• Title/Summary/Keyword: Accelerated chloride diffusion coefficient

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Chloride Penetration Resistance and UV Properties in Coating Materials Containing Various Slime-Forming Bacteria (슬라임 생성 박테리아를 혼입한 코팅재의 염해 저항성 및 초음파 특성)

  • Kwon, Seung-Jun;Yoon, Hyun-Sub;Yang, Keun-Hyeok
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.4
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    • pp.395-402
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    • 2017
  • Recently, many researches on crack healing and repairing technique using bacteria which can produce vital-reacted calcite have been proposed. This study is for a basic research on repair material with slime formation through bacteria and deals with durability evaluation for coating materials containing bacteria-forming slime. For the work, 4 types of bacteria (Rhodobacter capsulatus, Rhodopseudomonas palustris, Bacillus thuringiensis, and Bacillus subtilis) and 2 types of nutrient conditions are considered, and several tests covering strength evaluation under sulfate condition, accelerated chloride diffusion, and UV (Ultrasonic Velocity) measurement are performed. Strength improvement in coating materials containing bacteria is evaluated in spite of even exposure to sulfate attack to 7 days. Chloride diffusion coefficient and UV properties are also improved except for the case of Rhodopseudomonas palustris. With resistance of slime to long term exposure and aerobic conditions for bacteria longevity, the proposed bacteria shows an engineering feasibility for repair material of RC structure exposed harsh environment.

Evaluation of Time-Dependent Chloride Resistance in HPC Containing Fly Ash Cured for 1 Year (1년 양생 조건의 Fly Ash를 혼입한 고성능 콘크리트의 시간의존적 염해저항성 평가)

  • Yoon, Yong-Sik;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.4
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    • pp.52-59
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    • 2018
  • To control chloride attacks which is a representative deterioration in RC(Reinforced Concrete) structures, many studies have been conducted. Above all, a method using mineral admixture was known to be effective for corrosion protection. In this study, durability test about chloride attacks was carried out for concrete specimens containing FA(Fly Ash)-representative concrete mineral admixture and OPC concrete specimens considering 3 different levels of W/B(Water to Binder). Accelerated chloride diffusion coefficient tests referred to Tang's method, total passed charge tests referred to ASTM C 1202, and compressive strength tests based on KS F 2405 were performed at each target age day. Also, based on previous studies of 28 days, time-parameter which is a key parameter for diffusion behavior is evaluated and its relations with compressive strength at the age of 365 days is evaluated. After the age of 49 days, chloride resistance of FA concrete is much improved than that of OPC concrete, which arose out of stable hydrates due to pozzolan reaction of fly ash. Time-parameter of FA concrete is evaluated to be about 1.5 times larger than that of OPC concrete. Also, time-parameter of FA concrete has a linearly decreasing relation while that of OPC concrete has a linearly increasing relation with compressive strength development.

Relationship between Chloride Diffusivity and the Fundamental Properties of Concrete (염소이온의 확산계수와 콘크리트의 기초물성과의 관계)

  • Choi, Doo-Sun;Choi, Jae-Jin
    • Journal of the Korean Society of Hazard Mitigation
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    • v.9 no.1
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    • pp.15-20
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    • 2009
  • Marine concrete structure is exposed to salt injury and deteriorated by steel corrosion due to chloride ions diffusion. It, therefore, is very important to estimate the chloride diffusivity in concrete. In this paper the compressive strength and permeable pore volume of concrete are measured and the diffusion coefficient and penetration depth of chloride ions in concrete were investigated to estimate the chloride diffusivity efficiently. To correlate these results each other, regression analysis was done. The results showed a good linear relation between chloride diffusivity and the fundamental properties of concrete and the chloride diffusivity of concrete with water-cement ratios of $40%{\sim}60%$ were about $2.5{\sim}6.6{\times}10^{-12}m^2/s$.

Evaluation of Chloride Behavior and Service Life in Long-Term Aged FA Concrete through Probabilistic Analysis (장기재령 FA 콘크리트에 대한 염화물 거동 및 확률론적 염해 내구수명 평가)

  • Yoon, Yong-Sik;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.3
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    • pp.276-285
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    • 2020
  • In this study, accelerated chloride diffusion tests were performed on OPC(Ordinary Portland Cement) and FA(Fly Ash) concrete considering three levels o f W/B(Water to Binder) ratio o n 1,095 curing days. The accelerated chloride diffusion coefficient and the passed charge were evaluated in accordance with Tang's method and ASTM C 1202, and the resistance performance to chloride attack improved over time. FA concrete showed excellent resistance performance against chloride penetration with help of pozzolanic reaction. As the result of the passed charge, FA concrete showed durability improvement, "low" grade to "very low" grade, but OPC concrete changed "moderate" grade to "low" grade at 1,095 curing days. After assuming the design variables used for durability design as normal distribution functions, the service life of each case was evaluated by the probabilistic analysis method based on MCS(Monte Carlo Simulation). In FA concrete, the increase of probability of durability failure was lower than that of OPC concrete with increasing time, because the time-dependent coefficient of FA concrete was up to 3.2 times higher than OPC concrete. In addition, the service life by probabilistic analysis was evaluated lower than the service life by deterministic analysis, since the target probability of durability failure was set to 10%. It is considered that more economical durability design will be possible if the mo re suitable target probability of durability failure is set for various structures through researches on actual conditions and indoor tests under various circumstances.

A Study on Performance Evaluation of Early-age Concrete with EOS Fine Aggregate and GGBFS (EOS 잔골재 및 GGBFS를 혼입한 초기재령 콘크리트의 성능 평가에 관한 연구)

  • Kwon, Seung Jun;Cho, Sung Jun;Lim, Hee Seob
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.4
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    • pp.113-119
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    • 2019
  • Many researches on alternative materials as construction materials is continuing by recycling industrial byproducts due to shortage of sitereclamation and natural aggregates. In this paper, engineering properties in early-aged OPC (Ordinary Portland Cement) and GGBFS (Ground Granulated Blast Furnace Slag) concrete are evaluated with EOS aggregate replacement. The related experiments were carried out with 0.6 of water to binder ratio, three levels of EOS replacement ratios (0%, 30% and 50%) for fine aggregate, and two levels of cement replacement with GGBFS (0% and 40%). Several tests such as slump air content, and unit mass measurement are performed for fresh concrete, and compressive strength and diffusion coefficient referred to NT BUILD 492 method are measured for hardened concrete. Through the tests, it was evaluated that the compressive strength in concrete with EOS aggregate increased to 3 days and 7 days but slightly decreased at the age of 28 days. In the accelerated chloride penetration test, GGBFS concrete showed reduced diffusion coefficients by 60 - 67% compared with OPC concrete. The lowest chloride diffusion coefficient was evaluated in the 50% replacement with EOS aggregate, which showed an applicability of EOS aggregate to concrete production.

Evaluation of Chloride Diffusion Behavior and Analysis of Probabilistic Service Life in Long Term Aged GGBFS Concrete (장기 재령 GGBFS 콘크리트의 염화물 확산 거동 평가 및 확률론적 염해 내구수명 해석)

  • Yoon, Yong-Sik;Kim, Tae-Hoon;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.3
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    • pp.47-56
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    • 2020
  • In this study, three levels of W/B(Water to Binder) ratio (0.37, 0.42, 0.47) and substitution ratio of GGBFS (Ground Granulated Blast Furnace Slag) rate (0 %, 30 %, 50 %) were considered to perform RCPT (Rapid Chloride Diffusion Test) at the 1,095 aged day. Accelerated chloride diffusion coefficient and passed charge of each concrete mixture were assessed according to Tang's method and ASTM C 1202, and improving behaviors of durability performance with increasing aged days are analyzed based on the test results of previous aged days from the preceding study. As the age of concrete increases, the passed charge and diffusion coefficient have been significantly reduced, and especially the concrete specimens containing GGBFS showed a significantly more reduction than OPC(Ordinary Portland Cement) concrete specimen by latent hydraulic activity. In the case of OPC concrete's results of passed charge, at the 1,095 days, two of them were still in the "Moderate" class. So, if only OPC is used as the binder of concrete, the resistance performance for chloride attack is weak. In this study, the time-parameters (m) were derived based on the results of the accelerated chloride diffusion coefficient, and the deterministic and probabilistic analysis for service life were performed by assuming the design variable as a probability function. For probabilistic service life analysis, durability failure probabilities were calculated using Monte Carlo Simulation (MCS) to evaluate service life. The service life of probabilistic method were lower than that of deterministic method, since the target value of PDF (Probability of Durability Failure) was set very low at 10 %. If the target value of PDF suitable for the purpose of using structure can be set and proper variability can be considered for each design variable, it is believed that more economical durability design can be made.

Characteristics of Chloride Ion Behavior in an Cement Matrix Using Calcium Nitrite Inhibitor (아질산칼슘 방청제를 사용한 시멘트 경화체 내의 염소이온 거동 특성)

  • Min-Cheol Shin;Ki-Yong Ann
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.12 no.2
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    • pp.206-213
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    • 2024
  • The present study concerns the inhibition of Calcium Nitrite Inhibitor(Ca(NO2)2) in mortar contaminated by chloride ions. Thus, the corrosion resistance and chloride transport were measured for the mortar containing calcium nitrite inhibitor. As a result, an increase in the dosage of calcium nitrite inhibitor resulted in an increase in the chloride threshold concentration for reinforcement corrosion, while the rate of chloride transport was accelerated. However, the calcium nitrite inhibitor could not guarantee the time to corrosion, due to the increased mobility of chlorides. To ensure the passivity of steel, the dosage of calcium nitrite inhibitor must exceed a certain dosage, ranging from 2.0~3.0 % by cement weight.

Evaluation of Performance on Repair Materials for Creek Concrete Structures (콘크리트 복개구조물용 보수재료의 성능 평가)

  • Lee, Chang-Soo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.6 no.1
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    • pp.205-212
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    • 2002
  • The deterioration rate of concrete structures in urban area is accelerated due to rapid urbanization and environmental pollution. Repair materials and methods newly introduced in Korea should be investigated whether they are appropriate for the urban environment in Korea. The creek concrete structures are exposed in severe environmental condition than others. Based on these background in mind, the study is focused on evaluation of performance on repair materials used to rehabilitate creek concrete structures. To evaluate the performance of repair materials, four kinds of repair materials were selected based on polymer emulsion. This experimental study was conducted on fundamental performance such as setting time, compressive strength, bending strength, bonding strength, thermal expansion coefficient, and durability performance such as chloride diffusion, carbonation, chemical attack, and steel corrosion rate. On the basis of this study, the optimal repair material which is proper to the environment condition can be selected and service life of creek concrete structures can be extended. As a result, the life cycle cost can be reduced and the waste of material resources will be cut down.

The Evaluation of Durability Performance in Mortar Curbs Containing Activated Hwangtoh (활성 황토를 혼입한 모르타르 기반 경계석의 내구성능 평가)

  • Kwon, Seung-Jun;Kim, Hyeok-Jung;Yoon, Yong-Sik
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.4
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    • pp.520-527
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    • 2020
  • Hwangtoh is the rich resource that accounts for about 15.0% of the domestic soil, and can be used as the admixture of concrete with Pozzolan characteristics if activated by rapidly freezing after burning with high temperature. In this study, the mortar curbs containing active hwangtoh were produced, based on the mixture for the mortar curbs sold on the market. The substitution rate of active hwangtoh were considered 10.0% and 25.0%, and the test items were selected to compressive and flexural strength tests, freezing/thawing resistance tests, accelerated carbonation tests, and accelerated chloride diffusion tests. In the results of the mechanical performance, it was showed that the highest strength was evaluated in OPC mixture, and the increase in strength was small by the increase of age, which was believed to be due to the fact that most of the strength in each mixture was created in three days of steam curing. The results of the freezing/thawing tests for 28 aged days showed the reduction rate of compressive strength was 85.0% or higher for all specimen, meeting the criteria presented. The accelerated carbonation tests were carried out on the specimen at 28 days of age, and the results showed that the mortar with active hwangtoh had lower carbonation resistance performance than mortar with OPC. The passed charge of each mixture was assessed in accordance with ASTM C 1202 on 28 and 91 aged days. The OPC mixture had "Low" rate and the mortar with active hwangtoh had "Moderate" rate. So it was thought that the mortar with active hwangtoh had appropriate resistance performance for chloride attack.

Evaluation of Durability Characteristics of High Performance Shotcrete Using Fly Ash (폐석탄회를 이용한 고성능 숏크리트의 내구특성 평가)

  • Park, Cheol-Woo;Lee, Hyeon-Gi;Kang, Tae-Sung
    • Journal of the Korea Concrete Institute
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    • v.22 no.3
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    • pp.305-311
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    • 2010
  • The industrial by-product market has increased at a geometric rate worldwide with the rapid economic growth. At present time, conventional disposal methods of industrial by-products in Korea including landfill, incineration and storage already have reached their limits. In this study, the industrial by-products such as fly ash and silicafume were used as mineral admixtures, which are commonly added to concrete mix to inhance the economic efficiency, long-term strength and durability of concrete, to determine the optimized mix proportion of high performance shotcrete. Through the series of tests (compressive strength test, accelerated chloride ion penetration test, measurement of chloride diffusion coefficient). The results of the study showed that the proposed mix proportions satisfied the requirements of domestic as well as international guidelines for shotcrete, with a higher durability than the existing shotcrete.