• Title/Summary/Keyword: Adsorption process

Search Result 1,395, Processing Time 0.024 seconds

Distribution of Some Environmental Radionuclides in Rocks and Soils of Guemjeong-Gu Area in Busan, Korea (부산시 금정구 일대 암석 및 토양에서 일부 환경방사성 핵종들의 분포 특성)

  • Lee, Hyo-Min;Moon, Ki-Hoon;Kim, Jin-Seop;Ahn, Jung-Keun;Kim, Hyun-Chul
    • The Journal of the Petrological Society of Korea
    • /
    • v.17 no.3
    • /
    • pp.179-190
    • /
    • 2008
  • The distribution characteristics of some major environmental radionuclides ($^{40}K$, $^{228}Ac$, $^{226}Ra$, $^{222}Rn$) and U in rocks, soils and soil gas were studied at Geumjeong-Gu, Busan, Korea. The activities of radionuclides in granitic rocks are decreased in the odor of $^{40}K$>thorium decay series>uranium decay series. This reveals that Th was relatively more enriched in granitic rocks than U. The U content and activity of $^{226}Ra$ and $^{228}Ac$, however, don't reflect the fractionation sequence of granitic rocks in the study area. The activities of all these radionuclides and U content in soils are generally higher than in rocks, and their distribution in rocks, soils and soil gas show very low co-relationship. These facts indicate that the activities of radionuclides in soil and soil gas were greatly affected by leaching and adsorption properties of the radionuclides and their parents during weathering and pedogenetic process rather than their concentrations in parent rocks.

Preparation of equine blood typing reagents by isoimmunization (동종면역(同種免疫)에 의한 말항혈청(抗血淸)제조에 관한 연구)

  • Han, Bang-keun;Matsumoto, Hiroshi;Chang, Duk-gi
    • Korean Journal of Veterinary Research
    • /
    • v.30 no.2
    • /
    • pp.145-156
    • /
    • 1990
  • This study was purposed to produce blood typing reagents for classifing Cheju horse's blood group factors. The blood typing reagents were prepared by immunization of sixteen pairs out of fourty eight heads of Cheju horses, and seventeen different blood typing reagents (anti-$A_1$, A', H, Z, $ZZ_2$, C, J, K, $P_1$, Q, R, S, $T_1$, $N_1$, $U_2$, X and $E_2$) were prepared from equine isoimmunization. The result for the reagent production and the variation of agglutinin and hemolysin titer are as follows: 1. Anti-K, R, S, $N_1$, $U_2$ and X acted exclusively as hemolysins whereas anti-J, $P_1$, $T_1$ and $E_2$ acted exclusively as agglutinins, however, Anti-$A_1$, A', H, Z, $ZZ_2$, C and Q reacted both as hemolysins and agglutinins. 2. Among the antibodies in most of the reagents reacted both as hemolysins and agglutinins, But anti-$A_1$, H, Z, $ZZ_2$ and Q elevated higher agglutin titers than hemolysin titers, Anti-A' and anti-C elevated higher hemolysin titers than agglutinin titers. 3. Complex antibody $A_1U_2$ was adsorbed $U_2$ and unified to $A_1$, while complex antibody X $N_1$ went through an adsorption process and produced simple antibody X and $N_1$, respectively. 4. In the hemolytic reaction, anti-K and anti-R showed the highest titer, In the agglutination reaction, anti-Z and anti-$ZZ_2$ showed the highest titer. 5. In the case of No.138~No.140 horse immunization combination and No.133~No.146 horse immunization combination, Although production of complex antibody $CE_2$ and $JP_1$ were expected, only anti-$E_2$ and anti-J were produced respectively. 6. The degree of elevation of antibody titer was varied by the blood types and by the types of donor and recipient combination. The fast elevating types, slow elevating types and types that never elevate the antibody titer were identified.

  • PDF

Experimental and FEMLAB Simulation Study of Ibuprofen Racemate Separation in HPLC (Ibuprofen Racemate의 HPLC 분리실험과 FEMLAB 전산모사 연구)

  • Lee, Eun;Chang, Sang-Mork;Kim, Jong-Min;Kim, Woo-Shick;Kim, In-Ho
    • KSBB Journal
    • /
    • v.21 no.3
    • /
    • pp.224-229
    • /
    • 2006
  • FEMLAB is a powerful interactive environment for modeling, solving all kinds of scientific and engineering problems based on partial differential equations(PDEs). Separation process of chiral compound in HPLC columns was simulated by FEMLAB. To study change of elution profile with isotherm models, non-competitive and competitive Langmuir adsorption isotherm were adopted. Separated material was (R, S)-ibuprofen [(R, S)-2-(4-isobutyl phenyl) propionic acid], an anti-inflammatory agent, which retain the pharmacological activity in the (S)-(+)-enantiomer. Sample concentrations were changed from 0.5 mg/ml to 2.0 mg/ml at a flow rate of 1 ml/min and flow rate varied from 1 ml/min to 3 ml/min at an ibuprofen concentration of 2.0 mg/ml and $20{\mu}l$ of injection volume. Simulated results were well fitted with experimental data.

Analysis of Influence Factors for Remediation of Contaminated Soils Using Prefabricated Vertical Drains (연직배수재를 이용한 오염지반 복원의 영향인자 분석)

  • Park, Jeongjun;Shin, Eunchul
    • Journal of the Korean GEO-environmental Society
    • /
    • v.9 no.2
    • /
    • pp.39-46
    • /
    • 2008
  • Due to the growth in industrialization, potential hazards in subsurface environments are becoming increasingly significant. The extraction of the contaminant from the soil and movement of the water are restricted due to the low permeability and adsorption characteristics of the reclaimed soils. There are a number of approaches to in-situ remediation that are used in contaminated sites for removing contaminants. These include soil flushing, dual phase extraction, and soil vapor extraction. Among these techniques, soil flushing was the focus of the investigation in this paper. Incorporated technique with PVDs has been used for dewatering from fine-grained soils for the purpose of ground improvement by means of prefabricated vertical drain systems. The laboratory model tests were performed by using the flushing tracer solutions for silty soils and recorded the tracer concentration changes with the elapsed time and flow rates. The modeling was intended to predict the effectiveness and time dependence of the remediation process. Modeling has been performed on the extraction, considering tracer concentration and laboratory model test characteristics. The computer model used herein are SEEP/W and CTRAN/W, this 2-D finite element program allows for modeling to determine hydraulic head and pore water pressure distribution, efficiency of remediation for the subsurface environment. It is concluded that the coefficient of permeability of contaminated soil is related with vertical velocity and extracted flow rate. The vertical velocity and extracted flow rate have an effect on dispersivity and finally are played an important role in-situ soil remediation.

  • PDF

Characteristics of Shear Strength and Consolidation Behavior of Soft Ground according to Stage Fill (단계성토에 따른 연약지반의 전단강도 및 압밀거동 특성)

  • Bang, Seongtaek
    • Journal of the Korean GEO-environmental Society
    • /
    • v.21 no.7
    • /
    • pp.17-26
    • /
    • 2020
  • The soft ground in the southwest coastal area composed of marine clay is greatly influenced by sediment composition, particle size distribution, particle shape, adsorption ions and pore water characteristics, tide and temperature. In addition, the geotechnical properties are very complex due to stress history, change in pore water, dissolution process and gas formation. In this study, the physical and mechanical properties of the soft ground were evaluated through field tests and laboratory tests to investigate the strength increase characteristics according to consolidation on the soft ground in the southwest coast. In addition, in order to understand the consolidation behavior of soft ground such as subsidence, pore water pressure, horizontal displacement of soil by embankment load, measuring instruments such as pore water pressuremeter, settlement gauge, inclinometer and differential settlement gauge was installed, and a piezocon penetration test was carried out step by step to confirm the increase in shear strength of the ground. Through this, it was confirmed that the shear strength of the ground is increased according to the stages of filling. In addition, by evaluating the properties of consolidation behavior, strength increase and consolidation prediction by empirical methods and theories were compared to analyze the characteristics of strength increase rate and consolidation behavior in consideration of regional characteristics.

The Microstructure Control of SiC Ceramics Containing Porcelain Scherben (자기파를 함유한 SiCwlf 세라믹스의 미세구조 제어)

  • 이성희
    • Journal of the Korean Ceramic Society
    • /
    • v.32 no.5
    • /
    • pp.626-634
    • /
    • 1995
  • The SiC-porcelain powder mixtures containing 51.9wt% SiC are produced as by-products from the surface abrasion process of porcelain cores. This raw powders were used as starting materials for the synthesis of SiC containing ceramics. The specimen, which was fired at 135$0^{\circ}C$ from raw powders, had SiC, $Al_{2}O_{3}$, , cristobalite, mullite as crystalline phases, and the fractured microstructure showed dispersed SiC crystalline particles almost wetted with glassy matrix and spherical pores. Although the oxidation of SiC containing powder compacts wetted with glassy matrix and spherical pores. Although the oxidation of SiC containing powder compacts started at the range of 600~80$0^{\circ}C$ form the analysis of weight gain, the presence of $SiO_{2}$ crystallien phase and cristobalite was confirmed at 100$0^{\circ}C$ by XRD analysis. Mullitization of specimens was accelerated by preheating before the final firing. The specimen sintered at 135$0^{\circ}C$ after 100$0^{\circ}C$ preheating consisted of SiC, cristobalite, mullite as crystalline phases, and revealed 2.24g/$cm^{3}$ bulk density, 11.73% water adsorption, porous microstructure with small amount of glassy phase. SiC contents of specimens, which was 51.9 wt% in the raw powders, reduced to 37~22 wt% after firing at 135$0^{\circ}C$ depending on the preheating condition.

  • PDF

Dyeing Properties and Color of Silk Fabrics Dyed with Safflower Yellow Dye (홍화 황색소 견섬유에 대한 염색성과 색상)

  • Shin, Youn-Sook;Son, Kyung-Hee;Yoo, Dong-Il
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.32 no.6
    • /
    • pp.928-934
    • /
    • 2008
  • The objective of this study is to investigate the dyeing properties of safflower yellow dye on silk for the standardization of dyeing process and color reproducibility. Yellow colorants were water-extracted from safflower petals, concentrated, and freeze-dried to obtain colorants powder. The effects of dye concentration, dyeing temperature, and pH of dye bath were studied in terms of dye uptake and shade. Fastness to dry cleaning and light was evaluated. Dye uptake increased with raising temperature and brighter and more vivid yellow shade was obtained when dyed at $30^{\circ}C$. As colorants concentration increased, dye uptake increased progressively and the shade got darker and deeper. Maximum color strength was obtained at pH 3.5. It was speculated that the adsorption of colorants seemed to occur mainly by hydrogen bonding and physical force at pH 5.5 and by ionic bonding as well as hydrogen bonding below isoelectric point(pH 3.8-4.0). The results of reproducibility test showed acceptable color difference in the range of $1.11{\sim}2.01$. Washing fastness was fairly good as 4/5 rating, while light fastness was 2/3 rating.

Effect of Artificial Zeolite on Fermentation and Emission of Ammonia and Methane during Animal Waste Composting (인공제올라이트 처리가 가축분 퇴비의 발효 및 암모니아, 메탄가스 발생에 비치는 영향)

  • Lee, Deog-Bae;Kim, Jong-Gu;Lee, Kyung-Bo;Lee, Sang-Bok;Kim, Jae-Duk
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.33 no.5
    • /
    • pp.361-368
    • /
    • 2000
  • This study was carried out to investigate the influence of artificial zeolite on the change of temperature, gas emission, water content and chemical properties during the composting process with the mixture of animal feces, broken bark and extruded rice hull. Artificial zeolite was added 0, 0.5, 1, 3 and 5% volume of the raw composting material, and proceeded 1.2m every day with mobile stacking escalator. Temperature was increased, and water content was decreased in the composting pile by addition of artificial zeolite. This caused to accelerate decomposition of organic matter during composting. $NH_3$ was emitted the highest at 6th day after stacking, then decreased gradually. And addition of artificial zeolite caused to decrease greatly in $NH_3$ emission from composting pile. As result of this, content of nitrogen in the compost was increased by addition of artificial zeolite. Emission of $CH_4$ was the highest at early stacking stage, and that was decreased drastically at 8th day. Emission of $CH_4$ was also decreased greatly by addition of artificial zeolite at 5th days after stacking. It may be resulted from adsorption of $CH_4$ into the molecular sieve structure of artificial zeolite and low water content by high temperature fermentation.

  • PDF

Stability Enhancement of IZOthin Film Transistor Using SU-8 Passivation Layer (SU-8 패시베이션을 이용한 솔루션 IZO-TFT의안정성 향상에 대한 연구)

  • Kim, Sang-Jo;Yi, Moonsuk
    • Journal of the Institute of Electronics and Information Engineers
    • /
    • v.52 no.7
    • /
    • pp.33-39
    • /
    • 2015
  • In this work, SU-8 passivated IZO thin-film transistors(TFTs) made by solution-processes was investigated for enhancing stability of indium zinc oxide(IZO) TFT. A very viscous negative photoresist SU-8, which has high mechanical and chemical stability, was deposited by spin coating and patterned on top of TFT by photo lithography. To investigate the enhanced electrical performances by using SU-8 passivation layer, the TFT devices were analyzed by X-ray phtoelectron spectroscopy(XPS) and Fourier transform infrared spectroscopy(FTIR). The TFTs with SU-8 passivation layer show good electrical characterestics, such as ${\mu}_{FE}=6.43cm^2/V{\cdot}s$, $V_{th}=7.1V$, $I_{on/off}=10^6$, SS=0.88V/dec, and especially 3.6V of ${\Delta}V_{th}$ under positive bias stress (PBS) for 3600s. On the other hand, without SU-8 passivation, ${\Delta}V_{th}$ was 7.7V. XPS and FTIR analyses results showed that SU-8 passivation layer prevents the oxygen desorption/adsorption processes significantly, and this feature makes the effectiveness of SU-8 passivation layer for PBS.

A Study of Marine Response system for the tar type waste oil (타르성 기름찌꺼기 해상방제 방안에 관한 연구)

  • Jang, Duck-Jong;Kim, Tae-Ho;Yang, Kyung-Uk;Na, Sun-Cheol;Nam, Kwang-Hee
    • Proceedings of KOSOMES biannual meeting
    • /
    • 2008.05a
    • /
    • pp.117-120
    • /
    • 2008
  • As we can see at the oil spill occident on the coast of Taean, the viscosity of the spilled oil becomes thicker as time goes by. It becomes waste oil with the form of tar. It moves to other areas following a tide. When the temperature of the water goes up, the viscosity becomes lighter and forms oil film. It repeats the process spreading to and polluting extensive areas where the tide reaches. People have used hand nets to collect waste oil of tar at the sea. But it is very difficult for them to collect the tar type waste oil spread on large areas before it reaches to the beach. This paper tried to find a way to collect the tar type waste oil efficiently. It used absorption mat of boom type that uses the attachment characteristics of the tar type waste oil and floating waste recovery device of net type. It tested the possibility of using the devices at the oil spill accident on the beach of Taean. The result showed that net type recovery device was much more efficient in collecting the waste oil in short time than the hand net system of people. It confirmed that the net type recovery device could be used to collect tar type waste oil.

  • PDF