• Journal of Fashion Business
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• v.11 no.5
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• pp.79-89
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• 2007

The effect of chitosan treatment on the dyeing and dye fastness, and mechanical properties of hair was investigated in this study when the carotinoid dyestuffs extracted from African Marigold(Tagetes erecta L.) were applied to the hair. The sequences of the chitosan treatment were changed in dyeing and mordanting procedures, i.e., pre-treatment, mid-treatment, and post-treatment. While the effect of chitosan application on the color shade change was not significant, the pre-treatment of the chitosan increased the dye uptake. Discoloration and fading was observed in the lightfastness test when chitosan was mid-treated. Alkali perspiration and acid perspiration fastness test results showed that chitosan post-treatment gave lower tendency. Washing fastness results showed that chitosan post-treatment and mid-treatment gave lower values, which indicates that chitosan deters the direct formation of insoluble complex among fiber-dyestuff-mordant. In the mechanical characteristics results, however, initial modulus and breaking strength increased significantly in the post-treatment and pre-treatment of chitosan.

• Textile Coloration and Finishing
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• v.32 no.1
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• pp.38-43
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• 2020

To overcome the harmful effects caused by conventional oxidative hair dyes, natural colorants becomes more popular in the hair dyeing. By extracting Sagassum fusiforme powders with aqueous alkaline solution as a solvent at 130℃ for 60 minutes, a fucoxanthin concentration of up to 216㎍/ml can be obtained. UV/Vis analysis was used to prove the presence of fucoxanthin in the extract powder. A K/S value of 23.8 can be obtained when wool fabrics were dyed with the extract at 120℃ for 60 minutes under pH 2. The color fastness properties of the dyed wool fabrics were very good as indicated by rating 4 for laundering(color change), rating 3 or higher for rubbing, and rating 5 for light irradiation. The dyed wool fabric was found to have antimicrobial activity against Staphylococcus aureus. The antioxidant and antimicrobial activity of the Sagassum fusiforme extract can be an effective functional hair colorant. Hair dyeing with the extract formulation at 45℃ for 40 minutes under pH 5 accomplished a K/S value of 8.9. The color fastness of the dyed hair showed rating 3 against light irradiation, which increased to rating 5 with after-mordanting of tannin acid.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2011.03a
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• pp.64-64
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• 2011

모발(human hair)은 양모섬유와 마찬가지로 시스틴을 많이 함유하고 있는 섬유상 케라틴 단백질로써, 두부(頭部)를 보호할 뿐만아니라 신체에 필요하지 않는 중금속을 체외로 방출하는 기능을 지닌 신체의 일부분이다. 또한 모발은 미(美)와 관련하여 가장 관심을 가지는 부분이며, 다양한 방법으로 모발에 변화를 주어 신분을 표시하거나 자신의 미적 표현을 하고 있다. 퍼머넌트 웨이브는 모발에 형태학적 변화를 주는 유효한 수단이며, 염색과 탈색 등은 색상 변화를 주는 중요한 수단이다. 본 연구 에서는 모발을 산성염료로 염색할 때 염색성을 향상시키기 위하여 염색보조제로써 벤질알콜 등을 첨가하여 염색할 때 염색된 모발의 염착량, 보습성, 단백질 유출성, 주사전자 현미경 관찰을 측정하여 다음과 같은 결과를 얻었다. 1) 염색시간이 길어지고, 염색온도가 높아질수록 모발에의 염착량은 증가하며, 특히 벤질 알콜을 첨가하여 염색하는 경우에는 빠른 시간내에 염착평형에 도달하고 비교적 낮은 염색온도에서도 높은 염착량을 나타내었다. 2) 이와같은 용매 첨가의 효과는 염액에 계면활성제와 함께 첨가하여 염색하면 나타나지 않았다. 3) 염색시간이 길어질수록 모발의 보습성은 열악해지지만, 벤질 알콜을 첨가하여 염색하는 경우에는 오히려 보습성이 증가하였다. 또한 염색시간이 길어지면 모발의 단백질 유출성은 증가하지만, 벤질 알콜을 첨가하여 염색하는 경우에는 오히려 단백질 유출성이 감소하였다. 이와같은 결과는 벤질 알콜을 첨가하여 염색하는 경우에 모발의 손상이 적다는 것을 의미한다. 4) 모발의 손상정도에 대한 주사전자현미경의 측정결과는 벤질 알콜의 첨가여부에 따라 큰 차이를 보이지 않았다.

• Journal of the Korean Society of Food Science and Nutrition
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• v.35 no.8
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• pp.1010-1015
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• 2006

p-Pheylenediamimine (PPD) is one of hair dye's ingredients, and the mixture of PPD with hydrogen peroxide is generally used to dye hair at beauty shop. This study is conducted to investigate the effect of oxidized PPD on rat skin. 6% hydrogen peroxide, PPD (5% PPD in 2% $NH_4OH$) or the mixture (isovolumed mixture of 5% PPD and 6% hydrogen peroxide in 2% $NH_4OH$) was applied to rat skin ($25\;mg/16.5\;cm^2$) five times every other day. The activity of acid phosphatase (ACP) was more increased in the mixture of PPD with hydrogen peroxide applied group than PPD applied group. Furthermore, the activity of glucose 6-phosphatase (G6Pase) in the mixture of PPD with hydrogen peroxide applied group showed higher decreasing rate than that of PPD applied group. In histopathological findings, the mixed PPD with hydrogen peroxide applied group showed more thickening of epithelium, increased numbers of dermal fibroblasts, and the dilatation of dermal capillaries than PPD applied group. The significant increasing of xanthine oxidase (XO) activity was determined in mixture of PPD with hydrogen peroxide applied group compared with PPD applied group. However, reactive oxygen species (ROS) scavenging system, the activities of superoxide dismutase (SOD) and glutathione S-transferase (GST) were more significantly decreased in mixed PPD with hydrogen peroxide applied groups than in PPD applied group. In conclusion, topical application with the mixture of PPD with hydrogen peroxide compared with PPD application resulted in imbalance with ROS generating and scavenging which probably led to severe skin injury.

• Journal of the Korean Society of Food Science and Nutrition
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• v.34 no.9
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• pp.1330-1335
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• 2005

Red brownish p-pheylenediamine (PPD) has been widely used hair dye for women. The dye was known to cause systemic anaphylaxis, dermatitis and bladder cancer. But the effect of PPD toxicity with oxygen free radical has not been studied. This study investigated the degree of skin injury by PPD. PPD ($2.5\%$ PPD in $2\%\;NH_{4}OH$) was applied to the rat skin ($25 mg/16.5\;cm^2$) 3 or 5 times every other day. Histopathological findings demonstrated the proliferation of epithelial cells and the increased keratinization by PPD. The activities of glucose 6-phosphatase (G6Pase) was decreased and acid phosphatase (ACP) was increased in PPD-applied rat skin. Groups in which PPD was applied 5 times were more damaged than groups applied 3 times. To examine the relationship between tissue damage and oxygen free radicals, effect of PPD on xanthine oxidase (XO) activity was measured and XO activity was more significantly increased in the group treated with PPD 5 times than 3 times. However, reduced glutathione (GSH) content, and the activities of catalase (CAT), super-oxide dismutase (SOD) and glutathione S -transferase (GST) were more decreased in PPD-applied groups than in controls. Even though the activities of XOD was not changed in the group treated with PPD 3 times, the decreased activities of oxygen free radical system and the damaged skin tissue were observed. This result might be caused by the production of toxic PPD metabolites in rat skin. In conclusion, topical PPD application led to skin injury in a dose-dependent manner, probably due to the generation rate of oxygen free radical.