• Title/Summary/Keyword: Acidic Contaminants

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Feeding Strategies to Produce High Quality Pork - Review -

  • Bosj, P.
    • Asian-Australasian Journal of Animal Sciences
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    • v.12 no.2
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    • pp.271-281
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    • 1999
  • The cost of production of high quality pork is compensated by high returns, but constraints by the market are increasing. A few opportunities to maintain and improve pork quality by dietary means are presented. The healthy value of pork is a prerequisite. A careful control of suppliers and preservation of feeds are essential to protect pork against presence of contaminants from the feed. The feeding level and some dietary components modify the partition of the dietary energy into different pig tissues and chemical components of pork, affecting the hygienic and nutritional value, tenderness and taste. It is difficult to transfer a nutrient from the diet to pork, if the requirements. for growth are satisfied. Fatty acids and Vitamin E are the most studied exceptions. There is some evidence that iron and selenium contents can be affected too. Varying the content of a nutrient frequently changes sensorial and technological properties of pork. The addition of oils improves the acidic profile of depot fats, but the effect on phospholipid composition is not well studied and negative effects on oxidability and consistency of meat products are observed. Vitamin E can improve many healthy and sensorial characteristics, but its effect is clearer when the meat is stressed or manipulated.

Characteristics of Adsorption and Desorption of Metalaxyl in the Green Soil of Golf Course (골프장 그린 토양에서 Metalaxyl의 흡ㆍ탈착 특성)

  • 유병로;정경희
    • Journal of Environmental Science International
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    • v.11 no.3
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    • pp.227-234
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    • 2002
  • Laboratory experiments were conducted to examine the behavior of metalaxyl in environment which was used as pesticide in green soil of golf course and as functions of the characteristics of adsorption, desorption and degradation in soil texture and organic matter contents. Acid water containing metalaxyl was conducted to evaluate the effects on adsorption, desorption and degradation. The adsorption of metalaxyl played more significant role in organic contents than clay contents, and pH Increases more pH 2.5 than pH 5.6. The desorption of metalaxyl from contaminants soil decreased higher organic contents LS-soil than S-soil, but the desorption amount of metalaxyl increased more pH 5.6 than pH 2.5. The rate of degradation of metalaxyl in green soil environmental increased higher organic contents LS-soil than S-soil and decreased more pH 2.5 than pH 5.6. These results indicated that the behavior of metalaxyl of the green soil was affected the soil texture of the golf course. Increasing of organic contents, the adsorption amount of metalaxyl on soil increased. Moreover the decrease of the pH of solution increased adsorption amounts and decreased desorption amounts. As the results, the transportation of metalaxyl in soil decreased the acidic rates. The acidification of soil by the acid rain increased the adsorption amount of metalaxyl, but the degradation of metalaxyl decreased. Therefore, it is possible to sustain contamination in run-off the stream and ground water by residuals in soil.

Preparation of Bucky Paper using Single-walled Carbon Nanotubes Purified through Surface Functionalization and Investigation of Their Field Emission Characteristics (기능화에 의한 단일벽 탄소나노튜브 정제 및 페이퍼 제조와 전계방출 특성 연구)

  • Goak, Jeung-Choon;Lee, Seung-Hwan;Lee, Han-Sung;Lee, Nae-Sung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.5
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    • pp.402-410
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    • 2008
  • Single-walled carbon nanotubes (SWCNTs) were currently produced together with some contaminants such as a metallic catalyst, amorphous carbon, and graphitic nanoparticles, which should be sometimes purified for their applications. This study aimed to develop efficient, scalable purification processes but less harmful to SWCNTs. We designed three-step purification processes: acidic treatment, surface functionalization and soxhlet extraction, and heat treatment. During the soxhlet extraction using tetrahydrofuran, specifically, carbon impurities could be easily expelled through a glass thimble filter without any significant loss of CNTs. Finally, SWCNTs were left as a bulky paper on the filter through membrane filtration. Vertically aligned SWCNTs on one side of bulky paper were well developed in a speparation from the filter paper, which were formed by being sucked through the filter pores during the pressurized filtration. The bucky paper showed a very high peak current density of field emission up to $200\;mA/cm^2$ and uniform field emission images on phosphor, which seems very promising to be applied to vacuum microelectronics such as microwave power amplifiers and x-ray sources.

Design and Preparation of Magnetic CTAB/Montmorillonite Nanocomposite for Phenols Removal

  • Shen, Rong;Yu, Yichang;Wang, Yue;Xia, Zhining
    • Nano
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    • v.13 no.10
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    • pp.1850123.1-1850123.9
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    • 2018
  • The cetyltrimethyl ammonium bromide (CTAB)-modified montmorillonite (MMT) was synthesized via a novel "dissolution and reassembly" method. To determine the optimal formula, the adsorption of C.I. Reactive Red 2 (X3B) with CTAB/MMT was investigated. The optimal CTAB/MMT nanocomposite was used to remove 2,6-dichlorophenol and p-nitrophenol from aqueous solutions. The adsorption results can be described by Langmuir isotherm, and the adsorption capacities were 200 mg/g and 125 mg/g for 2,6-dichlorophenol and p-nitrophenol, respectively. To realize the quick separation and recycle, the magnetic CTAB/MMT was further strategized and synthesized. The adsorption equilibrium time was 15 min for both contaminants; the ions' strength showed a little bit of influence on the adsorption performance. In addition, compared with acidic condition, neutral condition was more beneficial to the adsorption reaction. Due to the addition of $Fe_3O_4$, the adsorption capacities of this magnetic nanocomposite for 2,6-dichlorophenol and p-nitrophenol were a little bit decreased, which were 170 mg/g and 91 mg/g, respectively. However, the magnetic nanocomposite can be separated within 30 s under an external magnetic field, which would be useful in the practical application.

Determination of acidic pharmaceuticals in aquatic environmental samples by LC/ESI-MS/MS (LC/ESI-MS/MS를 이용한 수질 환경 시료 중 산성의약물질 분석방법 비교)

  • Sim, Young-Eun;Cho, Hyun-Woo;Myung, Seung-Woon
    • Analytical Science and Technology
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    • v.21 no.3
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    • pp.191-200
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    • 2008
  • Pharmaceuticals and personal care products (PPCPs) are emerging contaminants in aquatic environmental samples. Therefore, it required rapidly and certainly analytical method for pharmaceuticals which are existed in environment. In this study, Liquid chromatography/tandem mass spectrometry (LC-MS/MS) with electrospray ionization (ESI) was used to measure the concentrations of 7 pharmaceuticals (quinoxaline-2-carboxylic acid, acetylsalicylic acid, diclofenac-Na, naproxen, ibuprofen, mefenamic acid, talniflumate) from environmental water or aquatic samples simultaneously. Effective sample clean-up by solid-phase extraction (SPE) prior to LC-MS/MS analysis is necessary. For further purification, Mixed Cation eXchange (MCX) and Hydrophilic-Lipophilic Balance (HLB) solid-phase extraction (SPE) cartridges were used to eliminate the remaining interferences. LODs (Limits of Detection) and MDLs (Method Detection Limits) for the spiked sample in fresh water were in the range of 0.05~1.50 pg/mL and 0.17~4.90 pg/mL, respectively. The absolute recovery in the concentration of 1.0 ng/mL were between 81.9 and 116.3%. The acidic pharmaceuticals were detected in concentrations of 0.018~16.925 ng/mL in aquatic environmental samples.

As(III) Oxidation and Phenol Adsorption by the Activated Carbon Impregnated with Mn Oxide (망간산화물이 첨착된 활성탄에 의한 페놀흡착 및 비소(III) 산화)

  • Yu, Mok-Ryun;Yang, Jae-Kyu;Chang, Yoon-Young
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.4
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    • pp.423-429
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    • 2008
  • Application of manganese-impregnated activated carbon(Mn-AC) in the treatment of synthetic wastewater containing both organic and inorganic contaminants was investigated. Phenol and As(III) was used as representative organic and inorganic contaminants, respectively. When the stability of Mn-AC at acidic condition was evaluated with variation of solution pH ranging from 2 to 4, Mn-AC was unstable below pH 3, while negligible dissolution of Mn was observed above pH 4. This stability test suggests a plausible applicability of Mn-AC in the treatment of wastewater above pH 4. Compared to AC-alone, the adsorption rates of phenol as well as adsorbed amounts of phenol by Mn-AC were slightly decreased due to the decrease of the surface area by impregnation. The maximum adsorbed amount of phenol by Mn-AC was corresponds to 75% of that by AC-alone from the adsorption isotherm study. The oxidation efficiency of As(III) by Mn-AC was greater than that by AC-alone at lower pHs while reverse trend was observed as pH increased above 7. From this work, it was found that Mn-AC could be used in the simultaneous treatment of both phenol and As(III).

Antifungal Activity of Polygodial against Food-Contaminants and Effects of Temperature and pH on the Action (Polygodial의 식품 오염 진균에 대한 항균 활성과 그 활성능에 미치는 온도 및 pH의 영향)

  • 이재란;이상화;홍순덕
    • Journal of Life Science
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    • v.8 no.4
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    • pp.421-425
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    • 1998
  • The antifungal activity of polygodial, which was isolated from Polygonum hydropiper used as a hot spice in Japan, was investigated through measuring its MICs and against food-contaminants including 4 strains of Saccharomyces cerevisiae, 3 strains of Zygosaccharomyces species, and 5 strains of Aspergillus species. All yeast-like fungi exhibited strong antifungal susceptivilities with MICs and MFCs below 3.13${\mu}g$/ml. Strains of Aspergillu species showed moderate with MIC of 25-50${\mu}g$/ml and MFC of 50-100${\mu}g$/ml. However these strains to sorbic acid, as already known, revealed very weak with MICs of 200-800${\mu}g$/ml and MFCs above 1600${\mu}g$/ml. In addition, effects of various pHs and temperatures on the antifungal activity of polygodial were tested against S. cerevisiae. At $4^{\circ}C$, the fungicidal activity of polygodial gradually increased with incubation time and reached the maximum(MFC of 3. 13${\mu}g$/ml) in 5 hours. At temperatures in the range of 30-$45^{\circ}C$, the activity of polygodial increased in proportion to temperature rise and in particular at $45^{\circ}C$ was possible with the concentration of 0.1${\mu}g$/ml. mOn the other hand, medium pH was also identified to affect the antifungal activity of polygodial. Namely, compared to neutral (pH7), acidic(pH 3) and basic(pH 9) medium synergized its activity (MIC and MFC) to 8- and 2- fold, respectively.

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Conservation of stapled books: Rebinding using colored iron cores (철제 스테이플이 박힌 책의 보존처리)

  • Ha, Hyojin;Choi, Jungeun
    • Journal of Conservation Science
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    • v.30 no.1
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    • pp.27-32
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    • 2014
  • The sample book was printed in 1935. Since the books in the early twentieth century were printed using acidic paper, the color of the paper would change to brown over time due to iron corrosion. In addition to corroding iron cores, the acidity of the paper (pH 3.2) also made the paper brown and fragile, as was true in the case of the sample book. To clean the paper of the sample book and to make it strong, we replaced the iron core and performed wet cleaning on the paper to remove contaminants. Then we pressed the sample book dry, and subsequently linening every page with Minoshi($4g/m^2$). Generally, book conservator rebinding the book using wires or threads: however we have devised a new method to rebind the book using colored iron cores. To color the iron core brown, they were dipped in an aqueous coloring solution ($H_2O$, $C_2H_5OH$, $CuSO_4{\cdot}5H_2O$, $FeCl_3{\cdot}6H_2O$); subsequently, a 20% paraloid B-72 was applied to protect the colored iron cores from corrosion.

Stabilization of Agricultural Soil Contaminated by Arsenic and Heavy Metals using Biochar derived from Buffalo Weed (단풍잎돼지풀 기반 바이오차를 이용한 비소 및 중금속 오염 농경지의 안정화)

  • Koh, Il-Ha;Kim, Jungeun;Kim, Gi Suk;Park, Mi Sun;Kang, Dae Moon;Ji, Won Hyun
    • Journal of Soil and Groundwater Environment
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    • v.21 no.6
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    • pp.87-100
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    • 2016
  • Biochar, which has high alkalinity, has widely studied for amendment of soil that contaminated with heavy metals. The aim of this study is assessment of amendment for arsenic and heavy metals contaminated acidic agricultural soil using biochar that derived from buffalo weed (A. trifida L. var. trifida). Pot experiments were carried out including analysis of soil solution, contaminants fractionation, soil chemical properties and plant (lettuce) uptake rate. Arsenic and heavy metals concentrations in soil solution showed relatively low in biochar added experiments when compared to the control. In the heavy metals fractionation in soil showed decrease of exchangeable fraction and increase of carbonates fraction; however, arsenic fractionations showed constant. Soil chemical properties indicated that biochar could induce recovery of soil quality for plant growth in terms of soil alkalinity. However, phosphate concentration in biochar added soil decreased due to Ca-P precipitation by exchangeable calcium from biochar. Arsenic and heavy metals uptake rate of plant in the amended experiment decreased to 50% when compared to the control. Therefore biochar derived from buffalo weed can be used as amendment material for agricultural soil contaminated with arsenic and heavy metals. Precipitation of As-Ca and metal-carbonates are major mechanisms for soil amendment using char.

Oxidative Degradation of Phenol Using Zero-Valent Iron-Based Fenton-Like Systems (영가철 기반 펜톤 시스템을 활용한 페놀의 산화분해)

  • Kim, Hak-Hyeon;Lee, Hye-Jin;Kim, Hyung-Eun;Lee, Hongshin;Lee, Byeong-Dae;Lee, Changha
    • Journal of Soil and Groundwater Environment
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    • v.18 no.4
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    • pp.50-57
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    • 2013
  • For the last couple of decades, the Fenton (-like) systems have been extensively studied for oxidation of organic contaminants in water. Recently, zero-valent iron (ZVI) has received attention as a Fenton catalyst as well as a reducing agent capable of producing reactive oxidants from oxygen. In this study, the ZVI-based Fenton reaction was assessed for the oxidative degradation of phenol using $ZVI/O_2$, $ZVI/H_2O_2$, ZVI/Oxalate/$O_2$ and hv/ZVI/Oxalate/$O_2$ systems. Reaction parameters such as pH and reagent dose (e.g., ZVI, $H_2O_2$, and oxalate) were examined. In the presence of oxalate (ZVI/Oxalate/$O_2$ and hv/ZVI/Oxalate/$O_2$ systems), the degradation of phenol was greatly enhanced at neutral pH values. It was found that ZVI accelerates the Fenton reaction by reducing Fe(III) into Fe(II). The conversion of Fe(III) into Fe(II) by ZVI was more stimulated at acidic pH than at near-neutral pH values.