• Title/Summary/Keyword: Accumulation layer

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Structural and C-V characteristics of SrTiO$_3$ /PbTiO$_3$ thin film deposited on Si (Si 기판위에 증착한 SrTiO$_3$ /PbTiG$_3$ 고용체 박막의 구조적 특성 및 C-V 특성)

  • 이현숙;이광배;김윤정;박장우
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.71-74
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    • 2000
  • Pt/Pb$TiO_3$/$SrTiO_3$/p-Si films were prepared by metallo-organic solution deposition(M0SD) method and investigated its structure and ferroelectric properties. Crystallinity of specimen as a funtions of post annealing temperature and the thickness of $SrTiO_3$(STO) buffer layer was studied using XRD and AFM. Based on C-V and P-E curve, $PbTiO_3$(PTO) capacitors showed good ferroelectric hysteresis arising from the polarization switching properties. When the thickness of ST0 buffer layer between PTO and Si substrate was 260 nrn and the post annealing temperature was $650^{\circ}C$, it was showed that production of the pyrochlore phase due to interdiffusion of Si into FTO was prevented. The dielectric constant of FTO thin films calculated from a maximum Cma in the accumulation region was 180 and the dielectric loss was 0.30 at 100 kHz frequency. The memory window in the C-V curve is 1.6V at a gate voltage of 5V.

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The Effective Capacitance of a Constant Phase Element with Resistors in Series

  • Byoung-Yong, Chang
    • Journal of Electrochemical Science and Technology
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    • v.13 no.4
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    • pp.479-485
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    • 2022
  • The power of energy storage devices is characterized by capacitance and the internal resistance. The capacitance is measured on an assumption that the charges are stored at the electrode interface and the electric double layer behaves like an ideal capacitor. However, in most cases, the electric double layer is not ideal so a constant phase element (CPE) is used instead of a capacitor to describe the practical observations. Nevertheless, another problem with the use of the CPE is that CPE does not give capacitance directly. Fortunately, a few methods were suggested to evaluate the effective capacitance in the literature. However, those methods may not be suitable for supercapacitors which are modeled as an equivalent circuit of a CPE and resistor connected in series because the time constant of the equivalent circuit is not clearly studied. In this report, in order to study the time constant of the CPE and find its equivalent capacitor, AC and DC methods are utilized in a complementary manner. As a result, the time constants in the AC and DC domains are compared with digital simulation and a proper equation is presented to calculate the effective capacitance of a supercapacitor, which is extended to an electrochemical system where faradaic and ohmic processes are accompanied by imperfect charge accumulation process.

Plant Growth and Nutrient Uptake of Kalanchoe Plants (Kalanchoe blossfeldiana 'New Alter') and Nutrient Accumulation of Growing Media with Growth Stage at Different Nutrient Strengths in Ebb and Flow Subirrigation Systems (Ebb and flow 저면관수 시스템에서 칼랑코에(Kalanchoe blossfeldiana 'New Alter') 생육단계별 배양액 농도에 따른 생육, 양분흡수 및 배지 양분 집적)

  • Noh, Eun-Hee;Son, Jung-Eek
    • Horticultural Science & Technology
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    • v.28 no.6
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    • pp.973-979
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    • 2010
  • The objective of this study was to determine the effect of electrical conductivity (EC) of nutrient solution on the growth, nutrient uptake of potted kalanchoe plants ($Kalanchoe$ $blossfeldiana$ 'New Alter') and the nutrient accumulation at the growing media with growth stage in ebb and flow subirrigation systems. Significant differences in leaf area, plant height, and dry weight of the plants were found among the different ECs of nutrient solution of 0.8, 1.6, 2.4, and $3.2dS{\cdot}m^{-1}$. Particularly the difference in plant growth became significantly greater from 5 weeks after treatment. The overall growth was the highest at EC $1.6dS{\cdot}m^{-1}$. Leaf area, plant height, and dry weight were maintained higher when EC increased to $2.4dS{\cdot}m^{-1}$, but rapidly decreased after EC $3.2dS{\cdot}m^{-1}$. The uptake of NO3-N was the greatest while that of $Mg^{2+}$ was the lowest at EC $1.6dS{\cdot}m^{-1}$, even though small differences were found among macro elements. The EC at the top layer of the growing media was 1 to 3 times higher than that at the bottom layer. Nutrient accumulation was accelerated in both the top and bottom layers with growth stage. At EC $3.2dS{\cdot}m^{-1}$, the growth of the plants was suppressed due to higher nutrient accumulation at the growing media. From the results, the strength and composition of nutrient solution should be determined by considering nutrient accumulation at the growing media in addition to EC of nutrient solution in ebb and flow subirrigation systems.

A Study on Freezing Characteristics of Pavements Using Data of Test Road (시험도로 자료를 이용한 포장의 동결특성 연구)

  • Jeong, Jin-Hoon;Bae, Sung-Ho;Kwon, Soon-Min
    • International Journal of Highway Engineering
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    • v.7 no.2 s.24
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    • pp.87-95
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    • 2005
  • To prevent the lowering of structural capability due to freezing and thawing in cold winter, numerous researches on frost heaving have been performed. As the result, the freezing index contour map of the Korea peninsula has been made for the design of the anti-freezing layer of pavements. However, the validity of the anti-freezing layer needs to be evaluated because systematic investigations on the variation of freezing depth with the thickness and material types of pavement layers and the configuration of the ground have been rarely performed. The freezing index of the Korea Highway Corporation test road site was calculated and the freezing depths of the concrete and asphalt pavements of the test road were investigated using the ambient and pavement temperature and water content. In addition, the investigated freezing depths were compared to the values estimated by existing freezing depth models. This is the preliminary study on the freezing-related data measured at the test road. The results with higher reliability will be produced by the long-term accumulation of the data and the analysis on it.

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Characteristics of Organic Carbon and Apparent Oxygen Utilization in the NE Pacific KODOS Area (북동태평양 KODOS 해역의 유기탄소 및 겉보기산소량 특성)

  • Son, Ju-Won;Son, Seung-Kyu;Kim, Kyeong-Hong;Kim, Ki-Hyune;Park, Yong-Chul;Kim, Dong-Hwa;Kim, Tae-Ha
    • Ocean and Polar Research
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    • v.27 no.1
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    • pp.1-13
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    • 2005
  • The samples for organic carbon analysis were collected between $5^{\circ}\;and\;17^{\circ}N$ along $131.5^{\circ}W$ in the northeast Pacific KODOS (Korea Deep Ocean Study) area. The mean concentration of total organic carbon (TOC) in the surface mixed layer $({\sim}50 m)$ was $100.13{\pm}2.05{\mu}M-C$, while the mean concentration of TOC in the lower 500m of the water column was $50.19{\pm}4.23{\mu}M-C$. A strong linear regression between TOC and temperature $(r^2=0.70)$ showed that TOC distribution was controlled by physical process. Results from the linear regression between chlorophyll-a and TOC, and between chlorophyll-a and particulate organic carbon (POC), decreasing of dissolved organic carbon (DOC) in the surface layer caused by non-biological photo-oxidation process. Below the surface layer, biological production and consumption occurred. DOC accumulation dominated in the depth range of $30{\sim}50m$ and DOC consumption occurred in the depth range of $50{\sim}200m$. TOC was inversely correlated with apparent oxygen utilization (AOU) and TOC/AOU molar ratios ranged from -0.077 to -0.21. These ratios indicated that TOC oxidation was responsible fur $10.9{\sim}30.1%$ (mean 20.2%) of oxygen consumption in the NE Pacific KODOS area. In the euphotic zone, distributions of dissolved and particulate organic matter were controlled by photo-chemical, chemical, biological and physical processes.

A Study on the Oogenesis of Pale Chub (Zacco platypus) (피라미(Zacco platypus)의 난자형성에 관한 연구)

  • Jang, Seung-Jae;Kim, Dong-Heui;Reu, Dong-Suck;Deung, Young-Kun
    • Applied Microscopy
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    • v.25 no.3
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    • pp.63-74
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    • 1995
  • The development of pale chub oocyte from the immature oogonium to mature oocyte was investigated by light and electron microscope. The cytoplasm of pale chub oogonia was acidic and many vesicles were located at inner side of nuclear membrane. In primary oocytes, yolk vesicles were distributed in cytoplasm. Also, fibrous materials and protuberances were distributed on the surface of zona radiata. The nucleus of secondary oocyte was enlarged and yolk vesicles in cytoplasm migrated to zona radiata. In early egg, yolk mass are formed and yolk vesicles were located at inner side of zona radiata. Three-layered zona radiata was about $3{\mu}m$ in thickness. The three layers were an outer fibrous material layer, a middle nurse cell layer in which microvilli of early egg cytoplasm contact with processes of nurse cells, and an inner layer with high electron density. In mature egg, euchromatin and a germinal vesicle were developed, mitochondria, free ribosomes, and yolk mass were distributed in cytoplasm. But, yolk vesicles were disappeared. Specially, zona radiata of matured eggs were better thin than the one of immature eggs In conclusion, it is summerized that the oogenesis of pale chub were the increase of cell size, the formation and accumulation of yolk, the decrease in nucleat electron density, changes of zona radiata, and the development of microvilli.

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Formation Mechanisms of Sn Oxide Films on Probe Pins Contacted with Pb-Free Solder Bumps (무연솔더 범프 접촉 탐침 핀의 Sn 산화막 형성 기제)

  • Bae, Kyoo-Sik
    • Korean Journal of Materials Research
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    • v.22 no.10
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    • pp.545-551
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    • 2012
  • In semiconductor manufacturing, the circuit integrity of packaged BGA devices is tested by measuring electrical resistance using test sockets. Test sockets have been reported to often fail earlier than the expected life-time due to high contact resistance. This has been attributed to the formation of Sn oxide films on the Au coating layer of the probe pins loaded on the socket. Similar to contact failure, and known as "fretting", this process widely occurs between two conductive surfaces due to the continual rupture and accumulation of oxide films. However, the failure mechanism at the probe pin differs from fretting. In this study, the microstructural processes and formation mechanisms of Sn oxide films developed on the probe pin surface were investigated. Failure analysis was conducted mainly by FIB-FESEM observations, along with EDX, AES, and XRD analyses. Soft and fresh Sn was found to be transferred repeatedly from the solder bump to the Au surface of the probe pins; it was then instantly oxidized to SnO. The $SnO_2$ phase is a more stable natural oxide, but SnO has been proved to grow on Sn thin film at low temperature (< $150^{\circ}C$). Further oxidation to $SnO_2$ is thought to be limited to 30%. The SnO film grew layer by layer up to 571 nm after testing of 50,500 cycles (1 nm/100 cycle). This resulted in the increase of contact resistance and thus of signal delay between the probe pin and the solder bump.

Effect of subsurface flow and soil depth on shallow landslide prediction

  • Kim, Minseok;Jung, Kwansue;Son, Minwoo;Jeong, Anchul
    • Proceedings of the Korea Water Resources Association Conference
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    • 2015.05a
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    • pp.281-281
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    • 2015
  • Shallow landslide often occurs in areas of this topography where subsurface soil water flow paths give rise to excess pore-water pressures downslope. Recent hillslope hydrology studies have shown that subsurface topography has a strong impact in controlling the connectivity of saturated areas at the soil-bedrock interface. In this study, the physically based SHALSTAB model was used to evaluate the effects of three soil thicknesses (i.e. average soil layer, soil thickness to weathered soil and soil thickness to bedrock soil layer) and subsurface flow reflecting three soil thicknesses on shallow landslide prediction accuracy. Three digital elevation models (DEMs; i.e. ground surface, weathered surface and bedrock surface) and three soil thicknesses (average soil thickness, soil thickness to weathered rock and soil thickness to bedrock) at a small hillslope site in Jinbu, Kangwon Prefecture, eastern part of the Korean Peninsula, were considered. Each prediction result simulated with the SHALSTAB model was evaluated by receiver operating characteristic (ROC) analysis for modelling accuracy. The results of the ROC analysis for shallow landslide prediction using the ground surface DEM (GSTO), the weathered surface DEM and the bedrock surface DEM (BSTO) indicated that the prediction accuracy was higher using flow accumulation by the BSTO and weathered soil thickness compared to results. These results imply that 1) the effect of subsurface flow by BSTO on shallow landslide prediction especially could be larger than the effects of topography by GSTO, and 2) the effect of weathered soil thickness could be larger than the effects of average soil thickness and bedrock soil thickness on shallow landslide prediction. Therefore, we suggest that using BSTO dem and weathered soil layer can improve the accuracy of shallow landslide prediction, which should contribute to more accurately predicting shallow landslides.

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Finite Element Method (FEM) Study on Space Charge Effects in Organic Light Emitting Diodes (OLED)

  • Kim, Kwang-Sik;Hwang, Young-Wook;Won, Tae-Young
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.12 no.4
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    • pp.467-472
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    • 2012
  • In this paper, we present a finite element method (FEM) study on the space charge effects in organic light emitting diodes. The physical model covers all the key physical processes in OLEDs, namely charge injection, transport and recombination, exciton diffusion, transfer and decay as well as light coupling, and thin-film-optics. The exciton model includes generation, diffusion, and energy transfer as well as annihilation. We assumed that the light emission originates from oscillation which thus is embodied as exciton in a stack of multilayer. We discuss the accumulation of charges at internal interfaces and their signature in the transient response as well as the electric field distribution. We also report our investigation on the influence of the insertion of the emission layer (EML) in the bilayer structure.

Effect of Accumulated charges on Surface Hydrophobicity of RTV Silicone Rubber (RTV 실리콘 고무 코팅재의 표면전하 축적이 발수성에 미치는 영향)

  • 연복희;허창수;조한구
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.597-600
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    • 2001
  • In this paper, we evaluated the effect of accumulated charges on hydrophobicity of room temperature vulcanized(RTV) silicone rubber, which could improve the contamination performance of porcelain insulators, with uv radiation time. Outdoor insulating material could be charged by the corona discharge on field intensified area of insulator and discharge between the water drops. In addition, we performed the accelerated uv radiation on samples and investigated the change of charging decay with time. In this results, it is found that silica-like structure on the surface of RTV silicone rubber was formed by uv treatments and this layer have the characteristic of retaining the charges on surface for a long time. These charges have effects on its hydrophobicity and so adversely effects on contamination performance. Based on our results, we discussed the other degradation mechanism with well known ones.

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