• Title/Summary/Keyword: Acid deposition

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Fabrication of Mixed Langmuir-Blodgett Ultra Thin Films with(N-eicosyl pyridinium)-TCNQ(1:2) Complex and Aracltidic acid ((N-eicosyl pyridinium)-TCNQ (1 : 2) 착체와 Arachidic acid의 혼합 Langmuir-Blodgett 초박막 제작)

  • Shon, Byoung-Chung;Jeong, Soon-Wook;Hwang, Kyo-Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.7 no.1
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    • pp.77-80
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    • 1990
  • Using $CdCl_2$ buffer solution as subphase for LB films deposition, it was achieved successively to fabricate the Y-type mixed LB films of (N-eicosyl pyridinium)-TCNQ(1:2) complex and arachidic acid. By measure of U.V spectra and capacitance, deposition status was confirmed. Electrical conductivity was measured on a perpendicular direction of the LB films and in consequence of calculated was average $2.5\;{\times}\;10^{-13}$ - $2\;{\times}\;10^{-14}$ S/cm.

Manipulating the Fatty Acid Composition of Eggs and Poultry Meat for the Human Health (건강을 생각하는 계란과 닭고기 생산을 위한 지방산 조성방안)

  • 남기홍
    • Korean Journal of Poultry Science
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    • v.26 no.4
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    • pp.217-236
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    • 1999
  • Among polyunsaturated fatty acids (PURAs) targeted for manipulation in animal tissues (poultry eggs and meat), omega-3 PUFAs(n-3 PUFAs) are discussed in this review. 3 or 5% dietary menhaden oil (MO) supplemented layer diets was reported to increase docosahexaenoic acid (DHA) and eicosapentaenoic acid (EPA) contents in the egg. MO at 1.5% also increased the deposition of up to 180mg total omega-3 fatty acids / yolk. Utilization of 5% ground flax seed (FS) resulted in similar total omega-3 fatty acid (FA) deposition as 1.5% MO. However, the basic feed formulations used in the Canadian feed industry usually include 10 to 20% FS in the egg laying diets. Recently several studies reported that addition of tocopherols in layer diets increased the tocopherol content more in the egg than any other tissue. One of reports said that 3.5% dietary oil with added tocopherols resulted in increasing tocopherol deposition and FA composition of the egg and other tissues. In the poultry meat, redfish meal (RM;4, 8, 12, 15 and 30% of diet) or redfish oil (RO;2.1 or 4.2% of diet) added to the practical corn-wheat-soybean based diets resulted in an increase in omega-3 FA and docosapentaenoic acid (DPA) contents in broiler meat lipids. Linseed oil (LO;1.0, 2.5, and 5.0% of broiler diet) supplemented in broiler diets also resulted in omega-3 FA and the ratio of omega-6 being significantly higher in poultry meat lipid than MO. Concern about fish flavor resulted in research about fish oil (FO) supplementation in broiler diets. Without the use of antioxidants, no more than 1.5% FO should be fed to broilers due to unacceptable orders from the chicken carcasses. One recent research project found that over 50mg/kg of vitamin E was required for maintaining the stability of unsaturated lipids in the meat. In regards to 'fishy'or 'crabby'taint in the eggs and poultry meat, poultry products remained acceptable when dietary fish oils were stabilized with antioxidants.

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Role of Acyl-CoA Synthetase 4, an Arachidonate-Preferring Enzyme Expressed in Steroidogenic Tissues

  • Kang, M.J.
    • Korean Journal of Animal Reproduction
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    • v.24 no.4
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    • pp.339-341
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    • 2000
  • In mammals, fatty acid utilization is initiated by activation of fatty acid, catalyzed by acyl-CoA synthetase(ACS, EC6.2.1.3). This enzyme reaction is essential in fatty acid metabolism, since mammalian fatty acid synthetase contains a specific thioesterase to produce fatty acid as th $\varepsilon$ final reaction product. Acyl-CoA, the product of ACS, is utilized in various metabolic pathways including membrane biogenesis, energy production and fat deposition. (omitted)

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The Effects of Additives and Residual Stresses on the Electroless Nickel Plating on Carbon Substrate (첨가제와 잔류응력이 탄소 기지상 무전해 니켈도금에 미치는 영향)

  • Cheon, So-Young;Rhym, Young-Mok;Lee, Jae-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.18 no.4
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    • pp.43-48
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    • 2011
  • Electroless nickel platings on carbon substrate were investigated for porous MCFC electrode applications. Acidic bath and alkaline bath were used in electroless nickel plating on carbon substrates. The rate of electroless plating in alkaline bath was faster than that in acidic bath. As pH was increased, the deposition rate was increased in both baths and the content of phosphorus in nickel deposit was decreased. The residual stresses of nickel deposit from acidic bath showed the compressive stress and on the other hand those from alkaline bath showed the high tensile stress. High tensile internal stress in nickel deposit caused the cracks over pH 11. Thiourea was added to both acidic and alkaline bath. The deposition rate of nickel was increased upto 0.5 ppm of thiourea and decreased. The maximum concentration of thiourea for the electroless nickel plating on carbon substrate was 1.5 ppm in both acidic and alkaline bath. Succinic acid was added to acidic bath. Addition of succinic acid up to 5 g/L increased the deposition rate of nickel and beyond which the deposition rate was decreased and maintained.

Gene expression of fatty acid binding protein genes and its relationship with fat deposition of Thai native crossbreed chickens

  • Tunim, Supanon;Phasuk, Yupin;Aggrey, Samuel E.;Duangjinda, Monchai
    • Animal Bioscience
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    • v.34 no.4
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    • pp.751-758
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    • 2021
  • Objective: The objectives of this study were to investigate the relationship between the mRNA expression of adipocyte type fatty acid binding protein (A-FABP) and heart type FABP (H-FABP) in Thai native chicken crossbreeds and evaluate the level of exotic inclusion in native chicken that will improve growth while maintaining its relatively low carcass fat. Methods: The fat deposition traits and mRNA expression of A-FABP and H-FABP were evaluated at 6, 8, 10, and 12 weeks of age in 4 chicken breeds (n = 8/breed/wk) (100% Chee breed [CH] [100% Thai native chicken background], CH male and broiler female [Kaimook e-san1; KM1] [50% CH background], broiler male and KM1 female [Kaimook e-san2; KM2] [25% CH background], and broiler [BR]) using abdominal fat (ABF) and muscular tissues. Results: The BR breed was only evaluated at 6 weeks of age. At week 6, the CH breed had a significantly lower A-FABP expression in ABF and intramuscular fat (IF) compared with the other breeds. At 8 to 12 weeks, the KM2 groups showed significant upregulation (p<0.05) of A-FABP in both ABF and IF compared to the CH and KM1 groups. The expression of H-FABP did not follow any consistent pattern in both ABF and IF across the different ages. Conclusion: Some level of crossbreeding CH chickens can be done to improve growth rate while maintaining their low ABF and IF. The expression level of A-FABP correlate with most fat traits. There was no consistency of H-FABP expression across breed. A-FABPs is involved in fat deposition, genetic markers in these genes could be used in marker assisted studies to select against excessive fat accumulation.

Correlation analysis of muscle amino acid deposition and gut microbiota profile of broilers reared at different ambient temperatures

  • Yang, Yuting;Gao, Huan;Li, Xing;Cao, Zhenhui;Li, Meiquan;Liu, Jianping;Qiao, Yingying;Ma, Li;Zhao, Zhiyong;Pan, Hongbin
    • Animal Bioscience
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    • v.34 no.1
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    • pp.93-101
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    • 2021
  • Objective: Temperature could influence protein and amino acid deposition as well as gut microbiota profile and composition. However, the specific effects of ambient temperature on amino acids deposition and gut microbiota composition remain insufficiently understood. Methods: A total of 300 one-day-old Avian broilers were randomly divided into three groups and reared at high, medium, and low temperature (HT, MT, and LT), respectively. Breast muscle and fecal samples were collected for amino acid composition analysis and 16S rRNA gene sequence analysis. Results: Our data showed that compared to the MT group, there was a decrease of muscle leucine and tyrosine (p<0.05), as well as an increase of methionine in the HT group (p<0.05) and a decrease of serine in the LT group. Examination of microbiota shift revealed that at genus level, the relative abundance of Turicibacter and Parabacteroides was increased in the HT group (p<0.05) and that the relative abundances of Pandoraea, Achromobacter, Prevotella, Brevundimonas, and Stenotrophomonas in the LT group were higher than those in the MT group (p<0.05). In addition, there were substantial correlations between microbes and amino acids. In the HT group. Turicibacter was negatively correlated with aspartic acid and tyrosine, whereas Parabacteroides was positively correlated with methionine (p<0.05). In the LT group, there were multiple positive correlations between Achromobacter and arginine, isoleucine or tyrosine; between Prevotella and cysteine or phenylalanine; between Brevundimonas and cysteine; and between Stenotrophomonas and cysteine as well as a negative correlation between Stenotrophomonas and serine. Conclusion: Our findings demonstrated that amino acid content of breast muscle and intestinal microbiota profile was affected by different ambient temperatures. Under heat exposure, augmented abundance of Parabacteroides was correlated with elevated methionine. Low temperature treatment may affect muscle tyrosine content through the regulation of Achromobacter.

Atmospheric Acidic Deposition: State of Acid Rain in Korea and the World (대기산성강하물: 한국과 세계의 산성비 실태)

  • Kim, Joon-Ho
    • The Korean Journal of Ecology
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    • v.28 no.3
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    • pp.169-180
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    • 2005
  • Nitrogen dioxide concentration was being grown ca. 8% per year although sulphur dioxide concentration was being reduced ca. 10% per year in Seoul from 1996 to 2003. The rainwater was heavily acidic with pH 4.19 to 4.68 in Seoul during 1980 to 1991. Acidity score on the basis of the total anion concentration of rainwater follows the higher in sequence with Seoul(Kwanaksan)(341.5 ${\mu}equiv{\cdot}L^{-1}$), Gwangneung(199.2 ${\mu}equiv{\cdot}L^{-1}$) and whole Korea mean(10.3 ${\mu}equiv{\cdot}L^{-1}$). Rainwaters from 38 sampling sites of 16 countries in the world, on the basis of the acidity score, are classified and designated as five acid rain grades(ARG): the least score is founded in Tana Rata(16.2 ${\mu}equiv{\cdot}L^{-1}$), Malaysia where has the best rain but the greatest founded in Chongquing(541.1 ${\mu}equiv{\cdot}L^{-1}$), China where has the worst rain in the world. Even though acidic deposition decrease with time in the world generally, it is expected to increase in Asia, Africa and Mid-South America.

Evaluation on Effects of Acid Deposition by analysis Rainfall in the Forest (산림내 강우에 의한 산성 강하물의 영향 평가)

  • 이총규;김종갑
    • The Korean Journal of Ecology
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    • v.21 no.5_1
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    • pp.449-456
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    • 1998
  • This study was carried out to investigate the characteristics of acid deposition by stemflow, throughfall, rainfall and $SO_{2}$ in the industrial, urban and rural areas where were affected by the acid rain areas air pollution in Pinus thunbergii than Quercus spp. forest. As the stemflow pH in industrial and urban area were lowed that of rural area, the result industrial and urban, and correlation of negative ($r=-0.9415^{**}$) between pH and EC. The concentration of acid ion by stemflow, throughfall, rainfall were high $SO_{4}^{2-}$ ion at industrial areas, especially of $NO_{3}^{-}$ ion at urban areas. The concentration of basic ion all rain fall were high $Ca^{2+},\;Na^{+}$ ion at industrial areas, but there were high $Ca^{2+}$, $Na^{+}$ ion at urban areas. The concentration of $SO_{2}$ at survey areas were high $SO_{2}$ concentration at industrial and urban areas, but there was low at rural areas. There was correlation of negative ($r=-0.8007^{**}$ between pH and $SO_{2}$ concentration at survey areas. Soil acidity was also affected by stemflow and showed sigificantly low pH in industerial and urban areas.

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Effect of the surface modification using MWCNTs with different L/D by two different methods of deposition on the IFSS of single carbon fiber-epoxy resin composite

  • Herrera-Sosa, Minerva L.;Valadez-Gonzalez, Alex;Vazquez-Torres, Humberto;Mani-Gonzalez, Pierre G.;Herrera-Franco, Pedro J.
    • Carbon letters
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    • v.24
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    • pp.18-27
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    • 2017
  • Multiwall carbon nanotubes (MWCNT) with two different (L/D) aspect ratios ($7{\pm}2{\mu}m/140{\pm}30nm$ and $0.5-2{\mu}m/8-15nm$) were surface treated using nitric acid ($HNO_3$) and polyethyleneimine (PEI) prior to their deposition on carbon fibers (CF). Before the hierarchical reinforcement with CF-MWCNT, the CFs were treated with 3-glycidoxypropyltrime-thoxysilane, a coupling agent (Z6040) and with poly(amidoamine) (PAMAM) a dendrimer containing an ethylenediamine core and amine surface groups. The MWCNT were deposited on the CF using two methods, by electrostatic attraction and by chemical reactions. The changes in the CF surface morphology after the MWCNT deposition were analyzed using SEM, which revealed a higher density and uniform coverage for the PAMAM-treated CF and the short MWCNTs. The interfacial adhesion of the composite materials was evaluated using the single fiber fragmentation technique. The results indicated an improvement in the interfacial shear strength with the addition of the short-MWCNTs treated with acid solutions and grafted onto the surface of the CF fiber using electrostatic attraction.