• Title/Summary/Keyword: Adsorption, Oxide

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Adsorption properties of magnesium oxide matrix using anthracite and vermiculite (안트라사이트와 버미큘라이트를 혼입한 산화마그네슘 경화체의 흡착특성)

  • Kim, Dae-Yeon;Pyeon, Su-Jeong;Lee, Dong-Hoon;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.224-225
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    • 2018
  • Modern people are more interested in the indoor environment as they spend more time indoors than in the past. Among the air pollutants in the indoor air, ladon gas is a colorless, tasteless, odorless, inert gas produced by nuclear decomposition of naturally occurring uranium in rocks and soils. It has been proven that ladon gas is introduced into the room through cracks on the floor of the building or basement wall, and it causes various diseases such as lung cancer when exposed to radon during human breathing. The US Environmental Protection Agency (EPA) specifies 4pCi / L as a necessary measure for radon, and the Korea Environmental Protection Agency has implemented comprehensive indoor radon management measures since 2007. Therefore, in this study, we intend to adsorb and reduce radon in indoor air pollutants.

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Characteristics of Oxidation System for Superconductor Thin Film( II ) (초전도 박막 제작을 위한 산화 시스템의 특성( II ))

  • An, I.S.;Park, Y.P.;Lim, J.K.;Jang, K.U.;Lee, H.K.;Kim, G.Y.;Lee, J.U.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.264-267
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    • 2002
  • An ozone condensation system is evaluated from the viewpoint of an ozone supplier for oxide thin film growth. Ozone is condensed by the adsorption method and its concentration is analyzed by three methods; ultraviolet absorption, thermal decomposition and Q-mass analyzing methods. Thermal decomposition method is found to be available to the concentration evaluation from dilution to highly condensed ozone. The highest ozone concentration condensed by the adsorption method is evaluated to be 97 mol%

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Current Variation in ZnO Thin-Film Transistor under Different Annealing Conditions (ZnO 박막트랜지스터의 어닐링 조건에 따른 전류 변화)

  • Yoo, Dukyean;Kim, Hyoungju;Kim, Junyeong;Jo, Jungyol
    • Journal of the Semiconductor & Display Technology
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    • v.13 no.1
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    • pp.63-66
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    • 2014
  • ZnO is a wide bandgap (3.3 eV) semiconductor with high mobility and good optical transparency. However, off-current characteristics of ZnO thin-film transistor (TFT) need improvements. In this work we studied the variation in ZnO TFT current under different annealing conditions. Annealing usually modifies gas adsorption at grain boundaries of ZnO. When oxygen is adsorbed, electron density decreases due to strong electronegativity of the oxygen, and TFT current decreases as a result. Our experiments showed that current increased after vacuum annealing and decreased after air annealing. We explain that the change of off-current is caused by the desorption and adsorption of oxygen at the grain boundaries.

Investigation of Cell Behavior on Nanoporous Surface (나노기공 표면에서의 세포 행동양식에 관한 연구)

  • Chung, Sung-Hee;Yoon, Won-Jung;Min, Jun-Hong
    • KSBB Journal
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    • v.27 no.1
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    • pp.45-50
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    • 2012
  • In this paper, we investigated the effect of nanostructure on the cell behaviors such as adhesion and growth rate. Nanoporous structures with various diameters (30, 40, 45, 50, 60 nm) and 500 nm of the depth were fabricated using the anodizing method. The water contact angle of the surface consisting of nanopores with 30 nm diameter was 40 degree and those were 60~70 degree in cases of nanopores with over 40 nm diameter. Hela cells were cultivated on various nanoporous structure surface to investigate the cell behavior on nanostructure. As a result, Hela cells preferred 30 nm diameter nanoporous surface that has lower water contact angle. This result was confirmed by protein adsorption experiment and scanning electron microscope investigation.

The Study of Structre-Peoperty-Process in Alumina Coating of Steel by Chemical Vapour Deposition Process (화학증착법에 의한 강에의 알루미나 피복에서 구조-성질-과정에 관한 연구)

  • 최진일
    • Journal of the Korean institute of surface engineering
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    • v.22 no.3
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    • pp.135-144
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    • 1989
  • Aluminium Oxide was deposited with a C.V.D.-technique on various substrates. The effects of various treating condition such as temperature, time, heat resistance and composition of substrates were investigated in order to understand the relationship of structure, property and process. Grain size depends upon the activity of adsorption siite and coarsened with increasing temperature and time. Deposition rate decreases in order of electrolytic iron, carbon steel STS430 and STS304, since the active site for adsorption of reactant was more decreased for Cr and Ni than Fe. Oxidation resistance of alumina coated specimens improved markedely and that of stainless steel was prominent.

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Fine Dust Adsorption Properties of Cement Matrix Mixed with Expanded Graphite (팽창흑연을 혼입한 시멘트 경화체의 흡착 특성)

  • Lee, Jin-Won;Lee, Chang-Woo;Hwang, Woo-Jun;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.105-106
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    • 2022
  • Now, the world is increasingly anxious about fine dust due to abnormal temperatures caused by global warming and increased yellow dust caused by desertification, and the World Health Organization (WHO) pointed out that more than 99% of the world's population is exposed to fine dust. In this situation, the reduction rate of fine dust and carbon dioxide of the matrix was tested by using expanded graphite, an eco-friendly and porous material, to improve air quality. As a result of the test, since expanded graphite is a material that expands between layers compared to conventional graphite, the reduction rate of fine dust and carbon dioxide decreases as the replacement rate of expanded graphite increases.

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Adsorption Characteristics of Co(II), Ni(II), Cr(III) and Fe(III) Ions onto Cation Exchange Resin - Application to the Demineralizing Process in a Primary Coolant System of PWR (양이온교환수지에 대한 Co(II), Ni(II), Cr(III), Fe(III) 이온의 흡착 특성 - 원자로 일차 냉각재 계통내 탈염 공정에의 적용)

  • Kang, So-Young;Lee, Byung-Tae;Lee, Jong-Un;Moon, Seung-Hyeon;Kim, Kyoung-Woong
    • Journal of Radiation Protection and Research
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    • v.27 no.1
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    • pp.27-35
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    • 2002
  • Characteristics of Amberlite IRN 77, a cation exchange resin, and the mechanisms of its adsorption equilibria with Co(II), Ni(II), Cr(III) and Fe(III) ions were investigated for the application of the demineralizing process in the primary coolant system of a pressurized water reactor (PWR). The optimum dosage of the resin for removal of the dissolved metal ions at $200mgL^{-1}$ was 0.6 g for 100 mL solution. Most of each metal ion was adsorbed onto the resin in an hour from the start of the reaction. Each metal adsorption onto the resin could be well represented by Langmuir isotherms. However, in the case of Fe(III) adsorption, continuous formation of Fe-oxide or -hydroxide and its subsequent precipitation inhibited the completion of the equilibrium between the metal and the adsorbent Cobalt(II) and Ni(II), which have an equivalent electrovalence, were adsorbed to the resin with a similar adsorption amount when they coexisted in the solution. However, Cr(III) added to the solution competitively replaced Co(II) and Ni(II) which were already adsorbed onto the resin, resulting in desorption of these metals into the solution. The result was likely due to a higher adsorption affinity of Cr(III) than Co(II) and Ni(II). This implies that the interactively competitive adsorption of multi-cations onto the resin should be fully considered for an efficient operation of the demineralizing ion exchange process in the primary coolant system.

A Study on the Mill Scale Pretreatment and Magnetite Production for Phosphate Adsorption (인 흡착을 위한 Mill Scale 전처리 및 Magnetite 제조 연구)

  • Chun, Hyuncheol;Choi, Younggyun
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.4
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    • pp.246-252
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    • 2015
  • In steel factory, hot roller cleaning process produces a lot of iron oxide particles called as mill scale. Major components of these particles are wustite (FeO), magnetite ($Fe_3O_4$), and hematite ($Fe_2O_3$). In this study, we tried to produce pure magnetite from the mill scale because of the largest phosphate adsorption capacity of the magnetite. The mill scale was treated with acid (HCl+$H_2O_2$), base (NaOH), and acid-base ($H_2SO_4$+NaOH). Batch adsorption tests showed the acid and/or base treatment could increase the phosphate adsorption capacity of the iron oxides from 0.28 to over 3.11 mgP/g. Magnetite, which could be obtained by acid and base treatment of the mill scale, showed the best adsorption capacity. From the kinetic analysis, both Freundlich and Langmuir isotherm well described the phosphate adsorption behavior of the magnetite. In Langmuir model, maximum phosphate adsorption capacity was found to be 5.1 mgP/g at $20^{\circ}C$.

Physicochemical Properties of Forest Soils Related to Sulfate Adsorption (황산이온의 흡착에 관여하는 산림토양의 물리화학적 특성)

  • Lee, Seung-Woo;Park, Gwan-Soo;Lee, Choong-Hwa;Kim, Eun-Young
    • Korean Journal of Soil Science and Fertilizer
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    • v.37 no.6
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    • pp.371-377
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    • 2004
  • Sulfate adsorption in forest soils is a process of sulfur dynamics playing an important role in plant uptake, cation movement, acid neutralization capacity and so on. The relationship between sulfate adsorption and some physicochemical properties of four forest soils was investigated. Extractable sulfate contents and sulfate adsorption capacity (SAC) in the forest soils varied much among study sites. Extractable sulfate contents were more in sub-surface soils with lower organic matter and greater Al and Fe oxides than in surface soils. The average contents of $Al_d$ and $Fe_d$ in the sub-surface soils were 8.49 and $12.45g\;kg^{-1}$, respectively. Soil pH, cation exchange capacity and clay content were positively correlated with the extractable sulfate contents and SAC. Organic carbon content, however, was negatively correlated with the extractable sulfate contents, implying the competitive adsorption of sulfate with soil organic matter. Considerably significant correlation was found between inorganic + amorphous Al and Fe oxides and the sulfate adsorption, but crystalline Al and other fractions of Fe oxide showed no correlation. Relatively close relationship between the adsorbed sulfates and soil pH, cation exchange capacity, or amorphous Al oxides indicates that the accelerated soil acidification may substantially reduce the potential for sulfate adsorption contributing to sulfur flux in forest ecosystems.

Preparation of PVdF/Fe3O4-GO (MGO) Composite Membrane by Using Electrospinning Technology and its Arsenic Removal Characteristics (전기방사법을 이용한 PVdF/Fe3O4-GO(MGO) 복합 분리막 제조 및 비소 제거 특성평가)

  • Jang, Wongi;Hou, Jian;Byun, Hongsik;Lee, Jae Yong
    • Membrane Journal
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    • v.26 no.6
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    • pp.480-489
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    • 2016
  • In this study, the PVdF/MGO composite nanofiber membranes (PMGs) introducing Iron oxide-Graphene oxide ($Fe_3O_4/GO$, Metallic graphene oxide; MGO) was prepared via electrospinng method and its arsenic removal characteristics were investigated. The thermal treatment was carried out to improve the mechanical strength of nanofiber membranes and then the results showed that of outstanding improvement effect. However, in case of PMGs, the decreasing tendency of mechanical strength was indicated as increasing MGO contents. From the results of pore-size analysis, it was confirmed that the porous structured membranes with 0.3 to $0.45{\mu}m$ were prepared. For the water treatment application, the water flux measurement was carried out. In particular, PMG2.0 sample showed about 70% improved water flux results ($153kg/m^2h$) compared to that of pure PVdF nanofiber membrane ($91kg/m^2h$) under the 0.3 bar condition. In addition, the PMGs have indicated the high removal rates of both As(III) and As(V) (up to 81% and 68%, respectively). Based on the adsorption isotherm analysis, the adsorption of As(III) and As(V) ions were both more suitable for the Freundlich. From all of results, it was concluded that PVdF/MGO composite nanofiber membranes could be utilized as a water treatment membrane and for the Arsenic removal applications.