• Bulletin of the Korean Chemical Society
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• v.30 no.10
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• pp.2259-2264
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• 2009

A new high-energy organic potassium salt, 2-(dinitromethylene)-1,3-diazepentane potassium salt K(DNDZ), was synthesized by reacting of 2-(dinitromethylene)-1,3-diazepentane (DNDZ) and potassium hydroxide. The thermal behavior and non-isothermal decomposition kinetics of K(DNDZ) were studied with DSC, TG/DTG methods. The kinetic equation is $\frac{d{\alpha}}{dT}$ = $\frac{10^{13.92}}{\beta}$3(1 - $\alpha$[-ln(1 - $\alpha$)]$^{\frac{2}{3}}$ exp(-1.52 ${\times}\;10^5$ / RT). The critical temperature of thermal explosion of K(DNDZ) is $208.63\;{^{\circ}C}$. The specific heat capacity of K(DNDZ) was determined with a micro-DSC method, and the molar heat capacity is 224.63 J $mol^{-1}\;K^{-1}$ at 298.15 K. Adiabatic time-to-explosion of K(DNDZ) obtained is 157.96 s.

• Solar Energy
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• v.11 no.2
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• pp.63-69
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• 1991

A Steady laminar natural convection heat transfer from two isothermal square beams attached to a vertical adiabatic plate has been studied numerically. The results have been obtained for dimensionless beam spacings, $0.5{\le}D/L{\le}3.0$, and for Gr=5000-10000 at ${\phi}_2/{\phi}_1=1.0$. 1. The local Nusselt number from the beam surface is increased with the dimension-less beam spacing D/L. but that of the downward surface of the lower beam is almost same as the D/L increases. And, the local Nusselt number from the upward surface of a lower beam is greatly increased with D/L. 2. The beam spacings of the maximum mean Nusselt number for the downward surface of an upper beam and the upward surface of a lower beam occur at. D/L =2.6 and 2.0 respectively. 3. The beam spacing for the maximum total mean Nusselt number occurs at D/L = 2.6.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.29 no.2 s.233
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• pp.189-196
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• 2005

The physical model considered here is a horizontal layer of fluid heated below and cold above with a conducting body placed at the center of the layer. The body has dimensionless thermal conductivities to the fluid of 0.1, 1 and 50. Two-dimensional solution for unsteady natural convection is obtained using an accurate and efficient Chebyshev spectral methodology for different Rayleigh numbers. Multi-domain technique is used to handle a square-shaped conducting body. The results for the case of a conducting body are also compared to those of adiabatic and neutral isothermal bodies. When the dimensionless thermal conductivity is 0.1, a pattern of fluid flow and isotherms and the corresponding time-averaged surface Nusselt number are almost the same as the case of an adiabatic body. When the dimensionless thermal conductivity is 50, a pattern of flow and isotherm and the corresponding surface and time-averaged Nusselt number are similar to those of neutral body. The results for the case of dimensionless thermal conductivity of unity are also compared to those of pure natural convection.

• Transactions of the Korean Society of Automotive Engineers
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• v.21 no.2
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• pp.87-97
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• 2013

Recently the use of gas spring in the combat and commercial vehicle's suspension is increasing. Because of its nonlinear characteristics, the gas spring can support wide range of dynamic loads and gives good ride quality. In design of gas spring, isothermal and adiabatic processes are applied generally, but those processes could not produce heat transfer effect in the simulation. So in this study, heat transfer differential equation and BWR/Ideal state equation are used to calculate the pressure of gas spring which is changing with time. The numerical analysis showed that the pressure of gas spring forms a hysteresis loop in the both of the state equations. But the peak pressure value of BWR equation over 0.1Hz frequency are higher than that of adiabatic process. And the test results showed that the differences between test results and ideal gas equation are smaller than those of BWR equation, so the ideal equation is more accurate than BWR equation in this case.

• Journal of the Korean Society of Safety
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• v.35 no.6
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• pp.32-45
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• 2020

The problem of determining the discharge rates of gases from pressurized vessels through pressure relief devices was dealt with comprehensively. First, starting from basic fluid flow equations, detailed modeling procedures were presented for isentropic nozzle flows and frictional flows in a pipe, respectively. Meanwhile, physical explanations were given to choking phenomena in terms of the acoustic velocity, elucidating the widespread use of Mach numbers in gas flow models. Frictional flows in a pipe were classified into adiabatic, isothermal, and general flows according to the heat transfer situation around the pipe, but the adiabatic flow model was recommended suitable for gas discharge through pressure relief devices. Next, for the isentropic nozzle flow followed by adiabatic frictional flow in the pipe, two equations were established for two unknowns that consist of the Mach numbers at the inlet and outlet of the pipe, respectively. The relationship among the ratio of downstream reservoir pressure to upstream pressure, mass flux, and total frictional loss coefficient was shown in various forms of MATLAB 2-D plot, 3-D surface plot and contour plot. Then, the profiles of gas properties and velocity in the pipe section were traced. A method to quantify the relationship among the pressure head, velocity head, and total friction loss was presented, and was used in inferring that the rapid increase in gas velocity in the region approaching the choked flow at the pipe outlet is attributed to the conversion of internal energy to kinetic energy. Finally, the Levenspiel chart reproduced in this work was compared with the Lapple chart used in API 521 Standatd.

• Journal of The Korean Astronomical Society
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• v.27 no.1
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• pp.13-29
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• 1994

We have constructed a 3-dim hydrodynamics code called BTSPH. The fluid dynamics part of the code is based on the smoothed particle hydrodynamics (SPH), and for its Poisson solver the binary tree (BT) scheme is employed. We let the smoothing length in the SPH algorithm vary with space and time, so that resolution of the calculation is considerably enhanced over the version of SPH with fixed smoothing length. The binary tree scheme calculates the gravitational force at a point by collecting the monopole forces from neighboring particles and the multipole forces from aggregates of distant particles. The BTSPH is free from geometric constraints, does not rely on grids, and needs arrays of moderate size. With the code we have run the following set of test calculations: one-dim shock tube, adiabatic collapse of an isothermal cloud, small oscillation of an equilibrium polytrope of index 3/2, and tidal encounter of the polytrope and a point mass perturber. Results of the tests confirmed the code performance.

• Elastomers and Composites
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• v.22 no.4
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• pp.333-339
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• 1987

A modern kinetic evaluation method for nonisothermal reactions measured with Differential Scanning Calorimetry(DSC) is presented. It is based on multiple linear regression analysis using a number of curve points in a selectable range of conversion. The obtained kinetic data are the basis to compute a reaction process under any condition e.g. isothermal or adiabatic. The DSC measurements was performed on a Mettler TA3000 SYSTEM with the built in evaluation software. Mainly the following reactions are discussed: vulcanization of natural rubber compounds containing vulcanizing accelerators. The purpose of this work is to analyse the vulcanization kinetics of typical NR vulcanization systems using DSC. These systems were chosen because they are typically reactive elastomer and are commercially important.

• Journal of Ocean Engineering and Technology
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• v.8 no.1
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• pp.105-113
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• 1994

Double-diffusive convection induced by simultaneously-imposed lateral temperature and concentration gradients in a rectangular enclosure with aspect retio, 2.0 has been studied experimentally for adiabatic and isothermal horizontal boundary conditions. Visual observations show two distinct flow structures depending on the buoyancy ratio. The unicell flow structure is observed for a lower buoyancy ratio while the layered flow structure appears for a higher buoyancy ratio. There exists an unstable flow regime between two buoyancy ratios.

• KSTLE International Journal
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• v.1 no.2
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• pp.76-82
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• 2000

Turbulence in journal bearing operation is examined and the thermal variability is studied for isothermal, convective and adiabatic conditions on the walls under aligned and misaligned conditions. Also, the effects of a contraction ratio at the cavitation region and the mixing between re-circulating oil and inlet oil on the fluid field of oil film are included. An algorithm for the solution of the coupled turbulent Reynolds and energy equations is used to examine the effects of the various factors. Heat convection is found to play only a small role in determining friction and load under no mixing condition. However, under realistic mixing condition, the heat convection cannot be ignored. The wall temperature and heat transfer have been found to be of secondary important factors to the mixing effectiveness at the groove and the final mixture temperature.

• Proceedings of the KSME Conference
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• 2000.11b
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• pp.609-614
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• 2000

This numerical study investigate resonance frequency of natural convection for steady state, periodic flow and chaotic flow in two-dimensional direct numerical simulations, differentially heated, vertical cavities having aspect ratios near unity. The enclosure cavity has isothermal and time dependent temperature side walls and adiabatic top/bottom walls. The aspect ratio is 1/3, 1/2, 1, 2, and 3 for the varying Rayleigh number. Resonance frequency for AR=1 has decrease as the aspect ratio and the Rayleigh number are increasing.