• Title/Summary/Keyword: Acid dyeing

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Modification of Tencel Fabric Treated with Chitosan( II ) - Change of Dyeing Properties - (키토산처리에 의한 텐셀 직물의 개질기능화(II) - 염색성의 변화 -)

  • 육은영;배현숙
    • Textile Coloration and Finishing
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    • v.14 no.3
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    • pp.1-10
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    • 2002
  • Tencel fabric cationized with chitosan can be effectively dyed with anionic dyes. To investigate the change of dyeing properties of cationized Tencel fabric, some experiments were performed under the several dyeing conditions with acid and reactive dyes. Whiteness index decreased with the increment of crosslinking agent concentration. The cationized Tencel fabric was dyed well by anionic dye such as acid dye, the dyeability of reactive dye was improved by addition of a little salt without alkali. The dye fixation on the cationized Tencel fabric was increased with chitosan concentration without electrolyte and alkali. The dyeability of Tencel treated with chitosan was better than controlled Tencel, especially under the acidic conditions. According to the number and the types of functional group of reactive dyes, dye affinity of the modified Tencel fabric varied and wash fastness of acid dye was better than reactive dye.

A Study on the One Bath Two Step Dyeing of Wool/Cationized Cotton Blends With Acid Dye/Direct Dye (양모/카티온화 면 혼방품의 산성염료/직접염료에 의한 1욕2단 염색에 관한 연구)

  • Sung, Woo-Kyung;Lee, Choon-Gil
    • Fashion & Textile Research Journal
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    • v.3 no.2
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    • pp.168-173
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    • 2001
  • In order to overcome the disadvantage of the conventional two bath dyeing method of wool/cotton blends, it had prompted significant effort to the development of the one bath dyeing method which can accomplish savings in energy, water usage and time. To improve the dyeability of cotton toward direct dyes in a non-electrolytic and acidic dyebath, cotton component was pretreated with cationizing agent containing chlorohydrine group in aqueous solution of sodium hydroxide. This study was carried out to investigate almost equal color strength between wool component and cationized cotton component when wool/cationized cotton blends was dyed with acid dye/direct dye by the one bath two step method in a non-electrolytic and acidic dyebath.

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Preparation and Dyeing of Superfine Down-powder/Viscose Blend Film

  • Wang Xin;Xu Weilin;Ke Guizhen
    • Fibers and Polymers
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    • v.7 no.3
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    • pp.250-254
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    • 2006
  • Superfine down-powder/viscose blend films were prepared and characterized for their dyeing properties. Down-powder with average size of $2.56{\mu}m$ were suspended in viscose dope and blend films were obtained by solution casting. When the blend films were dyed with acid dye, the dye uptake and K/S values increased with the increase in down-powder content. Amino-acid analyses showed that amino acid component of the down were not affected during the film formation, which confirmed the changes of dye uptake and K/S value.

Vat dyeing of Wool and Cotton fabrics with Sepia Melanin

  • Kim, Su-Jin;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.22 no.2
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    • pp.88-93
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    • 2010
  • Using extracted sepia melanin powder by repeated treatments with aqueous sodium hydroxide and acetic acid solutions, vat dyeing of wool and cotton fabrics was carried out under various dyeing conditions including concentration of melanin, alkali, reducing agent and salt, as well as dyeing time and temperature. A K/S of 25.3 for wool fabrics was obtained at the optimal dyeing condition with 9% owf melanin, 0.5g/L NaOH and 56g/L $Na_2S_2O_4$ without salt at $80^{\circ}C$ for 90minutes. The vat dyeing of sepia melanin was applicable to both cotton and wool fabrics but the wool showed higher dyeability. The color fastness properties of the dyed wool and cotton fabrics were excellent to washing, rubbing and light irradiation.

Studies on the Natural Dyes(11) -Dyeing Properties of Cochineal Colors for Wool Fibers- (천연염료에 관한 연구(11) -코치닐 색소의 양모섬유 염색성-)

  • 조경래
    • Textile Coloration and Finishing
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    • v.11 no.4
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    • pp.39-49
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    • 1999
  • In order to study the properties of cochineal colors, uv-visible spectra of cochineal colors solution, dyeing properties on the wool in several dyeing conditions and thermodynamic parameters were investigated. UV-visible spectra of cochineal colors solution showed hypochromic effect with the lapse of irradiation time but bathochromic shift with decreasing acidity of solution and addition of metallic ions. The concentration of cochineal colors in wool fiber increased with the increase of dyeing temperature, time, and acidity of initial dyebath. The value of apparent diffusion coefficients and standard affinities of dyeing decreased with the increase of dyeing temperature. The standard heats of dyeing$(\Delta{H}^\circ)$ and variation of entropy$(\Delta{S}^\circ)$ increased with the increase of concentration of initial dyebath. The activation energy$(E_a)$ were calculated to be 1.399~2.595kcal/mol in condition of 6~1%(o.w.f) dyebath. Wool fabrics were dyed reddish blue by iron sulfate, copper sulfate, aluminum acetate and tannic acid, and red by tin chloride, respectively. Lightfastness of wool fabrics dyed by cochineal colors were increased by mordant treatment, especially copper sulfate and iron sulfate treatment.

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The Characteristics of Mixed Dyeing Using Persimmons Juice and Onion Outer Skin Extract (감즙과 양파껍질 추출액을 이용한 혼합염색의 특징)

  • Han Young-Sook;Yoo Hye-Ja;Lee Hye-Ja
    • Journal of the Korean Society of Clothing and Textiles
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    • v.30 no.1 s.149
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    • pp.115-124
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    • 2006
  • Natural dyes are environmentally and human compatible. But they are not various or not fast in color. The mixed dyeing have been attempted to solve these disadventages of natural dyes. The persimmon juice dyed fabrics have brown-color and good hygienic properities however low color fastness. The onion dyeing show similar brown-color and have good color fastness caused by querectin existed in onion outer skins. Mixed dyeing was carryied out on silk fabrics using persimmion juice and onion outer skin extract in this study. The mixing method were persimmon juice dyeing and then onion dyeing(P-O), onion dyeing and then persimmon juice dyeing(O-P) and dyeing in the mixture of persimmon juice and onion outer skin extract simultaneously(P+O). The mordants were none-mordent, gallic acid after-treatment and alum after-treatment. Several persimmon juice dyed fabrics were irradiated for 2 hours before onion dyeing(PU-O). The color values of dyed silk fabrics were as follows. The persimmon juice dyed silk fabric developed to yellow-red color after 2 hours of uv irradiation. Onion dyed fabrics show similar yellow-red color after dyeing without uv irradiation. The effect of alum after-treatment on color difference were highest in onion dyeing. The dyeabilities of both P-O and O-P were higher than persimmom juice dyeing and onion dyeing. The dyeabilities of P+O was lower than persimmom juice dyeing and onion dyeing. The value of color difference of alum-treated fabric was the highest. The color difference of P-O and O-P caused from 2 to 4 hours of uv-irradiation were lower than those of persimmon juice dyed fabrics. Onion skin extract could prevent the color-change of persimmon juice dyed fabrics in mixed dyeing. The color difference of PU-O was higher than the P-O.

Effect of Protease on the Morphological Properties and Dyeability of Human Hair (프로테아제 처리가 모발의 염색성 및 형태적 특성에 미치는 영향)

  • Kim, Hong-Hee;Kwon, Tae-Jong
    • Textile Coloration and Finishing
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    • v.20 no.2
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    • pp.59-65
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    • 2008
  • The tannin acid and the enzymes have been used in order to improve the ruggedness in laundry and the absorption of dyes and pigments in the textile industry for several years. The enzyme processing on the protein fiber minimizes the damage of the entire fiber and improves the dyeability by effectively modifying only the hydrophobic surface. This study tried out the structural observation by applying the Castanea crenata sieb. et. zucc. containing abundant tannin to the hair dyeing as the natural dyeing pigment along with Protease of Rhizopus sp. The dyeability was improved as compared to the dyeing using only the synthetic tanning and iron mordant. When the depth of pigment was higher in accordance with the surface observation, the enzyme dissolution had impact on dyeing and so the keratin layer on the hair surface. Accordingly, it was found that the appropriate depth was between 0.01 and 0.03%. It was estimated that 0.1% protease would treated within 30min. Consequently, it would cause the good reaction with the functional group of tannin pigment.

On Bath Dyeing of silk/synthetic Fibre Blends(III) ―Adsorption Behavior of Acid Dyes/Disperse Dyes on Silk/PET― (견/합성섬유 혼방품의 일욕염색(III) ―산성염료/분산염료 염욕에서의 견/PET의 염착거동―)

  • Gwag, In Jun;Yoon, Kyung Sup;Kim, Ae Soon;Kim, Gong Ju
    • Textile Coloration and Finishing
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    • v.5 no.4
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    • pp.67-78
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    • 1993
  • In one bath dyeing system of silk/PET fiber blend fabric with acid/disperse dyes, adsorption behavior of disperse dyes and acid dyes on silk and PET fabrics were examined. In the dyeing of PET with C.I.Disperse Red 19(Red 19) and C.I.Disperse Red 60(Red 60) at 10$0^{\circ}C$(carrier dyeing) and 13$0^{\circ}C$, dye uptake with Red 60 was higher than that with Red 19. When the silk/PET dyed with Red 19 and Red 60 at 10$0^{\circ}C$(carrier dyeing) and 13$0^{\circ}C$, dye uptake on PET was influenced by affinity of the dye to the silk fabric dyed together. When the silk/PET dyed with Blue 80/Red 19 and Blue 80/Red 60 at 10$0^{\circ}C$(carrier dyeing) and 13$0^{\circ}C$ for 60 minutes, color of PET dyed with Red 19 and Red 60 was little influenced by Blue 80 but silk dyed with Blue 80 was influenced. Interrelation of K/S value and Munsell value was scarcely any but showed the change tendency of K/S value.

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A Study on Dyeing of Silk-Polyester Fabric (絹과 Polyester合絲絹織物의 染色法改善에 關한 硏究)

  • Nahm, Joong-Hee;Chang, Byong-Ho
    • Journal of Sericultural and Entomological Science
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    • v.23 no.1
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    • pp.56-64
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    • 1981
  • The textile fabric contains the functions of sanitation, decoration, wearing style and washing in the practical use. Among various tetile fiber, silk has less utilities than synthetic fiber in practical use although silk has good benefits of the high quality of silk fabric. Thus no textile fiber, neither natural norsynthetic, has all the functions. In this sense, many compound fabrics have been improved to reveal various functions of fabric However, this has been disturbed with the problem of dyeing, expecially in the case of compound fabric of silk. The work is carried out to improve the dyeing method of compound fabric of polyester and silk. The results obtained are as follows: 1. In the dyeing of compound fabric(P/S fabric), azo dyes was more suitable than anthraquinone dyes. 2. According to the carrier, dyeing spot was appeared by the high concentration in bath. 3. Degree of dye fixation was decreased in dyeing of methylnaptharine carrier(D.N) and anion disperser(T.S). 4. The affinity of dye was suitable in the dyeing bath of azo dye, trichlorobenzene carrier and nonion disperser. 5. Dye fixation of silk side in compound fabric by acid dye showed higher in acid bath of dyeing. 6. In printing of silk and polyester compound fabric, it must be understood relationship among fibers, dyes, and steaming conditions.

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Dyeing properties of Nylon/Spandex blends with vat dye (배트염료에 의한 나일론/스판덱스 교직물의 염착특성)

  • Park, Young-Min;Kim, Byung-Soon;Son, Young-A
    • Textile Coloration and Finishing
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    • v.18 no.6 s.91
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    • pp.63-68
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    • 2006
  • In synthetic/spandex blends fibers, contents of the synthetic fiber by percentage is higher than those of spandex. Thus, the dyeing process of the blends fiber is mainly focused on the synthetic fiber, but not the spandex. In this study, we used several series of vat dyes for dyeing the nylon/spandex blend fabrics and their dyeing properties(fk value) were investigated at various reduction agents, temperatures, pH which have the potential for deep shade dyeing effects. The formamidinesulfinic acid were found to be effective to increase the fk values of the blend fiber compared to sodium hydrosulfite and Rongalit C. Higher temperature($100^{\circ}C$) and lower pH(pH 4) were observed as suitable conditions for maximum fk values.