• Title/Summary/Keyword: Addition agent

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The Study of Water Stability of MDF Cement Composite by Addition of Silane Coupling Agent (Silane Coupling Agent 첨가에 의한 MDF Cement Composite의 수분안정성 연구)

  • 노준석;김진태;박춘근;오복진;최상홀
    • Journal of the Korean Ceramic Society
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    • v.35 no.5
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    • pp.421-428
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    • 1998
  • The effect of silane coupling agents on the water stability of HAC/PVA based MDF cement composites which were modified with urethane and epoxy resin were studied as a function of the functional groups and addition amount of silane coupling agent. According to the composition of polymer matrix the silanes with different functional groups showed the different effectiveness. In case of the only PVA matrix the silane with vinyl functional group was more effective than other silanes. When the epoxy resin was added the silane of epoxy-methodxy group enhanced the flexural strength of dry and wet state more than other. In case of urethane-added MDF cement the silane of diamine group was effective and enhanced the water sta-bility fo MDF cement composite more and more as the addition amount of silane increased, Especially in case of warm-presed composite the effect of silane was enhanced By addition of 2wt% of silane with 야-amine group the flexural strength of urethane-added composites were enhanced by 20% more in dry state 40-70% in wet state in accord with the porosity analysis. The flexural strength of the poxy resin-added MDF cement composite was increased by addition of 1wt% and 2wt% silane of epoxy-methoxy group However the addition of 4wt% of silane decreased the flexural strength of dry and wet state by formation of closed pore in the polymer matrix.

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Moisture Damage Evaluation of Asphalt Mixtures depending on the Types of Anti-Stripping Agent (아스팔트 혼합물의 박리방지제의 종류 및 함량에 따른 박리저항성 분석)

  • Choi, Sung Ho;Kim, Won Jae;Le Van, Phuc;Lee, Hyun Jong;Hwang, Sung Do
    • International Journal of Highway Engineering
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    • v.16 no.4
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    • pp.45-50
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    • 2014
  • PURPOSES : The objective of this study is to analyze the performance of anti-stripping agent depending on its type and content to reduce pothole, an increasing pavement distress due to abnormal climate intensity. METHODS : In the past years, U.S and many countries in Europe use hydrated lime and liquid anti-stripping agent in asphalt mixtures. Hydrated lime or liquid anti-stripping agent is substituted for filler and binder, respectively, to improve the anti-stripping property of asphalt mixtures. To investigate this, indirect tensile strength test was performed and TSR values were compared for different content of hydrated lime and types of liquid anti-stripping agent in asphalt mixture. RESULTS : Test results indicate that hydrated lime remarkably increased the asphalt mixture performance on anti-stripping denoted by the increased in TSR values from 55% to 100%. Liquid anti-stripping agent also increased the value of TSR but not significant. In addition, depending on the types of aggregate, TSR values and effect of liquid anti-stripping were different. CONCLUSIONS : Using anti-stripping agents improve the anti-stripping property of asphalt mixture especially hydrated lime; however, more experiments should be conducted to improve the reliability about the effect of liquid anti-stripping agent.

Properties of Bleeding Reduction of Concrete Using AE Water Reducing Agent for Reduction of Bleeding (블리딩저감용 AE감수제를 사용한 콘크리트의 블리딩 저감 특성)

  • Kim, Ki-Hoon;Hwang, Yin-Seong;La, Woon;Im, Ju Hyeuk;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2003.11a
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    • pp.69-72
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    • 2003
  • This study is intended to investigate the fundamental properties of concrete which AE water reducing agent for reduction of bleeding is used, and the properties of bleeding reduction. According to the results, when the adding ratio of AE water reducing agent for reduction of bleeding increases, a range of normal fluidity and aimed air content arc satisfied, setting time is faster than that of normal AE water reducing agent. And bleeding amount decreases, bleeding speed is highest between 60 and 90 min, and sinking depth increases drastically in 60 min. When, AE water reducing agent for reduction of bleeding is added, compressive strength shows a slight variation by air content, but there is not a large influence by addition of AE water reducing agent for reduction of bleeding. Synthetically, it proves that AE water reducing agent for reduction of bleeding satisfies aimed air content in the range of normal slump and can reduce only bleeding without quality variation of compressive strength.

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Properties of Bleeding Reduction of Concrete Using AE Water Reducing Agent for Reduction of Bleeding (블리딩저감용 AE감수제를 사용한 콘크리트의 블리딩 저감 특성)

  • Kim, Ki-Hoon;Hwang, Yin-Seong;La, Woon;Im, Ju-Hyeuk;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2003.05a
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    • pp.69-72
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    • 2003
  • This study is intended to investigate the fundamental properties of concrete which AE water reducing agent for reduction of bleeding is used, and the properties of bleeding reduction. According to the results, when the adding ratio of AE water reducing agent for reduction of bleeding increases, a range of normal fluidity and aimed air content are satisfied, setting time is faster than that of normal AE water reducing agent. And bleeding amount decreases, bleeding speed is highest between 60 and 90 min, and sinking depth increases drastically in 60 min. When. AE water reducing agent for reduction of bleeding is added, compressive strength shows a slight variation by air content, but there is not a large influence by addition of AE water reducing agent for reduction of bleeding. Synthetically, it proves that AE water reducing agent for reduction of bleeding satisfies aimed air content in the range of normal slump and can reduce only bleeding without quality variation of compressive strength.

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Engineering Properties of Bleeding Reduction of Concrete Using AE Water Reducing Agent for the Type of Bleeding Reduction (블리딩저감형 AE감수제를 사용한 콘크리트의 공학적 특성)

  • Han, Cheon-Goo;Hwang, Yin-Seong;Lee, Seung-Hoon;Kim, Gyu-Dong
    • Journal of the Korea Institute of Building Construction
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    • v.4 no.1
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    • pp.133-140
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    • 2004
  • This study is intended to investigate the properties of bleeding reduction of concrete using AE water reducing agent for the type of bleeding reduction with the replacement admixture. According to the results, when the adding ratio of AE water reducing agent for the type of bleeding reduction increases, a range of normal fluidity and aimed air content are satisfied, setting time is faster than that of normal AE water reducing agent. And bleeding amount decreases, bleeding speed is highest between 60 and 90 min, and sinking depth increases drastically in 50 min. When AE oater reducing agent for the type of bleeding reduction is added, compressive strength shows a slight variation by air content, but there is not a large influence by addition of AE water reducing agent for the type of bleeding reduction. Synthetically, it proves that AE water reducing agent for the type of bleeding reduction satisfies aimed air content in the range of normal slump and can reduce only bleeding without quality variation of compressive strength.

Setting Analysis of Super Retarding Agent according to Curing Temperatur (양생온도 변화에 따른 초지연제의 응결지연 성능 변화 분석)

  • Hyun, Seung-Yong;Lim, Gun-Su;Han, Soo-Hwan;Kim, Jong;Han, Min-Choel;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.10-11
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    • 2020
  • This research is part of the research for unifying the mass concrete and utilizing the rate of super retarding agent. We analyzed the performance of super retarding agent under low temperature conditions. It was found that there was no deterioration in fluidity and air quality due to the change in the super retarding agent mixing rate. It was found that when super retarding agent was mixed up to 0.5 %, it was delayed for 22.3 hours at 20℃, 48.2 hours at 10℃, and 48.5 hours at 5℃. Therefore in order to ensure the performance required at the site, the super retarding agent mixing rate must be determined by fully considering the situation at the site. In addition it will be analyzed that super retarding agent performance analysis at high temperature will be required in subsequent studies.

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Effect of Gelling Agent Molecular Weight on Self-Discharge Behavior for Zinc-Air Batteries (아연-공기 전지용 전해질의 Gelling Agent 분자량에 따른 자가 방전 억제 효과)

  • Park, Jeong Eun;Jo, Yong Nam
    • Korean Journal of Materials Research
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    • v.29 no.12
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    • pp.812-817
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    • 2019
  • A zinc-air battery is one of most promising advanced batteries due to its high specific energy density, low cost, and environmental friendliness. However, zinc anodes in zinc-air batteries lead to several issues including self-discharge, corrosion reaction, and hydrogen evolution reaction (HER). In this paper, viscosity of electrolyte has been controlled to suppress the corrosion reaction, HER, and self-discharge behavior. Various viscosity average molecular weights of poly(acrylic acid) (PAA) are adopted to prepare the electrolyte. The evaporation of electrolytes is proportional to the increase in molecular weight. In addition, enhanced self-discharge behavior is obtained when the gelling agent with high molecular weight is used. In addition, the zinc-air cell assembled with lower viscosity average molecular weight of PAA (Mv ~ 450,000) delivers 510.85 mAh/g and 489.30 mAh/g of discharge capacity without storage and with 6 hr storage, respectively. Also, highest capacity retention (95.78 %) is obtained among studied materials.

A Experimental Study on Autogenous Shrinkage properties of Ultra High-Strength Concrete Using Expansion Agent and Shrinkage-reducing (수축저감제 및 팽창재를 조합 사용한 초고강도 콘크리트의 자기수축 특성에 관한 실험적 연구)

  • Park, Hyun;Park, Heung-Lee;Kim, Hak-Young;Paik, Min-Su;Kim, Woo-Jae;Jung, Sang-Jin
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2009.11a
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    • pp.73-76
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    • 2009
  • In ultra-high-strength concrete, chemical shrinkage is larger than drying shrinkage due to using a large amount of cement and admixtures, and this is a factor deteriorating the quality of structures. Thus, we need a new technology for minimizing the shrinkage strain of ultra-high-strength concrete. So, this study have prepared super-high-strength concrete with specified mixing design strength of over 100MPa and have evaluated a method of reducing chemical shrinkage by using expander and shrinkage-reducing agent. According to the results of this study, with regard to the change in length by chemical shrinkage, an expansion effect was observed until the age of seven days. The expansion effect was higher than previous research that used only expander or shrinkage reducing agent. In addition, ultra-high-strength concrete showed a shrinkage rate that slowed down with time, and the effect of the addition of expander material on compressive strength was insignificant. That is shown that required more database to be accumulated through experimental research for the shrinkage strain of members.

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Analysis of Wafer Cleaning Solution Characteristics and Metal Dissolution Behavior according to the Addition of Chelating Agent (착화제 첨가에 따른 웨이퍼 세정 용액 특성 분석 및 금속 용해 거동)

  • Kim, Myungsuk;Ryu, Keunhyuk;Lee, Kun-Jae
    • Journal of Powder Materials
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    • v.28 no.1
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    • pp.25-30
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    • 2021
  • The surface of silicon dummy wafers is contaminated with metallic impurities owing to the reaction with and adhesion of chemicals during the oxidation process. These metallic impurities negatively affect the device performance, reliability, and yield. To solve this problem, a wafer-cleaning process that removes metallic impurities is essential. RCA (Radio Corporation of America) cleaning is commonly used, but there are problems such as increased surface roughness and formation of metal hydroxides. Herein, we attempt to use a chelating agent (EDTA) to reduce the surface roughness, improve the stability of cleaning solutions, and prevent the re-adsorption of impurities. The bonding between the cleaning solution and metal powder is analyzed by referring to the Pourbaix diagram. The changes in the ionic conductivity, H2O2 decomposition behavior, and degree of dissolution are checked with a conductivity meter, and the changes in the absorbance and particle size before and after the reaction are confirmed by ultraviolet-visible spectroscopy (UV-vis) and dynamic light scattering (DLS) analyses. Thus, the addition of a chelating agent prevents the decomposition of H2O2 and improves the life of the silicon wafer cleaning solution, allowing it to react smoothly with metallic impurities.

A Study on the Characteristics of Mortar Using Foaming Agents (기포제(起泡劑)를 사용(使用)한 모르터의 제특성(諸特性)에 관(關)한 연구(硏究))

  • Sung, Chan Yong
    • Korean Journal of Agricultural Science
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    • v.15 no.1
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    • pp.82-94
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    • 1988
  • This study was performed to obtain the basic data which can be applied to use of foaming mortars. The results obtained were summarized as follows ; 1. The lowest water-cement ratios were shown at the mixing ratio of 1 : 1. But, it was gradually increased in poorer mixing ratio and decreased in more addition of foaming agent. The water-cement ratios were decreased up to 1.6-53.1% by mix-foaming type and 4.4-24.1% by pre-foamed type than cement mortar. 2. The highest bulk densities were shown at the mixing ratio of 1 : 1. But, it was gradually decreased in poorer mixing ratio and more addition of foaming agent. The decreasing rates of bulk densities were increased in richer mixing ratio and more addition of foaming agent. 3. The bulk densities were decreased up to 38.8-55.9% by mix-foaming type and 9.7-23.6% by pre-foamed type than cement mortar. 4. The lowest absorption rates were shown at the mixing ratio of 1 : 1. But, it was gradually increased in poorer mixing ratio and more addition of foaming agent. The increasing rates of absorption rates were increased in richer mixing ratio and more addition of foaming agent. 5. Absorption rates when immersed in 72hours were shown up to 3.41-5.85 times greater by mix-foaming type and 1.05-1.55 times greater by pre-foamed type than those of cement mortar. it was significantly higher at the early stage of immersed time than cement mortar. 6. The highest strengths were shown at the mixing ratio of 1 : 1. But, it was gradually decreased in poorer mixing ratio and more addition of foaming agent. The decreasing rates of strengths were increased in poorer mixing ratio and more addition of foaming agent. 7. The strengths were decreased up to 77.0-92.8% by mix-foaming type and 36.7-74.4% by pre-foamed type than cement mortar. 8. The lowest air contents were shown at the mixing ratio of 1 : 1. But, it was gradually increased in poorer mixing ratio and more addition of foaming agent. The increasing rates of air contents were increased in richer mixing ratio and more addition of foaming agent. 9. Air contents were shown up to 26.0-63.8 times greater by mix-foaming type and 5.8-17.7 times greater by pre-foamed type than those of cement mortar. 10. The correlations between bulk density, absorption rate, compressive strength and air content were highly significant. The multiple regression equations of bulk density, absorption rate, compressive strength, tensile strength, bending strength and air content were computed depending on a function of mixing ratio and addition of foaming agent. They were generally highly significant.

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