• Title/Summary/Keyword: Acid-soil

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불포화 자연토의 포화도에 따른 동전기 정화특성에 관한 실험적 연구

  • 김병일;김익현;김기년;김수삼
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.302-305
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    • 2003
  • The electrokinetic remediation tests for natural soil contaminated by lead are performed on unsaturated conditions, in which the degree of saturation is controlled through the changes in water content and the constant unit weight. At the degree of saturation of 70% the small acid range and electrical potential is developed. The changes in the water content are little above the saturation of 90%. But it is increased by 1.7 times at the degree of saturation of 70%. Finally, the efficiency of extraction is improved at 70% than 100%.

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Release of Cu from SDS micellar solution using complexing agents

  • 김호정;백기태;김보경;이율리아;양지원
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.307-310
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    • 2004
  • Micellar enhanced ultrafiltration (MEUF) is a surfactant-based separation process and it can remove heavy metal ions from aqueous stream effectively. However, it is necessary to recover and reuse surfactants for economic feasibility because surfactant is expensive. Foam fractionation was investigated for both anionic and cationic surfactant recovery. Chelating agent such as ethylenediaminetetraacetic acid (EDTA) was studied for the separation of heavy metals from surfactant solution. Anionic surfactants bound with heavy metals can be recovered by lowering pH (acidification). In this study, citric acid and imminodiacetic acid (IDA) were applied to release copper from sodium dodecyl sulfate (SDS) micellar solution and compared with EDTA. Precipitation of copper by ferricynide and sodium sulfide were also investigated. As a result, ca. 100 % of copper was released from SDS micellar solution by 5 mM of EDTA and citric acid. And 3.3 mM of ferricyanide formed precipitate with 82.7 % of copper. 5 mM of IDA and sodium sulfide released or formed precipitate 82.5 % and 58.9 % of copper, respectively. Citric acid is harmless to environments and ferricyanide precipitates with Cu easily. Therefore, it is considered that citric acid and ferricyanide have competiveness over a famous chelating agent, EDTA, for the separation of Cu from SDS solution.

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Growth Characteristics and Removal Effect of Nitrogen and Phosphorus of Salix gracilistyla Grown in Waterway Soils (하천토양에서 갯버들의 생장특성과 질소와 인의 제거효과)

  • Seo, Byung-Soo;Choi, Su-Min;Park, Chong-Min
    • Journal of Korean Society of Forest Science
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    • v.94 no.1 s.158
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    • pp.1-5
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    • 2005
  • This study was carried out to survey the growth and the photosynthesis of Salix gracilistyla, the reduction rate of nitrogen and phosphoric acid by the plant grown in waterway soil. The results were summarized as follows; I. The contents of nitrogen and phosphoric acid at waterway soils of Mangyeong river showed the highest level in the around Samrye railway bridge where was located in the downstream and livestock complex. 2. The Salix gracilistyla which grown in waterway soil showed that the growth of stem length and diameter were 170~215% and 42.3~79.3%, respectively. In addition the growth rate of Salix gracilistyla was increased with increasing nitrogen concentrations in waterway soils. 3. The rate of photosynthesis was high in waterway soil contained high nitrogen and it appeared the highest in August. 4. The nitrogen and phosphoric acid by Salix gracilistyla grown in waterway soil were removed about 14~15% and 9~11 %, respectively. The Salix gracilistyla was effective removing nitrogen more than phosphoric acid.

Effect of fly ash on the physico-chemical properties (Fly Ash가 토양(土壤)의 물화학성(物化學性)에 미치는 영향(影響))

  • Park, Man;Hur, Nam-Ho;Choi, Jung
    • Korean Journal of Environmental Agriculture
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    • v.10 no.2
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    • pp.133-137
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    • 1991
  • The inorganic constituents in flay ash such as Ca, Mg, Al and Si were extracted by water and 0.5N-Acetic acid, and changes of the physical properties of the fly ash-treated soils were examined to find out the effect of fly ash on the chemical and physical properties of the soils. The dominant day minerals of fly ash were quartz and mullite. More inorganic constituents were extracted from the fly ash by acetic acid than by water. Si and A1 in fly ash were hardly extracted by water. Addition of fly ash to soil below 10%(W/W) caused improvement in the water permeability and the field moisture capacity of the soil, but did not influence the shrinkage and hardness of the soil. Therefore, it was apparent that the effect of the fly ash on the chemical and physical properties of the soils greatly dependedon soil reaction, the organic acid contents, and the amount of fly ash used in treatment.

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Determining Optimum Condition of Acid Hydrolysis Technique for Food Waste Reduction

  • Kim, Eui Yeong;Choi, Young Gwang;Kim, Sung Chul
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.6
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    • pp.606-614
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    • 2017
  • Amount of food waste has been increased annually in Korea and re-use of food waste as a fertilizer or soil amendment in agricultural field has been studied. Therefore, main purpose of this research was to determine optimum condition of hydrolysis for food waste management. Three different solvents, HCl, $H_2SO_4$, and KOH, were used and varied concentration at the range of 10~30% and hydrolysis time at the range of 1~3 hours were evaluated. In general, reduction rate of food waste was increased when concentration of solvent and hydrolysis time was increased except when KOH was used. Among different solvents, concentration, and hydrolysis time, the highest reduction rate (97.79%) was observed when 30% of HCl was used with temperature of $140^{\circ}C$ at 2 hours of hydrolysis time. In addition, neutralization effect of alkalic materials, shell waste (SW) and egg shell (ES) was evaluated. Both SW and ES increased pH of finished acid hydrolysis solution up to 7.61 indicating that neutralization effect of SW and ES was sufficient for finished acid hydrolysis solution. Contents of organic matter was also at the range of 10.7~13.04% and 5.53~8.04% respectively when HCl and $H_2SO_4$ were used as solvent. Overall, hydrolysis technique can be used to manage food waste with selected optimum condition in this study and characteristics of finished hydrolysis solution after neutralization might be suitable for soil amendments.

Processing and Fermentation of Food Wastes with MS Microorganism Complex for Swine Feeds (MS 미생물복합군에 의한 음식폐기물의 양돈사료화를 위한 적정처리공정)

  • Lee, Jeong-Chae;Jung, Woo-Jin;Lim, Kye-Taek;Kim, Tae-Hwan
    • Korean Journal of Environmental Agriculture
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    • v.19 no.4
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    • pp.270-275
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    • 2000
  • In order to investigate the proper processing of food wastes with miraculous soil-microorganisms (MS) for final use of swine feeds, calory, amino acid and fatty acid in food wastes were determined in relation with fermentation process with MS microorganism complex. Aflatoxin test was also performed to check safety of the fermented food wastes. Calory of food wastes was determined in average $7.60\;Kcal{\cdot}g^{-1}\;D.W.$ In finally processed food wastes, total content of amino acid was $93.0\;mg{\cdot}g^{-1}]\;D.W$, showing 18.5% of increase by the anaerobic fermentation. Essential and non-essential amino acids were measured at respectively 34.43 and $58.56\;mg{\cdot}g^{-1}\;D.W.$ Leucine, phenylalanine, isoleucine and threonine of essential amino acids and proline and glutamic acid of non-essential amino acids were highly composed as compared to others. The composition of fatty acid in food wastes was also increased by anaerobic fermentation for 3 weeks. Palmitic acid, oleic acid and palmitoleic acid were more important in quantity. Present results indicate that food wastes properly processed with MS have enough calory and are safe from aflatoxin, and that anaerobic fermentation with MS microorganism in an efficient process for hydrolyzing protein and lipids in food wastes.

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Characteristics of Soil Solution Extracted from Forest Soils Adjacent to Heavy Industrial Complexes (공단 인접지역 산림토양용액의 특성)

  • Lee, Wi-Young;Yang, Jae E.;Park, Chang-Jin;Zhang, Yong-Seon;Ok, Yong-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.37 no.3
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    • pp.184-191
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    • 2004
  • Forest soils were collected from various sites adjacent to the heavy industrial complexes and soil solutions were extracted to characterize the chemical properties and to find factors affecting forest decline by acid deposition. Concentrations of $NO_3{^-}$, $SO{_4}^{2-}$, $F^-$ and Al in the soil solutions collected from industrial complexes were 2-33 times higher than those from the non-industrial areas. pH and Al concentrations were significantly correlated with $NO_3{^-}$ and $SO{_4}^{2-}$ concentrations. Forest soils from Onsan and Ulsan regions had very low Ca and Mg concentrations in the soil solutions. In these sites, the molar ratios of Ca/Al and Mg/Al were also lower than 2 and 1, respectively. Aluminum concentrations in the A and B horizons were 547 and $683mg\;kg^{-1}$, respectively, which were considered to be high enough to inhibit tree growth. Magnesium deficiency in A horizon and high concentrations of Al and Mn in B horizon were considered as the major limiting factors for tree growth by inhibiting the uptake of Ca and Mg and causing the imbalance of nutrients in both soil solution and trees.

비소 및 중금속 오염 토양의 파일럿 토양 세척 연구

  • 고일원;이광표;이철효;김경웅
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.239-242
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    • 2004
  • Pilot-scale soil washing facility was developed and operation condition was determined in order to remediate a soil contaminated with As, Ni and Zn. Soil washing facility is composed of soil particle separation, soil washing and wastewater treatment process. Both oxyanionic As and cationic Ni and Zn were effciently removed using HCl rather 0than H$_2$SO$_4$ and H$_2$PO$_4$. This is why oxyanion and cation metals can be extracted simultaneously from the contaminated soil in acidic solution. Further, the contaminated soils include calcite and then demand much acidity, that is consumption of acid solution. Fine particles are enriched with contaminants, and coarse particles are removed effectively rather than fine particles. As, Ni and Zn are strongly associated with minerals, and then the residence time should be increased for a reaction with washing solution.

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Control effect of isobutyric acid on rice blast (벼 도열병에 대한 indole butyric acid(IBA)의 방제 효과)

  • Kim, Heung-Tae;Hong, Kyeong-Sik;Choi, Gyung-Ja;Jang, Kyung-Soo;Ryu, Choong-Min
    • The Korean Journal of Pesticide Science
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    • v.11 no.4
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    • pp.313-319
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    • 2007
  • Nine plant growth regulators (PGRs) were tested for in vivo antifungal activities against on rice blast. They showed higher in vivo antifungal activities when they were applied on rice plants by soil drench rather than foliar spray. Except for 2,4-D at $500\;{\mu}g\;mL^{-1}$, the others showed a very low or no activity against the disease in foliar spray applications. In contrast, 2,4-D, indole butyric acid (IBA) and triiodobenzoic acid, at $500\;{\mu}g\;mL^{-1}$, showed control values of 98.9, 97.8 and 88.9% in soil drench applications. Furthermore, the control activity of IBA was dependent on its concentration against rice blast; IBA suppressed the development of rice blast by 71.7% at $125\;{\mu}g\;mL^{-1}$ and 85.8% at $250\;{\mu}g\;mL^{-1}$. IBA also controlled the development of rice blast on adult plants by 63.9% at a dosage of 2.56 kg/10a. The results revealed that IBA has a good activity against rice blast when it is applied by soil drench.

Effect on Simulated Acid Rain and Wood Vinegar Treatment on Growth of Lonicera japonica (인공산성비 및 목초액 처리가 인동덩굴의 생장에 미치는 영향)

  • Seo, Dong-Jin;Kim, Jong-Kab
    • Journal of Korean Society of Forest Science
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    • v.99 no.3
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    • pp.432-438
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    • 2010
  • This study was carried out to understand the effect on soil chemical property, ion contents, and growth of Lonicera japonica by treatment of simulated acid rain and wood vinegar. It was treated total 30 times by one time per 2 weeks during 150 days from June to October dividing to various pH level of simulated acid rain (each pH 5.6, 4.5, 3.5 and 2.5) and the control site (pH 6.3). The wood vinegar diluted with 500 times was also treated total 10 times by one time per 2 weeks at the experimental sites. The soil pH was reduced as pH level of simulated acid rain was decreased. The organic content, total nitrogen, and Av. $P_2O_5$ in soil showed a tendency to increment. However, the soil improvement effect was exposed to be insufficient when a wood vinegar was treated. In the component of the plant body, $SO_4{^2}$ and $NO_3{^-}$ increased due to the simulated acid rain treatment and the increment ratio was reduced in the wood vinegar treatment plot. In addition, the cation contents showed a tendency to variation due to pH of simulated acid rain. And it showed more increment in the leaves than the root. The early fallen leaves and growth inhibition of L. japonica showed up after the simulated acid rain treatment but the growth of L. japonica increased after the wood vinegar treatment.