• 제목/요약/키워드: Activation Properties

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A study on mechanical properties of concrete including activated recycled plastic waste

  • Ashok, M.;Jayabalan, P.;Saraswathy, V.;Muralidharan, S.
    • Advances in concrete construction
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    • v.9 no.2
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    • pp.207-215
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    • 2020
  • This paper describes the experimental studies carried out to determine the properties of fresh and hardened concrete with Recycled Plastic Waste (RPW) as a partial replacement material for fine aggregates. In the experimental study, RPW was used for replacing river sand and manufactured sand (M sand) aggregates in concrete. The replacement level of fine aggregates was ranging from 5% to 20% by volume with an increment of 5%. M40 grade of concrete with water cement ratio of 0.40 was used in this study. Two different types of RPW were used, and they are (i) un-activated RPW and (ii) activated RPW. The activated RPW was obtained by alkali activation of un-activated RPW using NaOH solution. The hardened properties of the concrete determined were dry density, compressive strength, split tensile strength, flexural strength and ultrasonic pulse velocity (UPV). The properties of the concrete with river sand, M sand, activated RPW and un-activated RPW were compared and inferences were drawn. The effect of activation using NaOH solution was investigated using FT-IR study. The micro structural examination of hardened concrete was carried out using Scanning Electron Microscopy (SEM). The test results show that the strength of concrete with activated RPW was more than that of un-activated RPW. From the results, it is evident that it is feasible to use 5% un-activated RPW and 15% activated RPW as fine aggregates for making concrete without affecting the strength properties.

The Effect of Benzyl Alcohol on Dyeing Properties of Silk fiber (I) - The Rate of Dyeing by Milling Acid Dye - (Benzyl Alcohol이 견섬유의 염색성에 미치는 영향(I) - Milling계 산성염료에 의한 염색속도 -)

  • 탁태문;김종호;배도규
    • Textile Coloration and Finishing
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    • v.4 no.2
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    • pp.55-63
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    • 1992
  • The effects of benzyl alcohol on the properties of dyeing kinetic of silk fibroin were studied. The acid dye used was C.I. Acid Red 114. The half dyeing time is shorten by addition of benzyl alcohol. The diffusion activation energy is higher with the increase of the solvent. The rate of dyeing at benzyl alcohol addition to the purified silk fibroin is faster than that of the unpurified one.

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Hydration Mechanism of Alkali Activated Slag Cement

  • Jong Cheol Kim;Keun Ho Auh;Sung Yun Hong
    • The Korean Journal of Ceramics
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    • v.5 no.1
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    • pp.35-39
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    • 1999
  • For many years, alkali activated blast furnace slag cement containing no ordinary portland cement has received much attention in the view of energy saving and its many excellent properties. We examined the structural change of slag glass which was activated by alkali metal compounds using IR spectroscopy. The properties of hydrated products and unhydrated slag grains was characterized by XRD and micro-conduction calorimeter. Ion concentration change in the liquid during the hydration of blast furnace slag was also studied to investigated the hydration mechanism.

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Dielectric Properties of Orthorhombic Dysprosium Manganites

  • Wang, Wei Tian
    • Korean Journal of Materials Research
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    • v.29 no.12
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    • pp.753-756
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    • 2019
  • Orthorhombic dysprosium manganite DyMnO3 with single phase is synthesized using solid-state reaction technique and the crystal structure and dielectric properties as functions of temperature and frequency are investigated. Thermally activated dielectric relaxations are shown in the temperature dependence of the complex permittivity, and the respective peaks are found to be shifted to higher temperatures as the measuring frequency increases. In Arrhenius plots, activation energies of 0.32 and 0.24 eV for the high- and low-temperature relaxations are observed, respectively. Analysis of the relationship between the real and imaginary parts of the permittivity and the frequencies allows us to explain the dielectric behavior of DyMnO3 ceramics by the universal dielectric response model. A separation of the intrinsic grain and grain boundary properties is achieved using an equivalent circuit model. The dielectric responses of this circuit are discerned by impedance spectroscopy study. The determined grain and grain boundary effects in the orthorhombic DyMnO3 ceramics are responsible for the observed high- and low-temperature relaxations in the dielectric properties.

Electrical Properties and Surface Morphology for Temperature in PU Derivatives Monolayers (PU 유도체 단분자막의 온도에 따른 전기 물성과 표면 형상 관찰)

  • Seo, Jeong-Yeul;Kim, Do-Kyun;Park, Jae-Chul;Kwon, Young-Soo
    • Proceedings of the KIEE Conference
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    • 2000.11c
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    • pp.458-460
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    • 2000
  • We attempted to fabricate polyurethane derivatives (PU-CN, PU-DCM) LB films by using LB method. Also, we investigated the monolayer behavior at the air-water interface by surface pressure-area ($\pi$-A) isotherms. And, the surface morphologies and the physicochemical properties of LB films were investigated by atomic force microscopy (AFM) and UV-vis spectroscopy, respectively. Also, the electrical properties of polyurethane derivatives LB films were investigated by using the conductivity, the dielectric constant and activation energy. In the surface morphologies, physicochemical, electrical properties of polyurethane derivatives LB films, the properties is different as to the Polyurethane derivatives, it is considered that this phenomena could be described by the difference of lumophore pendant which was adhered at PU main chain.

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The Study of antibiotic Enzyme from higher plant (고등식물의 병원균에 대한 항균성을 나타내는 효소(Chitinase와 Glucanase)에 관한 고찰)

  • 홍순강
    • Journal of environmental and Sanitary engineering
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    • v.10 no.2
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    • pp.74-78
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    • 1995
  • Several reports have suggested that these hydrolases( chitlnase, glucanase ) are likely volved in defense reactions in this Plant. In this paper, Induction by ethylene, mechanism, properties and function for Activation of these enzymes were Summarized.

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Characteristics on Chemical Activation and VOCs Adsorption of Activated Carbon according to Mixing Ratio of Anthracite and Lignite (활성탄 제조시 유·무연탄 혼합에 따른 화학적 활성화 및 휘발성유기화합물 흡착 특성)

  • Cho, Joon-Hyung;Kang, Sung-Kyu;Kang, Min-Kyoung;Cho, Kuk;Oh, Kwang-Joong
    • Clean Technology
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    • v.23 no.4
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    • pp.364-377
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    • 2017
  • In this study, to improve the low surface area of domestic anthracite as raw materials of activated carbon, characteristics on chemical activation and VOCs adsorption of activated carbon according to mixing ratio of anthracite and lignite. For these, properties of raw materials, parameter characteristics of preparation processes for activated carbon, and VOCs adsorption characteristic of the prepared activated carbon are analyzed. The experimental results showed that, the domestic anthracite had disadvantages of high contents for ash and lead, arsenic, which were exceeded for the heavy metal limits, in the properties of raw materials. To improve these diadvantages, using the mixing ratio of anthracite and lignite, and the optimum conditions for pretreatment, activation, washing, and pellitization process, the activated carbon had a range of BET (Brunauer-Emmett-Teller) surface area of $1,154{\sim}1,420m^2g^{-1}$ with mesopore development and hydrophobic surface property. The carbons were satisfied with the quality standard for granular activated carbon, and had similar physicochemical properties with the commercial activated carbon. The minimum mixing condition for commercial VOCs activated carbon performance must have the caloric value of above $5,640kcal\;kg^{-1}$, and the carbon had higher adsorption capacity with order of xylene > toluene > benzene according to more higher molcular weight and hydrophobic property.

Measurement of the Device Properties of Photoelectric Smoke Detector for the Fire Modeling (화재모델링을 위한 광전식 연기감지기의 장치물성 측정)

  • Cho, Jae-Ho;Mun, Sun-Yeo;Hwang, Cheol-Hong;Nam, Dong-Gun
    • Fire Science and Engineering
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    • v.28 no.6
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    • pp.62-68
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    • 2014
  • The high predictive performance of fire detector models is essentially required for the reliable design of evacuation safety using the fire modeling. The main objective of the present study is to measure input information in order to predict the accurate activation time of photoelectric smoke detector adopted in fire dynamics simulator (FDS) recognized a representative fire model. To end this, the fire detector evaluator (FDE) which could be measured the device properties of detector was used, and the input information of Heskestad and Cleary's models was obtained for a spot-type photoelectric smoke detector. In addition, the activation times of smoke detector predicted using default values into FDS and measured values in the present study were quantitatively compared. As a result, the Heskestad model could result in an inaccurate the activation time of photoelectric smoke detector compared to the Cleary model. In addition, there was a distinct difference between the default values used into FDS and the measured values in terms of device properties of smoke detector, and thus the activation time also showed a significant difference.

Measurement of the Device Properties of Fixed Temperature Heat Detectors for the Fire Modeling (화재모델링을 위한 정온식 열감지기의 장치물성 측정)

  • Park, Hee-Won;Cho, Jae-Ho;Mun, Sun-Yeo;Park, Chung-Hwa;Hwang, Cheol-Hong;Kim, Sung-Chan;Nam, Dong-Gun
    • Fire Science and Engineering
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    • v.28 no.1
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    • pp.37-43
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    • 2014
  • The high predictive performance of fire detector models is essentially needed to assure the reliability of fire and evacuation modeling in the process of Performance-Based fire safety Design (PBD). The main objective of the present study is to measure input information in order to predictive the accurate activation time of fixed temperature heat detectors adopted in Fire Dynamics Simulator (FDS) as a representative fire model. To end this, Fire Detector Evaluator (FDE) which could be measured the device properties of detector was used, and the spot-type fixed temperature heat detectors of two thermistor types and one bimetal type were considered as research objectors. Activation temperature and Response Time Index (RTI) of detectors required for the fire modeling were measured, and then the RTI was measured for ceiling jet flow and vertical jet flow in consideration of the install location of detectors. The results of fire modeling using measured device properties were compared and validated with the experimental results of full-scale compartment fires. It was confirmed that, in result, the numerically predicted activation time of detector showed reasonable agreement with the measured activation time.

Thermal Inactivation of Crude Papain and Papaya Peroxidase (Papaya중의 단백질 분해 효소와 Peroxidase의 열 불활성화)

  • Park, Kwan-Hwa;Kim, Ze-Uook;Shin, Jae-Doo;Noh, Bong-Soo
    • Korean Journal of Food Science and Technology
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    • v.11 no.3
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    • pp.171-175
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    • 1979
  • Thermal properties of crude papain and crude peroxidase from domestic papaya were investigated. The crude extract of papaya was inactivated at the temperature range of $60^{\circ}{\sim}90^{\circ}C$ at pH 7.0 and the rest of the activities of papain and peroxidase were determined, respectively. The heat inactivation of papain and papaya peroxidase was biphasic at low temperature. For the thermal inactivation of papain extract, the enthalpy of activation was 91.4 kJ/mol, the entropy of activation, -49.6 J/mol K, and the free energy of activation, 108.5 kJ/mol. The activation energy for the inactivation of papaya peroxidase was 168.5 kJ/mol, the entropy of activation, $200.4\;J/mol{\cdot}K$ and the free energy of activation, 99.7 kJ/mol. The thermal stability of papain showed that it has a possibility for use as a meat tenderizer. It was also discussed that papaya peroxidase could be more suitable as a biochemical criteria for heat treatment than papaya catalase.

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