• Title/Summary/Keyword: Advanced Oxidation Technology

Search Result 437, Processing Time 0.041 seconds

A Study on the Separation and Recovery of Useful Metallic Elements(Zn, Pb) from the 2nd Dust in Refining of Crude-Zinc Oxide (조산화아연의 정제과정에서 발생된 2차분진으로부터 유용금속원소(Zn, Pb)의 분리회수에 관한 연구)

  • Yoon, Jae-hong;Yoon, Chi-hyun
    • Resources Recycling
    • /
    • v.30 no.1
    • /
    • pp.66-76
    • /
    • 2021
  • Electric arc furnace dust (EAFD) contains compounds, such as oxides and chlorides, including large quantities of Zn, Pb and Fe. An efficient and stable method for the extraction of metal elements from EAFD is the Rotary Kiln Process. This method is used to recover Zn in the form of crude ZnO (approximately 60%) via the addition of a reducing agent (coke, anthracite) and limestone (for basicity control) to EAFD. This process is commonly used in industry as well as in research and development. Currently, this method is used in many Korean commercial plants, producing approximately 150,000 tons of Crude ZnO per year. The majority of Zn is found in crude ZnO (approximately 76%). In addition components such as Pb, Cd, Sn, In, Fe, Cl, and F are present as oxides, chlorides, and alkaline compounds. This elements have an adverse effect on the zinc smelting process. Therefore, a refining process that eliminates these impurities is essential. In this study, we developed a process technology that efficiently separates Zn and Pb from byproducts (mainly chlorides). A bag filter was used to collect Zn and Pb generated during the dry purification process of crude ZnO. Pure components were recovered as metals or metal carbonate.

Quality characteristics of rice noodles treated with cold plasma (저온 플라즈마 처리한 쌀국수의 품질 특성)

  • Kim, Hyun-Joo;Lee, Byong Won;Baek, Ki Ho;Jo, Cheorun;Kim, Jae-Kyung;Lee, Jin Young;Lee, Yu-Young;Kim, Min Young;Kim, Mi Hyang;Lee, Byoungkyu
    • Korean Journal of Food Science and Technology
    • /
    • v.52 no.5
    • /
    • pp.560-563
    • /
    • 2020
  • Cold plasma has been applied to improve quality of food product; however, studies on its effects on microbial and physicochemical qualities of rice noodles are rarely conducted. In this study, changes in the quality characteristics of rice noodles treated by cold plasma were determined. Cold plasma was generated in a square-shaped plastic container (250 W, 15 kHz, ambient air), and dielectric barrier discharge plasma treatments were applied to rice noodle samples for 0, 10, or 20 min. Rice noodles inoculated with either Bacillus cereus or Escherichia coli O157:H7 were subjected to plasma treatment for 20 min, and the approximate bacterial count reduction were 4.10 and 2.75 log CFU/g, respectively. The Hunter color values of the sample were increased after cold plasma treatment. Peroxide values and thiobarbituric acid reactive substance (TBARS) were increased with an increase in cold plasma treatment time. Futhermore, lipid oxidation was enhanced. Although further studies are warranted to evaluate changes in chemical qualities, such as lipid oxidation of rice noodles, induced by cold plasma, the results suggest that cold plasma can improve the microbial and physical qualities of rice noodles.

Design of the self-oscillation UV flash lamp power supply and the characteristic of its operation using self-resonance of the transformer (트랜스포머의 자가 공진(Self-Resonance)특성을 이용한 자가 발진(Self-Oscillation) UV(Ultra Violet) 발생 플래시램프 전원장치설계 및 그 동작 특성)

  • Kim, Shin-Hyo;Cho, Dae-Kweon
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.38 no.1
    • /
    • pp.48-55
    • /
    • 2014
  • These Xenon flashlamp power supply for Ultra Violet has converter with high voltage conversion ratio. General model is composed of transformer with high voltage conversion ratio and voltage doubler rectifier circuit. Purpose of power supply leads dielectric breakdown of Xenon flashlamp and passes current rapidly. When passing current, it has to limit current to avoid over-heat, damage of electrode and acceleration of gas oxidation which are cause of performance degradation of lamps. Generally, inductors and resistors, which are called as "Ballast," are used to limit currents. Generally, Transformer has high turn ratio to make high voltages. But we can get high voltages using the transformer with low turn ratio which is driven with self resonance. Also, an advantage of self resonance is to make a circuit simply through impedance of transformer in resonance frequency which filters output voltage. As using an unique impedance of transformer, the circuit does not need other impedance elements like the ballast. So the power supply assures high efficiency of the arc discharge.

Bilolgical Activities of Conjugated Linoleic Acid (CLA) and Animal Products (Conjugated Linoleic Acid (CLA)의 생리활성과 축산식품)

  • Hur, S.J.;Lee, J.I.;Ha, Y.L.;Park, G.B.;Joo, S.T.
    • Journal of Animal Science and Technology
    • /
    • v.44 no.4
    • /
    • pp.427-442
    • /
    • 2002
  • Conjugated linoleic acid(CLA) is a collective term for a group of positional (c8, c10; c9, c11; c10, c12, and c11, c13) and geometric(cis,cis; cis,trans; trans,cis; and trans,trans) isomers of octadecadienoic acid (linoleic acid) with conjugated double bond system. CLA has been shown to have a variety of biological effects. Major effects of CLA on health, such as anti-cancer, anti-oxidation, anti-atherosclerosis and improving immuno-responses, might be derived or partially derived from the alternated lipid metabolism after CLA feeding. Most of studies on the effect of CLA on fat metabolism are concentrated on rats, mice, pigs and other mammals. The CLA inhibited carcinogen-induced neoplasia in several animal models and inhibited the proliferation of human malignant melanoma, colorectal and breast cancer cells and CLA reduced the atherosclerosis. Several studies have determined the antioxidant property of CLA; however, the property still remains controversial. Some of the studies have shown that CLA acted as an antioxidant, whereas some other studies have demonstrated that CLA might be a prooxidant. Several studies suggested that CLA could reduce fat accumulation in mammals. CLA was suggested to promote muscle growth and reduce fat deposition in mouse, and improve feed efficiency in rats. CLA has been shown to inhibit the activity of stearoyl-CoA reductase. CLA also reduced the content of arachidonic acid. Since arachidonic acid, and eicosapentaenoic acid (EPA) and docosahexenoic acid (DHA) are synthesized by different pathways, reducing the synthesis of arachidonic acid may not mean reducing that of EPA and DHA. Many sutdies have been shown biological effects of CLA. Therefore, further research is needed to answer the following questions: 1) how to synthesize the new CLA by new methods, 2) why CLA has shown biological effects, 3) how to increase CLA effects in animal products.

Determination of Efficient Operating Condition of UV/H2O2 Process Using the OH Radical Scavenging Factor (수산화라디칼 소모인자를 이용한 자외선/과산화수소공정의 효율적인 운전 조건도출)

  • Kim, Seonbaek;Kwon, Minhwan;Yoon, Yeojoon;Jung, Youmi;Hwang, Tae-Mun;Kang, Joon-Wun
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.36 no.8
    • /
    • pp.534-541
    • /
    • 2014
  • This study investigated a method to determine an efficient operating condition for the $UV/H_2O_2$ process. The OH radical scavenging factor is the most important factor to predict the removal efficiency of the target compound and determine the operating condition of the $UV/H_2O_2$ process. To rapidly and simply measure the scavenging factor, Rhodamine B (RhB) was selected as a probe compound. Its reliability was verified by comparing it with a typical probe compound (para-chlorobenzoic acid, pCBA); the difference between RhB and pCBA was only 1.1%. In a prediction test for the removal of Ibuprofen, the RhB method also shows a high reliability with an error rate of about 5% between the experimental result and the model prediction using the measured scavenging factor. In the monitoring result, the scavenging factor in the influent water of the $UV/H_2O_2$ pilot plant was changed up to 200% for about 8 months, suggesting that the required UV dose could be increased about 1.7 times to achieve 90% caffeine removal. These results show the importance of the scavenging factor measurement in the $UV/H_2O_2$ process, and the operating condition could simply be determined from the scavenging factor, absorbance, and information pertaining to the target compound.

Effects of Sulfur Substitution on Chemical Bonding Nature and Electrochemical Performance of Layered LiMn0.9Cr0.1O2-xSx

  • Lim, Seung-Tae;Park, Dae-Hoon;Lee, Sun-Hee;Hwang, Seong-Ju;Yoon, Young-Soo;Kang, Seong-Gu
    • Bulletin of the Korean Chemical Society
    • /
    • v.27 no.9
    • /
    • pp.1310-1314
    • /
    • 2006
  • Sulfur-substituted $LiMn_{0.9}Cr_{0.1}O_{2-x}S_x$ $(0\;\leq\;x\;\leq\;0.1)$ layered oxides have been prepared by solid state reaction under inert atmosphere. From powder X-ray diffraction analyses, all the present lithium manganates were found to be crystallized with monoclinic-layered structure. Electrochemical measurements clearly demonstrated that, in comparison with the pristine $LiMn_{0.9}Cr_{0.1}O_2$, the sulfur-substituted derivatives exhibit smaller discharge capacities for the entire cycle range but the recovery of discharge capacity after the initial several cycles becomes faster upon sulfur substitution. The effect of the sulfur substitution on the chemical bonding nature of $LiMn_{0.9}Cr_{0.1}O_{2-x}S_x$has been investigated using X-ray absorption spectroscopic (XAS) analyses at Mn and Cr K-edges. According to Mn K-edge XAS results, the trivalent oxidation state of manganese ion remains unchanged before and after the substitution whereas the local structure around manganese ions becomes more distorted with increasing the substitution rate of sulfur. On the other hand, the replacement of oxygen with sulfur has negligible influence on the local atomic arrangement around chromium ions, which is surely due to the high octahedral stabilization energy of $Cr^{+III} $ ions. Based on the present experimental findings, we have suggested that the decrease of discharge capacity upon sulfur substitution is ascribable to the enhanced structural distortion of $MnO_6$ octahedra and/or to the formation of covalent Li-S bonds, and the accompanying improvement of cyclability would be related to the depression of Mn migration and/or to the pillaring effect of larger sulfur anion.

Reliability Evaluation of ACP Component under a Radiation Environment (방사선환경에서 ACP 주요부품의 신뢰도 평가)

  • Lee, Hyo-Jik;Yoon, Kwang-Ho;Lim, Kwang-Mook;Park, Byung-Suk;Yoon, Ji-Sup
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
    • /
    • v.5 no.4
    • /
    • pp.309-322
    • /
    • 2007
  • This study deals with the irradiation effects on some selected components which are being used in an Advanced Spent Fuel Conditioning Process (ACP). Irradiation test components have a higher priority from the aspect of their reliability because their degradation or failure is able to critically affect the performance of an ACP equipment. Components that we chose for the irradiation tests were the AC servo motor, potentiometer, thermocouples, accelerometer and CCD camera. ACP facility has a number of AC servo motors to move the joints of a manipulator and to operate process equipment. Potentiometers are used for a measurement of several joint angles in a manipulator. Thermocouples are used for a temperature measurement in an electrolytic reduction reactor, a vol-oxidation reactor and a molten salt transfer line. An accelerometer is installed in a slitting machine to forecast an incipient failure during a slitting process. A small CCD camera is used for an in-situ vision monitoring between ACP campaigns. We made use of a gamma-irradiation facility with cobalt-60 source for an irradiation test on the above components because gamma rays from among various radioactive rays are the most significant for electric, electronic and robotic components. Irradiation tests were carried out for enough long time for total doses to be over expected threshold values. Other components except the CCD camera showed a very high radiation hardening characteristic. Characteristic changes at different total doses were investigated and threshold values to warrant at least their performance without a deterioration were evaluated as a result of the irradiation tests.

  • PDF

Effect of Intake Pressure on Emissions and Performance in Low Temperature Combustion Operation of a Diesel Engine (디젤 저온연소 운전 영역에서 흡기압이 엔진 성능에 주는 영향)

  • Lee, Sun-Youp;Chang, Jae-Hoon;Lee, Yong-Gyu;Oh, Seung-Mook;Kim, Yong-Rae;Kim, Duk-Sang
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.20 no.1
    • /
    • pp.88-94
    • /
    • 2012
  • One of the effective ways to reduce both $NO_x$ and PM at the same time in a diesel CI engine is to operate the engine in low temperature combustion (LTC) regimes. In general, two strategies are used to realize the LTC operation-dilution controlled LTC and late injection LTC - and in this study, the former approach was used. In the dilution controlled regime, LTC is achieved by supplying a large amount of EGR to the cylinder. The significant EGR gas increases the heat capacity of in-cylinder charge mixture while decreasing oxygen concentration of the charge, activating low temperature oxidation reaction and lowering PM and $NO_x$ emissions. However, use of high EGR levels also deteriorates combustion efficiency and engine power output. Therefore, it is widely considered to use increased intake pressure as a way to resolve this issue. In this study, the effects of intake pressure variations on performance and emission characteristics of a single cylinder diesel engine operated in LTC regimes were examined. LTC operation was achieved in less than 8% $O_2$ concentration and thus a simultaneous reduction of both PM and $NO_x$ emission was confirmed. As intake pressure increased, combustion efficiency was improved so that THC and CO emissions were decreased. A shift of the peak Soot location was also observed to lower $O_2$ concentration while $NO_x$ levels were kept nearly zero. In addition, an elevation of intake pressure enhanced engine power output as well as indicated thermal efficiency in LTC regimes. All these results suggested that LTC operation range can be extended and emissions can be further reduced by adjusting intake pressure.

A Study on Improvement of Durability for Run-out Table Roller with Hot Rolling by Porous Self-fluxing Alloy Coating (다공질 자용성 합금 피복에 의한 열간 압연용 런-아웃 테이블 롤러의 내구성 향상에 관한 연구)

  • Bae, Myung-Whan;Park, Byoung-Ho;Jung, Hwa
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.36 no.2
    • /
    • pp.276-285
    • /
    • 2012
  • The objective of this research is to develop the coating technique by a porous self-fluxing alloy for improving the mechanical properties of run-out table roller surface with the hot rolling. To enhance the durability of run-out table roller with the hot rolling, the high hardness of roller surface should be maintained at high temperatures, and the improvement of wear resistance, corrosion resistance, heat resistance, burn resistance and adhesion resistance should be maintained. In order to be able to transport reliably a hot rolled steel sheet, also, the appropriate friction coefficient on the roller surface should be maintained and the slip between roller and steel should not occur. In this study, the wear resistance of roller increases after the self-fluxing alloy is changed to a cermet by adding the tungsten carbide(WC), and the coefficient of friction increases and the ability of grip is improved because the porosities are made by coating with fine iron powder on the roller surface. As a result, it is found that the ability of grip between the steel and the roller coated by a porous self-fluxing alloy contained to 5 ~ 10 wt% of Fe in the coating layer is improved compared to the roller coated by Ni-Cr. This is because the porosities are made after Fe contained in the roller is partially alloyed by heating with a furnace in the fusing process and the rest is eliminated by oxidation and dissolution.

The Method of Exposure Determination for Digital Infrared Photography in Forensic Field (법과학 분야에서 디지털 적외선 사진을 위한 노출 결정 방법)

  • Kim, Sang-Ki;Kim, Yoo-Jin
    • The Journal of the Korea Contents Association
    • /
    • v.14 no.2
    • /
    • pp.181-191
    • /
    • 2014
  • In the past, making IR photography needed somewhat complicated process, so its application fields were limited. However, it has become easy to make IR photography with advanced digital technology, so it is expected that the fields of IR photography and existing limit due to difficult making process will be expanded. Therefore, in this study, it is decided that the need of IR standard chart which allows us to manage exposure and tone of IR photography for scientific purpose will increase. Two methods were used to make IR standard chart. First method is to use aluminum. When aluminum has oxide coating through anodic oxidation, it has high durability, corrosion resistance and heat resistance. Also, IR reflectance of aluminum can be controlled in some degree depending on the thickness of oxide coating. Second method is to use pigments. Yellow 10P150 pigment is used for the brightest patch. This pigment is appropriate in this study due to high heat resistance and IR reflectance. Carbon black is used for the darkest patch. Carbon black absorbs much IR, and its color is not faded by any source of light. IR reflectance is adjusted elaborately by mixing two pigments. Finally, 6 patches are selected with consideration for actual IR reflectance of patches. As a result, IR reflectance of random subjects can be known approximately and IR photographs can have appropriate contrast with the IR standard chart.