• Title/Summary/Keyword: Acid dyeing

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Alkaline Dissolution and Dyeing Properties of Sea-island Type Ultrafine Nylon Fiber (해도형 초극세 나일론 섬유의 알칼리 용출 및 염색성)

  • Lee, Hae-Jung;Lee, Hyo-Young;Park, Eun-Ji;Choi, Yeon-Ji;Kim, Sund-Dong
    • Textile Coloration and Finishing
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    • v.22 no.4
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    • pp.325-331
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    • 2010
  • The alkaline dissolution behavior of sea-island type ultrafine nylon fiber were dependent on the concentration of NaOH and treatment time, and the most appropriate condition for alkaline dissolution was to treat with 20g/l NaOH for 30 min at $80^{\circ}C$. The dyeing properties of sea-island type ultrafine nylon fiber and regular nylon fiber were examined with 3 different types of acid dyes in this study. The dye uptakes of ultrafine nylon fiber were higher than regular nylon fiber because of large surface area per unit mass, which increased as the dye bath pH decreased. The dyeing rates on ultrafine nylon fiber were faster and dye exhaustions were higher than regular nylon fiber, however color strength and rating of wash fastness were lower. It was also found that levelling type acid dye showed fast dyeing rate on both nylon fibers than metal-complex and milling type acid dyes.

Dyeing Properties on Polylactic Acid (PLA) Fabrics by Disperse Dyes (분산염료에 의한 PLA 직물의 염색성)

  • Lee, So Hee;Song, Wha Soon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.37 no.7
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    • pp.952-961
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    • 2013
  • This study optimizes a suitable dyeing method for polylactic acid (PLA) fabrics using disperse dyes. For this, disperse red 60 (DR 60), disperse blue 56 (DB 56), and disperse yellow 54 (DY 54) were used and dyed on PLA fabrics dependent of dyeing temperature and time. The fastness of PLA fabrics dyed with three disperse dyes were evaluated; in addition, dye exhaustion, color strength (K/S value), and colorimetric properties of PLA fabrics were compared with PET fabrics. The experiments indicated optimum dyeability of PLA fabrics with disperse dyes. The dyeing temperature was $90^{\circ}C$ for every dye and the dyeing time were 20 min, 60 min, and 40 min for DR 60, DB 56, DY 54, respectively. PLA fabrics had good color fastness to washing, dry cleaning fastness, hot pressing fastness, rub fastness, and perspiration fastness by DR 60, DB 56, and DY 54. The dye exhaustion of PLA fabrics were lower than PET fabrics; however, K/S values were higher than PET fabrics.

Dyeing Properties of Wool Using Hydrogen Peroxide/Glyoxal Redox System (과산화수소/글리옥살 산화환원계를 사용한 양모의 염색성)

  • Jeong, Dong Seok;Lee, Mun Cheul;Lee, Young Hee;Kim, Kyung Hwan
    • Textile Coloration and Finishing
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    • v.8 no.1
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    • pp.15-25
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    • 1996
  • Wool fabric and merino wool top were dyed with two dyes, C.I. Acid Red 13 and C.I. Direct Blue 1 in presence of hydrogen peroxide/glyoxal redox system at various conditions such as dyeing time, temperature and redox concentration. The pH of dye bath was 4.5 in buffer solution of $KH_{2}PO_{4}$ (0.1mol/1)/$Na_{2}HPO_{4}$ (0.1mol/1). Also dyeing of cotton fabric was carried out with C.I. Direct Blue 1 in absence or presence of redox system. The color depth(K/S) increased with redox concentration and dyeing temperature. The increases in dyeing rate and equilibrium dye exhaustion of Acid Acid 13 and Direct Blue 1 on wool fiber and fabric in the present of hydrogen peroxide/glyoxal have been caused by decreasing in pH value during dyeing process which due to the decomposition of hydrogen ion in glyoxal with the assistance of hydrogen peroxide. But the decreases in exhaustion of Direct Blue 1 on cotton may be attributed to repulsive interac ion between salt and salt.

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pH Control for Dyebath Reuse in Dyeing of Polyamide with Binary Mixtures of Acid Dyes

  • Koh, Joonseok;Park, Sang Hyuck;Shim, Goo Hwan;Cho, Dae Hwan;Kim, Jae Pil
    • Fibers and Polymers
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    • v.5 no.2
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    • pp.110-116
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    • 2004
  • Hydrolyzable organic esters were compared with ammonium sulphate as an acid donor for the pH control in dye-bath-reuse system of acid dyes mixtures. The ability of pH control, levelness, dyeing properties and reproducibility in dye-bath-reuse system were investigated comparatively. Hydrolyzable organic esters showed higher exhaustion and color yield than ammonium sulphate. In addition, hydrolyzable organic ester exhibited very low conductivity less than 0.5 mS, while ammonium sulphate give high conductivity. However, we could not observe any difference in levelness of dyed samples between two kinds of acid donors in laboratory scale dyeing. Over 10 cycles of reuse, hydrolyzable organic esters showed higher reproducibility than ammonium sulphate. No deterioration of the color fastness and levelness occurs over 10 cycles of reuse.

Effect of Low Temperature Plasma and DCCA treatment on the Dyeing Properties of Wool Fabric (DCCA 처리와 저온플라즈마 처리가 양모직물의 염색성에 미치는 영향)

  • Jung, Young-Jin
    • Textile Coloration and Finishing
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    • v.20 no.4
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    • pp.53-59
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    • 2008
  • For the modification of wool surface, wool fabrics treated with oxygen low-temperature plasma(LTP) and dichloroisocyanuric acid(DCCA) were dyed with milling type acid dye. The difference of dyeing properties on modified and control wool fabric were investigated. DCCA treated wool showed that saturation dye uptake and dyeing desorption ratio were higher than LTP treated wool. Dyeing transition temperatures of DCCA and LTP treated wool fabrics were 20$^{\circ}C$ degree lower than control wool fabric. In light color fastness test, DCCA treated wool fabric was 1 grade lower than LTP or control wool fabric.

Evaluation of Dyeing Properties of Modified Polypropylene Fibers by Electron Beam Irradiation (전자선조사에 의한 폴리프로필렌 섬유의 개질 및 염기성염료의 염착특성)

  • Kim, Hong-Je;Bae, Jin-Seok
    • Textile Coloration and Finishing
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    • v.21 no.1
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    • pp.46-52
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    • 2009
  • Dyeing properties of hydrophobic polypropylene fibers using cationic dyes were investigated to improve dyeability by electron beam irradiation and sulfonic acid incorporation. The color strength of irradiated polypropylene fibers was examined according to the dyeing conditions including pH of dyebath, absorbed doses, and introduction of functional group to fiber substrate. The best dyeing result was obtained when sulfonic acid group incorporated polypropylene fibers after electron beam irradiation were dyed with cationic dyes at alkaline conditions and 30$\sim$75kGy irradiation ranges.

A Study on the Dyeing Properties of Silk Fabrics Dyed with Impatiens balsamina extract(II) (봉선화 추출액의 견직물 염색(II))

  • 김애순
    • Textile Coloration and Finishing
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    • v.16 no.3
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    • pp.1-7
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    • 2004
  • To study the dyeability(K/S value) and surface color of silk fabrics dyed with Impatiens balsamina extract, its flower, leaf and stem, was extracted by water. This paper investigated some experiments with Impatiens balsamina extract under the various dyeing conditions such as dyeing temperature, dyeing time, repetition of dyeing, dyeing pH with silk fabrics. The results obtained were as follows. 1. It was found that it $\lambdamax$. of silk fabrics dyed with Impatiens balsamina extract was 260nm and its flower, leaf, stem and flowers(white, pink, violet) had same it $\lambdamax$ at 260nm. 2. K/S value was increased when dyeing temperature, repetition of dyeing and time was higher, value of munsell of silk fabrics dyed with Impatiens balsamina extract was yellow-red. dyeing temperature, repetition of dyeing and time was higher, shifted to longer wavelength side. 3. pH added acetic acid was colored reddish yellow-red, but pH added alum was colored yellowish yellow-red in silk fabrics dyed with Impatiens balsamina extract and repetition of dyeing was increased the dye-uptake.

The Studies of Low Temperature Dyeing on Silk Fibers I. Low Temperature Dyeing of Silk Fiber in the Milling Type Acid Dye (견의 저온 염색에 관한 연구 I. 산성 Milling형 염색에 있어서의 저온염색)

  • 배도규;배현석;정태암
    • Journal of Sericultural and Entomological Science
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    • v.34 no.2
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    • pp.52-57
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    • 1992
  • Using the new type auxiliary(K-1), dyeing experiment was done at the various dyeing conditions and the effects of auxiliary on the dyeing properties of acid milling dye for the silk fiber were dicussed. The results obtained were as follows; 1. The exhaust rate of acid milling dye was increased according to the auxiliary concentration at dyebath pH 7, But the increasing tendency of exhaust rate was decreased above auxiliary concentration 3% o. w. f.. 2. It was the same tendency of exhaust rate at dyebath pH 5, but the diffusion was more powerful at dyebath pH 7 than pH 5. 3. The decreasing ratio of exhaust rate according to dye concentration increasing was lower at auxiliary addition than auxiliary non-addition. 4. The exhaust rate curve according to increasing dyeing temperature showed the inflection point at auxiliary non-addition, but it was not observed in auxiliary addition. Consequently, it seems to be avoid that the occurrence of uneven dyeing at auxiliary addition.

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The Dyeability of Extract from Opuntia Ficusindica var. Saboten fruits (백년초열매 추출물의 염색성)

  • Kim, In-Young;Lee, So-Hee;Song, Wha-Soon
    • Textile Coloration and Finishing
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    • v.19 no.6
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    • pp.1-6
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    • 2007
  • Opuntia Ficus has been an epiphyte plant since it was introduced in Cheju island as an ornamental plant two hundred years ago. And now it is grown as many as it is designated to local souvenir No.35. The fruit of this plant contains red-purple sap, which is due to be used in coloring clothes. This study aims at confirmation of use possibility as eco-friendly dyeing stuffs on extract from opuntia ficus fruits and contributing to the practical use of natural dyeing. Thus this study was investigated the dyeability of extract from opuntia ficus fruits on the silk fabric. Antioxidants were used ascorbic acid, L-cysteine, prophyl gallete. After dyeing, K/S and dye fastness were measured. The results were as follows; Maximum absorption band of extract from opuntia ficus fruits was 534.5nm. The appropriate dyeing condition was bath ratio 50:1, dyeing temperature $30^{\circ}C$, dyeing concentration 50%, dyeing time 50min, pH 3,concentration of all antioxidants 3%. Addition of antioxidants brought increase of K/S value. And K/S value and dye fastness had the greatest value when ascorbic acid was added

Dyeing of Cotton Fabrics Using Zizania latifolia Turcz. Extracts (줄풀을 활용한 면직물의 염색)

  • Lee, Hyesun
    • Textile Coloration and Finishing
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    • v.27 no.1
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    • pp.96-104
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    • 2015
  • This study examined the pretreatment effect, appropriate dyeing conditions, color fastness and functionality of cotton fabrics dyed with Zizania latifolia Turcz. Dye uptake was substantially increased by pretreatment and chitosan pretreatment was much more effective than tannic acid pretreatment. Optimal dyeing conditions were colorant concentration of 100%, dyeing temperature of $100^{\circ}C$, dyeing time of 80 minutes and dyebath pH of 5.5. Color fastness of chitosan pretreatment and dyed cotton to washing, rubbing, perspiration and light was 4, 5, 3-4(acidic), 3(alkaline) and 3 respectively. Color fastness of tannic acid pretreatment and dyed cotton to washing, rubbing, perspiration and light was 4, 5, 3-4(acidic), 4-5(alkaline) and 4 respectively. Deodorization rates of ammonia(NH3) were 99.9% in both cases. UV protection rate were 98.3% of UV-A and 98.5% of UV-B in case of chitosan pretreatment. UV protection rate were 98.2% of UV-A and 98.5% of UV-B in case of tannic acid pretreatment. UV protection factor(UPF) was 50+ in both cases. Reduction rate of Staphyloccus aureus were 99.9% in both cases. Therefore Zizania latifolia Turcz. could be used a new functional colorant.