• Journal of the Korean Solar Energy Society
• /
• v.31 no.4
• /
• pp.80-86
• /
• 2011

Investigation of the effective soil thermal conductivity(k) is the first step in designing the ground loop heat exchanger(borehole) of a geothermal heat pump system. Another important factor is the borehole thermal resistance($R_b$). Thermal response tests offer a good method to determine the ground thermal properties for the total heat transport in the ground. This is done by supplying a constant heat power into a borehole heat exchanger. There are two methods to supply a constant heat power. One is to employ the electricity provided by Korea Electric Power Corporation(KEPCO). The other is to use electricity generated by a generator. In this study, the power supply regulation was found to reduce when the electricity generated by the generator was used. This is because the generator evaluated with the power supply characteristically reduces the power supply regulation between an overload and a complex using. But it sometimes occurs a power supply regulation in In-situ thermal response test. In this case getting of k,$R_b$ requires delay times and restored normal state. However, the effect of the delay times and restored normal state on the soil thermal conductivity and borehole thermal resistance is very small. Therefore it is possible to use a generally accepted delay times and restored normal state in the analysis. In this work, it is also shown that an acceptable range of ${\Delta}k$, ${\Delta}R_b$ for normal state and regulation state might be approximately 0.01-0.16W/m k, and -0.004-0.007m K/W, respectively. Thus, restored normal state of power supply regulation is valuable to recommend.

• Bulletin of the Korean Chemical Society
• /
• v.22 no.7
• /
• pp.753-757
• /
• 2001

1-(2'2'3'-Tricyano-3-carbomethoxycyclopropyl)-34-di-(2'-hydroxyethoxy)benzene, (4) was prepared by the reaction of bromomalononitrile with methyl 3,4-di-(2'-hydroxyethoxy)benzylidenecyanoacetate (3). Diol 4 was condensed with tolylene-2,4-diisocyanate, 3,3'-dimethoxy-4,4'-biphenylenediisocyanate, and 1,6-hexamethylenediisocyanate to yield polyurethanes 5, 6, and 7 containing tricyanocyclopropane functionalities in the pendant group. The resulting polymers 5-7 were soluble in common organic solvents and the inherent viscosities were in the range of 0.25-0.30 dL/g. Polyurethanes 5-7 showed a thermal stability up to 300 $^{\circ}C$ in TGA thermograms. Solution-cast films showed Tg values in the range of 100-125 $^{\circ}C$ and piezoelectric coeffcients (d31) of the poled polymer films were 1.3-2.0 pC/N, which are acceptable for piezoelectric device applications.

• Bulletin of the Korean Chemical Society
• /
• v.20 no.5
• /
• pp.567-572
• /
• 1999

5-Nitro-2-(2'-vinyloxyethoxy)benzylidenemalononitrile (2a), methyl 5-nitro-2-(2'-vinyloxyethoxy)benzylidenecyanoacetate (2b), 3-nitro-4-(2'-vinyloxyethoxy)benzylidenemalononitrile (4a), methyl 3-nitro-4-(2'-vinyloxyethoxy)benzylidenecyanoacetate (4b), 2-nitro-5-(2'-vinyloxyethoxy)benzylidenemalononitrile (6a), and methyl 2-nitro-5-(2'-vinyloxyetboxy)benzylidenecyanoacetate (6b) were prepared by the condensation of 5-nitro-2-(2'-vinyloxyethoxy)benzaldehyde (1), 3-nitro-4-(2'-vinyloxyethoxy)benzaldehyde (3), and 2-nitro-5-(2'-vinyloxyethoxy)benzaldehyde (5) with malononitrile or methyl cyanoacetate, respectively. Vinyl ether monomers 2a-b, 4a-b, and 6a-b were polymerized with boron trifluoride etherate as a cationic initiator to yield poly(vinyl ethers) 7-9 having oxynitrobenzylidenemalononitrile and oxynitrobenzylidenecyanoacetate, which is effective chromophore for second-order nonlinear optical applications. Polymers 7-9 were soluble in common organic solvents such as acetone and DMSO. Tg values of the resulting polymers were in the range of 67-83 ℃. Electrooptic coefficient (r33) of the poled polymer films were in the range of 15-27 pm/V at 633 nm. Polymers 7-9 showed a thermal stability up to 300 ℃ in TGA thermograms, which is acceptable for NLO device applications.

• Bulletin of the Korean Chemical Society
• /
• v.29 no.5
• /
• pp.933-938
• /
• 2008

2,4-Di-(2'-hydroxyethoxy)benzylidenemalononitrile (3) was prepared and polymerized with terephthaloyl chloride and adipoyl chloride to yield novel Y-type polyesters 4 and 5 containing dioxybenzylidenemalononitrile groups as NLO-chromophores, which constituted parts of the polymer backbone. The resulting polymers 4 and 5 are soluble in common organic solvents such as acetone and N,N-dimethylformamide. Polymers 4 and 5 showed thermal stability up to 300 ${^{\circ}C}$ in thermogravimetric analysis with glass-transition temperatures obtained from differential scanning calorimetry in the range 83-94 ${^{\circ}C}$. The second harmonic generation (SHG) coefficients ($d_{33}$) of poled polymer films at the 1064 nm fundamental wavelength were around $6.48\;{\times}\;10^{-9}$ esu. The dipole alignment exhibited high thermal stability even at 10 ${^{\circ}C}$ higher than $T_g$ and no significant SHG decay was observed below 105 ${^{\circ}C}$ partially due to the main-chain character of polymer structure, which is acceptable for NLO device applications.

• Journal of computational fluids engineering
• /
• v.20 no.1
• /
• pp.84-91
• /
• 2015

SMART adopts, very unique facility, an FMHA to enhance the thermal and flow mixing capability in abnormal conditions of some steam generators or reactor coolant pumps. The FMHA is important for enhancing thermal mixing of the core inlet flow during a transient and even during accidents, and thus it is essential that the thermal mixing characteristics of flow of the FMHA be understood. Investigations for the mixing characteristics of the FMHA had been performed by using experimental and CFD methods in KAERI. In this study, the temperature distribution at the core inlet region is investigated for several abnormal conditions of steam generators using the commercial code, FLUENT 12. Simulations are carried out with two kinds of FMHA shapes, different mesh resolutions, turbulence models, and steam generator conditions. The CFD results show that the temperature deviation at the core inlet reduces greatly for all turbulence models and steam generator conditions tested here, and the effect of mesh refinement on the temperature distribution at the core inlet is negligible. Even though the uniformity of FMHA outlet hole flow increases the thermal mixing, the temperature deviation at the core inlet is within an acceptable range. We numerically confirmed that the FMHA applied in SMART has an excellent mixing capability and all simulation cases tested here satisfies the design requirement for FMHA thermal mixing capability.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.3 no.4
• /
• pp.1-11
• /
• 1999

Thermal behavior of spacecraft propulsion system utilizing monopropellant hydrazine ($N_2$$H_4$) is addressed in this paper. Thermal control performance to prevent propellant freezing in spacecraft-operational orbit was test-verified under simulated on-orbit environment. The on-orbit environment was thermally achieved in space-simulation chamber and by the absorbed-heat flux method that implements an artificial heating through to the spacecraft bus panels enclosing the propulsion system. Test results obtained in terms of temperature history of propulsion components are presented and reduced into duty cycles of the avionics heaters which are dedicated to thermal control of those components. The duty cycles are subsequently converted into the electrical power required in the operational orbit. Additionally, cyclic temperature of each component, which was made under thermal-balanced condition of spacecraft, is compared to the acceptable design range and justified from the viewpoint of system verification.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
• /
• v.26 no.9
• /
• pp.26-32
• /
• 2012

This paper calculates the core and copper losses as heating sources of a 24MVA cast resin transformer, and analyzes the thermal distribution of the transformer to find out its hot-spot area by FEM program. Since the winding of the transformer is composed with many series and parallel circuits, the analyzing model of the winding is simplified and modelled by axi-symmetric domain. As the results, the maximum temperature is estimated by $137^{\circ}C$ in the upper part of the low-voltage winding. The maximum temperature has discrepancy of approximately $10^{\circ}C$, which is able to be considered as an acceptable error range in the design stage of power transformers. For the overall pattern of the temperature distribution is almost same as test results, the analyzing method can be a useful tool to find out a hot-spot area of the winding.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.15 no.3
• /
• pp.10-17
• /
• 2007

Design of experiments (DOE) technique has been used to design an exhaust heat exchanger to reduce the exhaust gas temperature under high load conditions in a spark-ignition engine. The DOE evaluates the influence and the interaction of a selected eight design parameters of the heat exchanger affecting the cooling performance of the exhaust gas through a limited number of experiments. The heat exchanger was installed between the exhaust manifold and the inlet of the close-coupled catalytic converter (CCC) to reduce thermal aging. To maximize the heat transfer between exhaust gas and coolant, fins were implemented at the inner surface of the heat exchanger. The design parameters consist of the fin geometry (length, thickness, arrangement, and number of fin), coolant direction, heat exchanger wall thickness, and the length of the heat exchanger. The acceptable range of each design parameter is discussed by analyzing the DOE results.

• Transactions of the Korean hydrogen and new energy society
• /
• v.29 no.5
• /
• pp.442-449
• /
• 2018

Research on High temperature polymer electrolyte fuel cell (HT-PEMFC) has actively been conducted all over the world. Since the HT-PEMFC can be operated at a high temperature of $120-180^{\circ}C$ using phosphoric acid-doped polybenzimidazole (PBI) electrolyte membrane, it has considerable advantages over conventional PEMFC in terms of operating conditions and system efficiency. However, If the thermal distribution is not uniform in the stack unit, degradation due to local reaction and deterioration of lifetime are difficult to prevent. The thin plate separator reduces the volume of the fuel cell stack and improves heat transfer, consequently, enhancing the cooling effect. In this paper, a large area flow field of thin plate separator for HT-PEMFC is designed and sub-stack is fabricated. We have studied stack performance evaluation under various operating conditions and it has been verified that the proposed design can achieve acceptable stack performance at a wide operating range.

• Proceedings of the KIPE Conference
• /
• 2001.07a
• /
• pp.364-367
• /
• 2001

ZVS Full-bridge converter is widely used in medium power level(1-3kW). ZVS can be designed within a limited load range and ZVS failure at light load condition is assumed to be acceptable within the given efficiency and thermal constraints. However, unbalanced ZVS resonant energy caused by dc blocking capacitor may alleviate the switching loss problem at light load condition. ZVS resonant energy is unbalanced by do blocking capacitor. This problem causes loss and heat concentration of a switch leg, In this paper, this problem is analyzed, and a novel control method is proposed to solve the problem.