• 제목/요약/키워드: Acid-rain

검색결과 369건 처리시간 0.028초

Nutritive Value of Grasses in Semi-arid Rangelands of Ethiopia: Local Experience Based Herbage Preference Evaluation versus Laboratory Analysis

  • Keba, Habtamu T.;Madakadze, I.C.;Angassa, A.;Hassen, A.
    • Asian-Australasian Journal of Animal Sciences
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    • 제26권3호
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    • pp.366-377
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    • 2013
  • We examined the nutritive value of common grass species in the semi-arid rangelands of Borana in southern Ethiopia using local experience based herbage preference (LEBHP) perception and laboratory techniques. Local pastoralists in the study area were asked to identify common grass species and rank them according to the species' preferences and palatability to cattle. The pastoralists listed a total of 15 common grass species which were then sampled during the main rain and cold dry seasons and analyzed for crude protein (CP), Neutral Detergent Fiber (NDF), Acid Detergent Fiber (ADF) and ash content to verify pastoralists' claim regarding the quality of individual species. The relative feed value (RFV) and dry matter digestibility (DMD) were also calculated using NDF and ADF contents. Spearman's rank correlation was used to examine possible relationships between laboratory results and pastoralists' experience on grass quality. Cenchrus ciliaris, Chrysopogon aucheri, Digitaria milanjiana, Eragrostis papposa and Panicum maximum were the top five species based on LEBHP perception. There were indications of inconsistency in terms of LEBHP perception among the different pastoral communities. The chemical composition of all grass species showed significant (p<0.05) variation between sites, seasons and species. The results showed that the CP values for the Borana rangelands were in the range of 8.7% in the main rain season to 5.1% for the cold dry season. The fiber constituents were relatively low in the main rain season compared to the cold dry season. Overall, Digitaria milanjiana had the highest CP (16.5%) content, while the least was recorded with Heteropogon contortus (10.8) and Aristida adoensis (9.8%) during the main rain season. It seems that the spatial variability of landscapes within the wider geographical regions, soil properties and texture, and land-use patterns probably contributed to site differences in species quality. Generally, the RFV of individual grass species was significantly (p<0.05) varied between and within sites. The ranking of species by pastoralists according to their preferences by cattle was highly correlated with the chemical composition of laboratory results of individual grass species with 'r' values for CP (0.94), ash (0.95), NDF (-0.98), ADF (-0.93) and ADL (-0.93). We suggest the complimentary use of LEBHP and laboratory techniques in evaluating the nutritive quality of rangeland forage species for sustainable animal production.

영농기 강우의 화학적 특성 및 부하량 평가 (Chemical Properties and Nutrient Loadings of Rainwater during Farming Season)

  • 고병구;김민경;이종식;김건엽;박성진;권순익;정구복;이덕배
    • 한국토양비료학회지
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    • 제43권5호
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    • pp.578-583
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    • 2010
  • 수원과 태안에 위치한 농업지역에서 영농기간 중 강우의 화학적 특성을 알아보기 위하여 2009년 4월부터 11월까지 강우 53점을 채수하여 강우 중의 이온조성, 산성도 및 강우량을 고려한 가중평균 이온농도 변화를 평가하였다. 강우의 조성에서 양이온 구성은 $Na^+>{NH_4}^+>Ca^{2+}>H^+>Mg^{2+}>K^+$의 순이었으며, $Na^+$${NH_4}^+$ 성분이 전체 양이온 조성의 65% 이상을 차지하였다. 음이온은 ${SO_4}^{2-}>{NO_3}^->Cl^-$ 순으로 ${SO_4}^{2-}$가 약 61%를 차지하였다. 조사 기간 중 평균 sulfate 함량은 수원 130.2 ${\mu}eq\;L^{-1}$ 태안121.3 ${\mu}eq\;L^{-1}$이었으며, 이중 비해염 sulfate (NSS-${SO_4}^{2-}$)함량이 92%를 차지하여 강우 중에 함유된 sulfate의 대부분이 인위적인 발생원에 기인된 것을 알 수 있었다. 강우량을 고려한 월별 질소 부하량은 약 1~2 kg $ha^{-1}$정도로 토양에 공급되는 것을 볼 수 있었다. 특히, 수원지역의 7월 강우사상별 강우량은 7.3 mm 이상으로 총질소는 6 kg $ha^{-1}$로 가장 많이 부하되는 것으로 나타났다. 주요 영농기인 4~10월 동안 ${SO_4}^{2-}$, $Ca^{2+}$, $K^+$, $Mg^{2+}$의 부하량은 수원에서 각각 56.0, 7.4, 5.7, 1.4 kg $ha^{-1}$ 이었고, 태안에서 각각 42.8, 4.7, 2.6, 1.4 kg $ha^{-1}$ 이었다.

산성우(酸性雨)에 대한 산림생태계(山林生態系)의 민감도(敏感度) 및 자정기능(自淨機能)(I) - 강우(降雨)의 산성화도(酸性化度)와 식생(植生) 활력도(活力度)(TVI)를 중심(中心)으로 - (Sensitivity and Self-purification Function of Forest Ecosystem to Acid Precipitation(I) - Acidification of Precipitation and Transformed Vegetation Index(TVI) -)

  • 이수욱;장관순
    • 한국산림과학회지
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    • 제83권4호
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    • pp.460-472
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    • 1994
  • 본 연구는 산림생태계(山林生態系)의 산성우(酸性雨)에 대한 민감성(敏感性)과 자정능력(自淨能力)을 분석(分析) 평가(評價)하므로서 도시내 또는 인접지역에 존재하는 삼림(森林)을 생태학적(生態學的)으로 건강하게 관리(管理)할 수 있는 기초 자료를 제공하기 위하여 수행되었다. 이를 위하여 공단지역 1개소, 상업지역 4개소, 주택지역 4개소와 외곽지역 5개소에서 강우를 조사, 측정하였고, 강우조사 장소에 인접해 있는 7개 산림지역을 선정하여 토양조사를 실시하였다. 또한 Landsat TM 데이타를 이용한 변환식생지수(TVI)로 산림 지역별 식생활력도를 분석하였다. 대전지역은 여러가지 대기(大氣) 오염물질(汚染物質)에 의해 심각하게 오염되어 있었고, 강우내 이온농도의 평균은 $SO_4{^{2-}}$ 20.16mg/l, $NO_3{^-}$ 3.65mg/l, $Cl^-$ 3.09mg/l로 나타났다. 오염물질(汚染物質) 총강하량(總降下量)은 음이온의 경우 $SO_4{^{2-}}$$1.09mg/m^2/month$, $NO_3{^-}$$0.23mg/m^2/month$, $Cl^-$$0.20mg/m^2/month$이었다. 양이온의 경우는 $Ca^{2+}$$0.14mg/m^2/month$, $NH_4{^+}$$0.10mg/m^2/month$이었고 $Na^+$, $K^+$$Mg^{2+}$는 각 각 0.08, 0.07 및 $0.08mg/m^2/month$이었다. 대전지역에서 가장 오염이 심한 지역은 공단지역으로 강우내 $SO_4{^{2-}}$, $NO_3{^-}$, $Cl^-$의 농도가 각각 43.08, 3.88, 3.64ppm이었으며, 산림토양(山林土壤) 평균 pH는 4.16-4.94로 강산성(强酸性)이었다. 식생활력도(TVI)는 당산 3.11, 계족산 4.00, 보문산 4.13, 갑하산 4.18, 봉산 3.34, 식장산 4.13, 성치산 4.20으로 공단지역에 인접되어 있는 당산지역에서 식생활력도가 가장 낮게 나타났다.

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폐자원(폐석회, 굴패각, 바닥재)을 이용한 토양 중화제 개발 연구 (A Study on the Development of Soil Neutrailizing-agent using Waste Materials (Waste-lime, Oyster, Bottom-ash))

  • 오승진;조미현;박찬오;정문호;이재영
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제17권6호
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    • pp.92-101
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    • 2012
  • Korea shows the soil pH is 5.8 ~ 6.2 by many factors including the geological structure and climate condition. There is known as the cause for soil acidification by weathering of the mineral, excessive use of the chemical fertilizer, and extensively diffused acid rain. The purpose of research is environmentally-friendly material neutralization technology development utilizing the waste resources against by acid soil. The experiment analyze the physico-chemical property of the acid soil and waste resource materials (waste lime, oyster shell, bottom ash). The Batch-Test was performed under 3 stage. As a result, the acid soil showed up acid soil about 3.19. And waste lime, oyster, bottom ash showed the alkalinity with 9.62, 10.08, 9.17. In case of 1 batch-test experimental result, waste lime and oyster shell, the alkalinity was shown over 7.5 and the good efficiency was showed, on the other hands, the bottom ash showed the pH 4 the neutralization efficiency which is low. waste resource materials to be applied to 2 steps was chosen as the waste lime except the bottom ash and oyster. In 2 step batch-test experiment, it was exposed to be the most appropriate in case of doing the combination ratio of the waste lime and oyster shell with 9 : 1. It was exposed to be efficient most in the effeciency and aspect of economical efficiency combination ratio of the soil and materials was 9.6 : 0.6 with 3 step batch-test experimental result.

대기오염 및 산성비가 서울지역 식물군집에 미치는 영향 (The Effect on the Plant Community Decline by the Air Pollutant & Acid Rain in the Metropolitan Area)

  • 유창희;이경재
    • 한국조경학회지
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    • 제20권1호
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    • pp.80-94
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    • 1992
  • To inspect the changing of the forest soil and plants community structrure by air plooutand & acid rain during from September to November in 1990, the smapling sites were selected in the Piwon, Namsan and Kwangnung forest. In sites, plots were set up in Q. aliena forest at Piwon, Quercus mongolica and Pinus densiflora forest at Namsan and Q. mongolica and Pinus densiflora forest at Kwangnung. To obtain the individual number of trees, number of species, importance values and species diversity, using the Curtis & McIntosh methods. The results are following that; 1) In Pinus densiflora community, it was almost dominated by Q. spp. in the canopy layer and P. densiflora and Carpinus laxiflora through the subtree to shrub layer at Kwangnung. It wassaid that C. laxiflora is the climax species in moddle temperature zone. On the contrary, in Namsan forest, there is no appearance thesamplings of P. densiflora & C. laxiflora, but Styrax japonica and Stephanandra incisa that are acid-tolerance species are dominant ones. On the other hand, in Q. spp. community, Q. spp. and C. laxiflora are dominant ones. On the other hand, in Q. spp. community, Q. spp. and C. laxiflora are dominant species through all layer, and in addition C. cordata somewhat appear at Kwangnung. But at Namsan and Piwon forest, Q. mongolica & Q. aliena that were dominant species in canopy layer disappeared in the subtreeand shrub layer, and C. laxiflora and Corunus cordata absolutely disappeared. It were similarly dominated by Robinia pseudo-acacia, Styrax japonica, Sorbus alnifolia, Acer pseudo-sieboldianum, Rhododendrn mucronulatum and so on at Namsn and Piwon forest. In the light of these facts, it found out that disclimax was similar between Namsan and Piwon forest. 2) Species diversity and maximum species diversity were decreased in Kwangnumg, Namsan, Piwon in order. It was xpected that vegetational community was affected by environmental pollutant. 3) As the vegetational community structure analyses, using DCA technique among the ordination, ecological successional series are stopped to Q. spp. from P. densiflora at Namsan and Piwon, but that of Kwangnung is on the way that P. densiflora, Q. alena, C. laxiflora. It was obvi ously different from Namsan and Piwon. 4) In Q. spp. & P. densiflora community, the number of woody plants inNamsan & Piwon is much less than that of Kwangnung through all Layer. Especially, Piwon shown very severe difference. Through all community, the number of individuals of Piwon and Namsan are less than that of Kwangnung. Specially, that of the shrub layer is obvious. 5) In the growth rate of trees, it found out that all sites showed the growth decline phenomena. Especially, since in 1975, there have been the micro disclimax phenomena in Q. community of Kwangnung. 6) In the Q. community, soil acidity of Namsan & Piwon measured 4.57, 4.40 respectively. It was very strong acidity and far lower than that of Kwangnung. Also the content amount of Mg++ in Namsan & Piwon forest were still lower than Kwangnung.

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대구지역의 빗물 중 화학적 성분의 계절별 및 지역별 농도분포 (Seasonal and Regional Concentrations of Chemical Composition in Rainwater in Daegu Area)

  • 송희봉;이은경;정동숙;김인옥;이명숙;권병윤;이경출
    • 대한환경공학회지
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    • 제28권5호
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    • pp.522-526
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    • 2006
  • 대구지역에 내린 빗물의 수질 특성을 조사하기 위해 2005년 1월부터 12월까지 채취한 빗물시료 34개에 대하여 pH, 전기전도도 TOC, TIC TC와 같은 화학성분을 분석하였다. 분석된 화학성분의 농도는 겨울철이 여름철보다 높게 나타났다. 공업지역과 상업지역은 주거지역과 대조지역보다 화학성분의 농도와 전기전도도가 높게 나타났다. 산성우의 발생빈도(27.2%)가 비산성우(72.8%)에 비해 훨씬 낮았고, 또한 TC의 구성비율은 유기성인 TOC(72.5%)가 무기성인 TIC(27.5%)보다 높게 나타났다. 강수가 잦을수록 화학성분의 농도는 어느 정도 낮아지고, 반대로 무강수일이 길수록 화학성분의 농도가 높아졌다. 2003년에 비해 2005년의 대기질이 다소 개선된 원인은 환경행정당국의 대기오염 저감노력과 함께 지역 경기침체로 인한 다양한 영향을 받는데 있었다.

광산매립지에서 중금속(As)의 용출 특성에 관한 실험적 연구 (Experimental Studies on Dissolution Characteristics of a Heavy Metal(As) in Mining Waste)

  • 한춘;서명조;윤도영;최상일;이화영;김성규;오종기
    • 한국토양환경학회지
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    • 제3권1호
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    • pp.55-63
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    • 1998
  • 본 연구에서는 광산 인근 토양에서 산성비를 비롯한 침출수에 의한 지하 환경 오염 메카니즘을 검토하고, 오염 방지 및 교정과 대안의 효과를 정량화 하기 위한 방안을 고찰하였다. 이를 위하여 중금속인 비소의 오염도가 높은 토양을 대상으로 인위적 산성용액에 의한 비소의 용출을 실험적으로 검토하였다. 한편, 산성 침출오염수에 의한 지하 환경의 오염을 방지하기 위하여 석회석을 활용한 토양의 안정화방법의 효과를 살펴 보았다. 오염된 시료토양에 포함된 비소는 pH 1이하의 강산성 용액일수록 격렬히 용출되었으며, pH 값이 낮아질 수록 최대 용출량은 증가되는 것으로 나타났다. 석회석에 의한 토양 안정화방안은 매우 효과적이었으며, 석회석에 의한 산성용액의 중화반응 특성식은 미반응 핵 모델중에서 화학반응이 속도지배인 특성식에 잘 부합되는 것으로 보여진다.

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골프장 그린 토양에서 Metalaxyl의 흡ㆍ탈착 특성 (Characteristics of Adsorption and Desorption of Metalaxyl in the Green Soil of Golf Course)

  • 유병로;정경희
    • 한국환경과학회지
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    • 제11권3호
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    • pp.227-234
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    • 2002
  • Laboratory experiments were conducted to examine the behavior of metalaxyl in environment which was used as pesticide in green soil of golf course and as functions of the characteristics of adsorption, desorption and degradation in soil texture and organic matter contents. Acid water containing metalaxyl was conducted to evaluate the effects on adsorption, desorption and degradation. The adsorption of metalaxyl played more significant role in organic contents than clay contents, and pH Increases more pH 2.5 than pH 5.6. The desorption of metalaxyl from contaminants soil decreased higher organic contents LS-soil than S-soil, but the desorption amount of metalaxyl increased more pH 5.6 than pH 2.5. The rate of degradation of metalaxyl in green soil environmental increased higher organic contents LS-soil than S-soil and decreased more pH 2.5 than pH 5.6. These results indicated that the behavior of metalaxyl of the green soil was affected the soil texture of the golf course. Increasing of organic contents, the adsorption amount of metalaxyl on soil increased. Moreover the decrease of the pH of solution increased adsorption amounts and decreased desorption amounts. As the results, the transportation of metalaxyl in soil decreased the acidic rates. The acidification of soil by the acid rain increased the adsorption amount of metalaxyl, but the degradation of metalaxyl decreased. Therefore, it is possible to sustain contamination in run-off the stream and ground water by residuals in soil.

은의 표면 부식 및 변색을 방지하기 위해 설치된 Al 희생양극의 전기화학적 특성에 미치는 황산 농도의 영향 (Effect of concentration of H2SO4 on electrochemical properties of equipped Al sacrificial anode to prevent the corrosion and discolor of silver surface)

  • 신병현;정원섭
    • 한국표면공학회지
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    • 제54권1호
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    • pp.12-17
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    • 2021
  • Among the various precious metals, silver is used in various fields because of its low price than other precious metals. However, the surface of silver remains after rain in the atmosphere containing sulfur ions and chlorine ions, causing silver corrosion and discoloration. Existing documents have developed a anode to prevent corrosion but that are concentrated on secondary batteries. This study tried to prevent corrosion and discoloration of silver by using an Al sacrificial anode. Sulfuric acid decreased the potential of silver and increased the current density at active polarization and OCP. The amount of corrosion of silver with the Al sacrificial anode was reduced from 0.5 % to 6.5%. When silver is used for decoration outside, corrosion and discoloration of silver can be suppressed by installing an Al anode.

집중 강우시 남한강 내 용존 유기물의 성상 변화 (Changes in Dissolved Organic Matter Composition in the Namhan River during a Heavy Rain Event)

  • 오세진;우성호;허진;정명숙;신현상
    • 한국물환경학회지
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    • 제25권5호
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    • pp.697-703
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    • 2009
  • In this study, changes in the composition of dissolved organic carbon (DOC) were investigated using water samples collected at a downstream site of the Namhan River near the Lake Paldang ($N37^{\circ}24^{\prime}05.33^{{\prime}{\prime}}E127^{\circ}32^{\prime}25.01^{{\prime}{\prime}}$) during a heavy rain event from July 23 to July 28, 2008. The DOC concentrations varied from 1.68 to 3.18 mg/L with the maxium value at a peak of the river water level. Each DOC sample was fractionated into three compositions including hydrophilic (Hi), hydrophobic acid (HoA) and hydrophobic neutral (HoN) fractions. The results showed that HoA was most abundant fractions, constituting 47.2~56.5% of DOC. Refractory dissolved organic carbon (R-DOC) contents were also determined by measuring the DOC concentration after 28-day dark incubation of the samples. R-DOC content was in the range from 83 to 99% of DOC and it was significantly correlated with HoA contents (r = 0.91, p<0.005), while it did not exhibit such a good correlation with the fractions of Hi and HoN (p>0.02). Our results suggest that the HoA, which is associated with humic substances, may be a major composition of refractory organic matters in rivers during storm events.