• Journal of the Korean Applied Science and Technology
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• 제26권3호
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• pp.328-334
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• 2009

Recently, much interest on mesoporous carbon has been shown in their use for both hydrogen and methane storage and as an electrode material for electric double layer capacitors. The mesoporous active carbons by ion exchange were prepared and physical properties such as specific surface area and pore structure of active carbon were investigated using BET. In this study, active carbons with mesopore fraction of $60{\sim}90%$ were obtained. The Fe/Ca-exchanged active carbons showed a greater mesoporosity compared with Fe-exchanged carbons. The mean mesopore size in active carbons using Ca- and Fe-exchange was about $5.5{\sim}6.0nm$ and was approximately 1nm higher than that of the Fe-exchanged active carbon.

• Proceedings of the Korean Vacuum Society Conference
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.291-291
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• 2010

Organic solar cells have attracted much interest due to the potential advantage of the lightness, simple solution processing and flexibility. Until recently, the focus of organic solar cells research has been on optimization of material processing to improve the power conversion efficiency. However, area scaling is an important position for alternative to the market dominating solar cells. Spray deposition technologies have advantage of less material wastage and possibility of large scale photoactive area coating when compared with spin coating process. We investigated the performance of organic solar cells as a function of active area using two types of deposition process. The commonly used process is spin coating which can be fabricated organic materials deposition for devices. Spray deposition process compare with spin coating for large-area organic solar cells. The spray deposition organic layer shows excellent performance up to the active area of $4\;cm^2$ with the PCE of ~3.0 % under AM.1.5 simulated illumination with an intensity of $100mW/cm^2$. This indicates that the spray deposition process can be used as a mass production process for evaluating large-area organic solar cells.

• Journal of Internet of Things and Convergence
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• 제8권4호
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• pp.17-23
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• 2022

NB-IoT and LTE Cat.M1 based on LPWA(Low Power Wide Area) are commercialized and serviced by mobile carriers. As the demand for IoT devices is increased, the number of subscribers to these services is also increasing. In the beginning of service, there was no issue that eNB capacity for NB-IoT and LTE Cat.M1. However, as the number of subscribers increases, there is an issue that the eNB capacity for these service is insufficient. Active UE capacity issue may cause overload by continuous increase and temporary increase. In this paper, we propose a solution to solve the problem of LTE RRC(Radio Resource Control) Active UE capacity shortage and base station overload caused by the increase of NB-IoT and LTE Cat.M1 UE in same eNB. The proposed solution can increase a cell capacity without cell division and additional eNB, and can also improve the service quality of these UEs.

• KEPCO Journal on Electric Power and Energy
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• 제5권4호
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• pp.331-335
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• 2019

In this study we investigate catalytic activity and selectivity of mixture of Ag and ketjenblack according to their ratios by product analysis and electrochemical experiments, such as cyclic voltammetry, linear sweep voltammetry and chronoamperometry. We reveal that catalytic activity toward CO₂ reduction to CO is improved by simple mixing Ag nanoparticle and ketjenblack because addition of ketjenblack suppresses aggregation of Ag nanoparticles and brings increase in electrochemical active surface area. However, excess amount of ketjenblack rather inhibit the CO₂ reduction to CO. These observations provide clues to develop highly active Ag catalyst or electrode toward electrochemical reduction of CO₂.

• Journal of the Korean Crystal Growth and Crystal Technology
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• 제22권6호
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• pp.269-273
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• 2012

Ammonia decomposition over titanium carbides were investigated using eight different samples which have been synthesized by TPR (temperature-programmed reduction) method of titanium oxide ($TiO_2$) with pure $CH_4$. The resulting materials which were synthesized using wo different heating rates and space velocity exhibited the different surface areas. These results indicated that the structural properties of these materials have been related to heating rates and space velocity employed. The titanium carbides prepared in this study proved to be active for ammonia decomposition, and the activity changed with the particle size/surface area. These showed the relationship between ammonia decomposition activity and the different active species. Compared to molybdenum carbide, the titanium carbides were one order of magnitude less active, suggesting the correlation between the activity difference and the degree of electron transfer between metals and carbon in metal carbides.

• Communications for Statistical Applications and Methods
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• 제8권2호
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• pp.407-416
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• 2001

Sample surveys are usually designed and analyzed to produce estimates for a large area or populations. Therefore, for the small area estimations, sample sizes are often not large enough to give adequate precision. Several small area estimation methods were proposed in recent years concerning with sample sizes. Here, we will compare simple Bayesian approach with Bayesian prediction for small area estimation based on linear regression model. The performance of the proposed method was evaluated through unemployment population data form Economic Active Population(EAP) Survey.

• The Bulletin of The Korean Astronomical Society
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• 제37권1호
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• pp.88.2-88.2
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• 2012

We investigate solar flare occurrence rate and daily flare probability depending on McIntosh sunspot classification, its area, and its area change. For this we use the NOAA active region and GOES solar flare data for 15 years (from January 1996 to December 2010). We consider the most flare-productive 10 sunspot classification: 'Dko', 'Dai', 'Eai', 'Fai', 'Dki', 'Dkc', 'Eki', 'Ekc', 'Fki', and 'Fkc'. Sunspot area and its change can be a proxy of magnetic flux and its emergence/cancellation, respectively. we classify each sunspot group into two sub-groups: 'Large' and 'Small'. In addition, for each group, we classify it into three sub-groups according to sunspot group area change: 'Decrease', 'Steady', and 'Increase'. As a result, in the case of compact groups, their flare occurrence rates and daily flare probabilities noticeably increase with sunspot group area. We also find that the flare occurrence rates and daily flare probabilities for the 'Increase' sub-groups are noticeably higher than those for the other sub-groups. In case of the (M+X)-class flares of 'Dkc' group, the flare occurrence rate of the 'Increase' sub-group is three times higher than that of the 'Steady' sub-group. Mean flare occurrence rates and flare probabilities for all sunspot regions increase with the following order: 'Steady', 'Decrease', and 'Increase'. Our results statistically demonstrate that magnetic flux and its emergence enhance major solar flare occurrence. We are going to forecast solar flares based on these results and NOAA scale.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2007년도 춘계학술대회
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• pp.305-308
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• 2007

The field of dye-sensitized solar cell (DSC) is being researched actively at present. Because DSC has several advantages to pass the limits of Si solar cells such as a low manufacturing expense, a simple manufacturing process and its transparency. A lot of researches are underway about materials and processes in the field of dye-sensitized solar cell but its structure has been fixed up as the sandwich structure that both edges are used as positive and negative terminals. But the structure as of present is a factor of decreasing efficiency because the more electrons are recombined the further distance from terminal, considering about the characteristic of dye-sensitized solar cell that electrons generated inside cell are moved by diffusion. In this study, we made experiment on expanding the terminal to shorten internal moving distance of electron and compared the results according to the variation of active area to find out the effect of this trial. As a result, we achieved about 15.5% improvement of maximum power and 0.5% improvement of efficiency from terminal-expanded dye-sensitized solar cell of $2cm^{2}$ active area and concluded that the increasing rate of efficiency is raised as the active area becomes wider.

• Carbon letters
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• 제28권
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• pp.105-110
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• 2018

Owing to their scalability, flexible operation, and long cycle life, vanadium redox flow batteries (VRFBs) have gained immense attention over the past few years. However, the VRFBs suffer from significant polarization, which decreases their cell efficiency. The activation polarization occurring during vanadium redox reactions greatly affects the overall performance of VRFBs. Therefore, it is imperative to develop electrodes with numerous catalytic sites and a long cycle life. In this study, we synthesized heteroatom-rich carbon-based freestanding papers (H-CFPs) by a facile dispersion and filtration process. The H-CFPs exhibited high specific surface area (${\sim}820m^2g^{-1}$) along with a number of redox-active heteroatoms (such as oxygen and nitrogen) and showed high catalytic activity for vanadium redox reactions. The H-CFP electrodes showed excellent electrochemical performance. They showed low anodic and cathodic peak potential separation (${\Delta}E_p$) values of ~120 mV (positive electrolyte) and ~124 mV (negative electrolyte) in cyclic voltammetry conducted at a scan rate of $5mV\;s^{-1}$. Hence, the H-CFP-based VRFBs showed significantly reduced polarization.

• JSTS:Journal of Semiconductor Technology and Science
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• 제13권3호
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• pp.198-206
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• 2013

This paper presents a wide band, fine-resolution digitally controlled oscillator (DCO) with an on-chip 3-D solenoid inductor using the 0.13 ${\mu}m$ digital CMOS process. The on-chip solenoid inductor is vertically constructed by using Metal and Via layers with a horizontal scalability. Compared to a spiral inductor, it has the advantage of occupying a small area and this is due to its 3-D structure. To control the frequency of the DCO, active capacitor and active inductor are tuned digitally. To cover the wide tuning range, a three-step coarse tuning scheme is used. In addition, the DCO gain needs to be calibrated digitally to compensate for gain variations. The DCO with solenoid inductor is fabricated in 0.13 ${\mu}m$ process and the die area of the solenoid inductor is 0.013 $mm^2$. The DCO tuning range is about 54 % at 4.1 GHz, and the power consumption is 6.6 mW from a 1.2 V supply voltage. An effective frequency resolution is 0.14 kHz. The measured phase noise of the DCO output at 5.195 GHz is -110.61 dBc/Hz at 1 MHz offset.