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http://dx.doi.org/10.12925/jkocs.2009.26.3.11

Preparation of mesoporous carbon using ion exchange  

Lee, Jong-Dae (Department of Chemical Engineering College of Engineering, Chungbuk National University)
Kang, Chae-Yoen (Department of Chemical Engineering College of Engineering, Chungbuk National University)
Kang, Min-Goo (Department of Chemical Engineering College of Engineering, Chungbuk National University)
Publication Information
Journal of the Korean Applied Science and Technology / v.26, no.3, 2009 , pp. 328-334 More about this Journal
Abstract
Recently, much interest on mesoporous carbon has been shown in their use for both hydrogen and methane storage and as an electrode material for electric double layer capacitors. The mesoporous active carbons by ion exchange were prepared and physical properties such as specific surface area and pore structure of active carbon were investigated using BET. In this study, active carbons with mesopore fraction of $60{\sim}90%$ were obtained. The Fe/Ca-exchanged active carbons showed a greater mesoporosity compared with Fe-exchanged carbons. The mean mesopore size in active carbons using Ca- and Fe-exchange was about $5.5{\sim}6.0nm$ and was approximately 1nm higher than that of the Fe-exchanged active carbon.
Keywords
mesoporous carbon; ion exchange; active carbon; Fe; Ca;
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1 T. Kyotani, Control of pore structure III carbon, Carbon, 38(2), 269 (2000)   DOI   ScienceOn
2 L. Li, H. Song and X. Chen, Ordered mesoporous carbonization silicaltriblock carbons from the of sulfuric-add-treated copolymer/sucrose composites, Microporous and Mesoporous Materials, 94(1-3), 9 (2006)   DOI   ScienceOn
3 I. Sutherland, E. Sheng, R. H. Bradley and P. K. Freakley, Effects of orone oxidation on carbon black surfaces, J. Mater. Sci., 31(21), 5651 (1996)   DOI   ScienceOn
4 P. Karandikar, K. R. Patil, A. Mitra, B. Kakade and A. J. Chandwadkar, Synthesis and characterization of rnesoporous carbon through inexpensive mesoporous silica as template, Microporous and Mesoporous Materials, 98(1 -3), 189 (2007)   DOI   ScienceOn
5 K. Kinoshita, Carbon : Electrochemical and physicochemical properies, Wiley, 465 (1988)
6 A. Tomita, Y. Yuhki, K. Higashiyama, T. Takarada and Y. Tamai, Nenryo Kyokaishi(J. Fuel Soc. Jpn), 64, 402 (1985)   DOI
7 F. Rodriguez-reinoso, The role of carbon materials in heterogeneous catalysis, Carbon, 36(3), 159 (1998)   DOI   ScienceOn
8 J S. Yu, S. Kang, S. B. Yoon and G. Chai, Fabrication of ordered uniform porous carbon networks and their application to a catalyst supporter, J. Am Chem Soc., 124(32), 9382 (2002)   DOI   ScienceOn
9 K. S. W. Sing, D. H. Everett, R. Haul, L. Moscou, R. A. Pierotti, J. Rouquerol and T. Siemieniewska, Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity, Pure and Applied Chem, 54(11), 2201 (1982)   DOI
10 O. Barbieri, M. Hahn, A. Herzog and R. Katz, Capacitance limits of high surface area activated carbons for double layer capacitors, Carbon, 43(6), 1303 (2005)   DOI   ScienceOn
11 C. Lin and J. A. Ritter, Effect of synthesis pH on the structure of carbon xerogels, Carbon, 35(9), 1271 (1997)   DOI   ScienceOn
12 G. Gryglewicz, J. Machnikowski, E. Lorenc-Grabowska, G. Lota and E. Frackowiak, Effect of pore size distribution of coal-based activated carbons on double layer capacitance, Electrochimiro Acta, 50(5), 1197 (2005)   DOI   ScienceOn
13 H. Li, H. Xi, S. Zhu, A. Wen and R. Wang, Preparation, structural characterizatioin, and electrochemical properties of chemically modified mesoporous carbon, Microporous and Mesoporous Materials, 96(1-3), 357(2006)   DOI   ScienceOn
14 E. Lorenc-Grabowska, G. Gryglewicz and S. Gryglewicz, Development of mesoporosity in activated carbons via coal modification using Ca- and Fe-exchange, Microporous and Mesoporous Materials, 76(1-3), 193 (2004)   DOI   ScienceOn
15 C. Morenocastilla, M. A. Ferrogarcia, J P. joly, I. Bautistatoledo, F. Carrascomarin and J. Riverautrilla, Activated carbon surface modifications by nitric-acid, hydrogen-peroxide, and ammonium peroxydisulfate treatments, Langmuir, 11(11), 4386 (1995)   DOI
16 Z. Liu, L. Ling, W. Qiao and L. Liu, Effect of hydrogen on the mesopore development of pitch-based spherical activated carbon containing iron during activation by steam, Carbon, 37(12), 2063 (1999)   DOI   ScienceOn
17 J. Ozaki, N. Endo, W. Ohizumi, K. Igarashi, M. Nakahara, A. Oya, S. Yoshida and T. Iizuka, Novel preparation method for the production of mesoporous carbon fiber from a polymer blend, Carbon, 35(7), 1031 (1997)   DOI   ScienceOn