• Atmosphere
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• v.17 no.4
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• pp.407-420
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• 2007

Optical characteristics of aerosols in Seoul are investigated from the measurements of sky radiance by Skyradiometer at Yonsei University from December 2005 to November 2006. Aerosol optical depth (AOD) shows a maximum in June due to weak ventilation and particle growth by aging process and hygroscopic effect. Single scattering albedo (SSA) and Angstrom Exponent (AE) show the lowest value in spring due to the Asian dust. It is clear that coarse mode is dominant in spring and fine mode is dominant in summer from the volume size distribution measured in this study. The explanations on the changes of aerosol loadings are provided through the correlation between AOD and AE, while the pattern of wavelength dependency related to particle size is shown through the correlation between SSA and AE. Backward trajectory analysis by HYSPLIT provides information about origin of aerosol, which allows us to classify the case according to the source region and the path distance. Although the direction of backward trajectory traces back mostly to west, coarse mode particle is dominant in the case of long pathway and fine mode particle is dominant in the case of short pathway. This discrepancy is caused by the regional difference of emitted particles.

• Atmosphere
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• v.23 no.3
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• pp.321-329
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• 2013

This study examines the effect of aerosols on the vertical invigoration of continental stratiform clouds, using a dataset of Atmospheric Radiation Measurement (ARM) Intensive Operational Period (IOP, March 2000) at the Southern Great Plains (SGP) site. To provide further support to our observation-based findings, the weather research and forecasting (WRF) sensitivity simulations with changing cloud condensation nuclei (CCN) concentrations have been carried out for the golden episode over SGP. First, cross correlation between observed aerosol scattering coefficient and cloud liquid water path (LWP) with a 160-minutes lag is the highest of r = 0.83 for the selected episode, which may be attributable to cloud vertical invigoration induced by an increase in aerosol loading. Modeled cloud fractions in a control run are well matched with the observation in the perspective of cloud morphology and lasting period. It is also found through a simple sensitivity with a change in CCN that aerosol invigoration (AIV) effect on stratiform cloud organization is attributable to a change in the cloud microphysics as well as dynamics such as the corresponding modification of cloud number concentrations, drop size, and latent heating rate, etc. This study suggests a possible cloud vertical invigoration even in the continental stratiform clouds due to aerosol enhancement in spite of a limited analysis based on a few observed continental cloud cases.

• Journal of Environmental Science International
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• v.16 no.10
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• pp.1157-1167
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• 2007

In an effort to interpret the characteristics of fine particle concentrations in Busan, time variations of hourly monitored concentrations $PM_{10}$ (Particulate Matter with aerodynamic Diameter ${\le}10\;{\mu}m$) in Busan are analyzed for the period from 2000 to 2005. The characteristics of aerosol second generation formation process is also interpreted qualitatively, by using the statistical analysis of the meteorological variables including temperature, wind speed, and relative humidity. The result shows some significant annual, seasonal, weekly and diurnal variations of $PM_{10}$ concentrations. In particular, seasonal(i.e., spring) variations are governed by frequency of yellow sand events even for the non-yellow sand cases where yellow-sand days are eliminated in our analysis. However, in seasonal variation, summer season predominate lower $PM_{10}$ concentrations due to the frequent precipitation, and weekly and diurnal variations are both found to be reflecting the emission rate from traffic amount. Correlation coefficients between $PM_{10}$ concentration and meterological variables for non-yellow sand days show overall negative correlation with visibility, wind speed, cloud amounts, and relative humidity. However for non-precipitation days, during non-yellow sand period positive correlation are found clearly with relative humidity, suggesting the importance of secondary aerosol formation in Busan that can be achieved by both homogeneous aerosol formation and heterogeneous transformations resulting from hygroscopic aerosol characteristics.

• Journal of Drive and Control
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• v.21 no.1
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• pp.8-15
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• 2024

This thesis investigates the jetting characteristics of an aerosol jet printing (AJP) process as a function of design and operating conditions. The governing equations of the AJP system are derived for experimentation and analysis. To understand the characteristics of the AJP system, it analyzes the jetting characteristics as a function of the flow rate of the carrier gas and the sheath gas, and the variation of the linewidth with the nozzle exit size based on particle tracking. The thesis focuses on computational fluid dynamics (CFD), which is a computer simulation. The particle tracking results obtained by CFD were analyzed using MATLAB. CFD analytical models can be analyzed in environments with different conditions and consider more specific situations than mathematical computational models. The validity of the CFD analysis is shown by comparing the experimental results with the CFD analysis.

• Journal of Drive and Control
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• v.21 no.2
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• pp.8-14
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• 2024

This paper investigates the jetting characteristics of an aerosol jet printing (AJP) process as a function of design and operating conditions. The governing equations of the AJP system are derived for experimentation and analysis. To understand the characteristics of the AJP system, this thesis analyzes the jetting characteristics as a function of the flow rate of the carrier gas and the sheath gas, and the variation of the linewidth with the nozzle exit size based on particle tracking. This thesis focuses on computational fluid dynamics (CFD), which is a computer simulation. The particle tracking results obtained by CFD were analyzed using MATLAB. CFD analytical models can be analyzed in environments with different conditions and consider more specific situations than mathematical computational models. The validity of the CFD analysis is shown by comparing the experimental results with the CFD analysis.

• Bulletin of the Korean Chemical Society
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• v.31 no.5
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• pp.1159-1164
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• 2010

Several triterpenoid saponins from root of Pulsatilla koreana Nakai (Ranunculaceae) were studied and their biological activities were reported. It is difficult to analyze triterpenoid saponins using HPLC-UV due to the lack of chromophores. So, evaporative light scattering detection (ELSD) is used as a valuable alternative to UV detection. More recently, a charged aerosol detection (CAD) has been developed to improve the sensitivity and reproducibility of ELSD. In this study, we developed and validated a novel method of high performance liquid chromatography coupled with a charged aerosol detector for the simultaneous determination of four triterpenoid saponins: pulsatilloside E, pulsatilla saponin H, anemoside B4 and cussosaponin C. Analytes were separated by the Supelco Ascentis$^{(R)}$ Express C18 column (4.6 mm ${\times}$ 150 mm, 2.7 ${\mu}m$) with gradient elution of methanol and water at a flow rate of 0.8 mL/min at $30^{\circ}C$. We examined various factors that could affect the sensitivity of the detectors, including various concentrations of additives, the pH of the mobile phase, and the CAD range. Linear calibration curves were obtained within the concentration ranges of 2 - 200 ${\mu}g$/mL for pulsatilloside E, anemoside $B_4$ and cussosaponin C, and 5 - 500 ${\mu}g$/mL for pulsatilla saponin H with correlation coefficient ($R^2$) greater than 0.995. The limit of detection (LOD) and quantification (LOQ) were 0.04 - 0.2 and 2 - 5 ${\mu}g$/mL, respectively. The validity of the developed HPLC-CAD method was confirmed by satisfactory values of linearity, intra- and inter-day accuracy and precision. This method could be successfully applied to quality evaluation, quality control and monitoring of Pulsatilla koreana.

• Journal of Environmental Science International
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• v.22 no.1
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• pp.7-15
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• 2013

Aerosol characterization study for individual particle in Busan metropolitan industrial complex was carried out from December 2010 to August 2011. SEM(scanning electron microscope)-EDX(energy dispersive x-ray) analysis was used for the analysis of 600 single particles during the sampling periods to identify non-metallic aerosol particle sources. Average $PM_{10}$ concentration was 65.5 ${\mu}g/m^3$ in summer, 104.1 ${\mu}g/m^3$ in winter during the sample periods. And Average $PM_{2.5}$ concentration was 24.5 ${\mu}g/m^3$ in summer, 64.5 ${\mu}g/m^3$ in winter individually. Particle density, enrichment factor, correlation analysis, principle component analysis were performed based on chemical composition data. Particle density distribution was measured to 2~4 $g/cm^3$, and the density of $PM_{2.5}$ was measured above 3 $g/cm^3$. In general, the elements Si, Ca, Fe and Al concentrations were higher in all samples of individual particles. The non-ferrous elements Zn, Br, Pb, Cu concentrations were higher in summer than in winter. The concentrations were not changed with the seasons because of non-ferrous industry emission pattern.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.6
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• pp.647-661
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• 2003

For continuous monitoring of atmospheric visibility in the city of Kwanaju, Korea, a transmissometer system consisting of a transmitter and a receiver was installed at a distance of 1.91 km across the downtown Kwanaju. At the transmitter site an integrating nephelometer and an aethalometer were also installed to measure the scattering and absorption coefficients of the atmosphere, respectively. At the receiver site. an URG PM$_{2.5}$ cyclone sampler and an URG-VAPS (Versatile Air Pollutant Sampler) with three filter packs and two denuders were used to collect both PM$_{2.5}$ and PM$_{10}$ samples at a 2-hour or 12-hour sampling interval for aerosol chemical analysis. Sulfate, organic mass by carbon (OMC), nitrate, elemental carbon (EC) components of fine aerosol were the major contributors to visibility impairment. Diurnal variation of visibility during best-case days showed rapid improvement in the morning hours, while it was delayed until afternoon during the worst-case days. Aerosol mass concentration of each aerosol component for the worst-case was calculated to be 11.2 times larger than the best-case for (NH$_4$)$_2$SO$_4$(NHSO), 19.0 times for NH$_4$NO$_3$ (NHNO), 2.2 times for OMC, respectively. Also result shows that elemental carbon and fine soil (FS) were 3.7 and 2.2 times more than those of best-case. respectively- Sum of total contributions of wet NHSO and NHNO to light extinction was calculated to be 301 Mm$^{-1}$ for the worst-case. However, sum of contributions by dry NHSO and NHNO was calculated to be 123 Mm$^{-1}$ for the best case. Mass extinction efficiencies of fine and coarse particles were calculated to be 5.8$\pm$0.3 $m^2$/g and 1.8$\pm$0.1 $m^2$/g, respectively.ely.

• Korean Journal of Remote Sensing
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• v.34 no.3
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• pp.507-517
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• 2018

Aerosol optical depth (AOD) data retrieved by the Communication, Ocean and Meteorological Satellite (COMS) during 2011-2014 were compared with AOD measurements from 134 Aerosol Robotic Network (AERONET) sites over the East Asia. Overall, COMS and AERONET AODs were weakly correlated (R = 0.297). The agreement between COMS and AERONET AODs was improved when data from near Korean peninsula sites were selected (R = 0.475). Regression analysis results for each AERONET site are vary from R=0.026 at AOE_Baotou to 0.905 at DRAGON_Anmyeon. It was also shown that the bias in COMS AOD was not systematic with respect to effective radius, precipitable water, surface reflectance, and sun zenith angle. Together, these results suggest that COMS AOD measurements may be suitable for near Korea. Finally, the current results will help to improve the retrieval algorithm and vary when using alternative COMS AOD version in the future.

• Journal of Korean Society for Atmospheric Environment
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• v.33 no.3
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• pp.233-240
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• 2017

To distinguish between high particulate matter (HPM) and light Asian dust (LAD) events, aerosol optical properties from GOCI were investigated in Seoul from 2014 to 2016. The poor air quality case caused by fine atmospheric particulate matter (i.e., 80<$PM_{10}$<$400{\mu}g/m^3$) is clearly separated from the case of heavy Asian dust that generally shows the $PM_{10}$ concentration more than $400{\mu}g/m^3$. In this study, we have found eight cases for the poor air quality and divided them into the two events(i.e., HPM and LAD). In case of aerosol optical depth (AOD), there was no big difference between two events. However, Angstrom exponent (AE) for HPM events was greater than 1, while that for LAD events less than 1. As a result of comparing aerosol type, non-absorbing fine mode aerosols were dominant for HPM events, but coarse and absorbing coarse mode aerosols for LAD events. Therefore, AE and aerosol type from GOCI can be used to distinguish between two events effectively.