• Korean Journal of Materials Research
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• v.24 no.4
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• pp.186-193
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• 2014

A thin Cu seed layer for electroplating has been employed for decades in the miniaturization and integration of printed circuit board (PCB), however many problems are still caused by the thin Cu seed layer, e.g., open circuit faults in PCB, dimple defects, low conductivity, and etc. Here, we studied the effect of heat treatment of the thin Cu seed layer on the deposition rate of electroplated Cu. We investigated the heat-treatment effect on the crystallite size, morphology, electrical properties, and electrodeposition thickness by X-ray diffraction (XRD), atomic force microscope (AFM), four point probe (FPP), and scanning electron microscope (SEM) measurements, respectively. The results showed that post heat treatment of the thin Cu seed layer could improve surface roughness as well as electrical conductivity. Moreover, the deposition rate of electroplated Cu was improved about 148% by heat treatment of the Cu seed layer, indicating that the enhanced electrical conductivity and surface roughness accelerated the formation of Cu nuclei during electroplating. We also confirmed that the electrodeposition rate in the via filling process was also accelerated by heat-treating the Cu seed layer.

• Journal of Environmental Health Sciences
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• v.40 no.4
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• pp.322-329
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• 2014

Objectives: The purpose of this study was to investigate the effect of BIO-CLOD on advanced wastewater treatment for enhanced removal efficiency and meeting the stringent discharge water requirements of wastewater treatment plants. Methods: Two experimental apparatuses consisting of anaerobic, anoxic and aeration tanks were operated. One included a BIO-CLOD cultivation tank. Organic and nutrient parameters and removal efficiency were analyzed by pH, BOD, CODcr, SS, T-N and T-P. Results: The average removal efficiencies of BOD, COD and SS from the apparatus with BIO-CLOD tank installation were 95.5%, 88.6% and 92.9%, respectively, and these were higher than the results from the apparatus without BIO-CLOD. The average TP removal efficiency with BIO-CLOD tank marked 56.0%, higher than the 47.3% from the apparatus without one. BIO-CLOD showed a higher performance for TN removal at 49.6%, compared to the result without BIO-CLOD of 34.3% Conclusion: By reaction with BIO-CLOD, ammonia removal was effective in the aeration tank, as was phosphorus release in the anaerobic tank. Phosphorus luxury uptake and nitrification in aeration tank proceeded smoothly. The application of BIO-CLOD can improve the decrease of odor and settleability of activated sludge in a wastewater treatment plant, as well as increase the removal efficiency of organic and nutrient materials in water.

• Journal of the Korean institute of surface engineering
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• v.40 no.1
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• pp.44-56
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• 2007

Excavated archaeological iron artifacts are usually conducted the conservation treatment for removal of chloride ions in the corrosion products. However, some iron artifacts are corroded again even after the conservation treatment due to unremoved chloride ions. Therefore, it is important to prevent desalinized artifacts from the occurrence of corrosion after the treatment. In this paper, we investigated the characteristics of corrosion products on salinized iron artifacts and evaluated the variety of desalination methods such as autoclave, intensive washing and NaOH. It was also found that ${\beta}-FeOOH$ (Akaganeite) played an important role on the occurrence of corrosion and the treatment for removal of chloride ions. The extents of desalination were compared between the desalination methods. Results showed that the autoclave method represented the highest efficiency for desalination while the intensive washing method was the lowest.

• Journal of Korean Society on Water Environment
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• v.29 no.1
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• pp.127-137
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• 2013

Reuse of wastewater will intensify in the coming decades due to water shortage, the change of climatic conditions, the need for industrial and agricultural use and the necessity of improving health and environmental conditions for the growing population. This paper considers (a) the status and trends of wastewater reuse and reclamation in the world, (b) case studies of wastewater reuse projects, (c) analysis of technology level, (d) forecast of global market, and (e) the future views and directions in development of wastewater reuse technologies. Based on the available documented literature, this paper provides a review assessment of the current status of the wastewater treatment processes including potential applications for reuse. Key challenges for both wastewater treatment and reuse are also discussed in the paper and include recommendations, e.g. cost, effluent water quality, energy use and technical solutions, for future developments.

• Journal of Environmental Science International
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• v.8 no.1
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• pp.75-81
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• 1999

In recent years increasing production and disposal of wastewater have caused an accelerated eutrophication of receiving waters. Therefore, in order to alleviate the detrimental impact of wastewater discharge, there is an increasing demand for removing the main nutrients, nitrogen and phosphorus, as well as the organic content of the waste water prior to disposal. This is effectively achieved by extended conventional treatment technology. However, the working expenses and energy requirements of such advanced treatment systems are rather high. So in a sparsely populated rural community is required development of wastewater treatment system combined with the regional characteristics. In this study, the systems are planted with Reeds and Amaryllis In A.C and estimated purification potential of system. The results obtained are as follows. BOD removal rate is 20% in the early stage, the last removal rate is 35% in A.C process and is 65% in Amaryllis+A.C process and is 50% in Reed+A.C process. T-N removal rate by Amaryllis is average 2.6g/$m^3$ㆍd, T-N removal rate by Reed is average 1.76g/$m^3$ㆍd. T-P removal rate by Amaryllis is average 0.27g/$m^3$ㆍd, T-P removal rate by Reed is average 0.25g/$m^3$ㆍd. BOD removal rate constant with retention time is 1.4494(1/d), T-N removal rate constant is 0.5428(1/d), T-P removal rate constant is 0.5287(1/d).

• Journal of the Korean Ceramic Society
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• v.50 no.6
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• pp.489-494
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• 2013

Nano-sized titanium oxide powders were synthesized by a polymer matrix technique using pulp and Titanium tetraisopropoxide (TTIP) as starting materials. The synthesized powders were characterized by XRD and FE-SEM. The particle size of the powders was controlled by preparation conditions, such as heat treatment temperature and time. After investigating various drying and heat treatment conditions, 50-100 nm sized homogeneous titanium oxide particles were obtained by treating at $600^{\circ}C$ for 1 h. The crystallization and rapid growth of particles was accelerated by increasing heat treatment temperature and time. Anatase phase generated below $600^{\circ}C$ transformed to the rutile phase with increasing heat treatment temperature. Moreover, above $800^{\circ}C$, heat treatment time had a very large influence on particle growth, and changing the heating condition also had a large influence on crystal growth.

• Journal of Korean Society of Water and Wastewater
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• v.34 no.6
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• pp.445-462
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• 2020

Industrial wastewater often contains a number of recalcitrant organic contaminants. These contaminants are hardly degradable by biological wastewater treatment processes, which requires a more powerful treatment method based on chemical oxidation. Advanced oxidation technology (AOT) has been extensively studied for the treatment of nonbiodegradable organics in water and wastewater. Among different AOTs developed up to date, ozonation and the Fenton process are the representative technologies that widely used in the field. Based on the traditional ozonation and the Fenton process, several modified processes have been also developed to accelerate the production of reactive radicals. This article reviews the chemistry of ozonation and the Fenton process as well as the cases of application of these two AOTs to industrial wastewater treatment. In addition, research needs to improve the cost efficiency of ozonation and the Fenton process were discussed.

• Journal of the Korean Society for Heat Treatment
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• v.37 no.1
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• pp.9-15
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• 2024

Nd-Fe-B permanent magnets have been utilized on various industrial fields such as electric vehicles, generator, robots with actuator, etc, due to their outstanding magnetic properties even 10 times better than conventional magnets. Recently, there are many researches that report magnetic properties improved by controlling microstructure through adjusting alloying elements or conducting various processing. Especially, post-sintering annealing (PSA) can significantly improve the coercivity by modifying the distribution and morphology of Nd-rich phase which formed at grain boundaries. In this study, Nd-Fe-B sintered magnets were subjected to primary heat treatment followed by secondary heat treatment at 460℃, 500℃, and 540℃ to investigate the changes in microstructure and magnetic properties with the secondary heat treatment temperature. EBSD analysis was conducted to compare anisotropic characteristics. Through the SEM and TEM observation for analyzing the morphology and distribution of Nd-rich phase, we investigated the relationship between microstructure and magnetic properties of sintered Nd-Fe-B magnets.

• Journal of Korean Society of Water and Wastewater
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• v.28 no.4
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• pp.367-376
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• 2014

This study assessed the removal efficiency of NOM which is known as the precursors of DBPs in advanced water treatment using the ceramic membrane filtration, introduced the first in the nation at the Y water treatment plant (WTP). It is generally well-known that the removal of NOM by MF Membrane is very low in water treatment process. But, the result of investigation on removal efficiency of NOM in advanced water treatment using the ceramic membrane was different as follows. The removal rate of organic contaminant by the ceramic membrane advanced water treatment was determined to be 65.5% for the DOC, 85.8% for UV254, and 77 to 86% for DBPFP. The removal rate of pre-ozonation was found to be 6 to 15% more effective compared with the pre-chlorination. The removal rate of DOC and $UV_{254}$ in biological activated carbon(BAC) process was over 50% and 75%, respectively although the rate was decreased 10 ~ 20% according to analysis items in converting from GAC to BAC.

• Asian Pacific Journal of Cancer Prevention
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• v.14 no.7
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• pp.4205-4208
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• 2013

Objective: The aim of this study was to explore change and significance of serum carcino-embryonic antigen (CEA) before and after gefitinib therapy in patients with advanced non-small-cell lung cancer (NSCLC). Methods: Forty patients with advanced NSCLCs in III~IV stages were selected as study objects given gefitinib therapy combined with routine local radiotherapy until tumor progression or intolerable toxicity. After treatment, all patients were divided into control and non-control groups according to the results of evaluation based on RECIST 1.1 (Response Evaluation Criteria in Solid Tumors in 2009). Peripheral fasting blood from all patients was collected in the early morning and serum CEA was assessed by electro-chemiluminescence immunoassay (ECLIA) before and after treatment. Before treatment, patients were divided into high CEA group (CEA level > 50 ng/mL) and low CEA group (CEA level ${\leq}$ 50 ng/mL). Adverse reactions were noted and progression-free survival (PFS) in both groups was recorded after long-term follow-up that ended in December, 2012. Results: There was no difference between control and non-control groups in CEA level before treatment (P>0.05), whereas serum CEA decreased more markedly lower in the control group after treatment (P<0.01). All patients were divided into high CEA group (26) and low CEA group (14) according to serum CEA level. There was no statistically significant difference between two groups in adverse reactions (P>0.05) but the rate in former group was lower. Additionally, survival rates at 9 and 12 months in high CEA group were clearly higher than in the low CEA group (P<0.01). Conclusions: Serum CEA level can serve as a biochemical index to evaluate the prognosis with gefitinib treatment for NSCLC.