• Title/Summary/Keyword: Additives Materials

검색결과 926건 처리시간 0.029초

자전고온합성법으로 제조한 이규화몰리브덴 발열체의 소결특성에 미치는 소결조건 및 첨가물의 영향 (Effects of Sintering Conditions and Additives on the Properties of Sintered MoSi$_2$Powders Prepared by Self-propagating High-Temperature Synthesies)

  • 심건주;장대규;서창열;김운백
    • 한국재료학회지
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    • 제5권8호
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    • pp.921-928
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    • 1995
  • MoSi$_2$heating elements were fabricated using MoSi$_2$, powder prepared by SHS. Their apparent density, electrical resistivity, bending strength and victors hardness were measured as a function of sintering temperature, time and the amount of ceramic additives. The additives were A1$_2$O$_3$, SiO$_2$and bentonite which were added as a plastisizer. The electrical resistivity of MoSi$_2$decreased with the increase in the apparent density as expected. It decreased when the additives were added and the increase was the largest for the case of SiO$_2$. The bending strength and hardness decreased when the grain size becomes larger which is opposite to the expectation from the Hall-Petch type relation. Instead, they showed inverse proportionality with the volume fraction of pores probably in an exponential manner. The strength and hardness also decreased with the additives.

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식품 포장재 중의 퍼플루오르옥탄설포네이트 분석 (The Determination of Perfluorooctane sulfonate in Food Packing Materials by HPLC-MS/MS)

  • 김일영;김애경;정보경;신영;김지영;김정헌;채영주
    • 한국식품위생안전성학회지
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    • 제28권4호
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    • pp.376-380
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    • 2013
  • 퍼플루오르옥탄설포네이트를 LC/MS/MS를 이용하여 분석한 결과 분석 대상물질의 고유한 스팩트럼을 얻어 정량하여 머므름 시간은 4.33분이었으며 상관계수($R^2$)은 0.9998로 양호한 직선상의 그래프를 얻을 수 있었다. 퍼플루오르옥탄설포네이트에 대한 분석법의 회수율은 99.84%로 전반적으로 좋은 회수율을 보였으며 또한 이 연구에 적용되기에 충분한 정밀도와 정확도를 가지고 있음을 확인할 수 있었다. 퍼플루오르옥탄설포네이트 정량한계 및 검출한계는 0.03, 0.009 ug/L이었다. 따라서 식품 용기포장재에서의 분석에 적용이 가능하였다.

생석회의 팽창압 발현에 미치는 첨가제 및 양생온도의 영향 (The Influences of Additives and Curing Temperature on the Expansion Pressure of Calcium Oxide Hydration)

  • 김원기;소정섭;김훈상;김홍주;이원준;신진호
    • 한국세라믹학회지
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    • 제44권9호
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    • pp.529-535
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    • 2007
  • Calcium oxide has been used as a demolition agent in fracturing rocks and old concrete structures, etc. With the agent, demolition work can be done in safety without a noise, vibration and any other pollution, since high expansive pressure is obtained gradually by only mixing the agents with water and pouring the slurry into boreholes. But application of the non-explosive demolition agent is a time-consuming job, especially in winter. Essentially, this problem is related to the reaction rate of calcium oxide with water. This study examines the influence of additives such as cement and anhydrite on expansion pressure of calcium oxide at different curing temperatures. The expansion pressure of calcium oxide began to increase steadily with the rise of the curing temperature. When mixing calcium oxide alone with water, blown-out shot occurred. But as additives were added to calcium oxide, the reaction of calcium oxide delayed and the expansion pressure showed gradual increment. Especially, anhydrite showed a superior delaying effect than cement on the reaction of calcium oxide.

Copper Seed Layer 형성 및 도금 첨가제에 따른 Copper Via Filling (Formation of Copper Seed Layers and Copper Via Filling with Various Additives)

  • 이현주;지창욱;우성민;최만호;황윤회;이재호;김양도
    • 한국재료학회지
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    • 제22권7호
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    • pp.335-341
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    • 2012
  • Recently, the demand for the miniaturization of printed circuit boards has been increasing, as electronic devices have been sharply downsized. Conventional multi-layered PCBs are limited in terms their use with higher packaging densities. Therefore, a build-up process has been adopted as a new multi-layered PCB manufacturing process. In this process, via-holes are used to connect each conductive layer. After the connection of the interlayers created by electro copper plating, the via-holes are filled with a conductive paste. In this study, a desmear treatment, electroless plating and electroplating were carried out to investigate the optimum processing conditions for Cu via filling on a PCB. The desmear treatment involved swelling, etching, reduction, and an acid dip. A seed layer was formed on the via surface by electroless Cu plating. For Cu via filling, the electroplating of Cu from an acid sulfate bath containing typical additives such as PEG(polyethylene glycol), chloride ions, bis-(3-sodiumsulfopropyl disulfide) (SPS), and Janus Green B(JGB) was carried out. The desmear treatment clearly removes laser drilling residue and improves the surface roughness, which is necessary to ensure good adhesion of the Cu. A homogeneous and thick Cu seed layer was deposited on the samples after the desmear treatment. The 2,2'-Dipyridyl additive significantly improves the seed layer quality. SPS, PEG, and JGB additives are necessary to ensure defect-free bottom-up super filling.

PMM for Surface Treatment of Concrete with the Utilization of By-Products

  • Drochytka, Rostislav;Zizkova, Nikol
    • International Journal of Concrete Structures and Materials
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    • 제2권1호
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    • pp.49-55
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    • 2008
  • The disadvantage of PMM's (polymer-modified mortars) that are currently on the market is the utilization of expensive polymer additives and also the cost of the other components. One of the possibilities how to decrease this price is the effective utilization of waste materials which are very inexpensive in spite of their good properties. The combinations of different degree in polymer adhesiveness and waste secondary raw materials - fly ash - are experimentally verified in the paper. The use of fly ash in adhesive materials for ceramic tiles is limited by unsatisfactory initial adhesiveness to sintered ceramic sherd as a result of a running pozzolanic reaction that lowers the efficiency of polymer additives. On the other hand, the use of adhesive and backfill coating materials for gluing ETICS board insulation materials has brought very good results.

Hot Pressing of the Silicon Nitride Based Ceramics and Their Mechanical Behavior

  • Park, D.S.;Lee, S.Y.;Kim, H.D.;Park, W.S.;D.S. Lim;B.D. Han
    • The Korean Journal of Ceramics
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    • 제1권1호
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    • pp.45-54
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    • 1995
  • Four kinds of silicon nitride based ceramic materials have been hot pressed. Effect of the sintering additives on the phase transformation, microstructural development and mechanical properties was investigated. While sintering under the same condition a big difference among the microstructures of the specimens, they appeared alike if sintered to have a similiar $\alpha$-$\beta$ phase ratio. The specimen of the stoichiometric $\alpha$-$\beta$ sialon composition showed very limited amount of the intergranular glassy phase and a significant degree of the residual stress. It exhibited almost no strength degradation up to $1300^{\circ}C$, and the strength of the specimen degraded more as its composition deviated from the stoichiometry.

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배향된 $\beta-Si_3N_4$ Whisker를 함유하는 $Si_3N_4$ 복합체의 기계적 특성에 미치는 소결조제와 소결온도의 영향 (Effect of Sintering Additives and Sintering Temperature on Mechanical Properties of the $Si_3N_4$ Composites Containing Aligned $\beta-Si_3N_4$ Whisker)

  • 김창원;최명제;박찬;박동수
    • 한국세라믹학회지
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    • 제37권1호
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    • pp.21-25
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    • 2000
  • Gas pressure sintered silicon nitride based composites with 5 wt% $\beta$-Si3N4 whiskers were prepared, and the variations depending on sintering additives and sintering temperature were studied. Sintering additives were 6 wt% Y2O3-1 wt% MgO(6Y1M), 6 wt%Y2O3-1 wt% Al2O3(6Y1A), 6 wt% Y2O3-1 wt% SiO2(6Y1S), and whiskers were unidirectionally oriented by a modified tape casting technique. Samples were fully densified by gas pressure sintering at 2148 K and 2273 K. As the sintering temperature increased, the size of large elongated grains was increased. Three point flexural strength of 6Y1M and 6Y1M samples was higher than that of 6Y1S sample, and the strength decreased as the sintering temperature increased. The indentation crack length became shorter for the sample sintered at higher temperature, and the difference between the cracks length parallel to and normal to the direction of whisker alignment was decreased. In case of cracks 45$^{\circ}$off the whisker alignment direction, the crack length anisotropy disappeared.

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다짐온도에서 골재 거칠기와 아스팔트 피막두께에 따른 중온화 첨가제의 윤활특성 평가 (Evaluation of Lubrication Characteristics of WMA Additives for Different Roughnesses of Aggregate Surfaces and Film Thicknesses of Binders at a Compaction Temperature)

  • 이상재;조동우;황성도;이석근
    • 한국도로학회논문집
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    • 제15권5호
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    • pp.1-9
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    • 2013
  • PURPOSES : This study is to develop a method to evaluate lubrication of asphalt binder using WMA additives and compare their lubrication effects on two types of WMA additives and three types of asphalt film thicknesses. METHODS : This study is based on laboratory experiments and rheological analysis of the experimental results. Testing materials are aggregate diskes, asphalt, and WMA additives. The main testing method is stress sweep test by using dynamic shear rheometer (DSR). RESULTS : Sasobit gives more lubrication effects on film thicknesses 0.2mm and under but LEADCAP does on film thicknesses over 0.3mm. CONCLUSIONS : LVE-Limit is a better parameter to discern the lubrication effects on the thin film asphalt thickness. Both Sasobit and LEADCAP WMA additives provide effective lubrication at the compaction temperature.

액상소결법에 의한 탄화규소 제조시 소결조제와 온도의 영향 (Influence of Sintering Additives and Temperature on Fabrication of LPS-SiC)

  • 정헌채;윤한기
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2004년도 학술대회지
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    • pp.266-270
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    • 2004
  • SiC materials have been extensively studied for high temperature components in advanced energy system and advanced gas turbine because it has excellent high temperature strength, low coefficient of thermal expansion, good resistance to oxidation and good thermal and chemical stability etc. However, the brittle characteristics of SiC such as low fracture toughness and low strain-to fracture still impose a severe limitation on practical applications of SiC materials. For these reasons, SiC/SiC composites can be considered as a promising for various structural materials, because of their good fracture toughness compared with monolithic SiC ceramics. But, high temperature and pressure lead to the degradation of the reinforcing jiber during the hot pressing. Therefore, reduction of sintering temperature and pressure is key requirements for the fabrication of SiC/SiC composites by hot pressing method. In the present work, monolithic Liquid Phase Sintered SiC (LPS-SiC) was fabricated by hot pressing method in Ar atmosphere at $1800^{\circ}C$ under 20MPa using $Al_2O_3,\;Y_2O_3\;and\;SiO_2$ as sintering additives in order to low sintering temperature and sintering pressure. The starting powder was high purity $\beta-SiC$ nano-powder with all average particle size of 30mm. The characterization of LPS-SiC was investigated by means of SEM and three point bending test. Base on the composition of sintering additives-, microstructure- and mechanical property correlation, tire compositions of sintering additives are discussed.

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의약품과 의약외품에 사용되는 타르순색소의 관리방안을 위한 조사연구 (Investigation for the Management Methods of Pure Tar Color Additives for Drugs and Quasi-drugs)

  • 김광준;김지연;박선희;방준석;이원재
    • 한국임상약학회지
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    • 제23권2호
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    • pp.97-105
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    • 2013
  • Background: This study was aimed to establish the systematic management methods of tar color additives used in Korea for drugs and quasi-drugs. Although tar color additives have been used in various areas, safety problems are continuously being reported by several studies. For that reason, major countries like US, Japan, Europe are trying to update the safety information of tar color additives and the related management methods, and Korea also need to complement them based on the updated information for their safer use. Method: This report includes the compared information of all legally used tar color additives of each country, such as color additive name, compound name and chemical abstracts service registry number. Conclusion: It is expected that these investigated results will be useful as the basic materials for proper management guidelines of tar color additives in Korea.