• Proceedings of the Korea Concrete Institute Conference
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• 2004.11a
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• pp.793-796
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• 2004

In domestic, various repair materials and method systems to keep up with these reinforced concrete deteriorated due to salt damage, carbonation. chemical decay et. being developed and applied. However, present polymer cement mortar applied to section restoration system cause the problem of long-term working and economica] efficiency. because that is divided into two process of liquid corrosion prevention agent and polymer cement mortar. In this background, accelerated test with due regard to $3\%$ NaCl soaking and autoclave cure was performed to confirm steel bar corrosion prevention properties of polymer cement mortar mixed with corrosion prevention agent of powdered type. In conclusion. we confirmed application possibility and excellency of steel bar corrosion prevention properties of polymer cement mortar mixed with corrosion prevention agent of powdered type comparing general polymer cement mortar applied to section restoration system of present study.

• Economic and Environmental Geology
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• v.55 no.4
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• pp.377-388
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• 2022

Laboratory-scale experiments were performed to identify the As removal mechanism of the residual slag generated after the mineral carbonation process. The residual slags were manufactured from the steelmaking slag (blast oxygen furnace slag: BOF) through direct and indirect carbonation process. RDBOF (residual BOF after the direct carbonation) and RIBOF (residual BOF after the indirect carbonation) showed different physicochemical-structural characteristics compared with raw BOF such as chemical-mineralogical properties, the pH level of leachate and forming micropores on the surface of the slag. In batch experiment, 0.1 g of residual slag was added to 10 mL of As-solution (initial concentration: 203.6 mg/L) titrated at various pH levels. The RDBOF showed 99.3% of As removal efficiency at initial pH 1, while it sharply decreased with the increase of initial pH. As the initial pH of solution decreased, the dissolution of carbonate minerals covering the surface was accelerated, increasing the exposed area of Fe-oxide and promoting the adsorption of As-oxyanions on the RDBOF surface. Whereas, the As removal efficiency of RIBOF increased with the increase of initial pH levels, and it reached up to 70% at initial pH 10. Considering the PZC (point of zero charge) of the RIBOF (pH 4.5), it was hardly expected that the electrical adsorption of As-oxyanion on surface of the RIBOF at initial pH of 4-10. Nevertheless it was observed that As-oxyanion was linked to the Fe-oxide on the RIBOF surface by the cation bridge effect of divalent cations such as Ca²⁺, Mn²⁺, and Fe²⁺. The surface of RIBOF became stronger negatively charged, the cation bridge effect was more strictly enforced, and more As can be fixed on the RIBOF surface. However, the Ca-products start to precipitate on the surface at pH 10-11 or higher and they even prevent the surface adsorption of As-oxyanion by Fe-oxide. The TCLP test was performed to evaluate the stability of As fixed on the surface of the residual slag after the batch experiment. Results supported that RDBOF and RIBOF firmly fixed As over the wide pH levels, by considering their As desorption rate of less than 2%. From the results of this study, it was proved that both residual slags can be used as an eco-friendly and low-cost As remover with high As removal efficiency and high stability and they also overcome the pH increase in solution, which is the disadvantage of existing steelmaking slag as an As remover.

• Journal of the Korea Concrete Institute
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• v.17 no.3 s.87
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• pp.385-392
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• 2005

The object of this study is to prove the quality and reliability of recycled aggregate concrete by finding a way to improve the durability of the material through the experiment on the accelerated carbonation, freezing and thaw, and drying shrinkage, analysing the influence on the durability to Promote more active use of recycled aggregate concrete. The result of study as follows. (1) Resistibility to the freeze and thaw of the recycled aggregate concrete showed relative dynamic modulus of elasticity over $90\%$ which is very good, and all cycles show $99.2{\~}91.0\%$ dynamic modulus of elasticity which is improved compared with the $97.5{\~}90.6\%$ relative dynamic modulus of elasticity of ordinary concrete made of broken stone. (2) Carbonated thickness of the recycled aggregate concrete and the normal concrete was similar or it appeared with the tendency which it diminishes more or less. (3) Length change rate in drying contraction of the recycled aggregate concrete made of the recycled aggregate was lower than the ordinary concrete made of the broken stone by $18.5{\~}3.9\%$ in all blending.

• Journal of the Korea Concrete Institute
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• v.20 no.6
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• pp.773-784
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• 2008

Even if the exploitation of copper slag produced during the smelting process of copper as aggregate for construction purpose has been permitted since 2004 in Korea, the lack of sufficient data enabling to evaluate its long-term stability that is its durability has to date impeded its application. This study intends to investigate experimentally the durability characteristics of 18 and 27 MPa-class commercial concretes in which natural sand (fine aggregates) has been partially replaced by copper slag through accelerated and exposure tests so as to provide bases promoting the application of copper slag concrete. The experimental results revealed insignificant difference of the durability characteristics in most of the mix proportions in which 30% of natural sand was replaced by copper slag. In the case where crushed sand was adopted, tests verified similar characteristics for replacement ratio of 50%. Particularly, the results of the exposure test conducted during 8 years demonstrated that equivalent level of durability was secured compared to the case using natural sand. In the case of 18MPa-class lower grade concrete, exposure test verified also that the physical lifetime similar to 50 years could be secured until carbonation reaches cover depth of 20 mm.

• Journal of the Korea Concrete Institute
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• v.29 no.3
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• pp.299-306
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• 2017

In this research, it was examined chloride ion penetration resistance of slag-replaced concrete and cementless slag concrete considering marine environmental exposure conditions of splash zone, tidal zone and immersion zone. In the design strength of grade 24 MPa, the specimens were tested to determine their compressive strength, scanning electron microscopy images and chloride migration coefficient. Further, chloride ion penetration depth and carbonation depth of specimens exposed to marine environment were measured. Experimental results confirm that chloride migration coefficient of specimens tended to decrease with increasing the replacement ratio of ground granulated blast-furnace slag in accelerated laboratory test. In addition, the specimens exposed to the tidal zone were found to be the greatest chloride ion penetration depth compared to splash zone and immersion zone. On the other hand, the chloride ion penetration depth of the specimens exposed to splash zone tended to increase with increasing the replacement ratio of ground granulated blast-furnace slag in contrast with the results for the tidal zone and immersion zone.

• Journal of the Korea Concrete Institute
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• v.23 no.3
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• pp.311-320
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• 2011

Fly ash (FA), byproduct from power plant has been actively used as mineral admixture for concrete. However, since bottom ash (BA) is usually used for land reclaim or subbase material, more active reuse plan is needed. Pond ash (PA) obtained from reclaimed land is mixed with both FA and BA. In this study, 6 PA from different domestic power plant are prepared and 5 different replacement ratios (10%, 20%, 30%, 50%, and 70%) for fine aggregate substitutes are considered to evaluate engineering properties of PA as fine aggregate and durability performance of PA concrete. Tests for fine aggregate of PA for fineness modulus, density and absorption, soundness, chloride and toxicity content, and alkali aggregate reaction are performed. For PA concrete, durability tests for compressive strength, drying shrinkage, chloride penetration/diffusion, accelerated carbonation, and freezing/thawing are performed. Also, basic tests for fresh concrete like slump and air content are performed. Although PA has lower density and higher absorption, its potential as a replacement material for fine aggregate is promising. PA concrete shows a reasonable durability performance with higher strength with higher replacement ratio. Finally, best PA among 6 samples is selected through quantitative classification, and limitation of PA concrete application is understood based on the test results. Various tests for engineering properties of PA and PA concrete are discussed in this paper to evaluate its application to concrete structure.

• Journal of the Korea institute for structural maintenance and inspection
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• v.28 no.1
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• pp.12-23
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• 2024

In this study, a structural concrete square beam was developed using the centrifugal molding technique. In order to secure the bending stiffness of the cross section, the hollow rate of the cross section was set to 10% or less. Instead of using the current poor mixture of concrete and a concrete mixing ratio with a high slump (150-200) and a design strength of 100 MPa or more was developed and applied. In order to investigate the durability of centrifugally formed PSC square beams to be used as the superstructure of the avalanch tunnel or ramen bridge, the durability performance of ultra-high-strength centrifugally formed concrete with a compressive strength of 100 MPa was evaluated in terms of deterioration and chemical resistance properties.Concrete durability tests, including chloride penetration resistance, accelerated carbonation, sulfate erosion resistance, freeze-thaw resistance, and scaling resistance, were performed on centrifugally formed square beam test specimens produced in 2022 and 2023. Considering the information verified in this study, the durability of centrifugally molded concrete, which has increased watertightness in the later manufacturing stage, was found to be superior to that of general concrete.