• Analytical Science and Technology
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• v.7 no.3
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• pp.1069-1084
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• 1994

수 MV급 탄뎀형 가속기와 정전형, 자장형 질량분석기를 결합함으로써 존재비가 극히 작은 동위원소 측정이 가능해진다. 수 MeV로 가속이 되면 분해에 방해가 되는 모든 분자이온들이 제거되며, 탄뎀형 가속기에서는 음이온으로부터 가속이 개시되므로 몇몇 음이온을 형성하지 못하는 동중원소의 간섭으로부터 자유로워지기 때문에 고감도분석이 실현될 수 있다. 이외에 음이온을 형성하는 동중원소들은 주로 이온함인 최종 검출기에서의 유효 전하에 따른 에너지손실 차이를 이용하여 효과적으로 제거할 수 있다. 현재는 주로 장반감기 방사성동위원소인 $^{10}Be$, $^{14}C$, $^{26}Al$, $^{36}Cl$과 $^{129}I$ 등의 측정법이 확립되어 천연시료 중에서 동위원소 존재비 $10^{-12}$에서 $10^{-15}$까지의 정량이 가능하며, 원자수로 환산한 검출하한을 $10^5$개가 된다. 또한 해당 원소를 기준으로 소요 시료량은 대부분 mg 정도로 충분하다. 지금까지는 불가능했던 이러한 특징으로 인해 지난 수년간 AMS(Accelerator Mass Spectrometry)가 활용되어 온 연구분야는 지구과학(기후학, 우주화학, 빙하학, 수문학, 해양학, 퇴적학, 화산학 및 광물탐사), 인류 및 고고학(연대측정), 그리고 물리학(천체물리, 핵 및 입자물리) 등으로 다양하다. 이외에 생의학 및 재료과학 분야에서도 AMS를 활용하고자 하는 노력이 계속되고 있다. 본 해설에서는 가속기질량분석기술의 특징, 원리, 장치 및 활용분야 등을 소개하고자 하며, 이로써 관련 분야의 연구 활성화에 기여하고자 한다.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.17 no.3
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• pp.189-201
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• 2012

Radiocarbon is a powerful tool for studies of carbon cycling in the ocean. Development of measurement technology of accelerator mass spectrometry has enabled researchers to measure radiocarbon even in specific compounds. In this paper, a brief introduction on radiocarbon measurement and reporting of radiocarbon data is provided. Researches that used radiocarbon measurements on bulk organic matter, organic compound classes, and specific organic compounds are reviewed. Examples include works to understand the cycling of particulate and dissolved organic matter, biochemical composition of particulate organic matter, post-depositional transport of sedimentary organic matter, selective incorporation of fresh organic matter by benthic organisms, chemoautotrophy by archaea, and sources of halogenated chemical compounds found in marine mammals.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.245-246
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• 2013

한국과학기술연구원에서는 2007년부터 시작된 중대형가속기구축사업을 통하여 3기의 정전형 가속기를 설치하였다. 1996년에 도입된 2.0 MV Pelletron을 비롯하여 신규 도입된 6 MVTandetron과 400 kV implanter 등 모두 3기의 정전형가속기로 30 keV부터 ~60 MeV까지의 단색 이온빔을 인출, 이용할 수 있는 실험설비의 구축이 완성되었다. 정전형가속기의 주요 활용분야는 femto~atto mole정도의 동위원소를 측정하는 가속기질량분석법(AMS)를 비롯하여 RBS/ERD로 대표되는 이온빔분석법(ion beam analysis, IBA) 그리고 고에너지 이온빔을 이용한 물질 개질분야(ion beam material modification, IBMM)로 크게 분류된다. 이 시설은 당 연구원의 연구 수요 뿐 아니라 국내 연구자의 수요를 아우르는 시설로 계획하고 있다. 여타 실험/분석장비와 달리 가속기시설은본체의 완성 후 활용목적에 맞춰 빔라인의 증설이 필요하며 최근 가장활용성이 큰 가속기질량분석(accelerator mass spectrometry, AMS)의 경우는 활용분야별 시료 전처리 시설과 기술의 개발이 요구된다. 따라서 KIST에서는 향후 수년간 활용 분야별 대표적인 주제를 선정하고 필요한 선행연구를 통하여 KIST 이온빔시설에 대한 연구자들의 접근편의성을 제고하고자한다. 본 발표에서는 지난 6년간의 수행된 가속기 시설의 개요와 함께 장차 수행할 선행연구의 방향과 내용을 소개한다(Figure capture). Layout of the newly constructed KIST ion beam facility.

• Economic and Environmental Geology
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• v.39 no.1 s.176
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• pp.53-61
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• 2006

Geochemical and sedimentological analyses of sediment piston core were used to trace paleoceanographic environmental changes in the East China Sea. The analytical results revealed three lithostratigraphic units (I, II, and III) corresponding to a highstand stage, a transgressive stage, and a lowstand stage, respectively. Accelerator mass spectrometry (AMS) $^{14}C$ dated the boundaries between the units as 7 ka and II ka. That is, Unit I extended from the present to 7 ka, Unit II occupied a transitional episode from 7 to 11 ka, and Unit III was older than 11 ka. The transitional episode was characterized by sudden fluctuations in various geochemical proxies. Most strikingly, there was a gradual upward increase in both carbonate and total organic carbon (TOe) contents post-7 ka, during which time the ${\delta}^{l3}C$ values of organic material increased to a constant value. The gradual upward increase in the TOC and $CaCO_3$ contents in Unit I were accompanied by slight variations in grain size that probably reflect a stable modern oceanographic environment. Within Unit II (7 to 11 ka), the geochemical signals were characterized by abrupt and steep fluctuations, typical of a transgressive stage. Vertical mixing may have provoked an increase in productivity during this interval, with large amounts of terrigenous organic matter and/or freshwater being supplied by neighboring rivers. The geochemical signals remained stable throughout Unit III but exhibited different patterns than signals in Unit I. The high terrigenous organic matter content of Unit III suggests correspondence to a lowstand stage.

• Safety and Health at Work
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• v.14 no.2
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• pp.237-242
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• 2023

Background: This study evaluated occupational exposure levels of doxorubicin in healthcare workers performing rotational intraperitoneal pressurized aerosol chemotherapy (PIPAC) procedures. Methods: All samples were collected during PIPAC procedures applying doxorubicin to an experimental animal model (pigs). All procedures were applied to seven pigs, each for approximately 44 min. Surface samples (n = 51) were obtained from substances contaminating the PIPAC devices, surrounding objects, and protective equipment. Airborne samples were also collected around the operating table (n = 39). All samples were analyzed using ultra-high performance liquid chromatography-mass spectrometry. Results: Among the surface samples, doxorubicin was detected in only five samples (9.8%) that were directly exposed to antineoplastic drug aerosols in the abdominal cavity originating from PIPAC devices. The telescopes showed concentrations of 0.48-5.44 ng/cm² and the trocar showed 0.98 ng/cm² in the region where the spraying nozzles were inserted. The syringe line connector showed a maximum concentration of 181.07 ng/cm², following a leakage. Contamination was not detected on the surgeons' gloves or shoes. Objects surrounding the operating table, including tables, operating lights, entrance doors, and trocar holders, were found to be uncontaminated. All air samples collected at locations where healthcare workers performed procedures were found to be uncontaminated. Conclusions: Most air and surface samples were uncontaminated or showed very low doxorubicin concentrations during PIPAC procedures. However, there remains a potential for leakage, in which case dermal exposure may occur. Safety protocols related to leakage accidents, selection of appropriate protective equipment, and the use of disposable devices are necessary to prevent occupational exposure.

• Analytical Science and Technology
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• v.21 no.1
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• pp.9-13
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• 2008

We have collected a batch of leaf samples at several main crossroads in Daejeon and a background site to obtain distribution of $CO_2$ (greenhouse gas) due to fossil fuel combustion. The leaf samples were treated with AAA method and ${\Delta}^{14}C$ values of them were measured using AMS. ${\Delta}^{14}C$ values of downtown sites were found to be lower by 27-102 ‰ than that of the background site, and the ratio of $CO_2$ originated from fossil fuel combustion in the atmosphere of Daejeon could be calculated from the differences of ${\Delta}^{14}C$ values. The average ${\Delta}^{14}C$ of the background site, around Kyeryong mountain, was measured to be $35{\pm}8$ ‰, and this value is lower than 66.3 ‰, which have been known as the backgdound values in USA.

• Korean Journal of Ecology and Environment
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• v.56 no.4
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• pp.281-302
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• 2023

Carbon is not only an essential element for life but also a key player in climate change. The radiocarbon (¹⁴C) analysis using accelerator mass spectrometry (AMS) is a powerful tool not only to understand the carbon cycle but also to track pollutants derived from fossil carbon, which have a distinct radiocarbon isotope ratio (Δ¹⁴C). Many studies have reported Δ¹⁴C of carbon compounds in streams, rivers, rain, snow, throughfall, fine particulate matter (PM_2.5), and wastewater treatment plant effluents in South Korea, which are reviewed in this manuscript. In summary, (1) stream and river carbon in South Korea are largely derived from the chemical weathering of soils and rocks, and organic compounds in plants and soils, strongly influenced by precipitation, wastewater treatment effluents, agricultural land use, soil water, and groundwater. (2) Unprecedentedly high Δ¹⁴C of precipitation during winter has been reported, which can directly and indirectly influence stream and river carbon. Although we cannot exclude the possibility of local contamination sources of high Δ¹⁴C, the results suggest that stream dissolved organic carbon could be older than previously thought, warranting future studies. (3) The ¹⁴C analysis has also been applied to quantify the sources of forest throughfall and PM_2.5, providing new insights. The ¹⁴C data on a variety of ecosystems will be valuable not only to track the pollutants derived from fossil carbon but also to improve our understanding of climate change and provide solutions.