• Title/Summary/Keyword: Acrylonitrile Butadiene Styrene (ABS)

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Reflectance and Flexural Modulus of ABS/TiO2 Composite Sheets (ABS/TiO2 복합체 쉬트의 반사율과 굴곡 탄성률)

  • Kim, Jun Hong;Yoon, Kwan Han
    • Polymer(Korea)
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    • v.38 no.1
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    • pp.103-107
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    • 2014
  • Poly(acrylonitrile-butadiene-styrene) (ABS) composite sheets containing titanium dioxide ($TiO_2$), barium sulfate ($BaSO_4$), calcium carbonate ($CaCO_3$) were prepared by using a co-rotating twin screw extruder, and the reflectance and flexural modulus of the composite sheets were measured. The fillers were well dispersed in ABS matrix. The reflectance of composite sheet was increased with increasing $TiO_2$ and $BaSO_4$ content. Sheet having $TiO_2$ 20 wt% composition, with 5~20 wt% $BaSO_4$ resulted in more than 95% of reflectance. The flexural modulus of composite sheet was increased from 1864 MPa for $ABS/TiO_2/BaSO_4$ 85/10/5 (w/w/w) to 3134 MPa for $ABS/TiO_2/BaSO_4$ 55/20/25 (w/w/w).

Effects of Blend Composition and Compatibilizer on the Mechanical Properties of Polypropylene/Acrylonitrile-Butadiene-Styrene Blends (블렌드 조성과 상용화제가 폴리프로필렌/ABS 블렌드의 기계적 물성에 미치는 영향)

  • Park, Jung-Hoon;Sung, Yu-Taek;Kim, Woo-Nyon;Hong, John-Hee;Hong, Byeong-Kwon;Yoo, Tae-Wook;Yoon, Ho-Gyu
    • Polymer(Korea)
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    • v.29 no.1
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    • pp.19-24
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    • 2005
  • Polymer blends containing polypropylene (PP) with compatibilizers were prepared using twin screw extruder. Physical properties were investigated using universal test machine (UTM) and Izod impact tester. In the PP/acrylonitrilebutadiene-styrene (ABS) blends, mechanical strength was increased with the addition of PP-g-styrene acryloritrile (PP-g-SAN) compatibilizer, and the ductility was increased with the addition of ethylene-ethyl acrylate-maleic anhydride (E-EAMAH-g-SAN) compatibilizer. For the PP/ABS/ polycarbonate (PC)/Nylon-6,6 blends, impact strength was increased with the addition of ethylene glycidylmethacrylate (E-GMA compatibilizer) up to 0.5 phr. In the case of the PP/ABS/PC/Nylon-6,6/poly(methyl methacrylate) (PMMA)/poly(oxymethylene) (POM)/poly(vinyl acetate) (PVC)/poly(butylene terephthalate) (PBT) blends, mechanical properties were increased by the complex compatibilizing effects of PP-g-SAN, E-EA-MAH-g-SAN and E-GMA, respectively.

Permeation Characteristics of Air and Water Vapor through ABS/filler Hybrid Films (ABS 복합 필름의 공기 및 수증기 투과 특성)

  • Hong, Seong-Uk;Ko, Young-Deok
    • Membrane Journal
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    • v.18 no.3
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    • pp.256-259
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    • 2008
  • In this study, graphite or zeolite 4A was mixed with poly(acrylonitrile-butadiene-strene) (ABS) to make hybrid films, and permeation characteristics of air and water vapor through these films were investigated. In all cases, gas permeabilities of hybrid films were lower than that of pure ABS films. The permeability decrease of oxygen was slightly larger than that of nitrogen, resulting in the little decrease of $O_2/N_2$ selectivity. In addition, the water vapor transfer rates (WVTR) of hybrid films were about half of ABS film's. The decrease of permeabilities may be owing to the increase of tortuosity for diffusion in hybrid films.

Evaluation of Nuclear Medicine Applications of 3D Printing Phantom - Gamma Camera Centrically (3D 프린팅 팬텀의 핵의학분야 적용 평가 - 감마카메라 중심으로)

  • Park, Hoon-Hee;Lee, Juyoung;Kim, Ji-Hyeon
    • The Korean Journal of Nuclear Medicine Technology
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    • v.21 no.2
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    • pp.65-73
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    • 2017
  • Purpose 3D 프린팅 기술은 3D 스캔이나 모델링을 통하여 적측가공 방식으로 제작하는 기공기술로서 금형 없이 직접 생산이 가능하고 빠른 시간 내에 제작이 가능하여 최근 다양한 산업분야에서 본격적으로 적용되고 있다. 3D 프린팅 기술은 의료분야에 있어, 영상의학 및 방사선 치료분야에서 다양하게 활용되고 있지만 핵의학 분야에서는 관련 연구가 미비한 실정이다. 그러므로 본 연구는 기존에 적용되고 있는 핵의학분야 팬텀과 3D 프린팅 기술로 제작된 텀의 특성을 비교하고 적용 가능성을 평가하는데 목적을 두었다. Materials and Methods 방사선 투과도 변화측정 국제기준 팬텀인 알루미늄(Aluminum) 계단 쐐기(step wedge)를 기준($140mm{\times}62mm{\times}35mm$)으로 PMMA(Poly Methyl Meta Acrylate)와 ABS(Acrylonitrile Butadiene Styrene)재질로 각각 동일한 크기의 팬텀을 제작하였다. PMMA 팬텀은 핵의학 분야에서 주로 적용되는 팬텀의 성분과 동일한 소재로 제작하였고, ABS 팬텀 제작은 3D 프린팅 기술의 액체 기반형의 SLA(Stereo Lithography Apparatus)기법을 사용하여 제작하였다. 본 연구는 SPECT/CT장비 BrightView XCT(Philips Health Care, Cleveland, USA)를 이용하였다. 영상 획득은 Rectangular Flood phantom(Biodex, New York, USA) $^{99m}TcO_4$ 3, 6 mCi와 $^{57}Co$ lood phantom(adqual, New Hampshire, USA) $^{57}Co$ 20 mCi를 이용하여 Aluminum, PMMA, ABS 팬텀에 대해 60 min 리스트모드(List mode)로 획득하였다. 획득한 영상의 분석을 위해 관심영역(ROI)을 설정하여 각 팬텀의 단계별로 평가하였다. Results 방사선원의 종류 및 방사선량에 따라 ABS 팬텀의 계수치는 PMMA 팬텀의 계수치와 유사한 값을 나타내며, 두께의 증가에 따라 선형적으로 감소하였다. Aluminum, PMMA, ABS 팬텀의 선감약계수를 비교했을 때, Aluminum 팬텀의 선감약계수는 나머지 두 팬텀보다 수치가 높았고, PMMA, ABS 팬텀에서는 근사치의 선감약계수가 나타났다. Conclusion 3D 프린팅 기술로 제작된 ABS 팬텀을 기준으로 PMMA 팬텀은 두께가 증가함에 따른 계수치의 변화가 유사하게 선형적으로 감소하였고, 선감약계수도 근사치로 나타내었다. ABS 팬텀의 핵의학적 적용 가능성을 확인할 수 있었으며, 추후 연구를 통해 세부적인 교정치(correction value)를 적용한다면 활발한 적용이 가능하리라 사료된다.

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Evaluation of Scintillation Camera Applications of 3D Printing Phantom (3D 프린팅 팬텀의 섬광카메라 적용 평가)

  • Park, Hoon-Hee;Lee, Ju-young;Kim, Ji-Hyeon
    • Journal of radiological science and technology
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    • v.44 no.4
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    • pp.343-350
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    • 2021
  • 3D printing technology is an additive manufacturing technology produced through 3D scanning or modeling method. This technology can be produced in a short time without mold, which has recently been applied in earnest in various fields. In the medical field, 3D printing technology is used in various fields of radiology and radiation therapy, but related research is insufficient in the field of nuclear medicine. In this study, we compare the characteristics of traditional nuclear medicine phantom with 3D printing technology and evaluate its applicability in clinical trials. We manufactured the same size phantom of poly methyl meta acrylate(PMMA) and acrylonitrile butadiene styrene(ABS) based on the aluminum step wedge. We used BrightView XCT(Philips Health Care, Cleveland, USA) SPECT/CT. We acquired 60 min list mode for Aluminum, PMMA and ABS phantoms using Rectangular Flood Phantom (Biodex, New York, USA) 99mTcO4 3 mCi(111 MBq), 6 mCi (222MBq) and 57Co Flood phantom(adq, New Hampshire, USA). For the analysis of acquired images, the region of interest(ROI) were drawn and evaluated step by step for each phantom. Depending on the type of radioisotope and radiation dose, the counts of the ABS phantom was similar to that of the PMMA phantom. And as the step thickness increased, the counts decreased linearly. When comparing the linear attenuation coefficient of Aluminum, PMMA and ABS phantom, the linear attenuation coefficient of the aluminium phantom was higher than that of the others, and the PMMA and ABS phantom had similar the linear attenuation coefficient. Based on ABS phantom manufactured by 3D printing technology, as the thickness of the PMMA phantom increased, the counts and linear attenuation coefficient decreased linearly. It has been confirmed that ABS phantom is applicable in the clinical field of nuclear medicine. If the calibration factor is applied through further research, it is believed that practical application will be possible.

Efficient Carbonization of ABS Rubber via Iodine Doping

  • Park, Chiyoung;Kim, Chae Bin
    • Elastomers and Composites
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    • v.57 no.1
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    • pp.9-12
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    • 2022
  • Herein, a facile approach for the development of effective and low-cost carbon precursors from acrylonitrile-butadiene-styrene (ABS) rubber is reported. ABS rubber with a negligible char yield can be converted into an excellent carbon precursor with approximately 54% char yield under a nitrogen atmosphere at 800℃ by simple iodine doping and subsequent heating at 110℃ under an inert atmosphere. The enhanced char yield is attributed to the improved intermolecular interactions between the ABS chains caused by the formation of covalent bonds between the butadiene segments, along with the newly developed charge-charge interactions and other indiscriminate radical-radical couplings. The charges and radicals involved in these interactions are also generated by iodine doping. We believe that this study will be useful for the development of low-cost carbon precursors.

Evaluation of the Applicability of PET/CT Phantom as a 3D Printing Material (PET/CT 팬텀의 3D 프린팅 소재 적용 가능성 평가)

  • Lee, Ju-young;Kim, Ji-Hyeon;Park, Hoon-Hee
    • Journal of radiological science and technology
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    • v.45 no.5
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    • pp.423-431
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    • 2022
  • The purpose of this study is to present objective information in applying 3D printing technology for PET/CT (Positron Emission Tomography/Computed Tomography) performance evaluation and use it as a basic research that can be applied to various purposes in the future. Phantoms were manufactured with step wedge of ABS(Acrylonitrile Butadiene Styrene) and ACR(Acrylic acid) material. The counts for each ROI(Region of Interest) were analyzed through image acquisition in PET/CT. And the variation rate of counts and CNR(Contrast Noise Ratio) was evaluated. In the counts analysis, the effect of thickness occurred. In addition, in the variation rate analysis, the thickness setting of steps wedge 4 to 5 levels should be considered first. These results minimize quantitative and qualitative changes in the phantom manufactured based on 3D printing, and enable more stable PET/CT performance evaluation. Based on 3D printing in PET/CT, various phantoms are expected to be produced in the future. If the characteristics of each material are considered and applied through the basic research such as this research, the result of the phantom manufactured through 3D printing can be more meaningful and will be used in a wide range.

Effects of Compatibilizer and Graphene Oxide on the Impact Strength of PC/ABS Blend (PC/ABS의 충격강도에 미치는 상용화제와 그래핀 옥사이드의 영향)

  • Park, Ju Young;Lee, Bom Yi;Cha, Hye Jin;Kim, Youn Cheol
    • Applied Chemistry for Engineering
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    • v.26 no.2
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    • pp.173-177
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    • 2015
  • In this study, effects of both the grafted ABS-g-MAH and the added graphene oxide (GO) on the impact strength of polycarbonate (PC)/poly(acrylonitrile-butadiene-styrene) (ABS) blends were discussed. The PC/ABS blends and PC/ABS/GO composites were fabricated by using twin screw extruder with ABS-g-MAH as a compatibilizer. The ABS-g-MAH was prepared by melting extrusion of ABS and maleic anhydride (MAH) with DCP (dicumyl peroxide) as an initiator using twin screw extruder and the synthesis of ABS-g-MAH was confirmed by the presence of carbonyl group (C=O) peak at $1780cm^{-1}$ of FT-IR spectrum. According to the thermal, rheological, and impact properties of PC/ABS blends, 5 phr (parts per hundred resin) of compatibilizer was chosen as an optimum content for the PC/ABS/GO composites. It was observed that the thermal decomposition of ABS/PC/GO composites increased with GO contents, but there was no significant changes or a decrease in the impact strength. Also the composite fabricated by ABS/GO showed small increase in the impact strength. From the result of the dynamic rheometer to observe the processing properties, the complex viscosities of PC/ABS blend including the compatibilizer increased, but the complex viscosities of composites added GO were not changed.

3D Printing Design for Minimizing Flection Phenomenon (3D 프린팅 휘어짐 현상 최소화를 위한 설계)

  • Choi, Seong-Ook;Hwang, Suk-Seung
    • The Journal of the Korea institute of electronic communication sciences
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    • v.9 no.12
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    • pp.1415-1420
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    • 2014
  • 3D printer is based on an additive manufacturing technology, which helps in creating the three-dimensional object using a 3D drawing. It is used in various fields, because it prints out a variety of three-dimensional products in a short period of time. In this paper, we consider a technique using the FDM(Fused Deposition Modeling) method by dissolving the ABS(Acrylonitrile Butadiene Styrene) resin among a diversity of printing technique and materials. This kind of the 3D printer prints out a product in high temperature and cools down it. In this process, a flection phenomenon is occurred according to the size of the printing product and the surrounding environment. Conventional methods for mitigating this phenomenon maintain the temperature at the optimum level, but they require using additional devices. In order to minimize the flection phenomenon in 3D printing products without additional devices, in this paper, we propose a noble technique, which creates holes on suitable positions when they are designed by 3D drawing tools. Also, we suggest mathematical model for the proposed method, and measure and analyse a printing output using a proposed technique.

Development of Criteria for Predicting Delamination in Cabinet Walls of Household Refrigerators (냉장고 캐비닛 벽면에서 발생하는 박리현상 예측을 위한 평가 기준 개발에 관한 연구)

  • Park, Jin Seong;Kim, Sung Ik;Lee, Gun Yup;Cho, Jong Rae
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.21 no.4
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    • pp.1-13
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    • 2022
  • Household refrigerator cabinets must undergo cyclic testing at -20 ℃ and 65 ℃ for quality control (QC) after their production is complete. These cabinets were assembled from different materials, including acrylonitrile butadiene styrene (ABS), polyurethane (PU) foam, and steel plates. However, different thermal expansion values could be observed owing to differences in the mechanical properties of the materials. In this study, a technique to predict delamination on a refrigerator wall caused by thermal deformation was developed. The mechanical properties of ABS and PU foams were tested, theload factors causing delamination were analyzed, delamination was observed using a high-speed camera, and comparison and verification in terms of stress and strain were performed using a finite element model (FEM). The results indicated that the delamination phenomenon of a refrigerator wall can be defined in two cases. A method for predicting and evaluating delamination was established and applied in an actual refrigerator. To determine the effect of temperature changes on the refrigerator, strain measurements were performed at the weak point and the stress was calculated. The results showed that the proposed FEM prediction technique can be used as a basis for virtual testing to replace future QC testing, thus saving time and cost.