• Title/Summary/Keyword: Activity Support

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Metal effects in Mn-Na2WO4/SiO2 upon the conversion of methane to higher hydrocarbons

  • Tang, Liangguang;Choi, Jonghyun;Lee, Woo Jin;Patel, Jim;Chiang, Ken
    • Advances in Energy Research
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    • v.5 no.1
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    • pp.13-29
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    • 2017
  • The roles of Na, Mn, W and silica, and the synergistic effects between each metal in the $MnNa_2WO_4/SiO_2$ catalyst have been investigated for oxidative coupling of methane (OCM). The crystallisation of amorphous silica during calcination at $900^{\circ}C$ was promoted primarily by Na, but Mn and W also facilitated this process. The interaction between Na and Mn tended to increase the extent of conversion of $Mn_3O_4$ to $Mn_2O_3$. The formation of $Na_2WO_4$ was dependent on the order in which Na and W were introduced to the catalyst. The impregnation of W before Na resulted in the formation of $Na_2WO_4$, but this did not occur when the impregnation order was reversed. $MnWO_4$ formed in all cases where Mn and W were introduced into the silica support, regardless of the impregnation order; however, the formation of $MnWO_4$ was inhibited in the presence of Na. Of the prepared samples in which a single metal oxide was introduced to silica, only $Mn/SiO_2$ showed OCM activity with significant oxygen conversion, thus demonstrating the important role that Mn plays in promoting oxygen transfer in the reaction. The impregnation order of W and Na is critical for catalyst performance. The active site, which involves a combination of Na-Si-W-O, can be formed in situ when distorted $WO_4^{2-}$ interacts with silica during the crystallisation process facilitated by Na. This can only occur if the impregnation of W occurs before Na addition, or if the two components are introduced simultaneously.

Maximizing TPBs through Ni-self-exsolution on GDC based composite anode in solid oxide fuel cells

  • Tan, Je-Wan;Lee, Dae-Hui;Kim, Bo-Gyeong;Kim, Ju-Seon;Mun, Ju-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.402.1-402.1
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    • 2016
  • The performance of solid oxide fuel cells (SOFCs) is directly related to the electrocatalytic activity of composite electrodes in which triple phase boundaries (TPBs) of metallic catalyst, oxygen ion conducting support, and gas should be three-dimensionally maximized. The distribution morphology of catalytic nanoparticle dispersed on external surfaces is of key importance for maximized TPBs. Herein in situ grown nickel nanoparticle onto the surface of fluorite oxide is demonstrated employing gadolium-nickel co-doped ceria ($Gd0.2-xNixCe0.8O2-{\delta}$, GNDC) by reductive annealing. GNDC powders were synthesized via a Pechini-type sol-gel process while maximum doping ratio of Ni into the cerium oxide was defined by X-ray diffraction. Subsequently, NiO-GNDC composite were screen printed on the both sides of yttrium-stabilized zirconia (YSZ) pellet to fabricate the symmetrical half cells. Electrochemical impedance spectroscopy (EIS) showed that the polarization resistance was decreased when it was compared to conventional Ni-GDC anode and this effect became greater at lower temperature. Ex situ microstructural analysis using scanning electron microscopy after the reductive annealing exhibited the exsolution of Ni nanoparticles on the fluorite phases. The influence of Ni contents in GNDC on polarization characteristics of anodes were examined by EIS under H2/H2O atmosphere. Finally, the addition of optimized GNDC into the anode functional layer (AFL) dramatically enhanced cell performance of anode-supported coin cells.

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A Study on the Effect of CEO and Eemployee's Intention to Innovation Activity Performances (경영자와 조직구성원의 의지가 혁신활동성과에 미치는 영향에 관한 연구)

  • Kim, Tae Sung;Koo, Il Seob
    • Asia-Pacific Journal of Business Venturing and Entrepreneurship
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    • v.10 no.2
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    • pp.11-16
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    • 2015
  • A lot of factor effects on the enterprise's innovation and business performance, for instance CEO and members intention etc.. Niehoff et al. says, The success factors of innovation enterprise's management lead to members of vision, innovation, innovation activities and support for an aggressive attitude of the enterprise members. However, today's products consumers wanted diverse and complex needs. CEO and members of the enterprise has been the diversity effort. The increase cost savings as well as in the profit improve factors that enterprise's participated a education and training, Subgroup activities, process quality, eliminate waste, improve yields, lead time reduction, process capability increasing, ets. This paper is a report of an empirical survey performed to 277 small and medium-sized enterprise in the korea. Cronbach's alpha coefficient is employed to analyze the reliability of the data. The effect analysis of each group is performed by the SEM(structural equation model). We use the SPSS' Amos program to analyze the equation modeling and test the hypotheses of the model.

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Control Method of Adaptive Duty-cycling for Monitoring System in Excavations (굴착현장 모니터링 시스템을 위한 적응적인 듀티사이클링 제어 기법)

  • Kim, Taesik;Min, Hong;Jung, Jinman
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.16 no.6
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    • pp.141-146
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    • 2016
  • Geotechnial engineering projects that requires excavation activity can cause massive ground deformation and this can damage adjacent structures. Depending on the engineering characteristics of ground material and the excavation depth, the ground movement is various. To overcome this issue, the ground deformation is monitored by multiple sensors. Typically, an inclinometer is installed behind the support wall. In this paper, we present an adaptive duty-cycling control mechanism using wireless sensors for monitoring ground deformation in excavations. The proposed mechanism dynamically adjusts the sleep time based on the urgency degree of sensed data from inclinometer. Through analytical evaluation of expected latency time, we confirm our adaptive duty-cycling mechanism has lower latency compared with periodic duty-cycling mechanism under variable conditions.

Service Platform and Mobile Application for Smart Tour Guide (스마트 투어 가이드를 위한 서비스 플랫폼과 모바일 앱)

  • Jwa, Jeong-Woo
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.16 no.6
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    • pp.203-209
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    • 2016
  • Digital tourism is the digital support of the tourist experience before, during and after the tourist activity[1]. The GPS-enabled mobile phones provide location-based mobile applications such as tour guide and storytelling services. In this paper, we propose the smart tour guide service platform based on GIS and develop the mobile application to provide the smart tour guide service. The proposed smart tour guide service platform consists of CMS, the multi-modal navigation system, the tour attraction content creation and management system, the tour commodity creation and management system, the smart search system, and the user terminal. The smart tour guide application supports digital tourism in the pre-tour, during tour, and post-tour using the proposed smart tour guide service platform in the popular tourist attractions in Jeju.

A Study on the Effects of Entrepreneurship and Innovation Activities of Venture Enterprises on the Increase Firms' Revenue (벤처기업의 기업가정신과 혁신활동이 기업 매출 신장에 미치는 영향에 관한 연구)

  • kim, In-Sue;Yoo, Kyeong-Sik;Kim, Yoon-Dong
    • Journal of the Korea Convergence Society
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    • v.8 no.12
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    • pp.329-341
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    • 2017
  • In order to analyze how the entrepreneurship affects the commercialization performance in relation to R&D input factors, technological innovation and technology in the course of technology commercialization process. Korean manufacturing venture companies has been surveyed. The structural equation model showed technology commercialization mechanism driven by entrepreneurship. Innovativeness is one of the most important factors in the success of venture firms. Technology commercialization was dependent on innovation rather than the input of research and development resources. Technological innovation shows mediating effects in the influence of entrepreneurship on commercialization performance, but technology capability has relatively small effect. Commercialization process of new product development and product improvement was different. The government needs to actively support R&D strategies and commercialization infrastructure in order to promote innovation, assist R&D workforce and enhance product commercialization in venture companies.

Effects of Lifestyle Intervention on Fatigue, Nutritional Status and Quality of Life in Patients with Gynecologic Cancer (생활습관중재가 부인암 환자의 피로와 영양상태 및 삶의 질에 미치는 효과)

  • An, Hyunjin;Nho, Ju-Hee;Yoo, Sunyoung;Kim, Hyunmin;Nho, Minji;Yoo, Hojeong
    • Journal of Korean Academy of Nursing
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    • v.45 no.6
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    • pp.812-822
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    • 2015
  • Purpose: The purpose of this study was to examine the effect of lifestyle intervention on the development of fatigue, nutritional status and quality of life of patients with gynecologic cancer. Methods: A nonequivalent control group quasi-experimental design was used. Participants were 49 patients with gynecologic cancer. They were assigned to the experiment group (n=24) or the control group (n=25). The lifestyle intervention for this study consisted of physical activity, nutritional education, telephone call counseling, health counseling, monitoring for lifestyle, and affective support based on Cox's Interaction Model of Client Health Behavior and was implemented for six weeks. Results: Significant group differences were found for fatigue (p =.037), nutritional status (p =.034) and social/family well-being (p =.035) in these patients with gynecologic cancer. Conclusion: Results indicate that this lifestyle intervention is effective in lessening fatigue, and improving nutritional status and social/family well-being. Therefore, nurses in hospitals should develop strategies to expand and provide lifestyle interventions for patients with cancer.

A Search for the Initiation and the Performances of the Small Capital Ventures: The Beauty Salon Business (소자본 창업과 성과에 대한 탐색적 연구 -미용 산업을 중심(中心)으로-)

  • Park, Il-Soon;Min, Sung-Ky
    • Asia-Pacific Journal of Business Venturing and Entrepreneurship
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    • v.4 no.3
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    • pp.23-38
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    • 2009
  • The paper tried to search the characteristics and performances of the new business openers in the area of the beauty salon business. Most of the business owners are women and university graduates. They are mostly active and positive. The search found that the location is one of the most important subject in the small service business. They also tend to calculate the revenues and expenses everyday. They pay lots of attention for the financial performance. They were not much confident with their capital raising. The lowest point was in the area of governmental support. The size and equity capital followed next. The regression analysis showed that continuous marketing activity is important for the performance of the venture.

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Biomechanical Analysis of the Elderly Gait with a Walking Assistive Device (노인의 보행보조기구 사용 보행시 보행패턴의 변화연구)

  • Yoon, Suk-Hoon
    • Korean Journal of Applied Biomechanics
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    • v.17 no.2
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    • pp.1-9
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    • 2007
  • Walking is not only an essential component of the human mobility, but also is a good exercise. Inability to walk freely can reduce an individual's quality of life and independence substantially. Being a relatively low impact activity, walking is particularly good for the elderly and research has shown that regular walking in the elderly reduces the chance of fall-related injuries and mental diseases as well. In spite of the documented benefits of regular walking, it is still difficult to walk without the aid of assistive devices for the frail elderly who have lower extremity problems. Assistive walking devices(AWD), such as crutches, canes, hiking-poles, T-Poles and walkers, are often prescribed to the elderly to make their walking be safe and efficient. Many researchers have demonstrated the effects of AWDs such as reducing lower extremity loading, improved dynamic/gait stability, yet, no study has been done for gait pattern when the elderly gait with AWDs. Therefore, the purpose of this study was to examine whether T-Poles, one of the AWDs, change the elderly gait pattern. Eight community-dwelling female elderly participated in this study. Laboratory kinematics during walking with T-Poles(PW) and with out T-Poles(NPW) was assessed. PW showed significant increase in step width, stride length, gait velocity and decrease in swing time. No significances were found in lower body joint angles but meaningful trend and pattern were found. Maybe the reason was due to the participants. Our participants were healthy enough so that the effect of T-Poles was minimum. PW also showed typical gait phases which are no single support phase during a gait cycle. It indicates that walking with T-Poles may guarantee safe and confident walking to the frail elderly.

Around East Sea Region Port Logistics Industry Activation Scheme with Gangwon Province (환동해권 항만물류산업 활성화방안 - 강원도를 중심으로 -)

  • Cha, Sun-Gwon
    • Journal of Korea Port Economic Association
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    • v.24 no.4
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    • pp.385-406
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    • 2008
  • This study aims to contribute regional economic development by means of searching port logistics industry activation scheme of Gangwon province which has locational advantage around the East Sea Region. Thus, this thesis was provided the port logistics industry activation schemes of that region in the point of local and government view. In the local government level, this study was provided the selection of a key port and its intensive development, establishment of port networking among major port and e-port system of this region, and enlargement of the FTA etc. Also this study was required the relative industry invitation and upbringing, and intensive port logistics marketing activity. On the other hand, in the government level, it needs larger SOC investment for enlargement of direct accessibility and connection to the Gangwon-do ports, and required the intensive and efficient support. Finally, it was proposed the establishment of the total logistics expert education system.

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