• Title/Summary/Keyword: Adsorber

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Emission Reduction using Unburned Exhaust Gas Ignition (미연배기가스 점화 기술을 이용한 배기저감)

  • 김득상;강봉균;양창석;조용석
    • Transactions of the Korean Society of Automotive Engineers
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    • v.11 no.3
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    • pp.39-47
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    • 2003
  • UEGI (Unburned Exhaust Gas Ignition) is an alternative method for fast light-off of a catalyst. It ignites the unburned exhaust mixture using two glow plugs installed in the upstream of the close-coupled catalysts. In addition, a hydrocarbon adsorber was applied to the UEGI, for more effective reduction of HC emission. Engine bench tests show that the CCC reaches the light-off temperature laster than the baseline exhaust system and HC and CO emissions are reduced significantly during the cold start. From the vehicle test, it was observed that a few amount of HC emission was reduced even the catalysts were aged. It is expected to develop a solution kit applicable to a new vehicle or used one, to meet the emission regulation

Study on Adsorption Characteristics of Tharonil from Aqueous Solution by Activated Carbon Adsorption (활성탄에 의한 Tharonil의 흡착특성에 관한 연구)

  • 이종집;유용호
    • Journal of the Korean Society of Safety
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    • v.15 no.4
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    • pp.88-94
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    • 2000
  • The adsorption characteristics of Tharonil on granular activated carbon were experimentally investigated in an adsorber and in a packed column. It was estabilished that the adsorption equilibrium of Tharonil on granular activated carbon was more successfully fitted by Freundlich isotherm equation than Langmuir isotherm equation in the concentration range from 1 to 1000 mg/1. Intraparticle diffusivities (pore and surface diffusivity) of Tharonil were estimated by the concentration-time curve and adsorption isotherm. The estimated values of pore diffusivity and surface diffusivity are $6.70{\times}10^{-6}$ and $2.0{\times}10^{-9}cm^2/s$, respectively. From comparison of intraparticle diffusivities, it was found that surface diffusion was the limiting step for adsorption rate. The break time and breakthrough curve predicted by constant pattern-linear driving force model were shown to agree with the experimental results.

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Effect of pore characteristics of activated carbon on adsorption of natural organic matter (활성탄의 세공이 자연유기물질의 흡착에 미치는 영향)

  • Pak, Jung-Sun;Hong, Seong-Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.2
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    • pp.249-255
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    • 2011
  • It is complicate problem to optimize removing natural organic matter (NOM) by activated carbon in drinking water treatment because the activated carbon has heterogeneous surface area and pore structure. Seven different coals based activated carbons which have different pore structures were used in the study. Sand filtered effluents which normally used as GAC adsorber influent were used. The molecular weight distribution showed that most of the NOM was bigger than 10,000Da. In this study, systematical approaches such as characteristics of surface area and pore volume were evaluated on NOM adsorption. Especially, the adsorption capacities for NOM were evaluated by effect of micro-pores and meso-pores in surface area and pore structure. The results show that the higher ratio of meso-pore compare to the micro-pore has not only the better adsorption capacities for NOM but also the higher strongly-adsorbable fraction. Therefore, the overall adsorption capacity is increased with higher meso-pore ratio with existing of reasonable micro-pore surface area and volume.

Fixed Bed Study for a Detritiation Adsorber

  • Kim K. R.;Lee M. S.;Paek S.;Yim S. P,;Ahn D. H.;Chung H.;Shim M. H.
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.11b
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    • pp.119-125
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    • 2005
  • A method of predicting the tritium concentration in the air leaving an atmospheric detritiation dryer was modeled for designing a fixed bed dryer and preparing an advanced dryer control. In order to quantify the bed utilization and the dynamic capacity against an inlet humidity and a flow rate, a series of quantitative tests based on the break-through behavior were carried out in an isothermal fixed bed of synthetic zeolites such type as molecular sieve 4A, 5A, 13X and mordenite. The amount of water vapor breaking during the adsorption was estimated to give a breakthrough capacity at the various inlet flow rates and humidity conditions. The molecular sieve 13X exhibited a better adsorption performance at a given bed height.

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Adsorption Charateristics of Tartrazine by Activated Carbon (활성탄에 의한 Tartrazine의 흡착 특성)

  • Yoon, Sung Wook;Lee, Jong-Jib
    • Journal of Korean Society on Water Environment
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    • v.25 no.4
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    • pp.568-572
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    • 2009
  • The adsorption characteristics of tartrazine by granular activated carbon were experimentaly investigated in the batch adsorber and the packed column. The adsorptivity of activated carbon for tartrazine was largely improved by pH control, and 98 percent of initial concentration could be removed at pH 3. It was estabilished that the adsorption equilibrium of tartrazine on granular activated carbon was sucessfully fitted by Freundlich isotherm equation in the concentration range from 50 mg/L to 1,000 mg/L. The characteristics of breakthrough curve of activated carbon packed column, which depend on the design variables such as initial concentration, bed height, and flow rate, were studied.

HCA AND TWC HYBRID SYSTEM FOR REDUCING COLD-START EMISSION

  • Lee, S.C.;Jang, J.H.;Lee, B.Y.;Bae, J.H.;Choung, S.J.
    • International Journal of Automotive Technology
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    • v.5 no.1
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    • pp.1-7
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    • 2004
  • In line with the Super Ultra Low Emission Vehicle (SULEV) regulation, the main idea in this study has been focused on the utilization of hydrocarbon adsorber (HCA) to adsorb the excess hydrocarbons emitted during a period of engine cold-start, As main recipes of HCA materials, many types of zeolite as well as the combination of alumina and precious metals were used, Representative physico-chemical factors of zeolite such as acidic and hydrophobic properties were characterized. The optimum recipe of HCA materials was also determined. Among the acid properties of zeolites, the Si/Al ratio was found to be the most important factor to get higher hydrocarbon adsorption capacity.

Performance of adsorption heat pump with radial shape adsorber heat exchanger for air cooling (공냉식 방사형 열교환기를 갖는 흡착식 히트펌프의 성능)

  • Baek, N.C.;Yang, Y.S.;yoon, E.S.;Lee, J.K.;Joo, M.C.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.9 no.1
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    • pp.73-81
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    • 1997
  • In this experimental study, the air cooling radial shape heat exchanger which influences on the COP and the cooling capacity by heat and mass transfer rate in the adsorbent bed was designed and applied to test its performance for adsorption heat pump(AHP). Zeolite-water was used for the adsorbent-adsorbat pair. As a result, the cooling COP and a cycle period of this adsorption heat pump are 0.28 and 2 hours, respectively, on the condition of none heat recovery from the adsorption reactor(absorber). The other results and recommendations are mainly related to improving the heat and mass transfer inside the absorber to reduce a cycle period.

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기체 방사성물질 제거용 활성탑 내에서의 유속분포 결정시험

  • 강덕원
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05d
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    • pp.88-94
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    • 1996
  • 원자력발전소의 공조계통에 설치되어 운영되는 기체 방사성물질 제거용 첨착 활성탄 탑내에서 균일한 공기 유속분포가 유지되고 있는지를 확인하기 위한 실험을 실시하였다. 본 실험에 사용되는 장비(Tester for Flow Distribution, 이하 TFD라 함)는 원자력발전소에서 사용하는 첨착 활성탄 필터(Adsorber)내의 흡착층을 모방하여 자체에서 제작하였으며, 시험조건들은 실제의 값을 기준으로 적용하였다. 각 위치에서의 보정된 용적 유속을 구하기 위해 자체에서 만든 "FLOWD"라는 계산프로그램을 사용하였으며, 입구 및 출구측 공간에 10" 간격으로 각 6개씩 유속 감지기를 설치하여 면속도를 구하였다. 각 지점에서의 면속도는 평균 0.24449m/s로 각 구간에서의 겉보기 면속도의 분포는 매우 균일한 값을 나타내었으며, 약 2% 이내의 편차로 활성탄 탑내에서의 공기의 흐름이 균일하게 통과함을 확인할 수 있었다.통과함을 확인할 수 있었다.

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Adsorption Characteristics of Nickel, Zinc and Cadmium Ions using Alginate Bead (Alginate Bead를 이용한 니켈, 아연, 카드뮴의 흡착특성에 관한 연구)

  • Jung, Heung-Joe
    • Journal of Integrative Natural Science
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    • v.4 no.2
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    • pp.130-136
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    • 2011
  • This study investigated the adsorption characteristics of nickel, zinc and cadmium ions from the aqueous solution onto the alginate bead. Adsorption equilibrium capacities of the heavy metal ions increased with increasing initial pH of the solution. The adsorption equilibrium isotherm of the heavy metal ions was well represented by Langmuir equation. The magnitude of adsorption capacity of the heavy metal ions onto alginate bead was the order of cadmium > zinc > nickel. Kinetic parameters were measured in a batch adsorber to analyze the adsorption rates of the heavy metal ions. The internal diffusion coefficient of the heavy metal ions in the intraparticle were determined by comparing the experimental concentration curves with those predicted from the surface diffusion model (SDM) and pore diffusion model (PDM). The internal diffusion of the heavy metal ions in the intraparticles was explained by PDM.

Removal of Amaranth by Activated Carbon Adsorption (활성탄 흡착에 의한 Amaranth의 제거)

  • Lee, Jong-Jib;Yoon, Sung-Wook
    • Journal of the Korean Society of Safety
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    • v.24 no.4
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    • pp.34-39
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    • 2009
  • The adsorption characteristics of amatanth by granular activated carbon were experimently investigated in the batch adsorber and the packed column. The adsorptivity of activated carbon for amaranth were largely improved by pH control, and 94 percent of initial concentration(100mg/L) could be removed at pH 9. It was estabilished that the adsorption equilibrium of amaranth on granular activated carbon was sucessfully fitted by Freundlich isotherm equation in the concentration range from 1mg/L to 100mg/L. The characteristics of breakthrough curve of activated carbon packed column, which depend on the design variables such as initial concentration, bed height, and flow rate, were studied.