• Title/Summary/Keyword: Acrylic binder

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A Study on Rheology Characteristics of Ag Paste for Screen Printing Method for Silicon Solar Cells Electrodes Capable of Forming High Aspect Ratio (고온 소결형 실리콘 태양 전지의 High Aspect Ratio 전극 형성이 가능한 Ag 페이스트의 레오로지 특성 연구)

  • Oh, Tae-Hun;Kim, Sung-Bin;Nam, Su-Yong
    • Journal of the Korean Graphic Arts Communication Society
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    • v.28 no.1
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    • pp.15-24
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    • 2010
  • Photovoltaic solar cells are all in the incident because they are not converted into electrical energy, high-efficiency solar cells in order to reduce the loss of elements must be. Significant factor in the loss of solar cells, optical loss and electrical loss can be divided into. Optical losses occur when the sun will be joined on the surface of the reflection, the shadow loss due to electrodes, and the losses are in the solar wavelengths. Commercialization is currently the most common solar cells on the front of the light incident on the electrode is formed. Therefore, the shadow caused by the electrode to cover the dead area of the sun, due to factors that hinder the absorption of sunlight which is shadowing them and conversion efficiency of solar cells is the inhibition factor. These barriers to eliminate the electrode linewidth reduces the shadowing to reduce, but simply of the electrode line width is reduced electrode area by reducing the series resistance elevates this because to improve the electrode Aspect ratio(height/width) to increase Ag development of paste is required. In this study, aspect ratio of screen-printing method to increase the electrode Ag paste composition of the binder for the characterization of rheology in the shadow of the electrode by reducing the optical loss of the photoelectric conversion efficiency of solar cells to boost the performance measures was. Properties and printability of the paste, the binder resin sintered characteristics that affect the thermal properties are excellent with a good screen printability acrylic resin, ethyl cellulose, using a resin were evaluated. Prepared paste rheology properties, was formed to evaluate the electrode conductivity and aspect ratio.

PHOTOCATALYTIC ANTIEUNGAL ACTIVITY AGAINST CANDIDA ALBICANS BY $TiO_2$ COATED ACRYLIC RESIN DENTURE BASE

  • Yang Ji-Yeon;Kim Hee-Jung;Chung Chae-Heon
    • The Journal of Korean Academy of Prosthodontics
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    • v.44 no.3
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    • pp.284-294
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    • 2006
  • Statement of problem. Proliferation of Candida albicans is primarily within the plaque on the fitting surface of the denture rather than on the inflamed mucosa. Consequently, the treatment of the denture is equally important as treatment of the tissue. Cleansing and disinfection should be efficiently carried-out as the organisms can penetrate into the voids of the acrylic resin and grow in them, from which they can continue to infect and reinfect bearing tissues. Purpose. The purpose of this study was to evaluate the applicability of photocatalytic reaction to eliminate Candida albicans from acrylic resin denture base, and to investigate the anti-fungal effect with various UVA illumination time. Materials and Methods. The specimens were cured by the conventional method following the manufacturer's instruction using thermal polymerized denture base resin (Vertex RS: Dentimex, Netherlands). $TiO_2$ photocatalyst sol(LT), which is able to be coated at normal temperature, was made from the Ti-alkoxide progenitor. The XRD patterns, TEM images and nitrogen absorption ability of the $TiO_2$ photocatalyst sol(LT) were compared with the commercial $TiO_2$ photocatalyst P-25. The experimental specimens were coated with the mixture of the $TiO_2$ photocatalyst sol(LT) and binder material (silane) using dip-coater, and uncoated resin plates were used as the control group. Crystallinity of $TiO_2$ of the specimen was tested by the XRD. Size, shape and chemical compositions were also analyzed using the FE-SEM/ EDS. The angle and methylene blue degradation efsciency were measured for evaluating the photocatalytic activity of the $TiO_2$ film. Finally, the antifungal activity of the specimen was tested. Candida albicans KCTC 7629(1 ml, initial concentration $10^5$ cells/ ml) were applied to the experiment and control group specimens and subsequently two UVA light source with 10W, 353 nm peak emission were illuminated to the specimens from 15cm above. The extracted $2{\mu}l$ of sample was plated on nutrient agar plate ($Bacto^{TM}$ Brain Heart Infusion; BD, USA) with 10 minute intervals for 120 minute, respectively. It was incubated for 24 hours at $37^{\circ}C$ and the colony forming units (CFUs) were then counted. Results. Compared the characteristics of LT photocatalyst with commercial P-25 photocatalyst, LT were shown higher activity than P-25. The LT coated experimental specimen surface had anatase crystal form, less than 20 nm of particle size and wide specific surface area. To evaluate the photocatalytic activity of specimens, methylene blue degradation reaction were used and about 5% of degradation rate were measured after 2 hours. The average contact angle was less than $20^{\circ}$ indicating that the LT photocatalyst had hydrophilicity. In the antifungal activity test for Candida albicans, 0% survival rate were measured within 30 minute after irradiation of UVA light. Conclusion. From the results reported above, it is concluded that the UVA-LT photocatalytic reaction have an antifungal effect on the denture surface Candida albicans, and so that could be applicable to the clinical use as a cleaning method.

Research on Technique of Gold Powder Painting and Conservation Process for White Porcelain Bottle with Phoenix and Peony Design Poly Chrome (백자채색봉황모란문병 보존처리와 금채장식 기법 연구)

  • Lee, Dahae;Hwang, Hyunsung
    • Conservation Science in Museum
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    • v.12
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    • pp.25-34
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    • 2011
  • This study examined conservation process of white porcelain bottle with phoenix and peony design poly chrome, recovery of golden powder painted porcelain being damaged and colored, and recovery material and conservation methods by using a variety of experiments. Not only traditional method but also modern method can recover golden powder painted area being damaged and/or peel off, and suitable recovery was found out by using experiments. The golden powder paint of pattern edge was recovered not by traditional method but by modern method of golden powder paint with acrylic paint and binder.

Fabrication of Photoimageable Silver Paste for Low-Temperature Cofiring Using Acrylic Binder Polymers and Photosensitive Materials

  • Park, Seong-Dae;Yoo, Myong-Jae;Kang, Nam-Kee;Park, Jong-Chul;Lim, Jin-Kyu;Kim, Dong-Kook
    • Macromolecular Research
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    • v.12 no.4
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    • pp.391-398
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    • 2004
  • Thick-film photolithography is a new technology that combines lithography processes, such as exposure and development, with the conventional thick-film process applied to screen-printing. In this study, we developed a low-temperature cofireable silver paste applicable for thick-film processing to form fine lines using photolitho-graphic technologies. The optimum paste composition for forming fine lines was investigated. The effect of processing parameters, such as the exposing dose, had on the fine-line resolution was also investigated. As the result, we found that the type of polymer and monomer, the silver powder loading, and the amount of photoinitiator were the main factors affecting the resolution of the fine lines. The developed photoimageable silver paste was printed on a low-temperature cofireable green sheet, dried, exposed, developed in an aqueous process, laminated, and then fired. Our results demonstrate that thick-film fine lines having widths < 20 $\mu\textrm{m}$ can be obtained after cofiring.

A Study on Adhesion of Mechanical Properties of Rubber by MgCl2 (투명 차폐 필름 구현을 위한 전도성 복합 바인더의 입자구조에 따른 성능 평가)

  • Park, Ji-won;Back, Jong-Ho;Lee, Tae-Hyung;Kim, Hyun-Joong
    • Journal of Adhesion and Interface
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    • v.18 no.2
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    • pp.59-67
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    • 2017
  • Recently, integration of parts is accelerating according to the growth of the smart mobile industry. The integration of these parts causes problems of interference phenomena between the parts, and the importance of electromagnetic wave shielding technology to solve this problem is highlighted. Electromagnetic wave shielding technology is implemented so as to reflect or absorb electromagnetic waves, and generally conductive materials are utilized for electromagnetic wave shielding. Transparent shielding technology is required according to recent industrial changes. In this research, we propose transparent the shielding film using imprint technology with conductive composite binder. Utilizing UV polymerized acrylic binder to produce a conductive composite binder. Spherical, plate and stacked silver particles were used for conductivity. The changes of the curing characteristics, conductivity and adhesion were observed according to the structural characteristics of the silver particles. The use of spherical particles was the most efficient in the curing process, and an additional curing system was required to complement the UV-shadowing structure. In the conductivity evaluation, the stacked structure showed excellent characteristics. The adhesion of spherical system was the best. It is evaluated as a result of irregularities on the surface. Ultimately, the patterned film using this showed excellent transparency characteristics.

Curing Behaviours and Adhesion Performance of Thermal Cured Acrylic PSAs Synthesized by UV-polymerization (UV 중합을 활용하여 제조된 열경화형 아크릴 점착제의 경화특성 및 접착특성 분석)

  • Nguyen, Hung-Cuong;Lee, Seung-Woo;Back, Jong-Ho;Park, Ji-Won;Kim, Hyun-Joong
    • Journal of Adhesion and Interface
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    • v.19 no.2
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    • pp.74-82
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    • 2018
  • Many methods for cross-linking acrylic PSAs have been discussed previously. For high cross-linking density, epoxy functionalized monomer and methyl aziridines as cross-linking agents were used in this study. Additionally, photopolymerization using different UV doses was investigated to synthesize a binder because of its rapid productivity. FT-IR analysis, curing behaviours and adhesion performance were examined for the relationship between UV doses and temperature as curing conditions. According to the results, the gel fraction was over 50% even at $120^{\circ}C$ after UV curing at a dose of $800mJ/cm^2$. On the other hand, while gel fractions of all samples reached approximately 80% only at $180^{\circ}C$ in thermal curing for 1 hour, gel fractions of the samples after thermal curing for 3 hours increased rapidly above $120^{\circ}C$ regardless of UV doses and reached approximately 100% at $180^{\circ}C$. This means that the second cross-linking reaction, esterification, is mainly dependent on the curing temperature.

Conservation of Iron Dagger & Scabbard Excavated in Daho-ri, Changwon (다호리 출토 칠초철검(漆鞘鐵劍)의 보존)

  • Sim, Myungbo;Lim, Jihyun;Ma, Daewan;Kim, Midori
    • Conservation Science in Museum
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    • v.12
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    • pp.19-24
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    • 2011
  • This study presents an investigation into the conservation process of an iron dagger and scabbard, which are a lacquered scabbard and a dagger inserted in it, excavated in the Daho-ri relic of Changwon by Gimhae National Museum. The bronze dagger whose condition was poor due to corrosion was coated with Incralac, an intensifier, to reveal the surface patterns through a microscope. The lacquered scabbard was removed of foreign substances on the surface and coated with HPC 2%(in water) to protect the film. Applied onto the surface from which foreign substances were removed was Caparol Binder 5%(in water) two to three times to form a protective film and then faced with Korean paper. Once it was fixed in a polyurethane foam in a stable manner, it was turned over to receive the same process on the back. Three layers of Korean paper were attached to the back of the scabbard to support the thin artifact. HPC 2%(in water), which was applied to the scabbard, was also applied to the iron dagger inside for cementing effect. After all the processes were completed, the artifact was put in a transparent acrylic box for future display.

A Study on Painting Layer Fixative Processing of Mural Paintings of Buddhist Temples in Korea (한국 사찰벽화 채색층 고착처리제 적용 연구)

  • Lee, Haw-Soo;Han, Kyeong-Soon;Lee, Sang-Jin
    • Journal of Conservation Science
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    • v.29 no.1
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    • pp.81-92
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    • 2013
  • In the past, European material and method were applied to conservation of Buddhist mural paintings in Korea. At that time, there were inadequate to selection of materials in consideration of porosity and hydrophilicity, therefore insufficiency to assessing their suitability for materials. The treatment result of mural painting are dissatisfied with consolidation of painting layer using synthetic resin. Therefore, it has experimented on applying fixative for reinforcement of painting layer on Buddhist mural painting in order to establish the effects of conservation. In relationship of binder's viscosity, adhesion and penetrating depth, adhesion increased in high-viscosity specimen whereas it decreased in low-viscosity specimen. While the binder's penetrating depths show similar patterns, the surface's response and combination adjacent to painting layer have differences. Animal glue and methyl cellulose (MC) shows excellent performance in their reaction with soil and painting layer. It is estimated that the fixative penetrates deep into soil to produce a stable fixing effect. The viscosity of polyvinyl acetate resin (PVAc) and acrylic resins are low, and thus penetrates well into soil, but they adhere poorly to soil.

Antimicrobial Activity of High Density Polyethylene Fabric Containing Scutellaria Baicalensis Extract-Loaded Zeolite Microparticles (황금추출물 담지 제올라이트 마이크로입자를 함유한 고밀도 폴리에틸렌 원단의 항균 특성)

  • Lee, Sook-Young;Jo, Mi-Rae;Kim, Hyun-Jin;Kwon, Tae-Yub;Han, Hyunjung;Yoon, Young Il;Son, Jun Sik
    • Textile Coloration and Finishing
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    • v.29 no.4
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    • pp.247-255
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    • 2017
  • Scutellaria Baicalensis(SB) is widely used in traditional and modern oriental medicine. It possesses several biology activities such as anti-oxidative, anti-inflammatory, antimicrobial and antiviral activities. In this study, a functional high density polyethylene (HDPE) fabric with antimicrobial properties was developed using zeolite microparticles as a SB extract delivery carrier. Zeolites loaded with SB extract were prepared by immersing in an SB extract aqueous solution. The average size of the SB extract-loaded zeolites was about 0.1 to $2.0{\mu}m$, and the morphology of the zeolites was not altered after SB extract binding. The resulting SB extract-loaded zeolites were then immobilized homogeneously onto the HDPE fabric using acrylic binder. The encapsulation efficiency of SB extract to the zeolite was more than 45%. The in vitro release test of SB extract-loaded zeolites containing HDPE fabrics showed release of 35% of the total SB extract by day 1 in a 24hours immersion study. Moreover, the SB extract-loaded zeolites containing HDPE fabrics showed effective antimicrobial activity against Streptococcus mutans, Staphylococcus aureus, and Klebsiella pneumoniae, indicating that this innovative delivery platform potently imparted antimicrobial activity to the HDPE fabric. In conclusion, the current study suggests that the HDPE fabric containing the SB extract-loaded zeolites microparticle carrier system has potential as an effective antimicrobial textile such as safety gloves, protective gloves etc.

Printing Technology of Nano fiber under 900nm (900nm 이하급 나노섬유의 현장적용 날염기술)

  • Yong, Kwang-Joong;Lee, Beom-Soo;Lee, Hee-Jun;Hwang, Tea-Yeon
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.83-83
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    • 2011
  • 나노섬유는 마이크로 섬유에 비해 $10^3$배 정도의 넓은 표면적을 가지며, 다른 섬유와 비교하여 유연성, 투습성과 같은 특성이 우수하다. 나노섬유의 제조방법은 여러 가지가 있으나, 상용화의 가능성, 적용 고분자의 다양성, 제조공정의 단순성, 다양한 제품기술에의 응용성 등을 고려하여 선택하여야 한다. 나노섬유의 제조기술은 방법에 따라 전기방사, 복합방사, 멜트블로운 공정, 에어레이드 공정, 습식 공정 등으로 나눌 수 있다. 전기방사 등 나노섬유를 대량생산하여 상용화하려는 노력을 지속적으로 하고 있으나 나노섬유의 염색가공에 관련되어 기술적 한계로 제품전개에 많은 어려움을 겪고 있다. 그리하여 본 연구에서는 나노섬유 단독으로 제품화하기에는 강도 등의 문제로 PET에 워터펀칭한 복합소재로 개발하여 900nm 이하의 나노섬유에 대한 최적의 날염조건과 현장적용 생산기술을 개발하고자 하였다. 나노섬유 복합소재에 대하여 Brown, Red, Blue, Black 색상의 안료와 Urethane, Rubber, Acrylic, Eco Binder를 사용하여 날염 실험하였으며, 최적의 조건으로 현장생산에 적용하여 생산하였다. 안료의 고착성을 높여 날염성과 염색견뢰도를 증진시키기 위하여 원적외선 열처리기를 개발하여 현장생산에 접목시켰다. 원적외선 열처리기는 벙커C유 또는 가스 등을 사용하는 텐터나 증열기와는 다르게 전기를 에너지원으로 하여 원적외선 램프를 이용한 건열시스템의 형태로 저공해 및 그린 형태의 열처리기 시스템으로, 섬유에 대한 원적외선의 조사거리, 원적외선 램프의 간격, 적용 온도, 원단이송 속도 등에 따른 최적의 원적외선 열처리기 날염조건을 설정하였다. 바인더에 따른 날염성은 우레탄계 바인더를 사용하였을 경우에 가장 선명하고 깊은 색상을 보였으며, 아크릴계 바인더의 경우가 가장 낮은 색상을 보였으며 염색견뢰도는 대체적으로 양호한 결과를 얻었다. 그리고, 최근 환경적인 추세에 맞추어 에코 바인더를 사용하여 날염한 결과 염색성과 내구성 등은 우레탄계와 아크릴계 바인더의 중간 정도의 결과를 보였다.

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