to a big difference of latent heat capacity. At no wind condition, the white plume rises 120 m upward from the top of the stack, and expands to 40 m around from the stack in cold winter after flue gas heat recovery. The influencing distance of relative humidity will be about 100 m to 400 m downstream from the stack with a cross wind effect. The decrease of flue gas temperature by heat recovery of thermal energy facilitates the formation of the plume and restrains its dispersion. Wind speed with vertical distribution affects the plume dispersion as well as the density.

• Korean Journal of Remote Sensing
• /
• v.29 no.6
• /
• pp.663-670
• /
• 2013

Total Vertical Column Density (VCD) of $NO_2$, a key component in air quality and tropospheric chemistry was measured using a ground-based instrument, Pandora, in Seoul from March 2012 to October 2013. The $NO_2$ measurements using Pandora were compared with those obtained by satellite remote sensing from Ozone Monitoring Instrument (OMI) where the intercomparison characteristics were analyzed as a function of measurement geometry, cloud amount and aerosol loading. The negative biases of the OMI $NO_2$ VCD were larger when cloud amount and Aerosol Optical Depth (AOD) were higher. The correlation coefficient between $NO_2$ VCDs from Pandora and OMI was 0.53 for the entire measurement period, whereas the correlation coefficient between the two was 0.74 when the cloud amount and AOD were low (cloud amount<3, AOD<0.4). The low bias of OMI data was associated with the shielding effect of the cloud and the aerosols.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2008.11a
• /
• pp.31-31
• /
• 2008

고주파 잡음 발생과 고집적화 문제 해결을 위해 고용량 디커플링 캐패시터를 기판에 내장하는 연구가 활발히 진행되고 있다. 본 연구에서는 초고주파 환경에서 고용량 기판 내장형 디커플링 캐패시터로의 응용을 위해 $BaTiO_3$박막을 에어로졸 데포지션 법을 이용하여 12~0.2 ${\mu}m$의 두께로 제조하였고 그 유전특성을 조사하였다. 그결과, 1 MHz에서 permittivity가 70, loss tangent은 3% 이하였으며, capacitance density는 $1{\mu}m$의 두께에서 59 nF/$cm^2$이었다. 하지만, 박막의 두께가 $1{\mu}m$ 이하에서는 XRD를 통해 결정성이 확인 되었음에도 큰 누설전류로 인해 유전특성을 확인할 수 없었다. 이 누설전류의 발생 원인을 조사하기 위해 $BaTiO_3$박막의 표면의 미세구조를 SEM으로 관찰한 결과 여러 결함들이 확인되었으며, 또한 전극 직경의 크기를 1.5 mm에서 0.33 mm로 작게 변화시킴으로서 그 유전특성을 조사하여 박막의 불균일성과 박막화의 가능성을 확인하였다.

• Particle and aerosol research
• /
• v.8 no.2
• /
• pp.47-54
• /
• 2012

Paved road dust emissions were investigated 14 times on 12 main roads in Seo-Cho Gu, Seoul, Korea by vehicle-based mobile sampling system(Road Dust Monitoring System) during September to December 2011. Also, fourteen heavy metals present in the dust samples were analyzed by ICP. ICP analysis showed that one of major source of the road dust would be urban construction. A large amount of silt was found, which might be originated mainly from building construction and open beds of trees. Trace element and pollution indices of heavy metals(Cd, Cu, Ni, Pb, Zn) on the roads adjacent to the commercial area had higher concentrations than those on the roads adjacent to the construction and residential areas because of traffic density and heavy traffic.

• Particle and aerosol research
• /
• v.6 no.1
• /
• pp.21-27
• /
• 2010

New process consisting of electrospray and epitaxial crystal growth processes was applied to the preparation of c-plane oriented barium ferrite ($BaFe_{12}O_{19}$) thin film for high density magnetic recording media. Sodium citrate aided process was proper to preparation of amorphous $BaFe_{12}O_{19}$ nanoparticles with geometric mean diameter of 3 nm and geometric standard deviation of 1.1. The electrospray was applicable to the prepare of amorphous $BaFe_{12}O_{19}$ thin film on a substrate, and the film thickness could be controlled by adjusting the electrospray deposition time. The c-plane oriented $BaFe_{12}O_{19}$ thin film was successfully prepared by 3 step annealing process of the $BaFe_{12}O_{19}$ amorphous film on a sapphire($Al_2O_3$) substrate; annealing at $350^{\circ}C$ for 30 min, annealing at $500^{\circ}C$ for 30 min, and annealing at $700^{\circ}C$ for 60 min.

• Particle and aerosol research
• /
• v.4 no.1
• /
• pp.21-25
• /
• 2008

$Pb(Zr_{0.53}Ti_{0.47})O_3$ (PZT) was synthesized by a multiple wet dry process. Precipitates prepared from reaction between $ZrOCl_2{\cdot}8H_2O$ and $TiOCl_2$ and $NH_4OH$ in an aqueous solution was dried at $100^{\circ}C$, and calcined at $500^{\circ}C$ and $700^{\circ}C$. The mixture mixed with PbO and as-dried or calcined $Zr_{0.53}Ti_{0.47}O_4$ (ZT) powders was calcined again at 700 and $800^{\circ}C$. Well crystallized ZT and PZT were formed at even $700^{\circ}C$. PZT piezoelectric ceramics of more than 98.5% in a relative density was obtained by sintering at as low as $900^{\circ}C$.

• Journal of Korean Society for Atmospheric Environment
• /
• v.26 no.5
• /
• pp.475-489
• /
• 2010

In order to verify the enhancement of ozone and carbon monoxide (CO) during springtime in East Asia, we investigated weather conditions and data from remote sensors, air quality models, and air quality monitors. These include the geopotential height archived from the final (FNL) meteorological field, the potential vorticity and the wind velocity simulated by the Meteorological Mesoscale Model 5 (MM5), the back trajectory estimated by the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model, the total column amount of ozone and the aerosol index retrieved from the Total Ozone Mapping Spectrometer (TOMS), the total column density of CO retrieved from the Measurement of Pollution in the Troposphere (MOPITT), and the concentration of ozone and CO simulated by the Model for Ozone and Related Chemical Tracers (MOZART). In particular, the total column density of CO, which mightoriginate from the combustion of fossil fuels and the burning of biomass in China, increased in East Asia during spring 2000. In addition, the enhancement of total column amounts of ozone and CO appeared to be associated with both the upper cut-off low near 500 hPa and the frontogenesis of a surface cyclone during a weak Asian dust event. At the same time, high concentrations of ozone and CO on the Earth's surface were shown at the Seoul air quality monitoring site, located at the surface frontogenesis in Korea. It was clear that the ozone was invaded by the downward stretched vortex anomalies, which included the ozone-rich airflow, during movement and development of the cut-off low, and then there was the catalytic photochemical reaction of ozone precursors on the Earth's surface during the day. In addition, air pollutants such as CO and aerosol were tracked along both the cyclone vortex and the strong westerly as shown at the back trajectory in Seoul and Busan, respectively. Consequently, the maxima of ozone and CO between the two areas showed up differently because of the time lag between those gases, including their catalytic photochemical reactions together with the invasion from the upper troposphere, as well as the path of their transport from China during the weak Asian dust event.

• Particle and aerosol research
• /
• v.16 no.2
• /
• pp.31-47
• /
• 2020

Although interest in air quality has increased due to the frequent occurrence of high-concentration fine particulate matter recently, the official fine particulate matter measuring network has failed to provide spatial detailed air quality information. This is because current measurement equipment has a high cost of installation and maintenance, which limits the composition of the measuring network at high resolution. To compensate for the limitations of the current official measuring network, this study constructed a spatial high density measuring network using the fine particulate matter simple measuring device developed by Observer, W-Station. W-Station installed 48 units on Jeju Island and measured PM_2.5 for six months. The data collected in W-Station were corrected by applying the first regression equation for each section, and these measurements were compared and analyzed based on the official measurements installed in Jeju Island. As a result, the time series of PM_2.5 concentrations measured in W-Station showed concentration characteristics similar to those of the environmental pollution measuring network. In particular, the results of comparing the measurements of W-Station within a 2 km radius of the reference station and the reference station showed that the coefficient of determination (R²) was 0.79, 0.81, 0.67, respectively. In addition, for W-Station within a 1 km radius, the coefficient of determination was 0.85, 0.82, 0.68, respectively, showing slightly higher correlation. In addition, the local concentration deviation of some regions could be confirmed through 48 high density measuring networks. These results show that if a network of measurements is constructed with adequate spatial distribution using a number of simple meters with a certain degree of proven performance, the measurements are effective in monitoring local air quality and can be fully utilized to supplement or replace formal measurements.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.20 no.12
• /
• pp.820-824
• /
• 2008

Electret filter media are used in general ventilation filters, disposable respirators, vehicle cabin filters, vacuum cleaners and room air cleaners. There are basic mechanisms of interception, inertial impaction, diffusion, gravitational settling, electrostatic attraction by which an aerosol particle can be deposited onto a fiber in a filter. The ability of fine particle removal strongly depends on the electrostatic forces between particles and polarized fibers. Thus, the stability of the fiber polarization is a major factor in the reliability of electret filters. In this study, the electret filter is made by electrospinning process using Polystyrene which is dissolved by 5 : 5 of Tetrahydrofuran (THF) and Dimethylformamide (DMF). Also the electrical properties and the filtration performances of electrospun filter media are Quantitatively investigated. Electrical properties of electrospun filters have been studied on surface charge potential and surface charge density. Also the filtration performance of the electret filters are evaluated on collection efficiency. The surface charge potential and the surface charge density of electrospun PS filters are increased with increasing applied voltage and saturated at 30 kV of applied voltage. Also collection efficiency of electro spun filters is increased with increasing surface charge potential and surface charge density. But the surface charge potential is decreased by natural decay and it causes deterioration of particle collection efficiency.