• Membrane Journal
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• v.23 no.6
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• pp.409-417
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• 2013

Adsorptive permeation hollow fiber membrane (APM) has been developed for effectively separating $CO_2$ from gas mixture. Inside the APM, zeolite 13X particles were uniformly dispersed without covering their surfaces by a symmetric porous structure of polypropylene lattice. In this study, $CO_2/N_2$ mixture was used as a simulated gas mixture. Separation was achieved by adsorbing $CO_2$ on the zeolite particles in the APM and then permeating $N_2$ into permeate side in passing all the feed gas through the APM. Adsorptive permeation tests were carried out with a set of APM modules, and the adsorptive permeation performances of the modules were analyzed from the test results. After saturation of the adsorbent with $CO_2$, the APM was regenerated by desorption of $CO_2$ from it through vacuuming both inside of outside of the APM hollow fiber, and the regeneration process of the APM by vacuuming was discussed in terms of regeneration efficiency and energy consumption.

• Clean Technology
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• v.19 no.4
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• pp.370-378
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• 2013

This review has shown the capability of MOFs and ZIFs materials to adsorb $CO_2$ under typical PSA temperatures and pressures. The usual operating conditions are adsorption temperatures of $15{\sim}40^{\circ}C$ and adsorption pressures of 4~6 bar based on numerous PSA processes which are widely employed in gases industry for adsorptive separation of $CO_2$. The extent of $CO_2$ adsorption on the microporous materials depends on the metal species and organic linkers existing in the frameworks. The pore size and the surface area, and the process variables are the key parameters to be associated with the efficiency of the adsorbents, particularly adsorption pressures if other variables are comparable each other. The MOFs and ZIFs materials require high pressures greater than 15 bar to yield significant $CO_2$ uptakes. They possess a $CO_2$ adsorption capacity which is very similar to or less than that of conventional benchmark adsorbents such as zeolites and activated carbons. Consequently, those materials have been much less cost-effective for adsorptive $CO_2$ separation to date because of very high production price and the absence of commercially-proven PSA processes using such new adsorbents.

• Journal of Environmental Science International
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• v.23 no.5
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• pp.943-962
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• 2014

Industrial gas drying, dilute gas mixtures purification, air fractionation, hydrogen production from steam reformers and petroleum refinery off-gases, etc are conducted by using adsorptive separation technology. The pressure swing adsorption (PSA) has certain advantages over the other methods, such as absorption and membrane, that are a low energy requirement and cost-effectiveness. A key component of PSA systems is adsorbents that should be highly selective to a gas being separated from its mixture streams and have isotherms suitable for the operation principle. The six standard types of isotherms have been examined in this review, and among them the best behavior in the adsorption of $CO_2$ as a function of pressure was proposed in aspects of maximizing a working capacity upon excursion between adsorption and desorption cycles. Zeolites and molecular sieves are historically typical adsorbents for such PSA applications in gas and related industries, and their physicochemical features, e.g., framework, channel structure, pore size, Si-to-Al ratio (SAR), and specific surface area, are strongly associated with the extent of $CO_2$ adsorption at given conditions and those points have been extensively described with literature data. A great body of data of $CO_2$ adsorption on the nanoporous zeolitic materials have been collected according to pressure ranges adsorbed, and these isotherms have been discussed to get an insight into a better $CO_2$ adsorbent for PSA processes.

• Applied Chemistry for Engineering
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• v.20 no.6
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• pp.663-669
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• 2009

The honeycomb adsorbent was prepared for adsorbing and seadsorbent was prepared by using zeolite sheet, which contained zeolite as component. The steady-state adsorption properties and surface morphologies were analyzed and breakthrough characteristics were ananlyzed by providing 16% carbon dioxide mixed gas. By thermal regeneration, carbon dioxide concentration properties were analyzed, and the adsorptive separation process was compared between thermal swing adsorption and pressure swing adsorption after adsorbent temperature change during heating. The breakthrough results of the honeycomb showed possibility parating carbon dioxide from combustion exhaust gas, which had deep impact on climate change, and the characteristics of the adsorbent were studied. Na-X zeolite was coated on a honeycomb prepared with ceramic sheet or active carbon sheet so that the two honycomb can be used at high temperature. Third honeycomb of rotary adsorptive concentration process.

• Applied Chemistry for Engineering
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• v.31 no.2
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• pp.179-186
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• 2020

In this study, chitosan/zeolite composites were prepared by using basalt-based zeolite impregnated with aqueous chitosan solution for the adsorptive separation of CO₂. The prepared composites were characterized by scanning electron microscopy (SEM), Fourier-transform infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS), and nitrogen adsorption analysis. In addition, the adsorption equilibrium isotherms for CO₂ and N₂ were measured at 298 K using a volumetric adsorption system, and the results were analyzed by applying adsorption isotherm equations (Langmuir, Freundlich, and Sips) and energy distribution function. It was found that CO₂ adsorption capacities were well correlated with the structural characteristics of chitosan and zeolite, and the ratio of elements [N/C, Al/(Si + Al)] formed on the surface of the composite. Moreover, the CO₂/N₂ adsorption selectivity was calculated under the mixture conditions of 15 V : 85 V, 50 V : 50 V, and 85 V : 15 V using the Langmuir equation and the ideal adsorption solution theory (IAST).