• Title/Summary/Keyword: Activation parameters

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Preparation and Characterization of KOH-Activated Carbons Developed from Petroleum Coke

  • Sayed Ahmed, S.A.;Abo El-Enin, Reham M.M.;El-Nabarawy, Th.
    • Carbon letters
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    • v.10 no.4
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    • pp.293-299
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    • 2009
  • Potassium hydroxide activated carbons were prepared from Egyptian petroleum cokes with different KOH/coke ratios and at different activation temperatures and times. The textural properties were determined by adsorption of nitrogen at $-196^{\circ}C$. The adsorption of iodine and methylene blue was also investigated at $30^{\circ}C$. The surface area and the non-micropore volume increased whereas the micropore volume decreased with the increase of the ratio KOH/coke. Also the surface area and porosity increased with the rise of activation temperature from 500 to $800^{\circ}C$. Textural parameter considerably increased with the increase of activation time from 1 to 3 h. Further increasing of activation time from 3 to 4 h was associated with a less pronounced increase in textural parameters. The adsorption of iodine shows the same trend of surface area and porosity change exhibited by nitrogen adsorption, with KOH/coke ratio and temperature of activation. Adsorption of methylene blue follows pseudo-first-order kinetics and its equilibrium adsorption follows Langmuir and D-R models.

Effects of Curcumin on the Microglial Activation (Curcumin이 microglia의 활성화에 미치는 영향)

  • 정기경;이상진;이선우;강석연;김태균;강주혜;홍성렬;주일로;김승희
    • YAKHAK HOEJI
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    • v.44 no.5
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    • pp.448-454
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    • 2000
  • Microglia, brain resident macrophages, play a central role in the inflammatory responses of the brain and are activated in brain injuries and several neurodegenerative diseases such as Alzheimer's and Parkinson's disease, thereby aggravating the course of these diseases. In this study, the effects of plantderived compounds such as curcumin or gingerol on the microglial activation were examined. Microglial cultures were prepared from 2~3 week mixed primary glial cultures obtained from the cerebral cortex of 1~2 day old rats and identified by immunocytochemistry using microglial-specific antibody OX-42. Microglia were activated by lipopolysaccharide (LPS) and interferon-${\gamma}$ (IFN-${\gamma}$) and the effect of curcumin or 6-gingerol on the microglial activation was examined. Specific parameters measured to monitor microglial activation were nitric oxide (NO), prostaglandin E$_2$(PGE$_2$) and tumor necrosis factor-$\alpha$ (TNF-$\alpha$) release. Curcumin (1~10 $\mu$M) inhibited NO release induced by LPS and IFN-${\gamma}$ in a dose-dependent manner whereas 6-gingerol (2~20 $\mu$M) did not have any effect on LPS/IFN-${\gamma}$-induced NO release. The levels of PGE$_2$and TNF-$\alpha$ induced by LPS and IFN-${\gamma}$ were also inhibited by 1~10 $\mu$M curcumin in a dose-dependent manner. These results showed that curcumin could modulate microglial activation.

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A study on time-varying control of learning parameters in neural networks (신경망 학습 변수의 시변 제어에 관한 연구)

  • 박종철;원상철;최한고
    • Proceedings of the Korea Institute of Convergence Signal Processing
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    • 2000.12a
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    • pp.201-204
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    • 2000
  • This paper describes a study on the time-varying control of parameters in learning of the neural network. Elman recurrent neural network (RNN) is used to implement the control of parameters. The parameters of learning and momentum rates In the error backpropagation algorithm ate updated at every iteration using fuzzy rules based on performance index. In addition, the gain and slope of the neuron's activation function are also considered time-varying parameters. These function parameters are updated using the gradient descent algorithm. Simulation results show that the auto-tuned learning algorithm results in faster convergence and lower system error than regular backpropagation in the system identification.

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Kinetic Data for Texture Changes of Foods During Thermal Processing

  • Lee, Seung Hwan
    • Food Engineering Progress
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    • v.21 no.4
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    • pp.303-311
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    • 2017
  • To automate cooking processes, quantitative descriptions are needed on how quality parameters, such as texture change during heating. Understanding mechanical property changes in foods during thermal treatment due to changes in chemical composition or physical structure is important in the context of engineering models and in precise control of quality in general. Texture degradation of food materials has been studied widely and softening kinetic parameters have been reported in many studies. For a better understanding of kinetic parameters, applied kinetic models were investigated, then rate constants at $100^{\circ}C$ and activation energy from previous kinetic studies were compared. The food materials are hardly classified into similar softening kinetics. The range of parameters is wide regardless of food types due to the complexity of food material, different testing methods, sample size, and geometry. Kinetic parameters are essential for optimal process design. For broad and reliable applications, kinetic parameters should be generated by a more consistent manner so that those of foods could be compared or grouped.

Synthesis of Activated Carbon from Rice Husk Using Microwave Heating Induced KOH Activation

  • Nguyen, Tuan Dung;Moon, Jung-In;Song, Jeong-Hwan;Kim, Taik-Nam
    • Korean Journal of Materials Research
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    • v.22 no.6
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    • pp.321-327
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    • 2012
  • The production of functional activated carbon materials starting from inexpensive natural precursors using environmentally friendly and economically effective processes has attracted much attention in the areas of material science and technology. In particular, the use of plant biomass to produce functional carbonaceous materials has attracted a great deal of attention in various aspects. In this study the preparation of activated carbon has been attempted from rice husks via a chemical activation-assisted microwave system. The rice husks were milled via attrition milling with aluminum balls, and then carbonized under purified $N_2$. The operational parameters including the activation agents, chemical impregnation weight ratio of the calcined rice husk to KOH (1:1, 1:2 and 1:4), microwave power heating within irradiation time (3-5 min), and the second activation process on the adsorption capability were investigated. Experimental results were investigated using XRD, FT-IR, and SEM. It was found that the BET surface area of activated carbons irrespective of the activation agent resulted in surface area. The activated carbons prepared by microwave heating with an activation process have higher surface area and larger average pore size than those prepared by activation without microwave heating when the ratio with KOH solution was the same. The activation time using microwave heating and the chemical impregnation ratio with KOH solution were varied to determine the optimal method for obtaining high surface area activated carbon (1505 $m^2$/g).

Performance Improvement Method of Fully Connected Neural Network Using Combined Parametric Activation Functions (결합된 파라메트릭 활성함수를 이용한 완전연결신경망의 성능 향상)

  • Ko, Young Min;Li, Peng Hang;Ko, Sun Woo
    • KIPS Transactions on Software and Data Engineering
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    • v.11 no.1
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    • pp.1-10
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    • 2022
  • Deep neural networks are widely used to solve various problems. In a fully connected neural network, the nonlinear activation function is a function that nonlinearly transforms the input value and outputs it. The nonlinear activation function plays an important role in solving the nonlinear problem, and various nonlinear activation functions have been studied. In this study, we propose a combined parametric activation function that can improve the performance of a fully connected neural network. Combined parametric activation functions can be created by simply adding parametric activation functions. The parametric activation function is a function that can be optimized in the direction of minimizing the loss function by applying a parameter that converts the scale and location of the activation function according to the input data. By combining the parametric activation functions, more diverse nonlinear intervals can be created, and the parameters of the parametric activation functions can be optimized in the direction of minimizing the loss function. The performance of the combined parametric activation function was tested through the MNIST classification problem and the Fashion MNIST classification problem, and as a result, it was confirmed that it has better performance than the existing nonlinear activation function and parametric activation function.

The Effect of Pressure on the Rate of Solvolysis (Ⅲ) Kinetics on the Nucleophilic Substitution Reactions of Acyl- and Alkyl groups in Binary Solvents (가용매분해반응속도에 대한 압력의 영향(Ⅲ) 이성분용매내 Acyl류와 Alkyl류의 친핵성 치환반응의 속도론적 연구)

  • Kyong, Jin Burm;Park, Byoung Chun;Kwun, Oh Cheun
    • Journal of the Korean Chemical Society
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    • v.41 no.9
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    • pp.443-448
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    • 1997
  • Kinetics for the solvolyses of acyl chlorides and alkyl chlorides in hydroxylic solvent mixtures have been measured by conductometric method at various temperatures and pressures. The activation parameters (${\Delta}V^{\neq},\; {\Delta}H^{\neq},\; {\Delta}S^{\neq}$) were estimated from the rate constants. The reactivities of these reactions were also estimated from the correlation of the activation volumes with the activation entropies.

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Theoretical Studies on the Hydrogen Atom Transfer Reaction (III) (수소원자 전달반응에 관한 이론적 연구 (제 3 보))

  • Ikchoon Lee;Chang Hyun Song;Byung Seo Park
    • Journal of the Korean Chemical Society
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    • v.30 no.2
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    • pp.166-171
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    • 1986
  • Hydrogen atom transfer reactions, $RNH_2+CH_3{\to}RNH+CH_4\;where\;R=H\;and\;CH_3$, were studied by MINDO/3 MO method. It is expected that stable complex may exist between $CH_3\;and\;NH_3$. Transition state characteristics and activation parameters including activation entropies have been determined. In cases of absolute and activation entropies, results are found to agree in general with ab initio and experimental values, wherever comparisions are possible.

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Application of the Arrhenius Equation in Geotechnical Engineering

  • Yoon, Hyung-Koo
    • The Journal of Engineering Geology
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    • v.24 no.4
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    • pp.575-581
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    • 2014
  • The reliable measurement of geotechnical properties in cold regions should account for their fluctuations with temperature. The objective of this paper is to introduce a chemical model based on the Arrhenius equation that can predict the properties of materials as their temperature changes. The model can monitor phases and reaction rates as they change with temperature. It has been already applied in the fields of geology, construction, chemistry, materials engineering, and food science. The application of the Arrhenius equation requires a reliable estimate of the activation energy. Therefore, this study also demonstrates several methods for evaluating activation energy in different contexts through summaries and reviews of previous research related to the Arrhenius equation. This paper may be of wide use in obtaining temperature-dependent parameters in geotechnical engineering.

The investigation of Magnetohydrodynamic nanofluid flow with Arrhenius energy activation

  • Sharif, Humaira;Khadimallah, Mohamed A.;Naeem, Muhammad Nawaz;Hussain, Muzamal;Mahmoud, S.R.;Al-Basyouni, K.S.;Tounsi, Abdelouahed
    • Advances in nano research
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    • v.10 no.5
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    • pp.437-448
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    • 2021
  • In this article, an analytically and numerically 3D nanoliquid flow by a porous rotatable disk is presented in the presence of gyrotactic microorganisms. The mathematical model in the form of partial differential system is transmuted into dimensionless form by utilizing the appropriate transformation. The homotopy analysis approach is applied to attain the analytic solution of the problem. The effect of promising parameters on velocity distribution, temperature profile, nanoparticles volume fraction and motile microorganism distribution field are evaluated through graphs and in tabular form. The existence of Brownian motion and thermophoresis impacts are more proficient for heat transfer enhancement. Further the unique features like heat absorption/generation and energy activation are also examined for the present flow problem. The obtained results are compared with the earliear investigation to check the accuracy of present model.