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http://dx.doi.org/10.5714/CL.2018.28.105

Catalytic effects of heteroatom-rich carbon-based freestanding paper with high active-surface area for vanadium redox flow batteries  

Lee, Min Eui (Department of Polymer Science and Engineering, Inha University)
Kwak, Hyo Won (Department of Polymer Science and Engineering, Inha University)
Jin, Hyoung-Joon (Department of Polymer Science and Engineering, Inha University)
Publication Information
Carbon letters / v.28, no., 2018 , pp. 105-110 More about this Journal
Abstract
Owing to their scalability, flexible operation, and long cycle life, vanadium redox flow batteries (VRFBs) have gained immense attention over the past few years. However, the VRFBs suffer from significant polarization, which decreases their cell efficiency. The activation polarization occurring during vanadium redox reactions greatly affects the overall performance of VRFBs. Therefore, it is imperative to develop electrodes with numerous catalytic sites and a long cycle life. In this study, we synthesized heteroatom-rich carbon-based freestanding papers (H-CFPs) by a facile dispersion and filtration process. The H-CFPs exhibited high specific surface area (${\sim}820m^2g^{-1}$) along with a number of redox-active heteroatoms (such as oxygen and nitrogen) and showed high catalytic activity for vanadium redox reactions. The H-CFP electrodes showed excellent electrochemical performance. They showed low anodic and cathodic peak potential separation (${\Delta}E_p$) values of ~120 mV (positive electrolyte) and ~124 mV (negative electrolyte) in cyclic voltammetry conducted at a scan rate of $5mV\;s^{-1}$. Hence, the H-CFP-based VRFBs showed significantly reduced polarization.
Keywords
catalytic effect; carbon-based freestanding papers; heteroatom; high active-surface area; vanadium redox flow batteries;
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1 Pezeshki AM, Clement JT, Veith GM, Zawodzinski TA, Mench MM. High performance electrodes in vanadium redox flow batteries through oxygen-enriched thermal activation. J Power Sources, 294, 333 (2015). https://doi.org/10.1016/j.jpowsour.2015.05.118.   DOI
2 Kim J, Lim H, Jyoung JY, Lee ES, Yi JS, Lee D. High electrocatalytic performance of N and O atomic co-functionalized carbon electrodes for vanadium redox flow battery. Carbon, 111, 592 (2017). https://doi.org/10.1016/j.carbon.2016.10.043.   DOI
3 Kim KJ, Lee HS, Kim J, Park MS, Kim JH, Kim YJ, Skyllas-Kazacos M. Superior electrocatalytic activity of a robust carbonfelt electrode with oxygen-rich phosphate groups for all-vanadium redox flow batteries. ChemSusChem, 9, 1329 (2016). https://doi.org/10.1002/cssc.201600106.   DOI
4 Lee ME, Jin HJ, Yun YS. Synergistic catalytic effects of oxygen and nitrogen functional groups on active carbon electrodes for all-vanadium redox flow batteries. RSC Adv, 7, 43227 (2017). https://doi.org/10.1039/c7ra08334c.   DOI
5 Huang Y, Deng Q, Wu X, Wang S. N, O Co-doped carbon felt for high-performance all-vanadium redox flow battery. Int J Hydrogen Energy, 42, 7177 (2017). https://doi.org/10.1016/j.ijhydene.2016.04.004.   DOI
6 Dixon D, Babu DJ, Langner J, Bruns M, Pfaffmann L, Bhaskar A, Schneider JJ, Scheiba F, Ehrenberg H. Effect of oxygen plasma treatment on the electrochemical performance of the rayon and polyacrylonitrile based carbon felt for the vanadium redox flow battery application. J Power Sources, 332, 240 (2016). https://doi.org/10.1016/j.jpowsour.2016.09.070.   DOI
7 Liu T, Li X, Nie H, Xu C, Zhang H. Investigation on the effect of catalyst on the electrochemical performance of carbon felt and graphite felt for vanadium flow batteries. J Power Sources, 286, 73 (2015). https://doi.org/10.1016/j.jpowsour.2015.03.148.   DOI
8 Kabtamu DM, Chen JY, Chang YC, Wang CH. Water-activated graphite felt as a high-performance electrode for vanadium redox flow batteries. J Power Sources, 341, 270 (2017). https://doi.org/10.1016/j.jpowsour.2016.12.004.   DOI
9 Li W, Liu J, Yan C. Multi-walled carbon nanotubes used as an electrode reaction catalyst for $VO_2{^+}/VO^{2+}$ for a vanadium redox flow battery. Carbon, 49, 3463 (2011). https://doi.org/10.1016/j.carbon.2011.04.045.   DOI
10 Park M, Jung Y, Kim J, Lee HI, Cho J. Synergistic effect of carbon nanofiber/nanotube composite catalyst on carbon felt electrode for high-performance all-vanadium redox flow battery. Nano Lett, 13, 4833 (2013). https://doi.org/10.1021/nl402566s.   DOI
11 Han P, Wang H, Liu Z, Chen X, Ma W, Yao J, Zhu Y, Cui G. Graphene oxide nanoplatelets as excellent electrochemical active materials for $VO_2^+/VO^{2+}$ and $V^{2+}/V^{3+}$ redox couples for a vanadium redox flow battery. Carbon, 49, 693 (2011). https://doi.org/10.1016/j.carbon.2010.10.022.   DOI
12 Zhang ZH, Zhao TS, Bai BF, Zeng L, Wei L. A highly active biomass-derived electrode for all vanadium redox flow batteries. Electrochim Acta, 248, 197 (2017). https://doi.org/10.1016/j.electacta.2017.07.129.   DOI
13 Maharjan M, Bhattarai A, Ulaganathan M, Wai N, Oo MO, Wang JY, Lim TM. High surface area bio-waste based carbon as a superior electrode for vanadium redox flow battery. J Power Sources, 362, 50 (2017). https://doi.org/10.1016/j.jpowsour.2017.07.020.   DOI
14 Park JH, Park JJ, Park OO, Jin CS, Yang JH. Highly accurate apparatus for electrochemical characterization of the felt electrodes used in redox flow batteries. J Power Sources, 310, 137 (2016). https://doi.org/10.1016/j.jpowsour.2016.02.005.   DOI
15 Ulaganathan M, Jain A, Aravindan V, Jayaraman S, Ling WC, Lim TM, Srinivasan MP, Yan Q, Madhavi S. Bio-mass derived mesoporous carbon as superior electrode in all vanadium redox flow battery with multicouple reactions. J Power Sources, 274, 846 (2015). https://doi.org/10.1016/j.jpowsour.2014.10.176.   DOI
16 Lee ME, Lee S, Jin HJ, Yun YS. Standalone macroporous graphitic nanowebs for vanadium redox flow batteries. J Ind Eng Chem, 60, 85 (2018). https://doi.org/10.1016/j.jiec.2017.09.043.   DOI
17 Mustafa I, Lopez I, Younes H, Susantyoko RA, Al-Rub RA, Almheiri S. Fabrication of freestanding sheets of multiwalled carbon nanotubes (Buckypapers) for vanadium redox flow batteries and effects of fabrication variables on electrochemical performance. Electrochim Acta, 230, 222 (2017). https://doi.org/10.1016/j.electacta.2017.01.186.   DOI
18 Yun YS, Lee ME, Joo MJ, Jin HJ. High-performance supercapacitors based on freestanding carbon-based composite paper electrodes. J Power Sources, 246, 540 (2014). https://doi.org/10.1016/j.jpowsour.2013.08.011.   DOI
19 Yun YS, Park KY, Lee B, Cho SY, Park YU, Hong SJ, Kim BH, Gwon H, Kim H, Lee S, et al. Sodium-ion storage in pyroprotein-based carbon nanoplates. Adv Mater, 27, 6914 (2015). https://doi.org/10.1002/adma.201502303.   DOI
20 Kudin KN, Ozbas B, Schniepp HC, Prud’homme RK, Aksay IA, Car R. Raman spectra of graphite oxide and functionalized graphene sheets. Nano Lett, 8, 36 (2008). https://doi.org/10.1021/nl071822y.   DOI
21 Yoon HJ, Lee ME, Kim, NR, Yang SJ, Jin HJ, Yun YS. Hierarchically nanoporous pyropolymer nanofibers for surface-induced sodium-ion storage. Electrochim Acta, 242, 38 (2017). https://doi.org/10.1016/j.electacta.2017.05.014.   DOI
22 Larcher D, Tarascon JM. Towards greener and more sustainable batteries for electrical energy storage. Nat Chem, 7, 19 (2015). https://doi.org/10.1038/nchem.2085.   DOI
23 Chu S, Majumdar A. Opportunities and challenges for a sustainable energy future. Nature, 488, 294 (2012). https://doi.org/10.1038/nature11475.   DOI
24 Dunn B, Kamath H, Tarascon JM. Electrical energy storage for the grid: a battery of choices. Science, 334, 928 (2011). https://doi.org/10.1126/science.1212741.   DOI
25 Tarascon JM, Armand M. Issues and challenges facing rechargeable lithium batteries. Nature, 414, 359 (2001). https://doi.org/10.1038/35104644.   DOI
26 Munoz PM, Correa G, Gaudiano ME, Fernandez D. Energy management control design for fuel cell hybrid electric vehicles using neural networks. Int J Hydrogen Energy, 42, 28932 (2017). https://doi.org/10.1016/j.ijhydene.2017.09.169.   DOI
27 Sangsefidi FS, Salavati-Niasari M, Varshoy S, Shabani-Nooshabadi M. Investigation of $Mn_2O_3$ as impurity on the electrochemical hydrogen storage performance of $MnO_2-CeO_2$ nanocomposites. Int J Hydrogen Energy, 42, 28473 (2017). https://doi.org/10.1016/j.ijhydene.2017.09.144.   DOI
28 Lin K, Chen Q, Gerhardt MR, Tong L, Kim SB, Eisenach L, Valle AW, Hardee D, Gordon RG, et al. Alkaline quinone flow battery. Science, 349, 1529 (2015). https://doi.org/10.1126/science.aab3033.   DOI
29 Mayer T, Kreyenberg D, Wind J, Braun F. Feasibility study of 2020 target costs for PEM fuel cells and lithium-ion batteries: a two-factor experience curve approach. Int J Hydrogen Energy, 37, 14463 (2012). https://doi.org/10.1016/j.ijhydene.2012.07.022.   DOI
30 Wang W, Luo Q, Li B, Wei X, Li L, Yang Z. Recent progress in redox flow battery research and development. Adv Funct Mater, 23, 970 (2013). https://doi.org/10.1002/adfm.201200694.   DOI
31 Park M, Ryu J, Wang W, Cho J. Material design and engineering of next-generation flow-battery technologies. Nat Rev Mater, 2, 16080 (2016). https://doi.org/10.1038/natrevmats.2016.80.
32 Su L, Zhang D, Peng S, Wu X, Luo Y, He G. Orientated graphene oxide/Nafion ultra-thin layer coated composite membranes for vanadium redox flow battery. Int J Hydrogen Energy, 42, 21806 (2017). https://doi.org/10.1016/j.ijhydene.2017.07.049.   DOI
33 Li L, Kim S, Wang W, Vijayakumar M, Nie Z, Chen B, Zhang J, Xia G, Hu J, Graff G, et al. A stable vanadium redox-flow battery with high energy density for large-scale energy storage. Adv Energy Mater, 1, 394 (2011). https://doi.org/10.1002/aenm.201100008.   DOI
34 Skyllas-Kazacos M, Rychcik M, Robins RG, Fane AG, Green MA. New all-vanadium redox flow cell. J Electrochem Soc, 133, 1057 (1986). https://doi.org/10.1149/1.2108706.   DOI
35 Skyllas-Kazacos M, Grossmith F. Efficient vanadium redox flow cell. J Electrochem Soc, 134, 2950 (1987). https://doi.org/10.1149/1.2100321.   DOI
36 Sadhasivam T, Kim HT, Park WS, Lim H, Ryi SK, Roh SH, Jung HY. Low permeable composite membrane based on sulfonated poly(phenylene oxide) (sPPO) and silica for vanadium redox flow battery. Int J Hydrogen Energy, 42, 19035 (2017). https://doi.org/10.1016/j.ijhydene.2017.06.030.   DOI
37 Park M, Jeon IY, Ryu J, Baek JB, Cho J. Exploration of the effective location of surface oxygen defects in graphene-based electrocatalysts for all-vanadium redox-flow batteries. Adv Energy Mater, 5, 1401550 (2014). https://doi.org/10.1002/aenm.201401550.
38 Park M, Ryu J, Kim Y, Cho J. Corn protein-derived nitrogen-doped carbon materials with oxygen-rich functional groups: a highly efficient electrocatalyst for all-vanadium redox flow batteries. Energy Environ Sci, 7, 3727 (2014). https://doi.org/10.1039/c4ee02123a.   DOI