• Restorative Dentistry and Endodontics
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• 제25권4호
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• pp.575-586
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• 2000

In this study, adaptation of compomer to saliva contaminated dentin was evaluated with scanning electron microscope(SEM) and confocal laser scanning microscope(CLSM). For the SEM study, the occulusal surfaces of thirty two molar teeth were grounded to exposure dentin surfaces. The specimen were randomly assigned to control and three experimental groups with four samples in each group. In control group, Dyract and F-2000 compomer were bonded on the specimens according to the manufactures direction. Experimental groups were subdivided into three groups. They were contaminated with saliva on dentin surfaces ; Experimental group 1 : Saliva was dried with compressed air. Experimental group 2 : Saliva was rinsed with air-water spray and dried. Experimental group 3 : After polymerization of an adhesive, they were contaminated with saliva, and then saliva was rinsed with air-water spray and dried. Dyract and F-2000 compomer were bonded on saliva-treated dentin surfaces. The interfaces between dentin and compomer were observed with SEM. For the CLSM study, Class V cavities were prepared in buccal and ligual surfacess of thirty two molars. The specimens were divided into control and experimental groups. Class V cavities in experimental group were contaminated with saliva and those surfaces in each experimental groups received the same treatments as for the SEM study. Cavities were applied Prime & Bond 2.1 and F-2000 compomer primer/adhesive that were mixed with fluorescein, and then were filled with Dyract and F-2000 compomer. Specimens were embedded in transparent acrylic resin and sectioned buccolingual1y with diamond wheel saw, and then mounted on cover slide for CLSM study. The interface between cavity and compomer was observed by fluoresence imaging with a CLSM. The results were as follows : 1. In SEM exammination of Dyract group, control group, experimental group 2, 3 showed close adaptation to dentin and hybrid layer of $3{\sim}4{\mu}m$ diameter. Interfacial gap between compomer and dentin in experimental group 1 was wider than in control group. 2. In SEM examination of F-2000 group, adaptation to dentin of control group was closer than Dytact control group, but hybrid-like layer was not observed. Interfacial gap between compomer and dentin in experimental group 1 was wider than in Dyract experimental group 1. 3. In dissolution specimens of Dyract and F-2000 group, resin tags penetrated through dentinal tubules in control group and experimental group 1 and 3, but the penetration of resin tag was irregular and partial in experimental group 1. 4. In CLSM exammination of Dyract and F-2000 group, adhesive patterns of control and experimental groups showed same as in SEM. This result suggests the treatment methods, rinsing & drying, repeating all adhesive procedures, will produce good effect on adaptation of compomer to dentin if the dentin surface or polymerized adhesive is contaminated by saliva.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2004년도 춘계 학술발표회 제16권1호
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• pp.794-797
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• 2004

In this study, tensile adhesive strength(TAS) test was carreid out for evaluated the effects of temperature conditions (-20, -10, 0, 5, 10, 20, 30, $40^{\circ}C$) on the tensile adhesive characteristics about 4 type waterproofing membranes which were commercially used in bridge decks. And, failure appeariences of waterproofing systems in each temperature after TAS test were observed the sawing surfaces of waterproofing systems for whether or not damaged of waterproofing membranes. Also, correction coefficient of TAS with temperature were calculated using 4 type waterproofing membrane. It could be shown that the higher TAS and shear adhesive strength, the lower temperature, regardless of the type of waterproofing membrane. Temperature sensibility of TAS was especially remarkable in epoxy membrane. Failure type was occurred the ductile failure in $30^{\circ}C\;and\;40^{\circ}C$. From these results, it was shown that if ambient temperature above $30^{\circ}C$ maintains for a long time, waterproofing membrane will be deformed by softening. Otherwise, waterproofing membrane in temperature below $20^{\circ}C$ shown that occurred the brittle failure. From the results of visual observation of cutting surface for specimen, the thin waterproofing membranes shown indented by hot aggregate of the asphalt mixtures. Therefore, it could be known that the specification of waterproofing membrane thickness is necessary by waterproofing membrane type. As temperature change varied with pavement depth, the interface temperature was more important than ambient temperature in TAS test. Now, TAS test results were limited only in $-10^{\circ}C\;and\;20^{\circ}C$ temperature, but correction coefficient of TAS by ambient temperature could be used as a solution to deal with this problem.

• The Journal of Advanced Prosthodontics
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• 제5권4호
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• pp.457-463
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• 2013

PURPOSE. The purpose of this study was to compare the effect of a diode laser and traditional irrigants on the bond strength of self-adhesive cement. MATERIALS AND METHODS. Fifty-five incisors extracted due to periodontal problems were used. All teeth were instrumented using a set of rotary root canal instruments. The post spaces were enlarged for a No.14 (diameter, 1.4 mm) Snowlight (Abrasive technology, OH, USA) glass fiber reinforced composite post with matching drill. The teeth were randomly divided into 5 experimental groups of 11 teeth each. The post spaces were treated with the followings: Group 1: 5 mL 0.9% physiological saline; Group 2: 5 mL 5.25% sodium hypochlorite; Group 3: 5 mL 17% ethylene diamine tetra acetic acid (EDTA), Group 4: 37% orthophosphoric acid and Group 5: Photodynamic diode laser irradiation for 1 minute after application of light-active dye solution. Snowlight posts were luted with self-adhesive resin cement. Each root was sectioned perpendicular to its long axis to create 1 mm thick specimens. The push-out bond strength test method was used to measure bond strength. One tooth from each group was processed for scanning electron microscopic analysis. RESULTS. Bond strength values were as follow: Group 1 = 4.15 MPa; Group 2 = 3.00 MPa; Group 3 = 4.45 MPa; Group 4 = 6.96 MPa; and Group 5 = 8.93 MPa. These values were analysed using one-way ANOVA and Tukey honestly significant difference test (P<.05). Significantly higher bond strength values were obtained with the diode laser and orthophosphoric acid (P<.05). There were no differences found between the other groups (P> .05). CONCLUSION. Orthophosphoric acid and EDTA were more effective methods for removing the smear layer than the diode laser. However, the diode laser and orthophosphoric acid were more effective at the cement dentin interface than the EDTA, Therefore, modifying the smear layer may be more effective when a self-adhesive system is used.

• 한국융합학회논문지
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• 제9권5호
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• pp.151-156
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• 2018

본 연구에서는 CFRP와 금속 또는 비금속을 접착제로 접합시켜 이 재료에 대한 파손 연구를 수행하였다. 그 해석 조건으로는 DCB 시험편을 이용하여 시험편의 상부에는 CFRP, 시험편의 하부에는 금속 또는 비금속 재료로 지정하였고 두 상부와 하부 사이를 구조용 접착제로 부착하는 것을 묘사하였다. 이 해석 결과로는 알루미늄으로 접착된 시험편에서 가장 작은 등가응력 보였고 티타늄을 사용하였을 때 박리된 CFRP시험편에서의 최대 전단응력은 가장 낮음을 보였다. 결론적으로 티타늄을 사용하였을 때 시험편의 변형이 가장 작은 것을 알 수 있었고 본 연구 결과를 토대로 접착제를 이용한 접착 계면의 파손데이터를 실생활에 융합하여 그 미적 감각을 나타낼 수 있다.

• Restorative Dentistry and Endodontics
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• 제20권1호
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• pp.113-128
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• 1995

The purpose of this study was to investigate the effect of stannous fluoride on the dentin bonding with three kinds of commercially available dentin bonding systems containing different adhesive monomers. Dentin specimens with exposed labial dentin prepared from freshly extracted bovine mandibular anterior teeth were divided into experimental and control groups. The specimens of experimental groups were bonded with dentin bonding systems and composite resins including All bond 2 ㅡ& Bisfil, Scotchbond Multi-Purpose & Z100, and Denthesive II Charisma after 2 % stannous& fluorided application for S minutes and washing for 1 minute. The specimens of control groups were bonded with the same dentin bonding systems and composite resins as used in the experimental groups. After bonded specimens were stored in $37^{\circ}C$ distilled water for 24 hours, the tensile bond strength and cohesive failure rate were measured, and then the pretreated dentin surfaces and the fractured dentin surfaces were examined under scanning electron microscope. The results were as follows : Mean bond strength of stannous fluoride applied groups of All bond 2, Scotchbond MP, and Denthesive II were 2.5MPa, 1.1MPa, and 1.1MPa respectively, and those of control groups were 7.5MPa, 8.1MPa, and 4.6MPa. Bond strength values of stannous fluoride applied groups were significantly lower than those of the control groups(p<0.05). SEM findings of dentin surfaces after stannous fluoride application demonstrated an appearance of partially remained smear layer and smear plugs inspite of pretreatment with 10 % phosphoric aicd or maleic acid solution, and an appearance of smear layer covered surface under Denthesive II priming. But those of control groups commonly showed clean dentin surfaces without smear layer and smear plugs. On SEM observation of the fractured dentin-resin interface, while most of the specimens of stannous fluoride applied groups showed adhesive failure mode, those of All bond 2 and Scotchbond MP control groups showed mainly adhesive-cohesive mixed failure mode, and mainly adhesive failure mode in Denthesive II control group.

• Restorative Dentistry and Endodontics
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• 제42권3호
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• pp.188-199
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• 2017

Objectives: This in vitro study evaluated the effect of dentin biomodifiers on the immediate and long-term bond strengths of a simplified etch and rinse adhesive to dentin. Materials and Methods: Flat coronal dentin surfaces were prepared in 120 extracted human molars. Teeth were randomly divided into 5 groups (n = 24) according to 5 different surface pre-treatments: No pre-treatment (control); 1M carbodiimide (EDC); 0.1% epigallocatechin-3-gallate (EGCG); 2% minocycline (MI); 10% sodium ascorbate (SA). After surface pre-treatment, adhesive (Adper Single Bond 2 [SB], 3M ESPE) was applied. Composite was applied into transparent plastic tubes (2.5 mm in diameter), which was placed over the bonded dentin surface. From each group, 10 samples were subjected to shear bond strength (SBS) evaluation at 24 hours (immediate) and remaining 10 samples were tested after 6 months (delayed). Additionally, 4 samples per group were subjected to scanning electron microscopic analysis for observation of resin-dentin interface. The data were statistically analysed with Shaperio-Wilk W test, 2-way analysis of variance (ANOVA), and post hoc Tukey's test. Results: At 24 hours, SBS of all surface pre-treatment groups were comparable with the control group, with significant differences found between EDC and SA groups only (p = 0.009). After 6 months storage, EDC, EGCG, and MI pre-treatments preserved the resindentin bond strength with no significant fall. Conclusions: Dentin pre-treatment with all the dentin biomodifiers except SA resulted in significant preservation of resin-dentin bond over 6 months storage period, without negatively affecting the immediate bond strength of the etch and rinse adhesive tested.

• Structural Engineering and Mechanics
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• 제63권3호
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• pp.361-370
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• 2017

Through the use of finite element analysis and acoustic emission techniques we have evaluated the interfacial failure of a carbon fiber reinforced polymer (CFRP) repair patch on a notched aluminum substrate. The repair of cracks is a very common and widely used practice in the aeronautics field to extend the life of cracked sheet metal panels. The process consists of adhesively bonding a patch that encompasses the notched site to provide additional strength, thereby increasing life and avoiding costly replacements. The mechanical strength of the bonded joint relies mainly on the bonding of the adhesive to the plate and patch stiffness. Stress concentrations at crack tips promote disbonding of the composite patch from the substrate, consequently reducing the bonded area, which makes this a critical aspect of repair effectiveness. In this paper we examine patch disbonding by calculating the influence of notch tip stress on disbond area and verify computational results with acoustic emission (AE) measurements obtained from specimens subjected to uniaxial tension. The FE results showed that disbonding first occurs between the patch and the substrate close to free edge of the patch followed by failure around the tip of the notch, both highest stress regions. Experimental results revealed that cement adhesion at the aluminum interface was the limiting factor in patch performance. The patch did not appear to strengthen the aluminum substrate when measured by stress-strain due to early stage disbonding. Analysis of the AE signals provided insight to the disbond locations and progression at the metal-adhesive interface. Crack growth from the notch in the aluminum was not observed until the stress reached a critical level, an instant before final fracture, which was unaffected by the patch due to early stage disbonding. The FE model was further utilized to study the effects of patch fiber orientation and increased adhesive strength. The model revealed that the effectiveness of patch repairs is strongly dependent upon the combined interactions of adhesive bond strength and fiber orientation.

• Composites Research
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• 제16권5호
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• pp.45-53
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• 2003

본 논문에서는 이차 본딩으로 접착된 복합재료-복합재료 Single-Lap 조인트 시편에 대해 인장 시험 및 수치해석을 통해 그 파손 특성을 조사하였다. 시편시험에서는 시험 중에 CCD 카메라 및 AE 센서를 이용해 초기 균열의 발생 및 진전양상에 대한 시험적인 관찰을 수행하였다. 시편에 대해 기하비선형 유한요소해석 및 VCCT(Virtual Crack Closure Technique)기법을 이용해 시편의 거동 및 변형율에너지방출률을 계산하고 세 가지 관찰된 초기 균열 모드에 대해 파손강도를 계산하였다. 인장시험에서 초기 균열은 모서리 계면 균열, 측면 계면 균열 및 층간 분리 균열의 세 가지 형태로 최종 파손의 60∼90% 하중에서 발생하였다. 주된 파손 모드는 접착제 계면 파손(adhesive failure) 및 적층판의 첫 번째 및 두 번째의 층간 분리 파손이었다. 두꺼운 접착제 층을 갖는 시편들은 초기균열이 낮은 하중에서 발생하였지만 균열진전에 대한 저항성 및 파손하중은 높게 나타났다. 층간분리파손은 주로 두꺼운 접착제의 경우에 발생하였다. 세 가지 초기 균열 모드에 대해 변형률에너지방출률은 Mode I의 G값이 Mode II의 G값보다 크게 계산되었다. Mode I 및 전체 G값은 측면 계면 균열, 모서리 계면 균열, 층간분리 균열의 순서로 크게 계산되었다.

• 접착 및 계면
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• 제16권2호
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• pp.69-75
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• 2015

돌침대에 사용되는 석재의 무게를 줄여 경량화를 추구하려면 석재의 두께를 줄이고 보강재료로 석재의 강도를 유지해야 한다. 본 연구에서는 돌침대용 석재/목재 보드 개발에 대한 연구를 진행하였다. 돌침대에 삽입될 돌의 무게를 줄이기 위해 석재와 목재를 접합하였다. 목재의 강도 향상과 표면개질을 위하여 열처리 조건에 따른 목재의 물성변화를 관찰하였다. 대기 조건에서 열처리한 목재의 경우 고온의 온도에 따라 목재의 강성이 높아졌다. 열처리 최적조건은 표면에너지와 인장, 굴곡 강도변화 경향을 바탕으로 $100^{\circ}C$ 조건임을 확인하였다. 석재와 목재간 높은 접착력을 확보하기 위해 최적의 접착제 조성을 연구하였다. 아민계 에폭시 접착제, 폴리우레탄(PU)계 접착제, 염화고무계(CR) 접착제 마지막으로 염화비닐초산계 접착제에 따른 석재와 목재간 랩 전단실험을 진행하였다. 랩 전단 실험 후 파단면을 관찰해볼 때 에폭시 접착제를 이용할 때 목재 기지의 인열 파괴가 발생되었다. 접착면에서의 전단력이 목재 자체의 파괴 강도보다 높다는 결과를 바탕으로 최적의 접착제 조건이 에폭시계 접착제임을 확인할 수 있었다.

• 접착 및 계면
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• 제12권4호
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• pp.111-116
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• 2011

각종 산이나 알칼리에 부식되지 않고 내열성 및 방수, 방부, 방충 등에도 뛰어난 성질을 지니고 있는 천연수지인 옻을 토기 복원을 위한 접착제로 활용하기 위해 특성연구를 진행하였다. 옻의 경화조건인 고습(RH 75~85%) 또는 고온($120{\sim}170^{\circ}C$)이 아닌 일반적인 환경에서 접착제로 활용하기 위해 생칠에 어교 및 아교를 일정 비율로 첨가하였으며, 혼합 비율별 점도와 건조시간을 측정하고 인장강도 및 접착력 측정을 통해 적용가능성을 검토하였다. 실험 결과 생칠에 교(膠)를 첨가함으로써 상온, RH $50{\pm}5%$의 환경에서 건조가 가능하였고 어교보다 아교를 첨가한 시료에서 건조시간이 더 빠른 것으로 나타났다. 또한 교를 첨가함으로써 생칠보다 접착력이 더 증가하였다. 향후 토기 유물의 적용성 및 내후성에 대한 검증이 이루어진다면 친환경적인 전통접착제를 활용한 유물의 접합복원이 가능할 것으로 판단된다.