• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2020년도 봄 학술논문 발표대회
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• pp.71-72
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• 2020

γ-dicalcium silicate (γ-C2S) is characterized by its strong carbonation reactivity and has the prospect to be utilized as a building material with the added benefit of CO2 capture. This paper aims to point out the impact of γ-C2S on the microstructure characteristics and mechanical properties of GGBFS paste, and mortar samples. Three curing conditions including un-carbonation, natural carbonation, and accelerated carbonation were applied to the research. Besides, hydration products after the carbonation process are also detected. What's more, the carbonation treatment method also meets the requirement of capture more greenhouse gas and recycles the waste products of metallurgy.

• Corrosion Science and Technology
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• 제6권4호
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• pp.186-192
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• 2007

Carbonation is one of the most important factors causing the corrosion of reinforcement concrete. Nevertheless, experimental studies on the concrete carbonation have not been carried out sufficiently because of the slow process of carbonation process. Therefore, this study adopts an experimental system exploiting a vacuum instrument that has been recently developed to accelerate carbonation instead of existing experimental system to conduct rapid carbonation tests on Portland cement and fly-ash cement concretes. Test results revealed that, compared to water-cement ratio of 40%, the carbonation depth increases from 103% to 138% for an increase of water-cement ratio from 45% to 60%. These results are larger than the carbonation depths obtained by mathematical model, and such difference is increasing with larger water-cement ratios. The results also indicated that larger fly-ash contents lead to sharp increase of the carbonation depth, which is in agreement with previous experimental researches. The adoption of the new accelerated carbonation test system enabled to shorten effectively the time required to produce experimental data compared to the existing carbonation test method. The experimental data obtained in this study together with ongoing acquisition of data using the new carbonation test method are expected to contribute in the understanding of the carbonation process of concrete structures in Korea.

• 한국구조물진단유지관리공학회 논문집
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• 제25권5호
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• pp.165-172
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• 2021

이 연구는 건설재료로 활용 가능성이 높은 다양한 무기계 재료의 탄소포집에 대한 성능 평가를 목적으로 한다. 이러한 목적을 위해 광물탄산화가 가능한 보통포틀랜드 시멘트(OPC), 고로슬래그 미분말(GGBS), 순환유동층 보일러 애시(CFBC)의 탄산화 반응에 대한 특성 변화를 분석하였다. 촉진 탄산화 실험을 통해 모든 재료에 대한 탄산화 양생을 수행하였으며, 탄산화 재령에 따라 열중량 분석에 의해 탄소포집량을 정량분석하였다. 모든 재료에서 탄소포집 효과가 확인되었고, 실험결과 탄소포집량은 CFBC, OPC, GGBS 순으로 나타났다. CFBC, OPC, GGBS의 28일 탄소포집량은 각각 9.4 wt.%, 3.9 wt.%, wt.1.3 %이다. 탄소포집은 탄산화 초기에 빠르게 발생하였으며, 재령이 증가함에 따라 느리게 발생하였다. SEM 이미지 분석을 통해, 모든 실험체에서 탄산화 양생에 의해 발생된 추가적인 생성물은 탄산칼슘(CaCO₃)으로 나타났다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2004년도 학술.기술논문발표회
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• pp.41-44
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• 2004

Recently, in the case of domestic, for all that the deterioration environment about the carbonation of reinforced concrete structures is accelerated, systematic diagnosis and researches are not completed. And the selection techniques of repair material and method used under the situation that the indicator and the performance evaluation method are nor established are dependant on existing experience. Therefore, the purpose of this study is intend to present fundamental data for the reasonable selection of repair material and method. durability design and longevity on the deteriorated reinforced concrete structures, through computing the carbonation depth and velocity coefficient by accelerating carbonation test under various accelerating conditions and investigating the application of carbonation evaluation method. The results of this study are as follow; The resistances to carbonation are increased when the W/C ratio if lower and the treatment of surface coating is executed. And the carbonation depth and velocity coefficient according to accelerating carbonation test conditions are increased when the conditions of temperature, relative humidity and $CO_2$density are higher individually.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 봄 학술발표회 논문집
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• pp.175-180
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• 2002

Regardless of the carbonation of concrete is one of the importants causes of corrosion of reinforing steel in concrete with the cloride attack and the frost damage, the investigacion about the carbonation of concrete is limited and each investigator experiments under different condition. In this paper, the effect of temperature, relative humidity, concentration of $CO_2$, type of specimen, etc., were investigated according to the accelerated carbonation test. The principal conclusions from this research were as follows: 1) The carbonation of concrete is higher in olden of, under environmental condition(temperature-relative humidity, concentration of $CO_2$, ) of 40-40-10＞40-50-10＞40-60-5＞20-60-5. 2) Under same environmental condition, the carbonation of concrete in $\Phi$10$\times$20cm cylinder specimen is 2-8% higher then 10$\times$10$\times$40cm specimen.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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• pp.185-188
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• 2006

During the carbonation process in concrete, the rate of carbonation depends on porosity and moisture content of the concrete. For underground reinforced concrete structures, the interior concrete surface may be exposed to carbonation and the exterior concrete surface exposed to moisture due to wet soil or underground water. In this study, the permeability coefficients in mortar partially carbonated is derived as a function of carbonation depth and porosity of mortar by applying the so-called micro pore structure formation model (MPSFM) which was developed for the modeling of early-aged concrete. The permeability coefficient obtained from the micro-level modeling of carbonated mortar is verified with the results of accelerated carbonation test and water penetration test in cement mortar.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2005년도 봄학술 발표회 논문집(II)
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• pp.193-196
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• 2005

In this study, the purpose is to suggest the data on mixing ratio which effects on the carbonation of concrete by replacing various admixture such as silica fume, fly ash, slag powder. Thus, we have experimented the accelerated test on the carbonation related to hardened body of the concrete which was admixed by slag powder, silica fume, fly ash and it was cured for 4 weeks in carbonation accelerator after 28 days curing water. The result of this experiment showed that carbonation speed increased highly when admixtures be used to replacing by growing of admixture ratio. especially, the test sample which was replaced with silica fume 15$\%$ and slag powder 40$\%$, was promoted highly to carbonation.

• 한국산업융합학회 논문집
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• 제23권6_2호
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• pp.1111-1117
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• 2020

In this study, the carbonation characteristics of concrete according to the mixture of OLED waste glass were evaluated. Replacement capacities of OLED waste glass were 0%, 10%, 20%, and 30% of cement, and they were named OG 0, OG 10, OG 20, and OG 30. As a result of the compressive strength test, OG 0 without replacing OLED waste glass showed high intensity until the 14th. However, the higher the replacement rate of OLED waste glass, the higher the compressive strength of 28 days. In addition, the speed of carbonation was faster with the higher the replacement rate of OLED waste glass, and the accelerated carbonation experiment was about three times faster than the natural carbonation test. In conclusion, the carbonation characteristics of OLED concrete are expected to be positive in terms of atmospheric CO2 absorption.

• 에너지공학
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• 제26권4호
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• pp.74-83
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• 2017

Coal-fired power plants supply roughly 50 percent of the nation's electricity but produce a disproportionate share of electric utility-related air pollution. Coal combustion technology can facilitate volume reduction of up to 90%, with the inorganic contaminants being captured in furnace bottom ash and fly ash residues. These disposal coal ash residues are however governed by the potential release of constituent contaminants into the environment. Accelerated carbonation process has been shown to have a potential for improving the chemical stability and leaching behavior of bottom ash residues. The aim of this work was to quantify the volume of $CO_2$ that could be sequestrated with a view to reducing greenhouse gas emissions and stabilize the contaminated heavy metals from bottom ash samples. In this study, we used PC boiler bottom ash, Kanvera reactor (KR) slag and calcined waste lime for measuring chemical analysis and heavy metals leaching tests were performed and also the formation of calcite resulting from accelerated carbonation process was investigated by thermo gravimetric and differential thermal analysis (TG/DTA).

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2000년도 가을 학술발표회논문집(I)
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• pp.403-408
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• 2000

Hardened concrete contains pores of varying types and sizes, and therefore the transport of air through concrete can be considered. The rate of permeability will not only depend on the continuity of pores, but also on the moisture contents in concrete. In this paper, the effects of curing conditions and moisture content ratios on the carbonation and air permeability are investigated according to the accelerated carbonation test. The results are follows. 1) Compressive strength, carbonation velocity and air permeability are influenced by the moisture content and curing method. 2) The relationship between carbonation velocity coefficient and air permeability coefficient has been quite well established.