• Title/Summary/Keyword: Absorption phenomena

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An investigation of absorption phenomena in the horizontal staggered tube absorber for various LiBr solution flow rates (LiBr용액량 변화에 따른 수평다관 흡수기의 특성 연구)

  • Kwon, Yul;Yoon, Sang-Guk
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.11 no.3
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    • pp.332-338
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    • 1999
  • An experimental study of absorption phenomena of water vapor into LiBr solution was carried out to find out the optimum solution flow rate. The staggered bundle of horizontal absorption tubes, which are the same configuration as the commercial heat pump, were tested. The results showed that the heat transfer and absorption rate were enhanced with the increase of LiBr solution flow rate. Those values for different absorber pressures showed the same qualitative trends. The optimum flow rate of solution was obtained as three times of the designed flow rate.

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A Review of Heat and Mass Transfer Analysis for Absorption Process

  • Kim, Jin-Kyeong;Kang, Yong-Tae
    • International Journal of Air-Conditioning and Refrigeration
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    • v.14 no.4
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    • pp.131-137
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    • 2006
  • The absorber in which heat and mass transfer phenomena occur simultaneously is one of the most critical components in the absorption system. It has the most significant influence on the performance and the size of the absorption system. During the absorption process, heat and mass transfer resistances exist in both liquid and vapor regions, so that the heat transfer mode should be carefully selected to reduce them. The objective of this paper is to review the previous papers analysing mathematical models of simultaneous heat and mass transfer phenomena during the absorption process. The most conventional working fluids ($H_2O$LiBr and $NH_3/H_2O$) are considered and the most common absorption modes (falling film and bubble mode) are dealt with in this review.

Numerical Study of Hydrogen Absorption in a Metal Hydride Hydrogen Storage Vessel (금속수소화물 수소 저장 용기 내부의 수소흡장에 대한 수치해석적 연구)

  • Nam, Jin-Moo;Kang, Kyung-Mun;Ju, Hyun-Chul
    • Journal of Hydrogen and New Energy
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    • v.21 no.4
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    • pp.249-257
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    • 2010
  • In this paper, a three-dimensional hydrogen absorption model is developed to precisely study hydrogen absorption reaction and resultant heat and mass transport phenomena in metal hydride hydrogen storage vessels. The 3D model is first experimentally validated against the temperature evolution data available in the literature. In addition to model validation, the detailed simulation results shows that at the initial absorption stage, the vessel temperature and H/M ratio distributions are uniform throughout the entire vessel, indicating that the hydrogen absorption is so efficient during the early hydriding process and thus local cooling effect is not influential. On the other hand, nonuniform distributions are predicted at the latter absorption stage, which is mainly due to different degrees of cooling between the vessel wall and core regions. This numerical study provides the fundamental understanding of detailed heat and mass transfer phenomena during hydrogen absorption process and further indicates that efficient design of storage vessel and cooling system is critical to achieve fast hydrogen charging and high hydrogen storage efficiency.

A Study on the Reversibility Scalar Phenomena in Amorphous Chalcogenides (비정질 칼코게나이드에서 광유기 스칼라 현상의 가역성에 관한 연구)

  • 박수호;정진만;이현용;정홍배
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.04a
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    • pp.31-34
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    • 1997
  • A reversible scalar phenomena in amorphous As$_{40}$ Ge$_{10}$ Se$_{15}$ S$_{35}$ have been investigated by blue-pass-filtered Hg lamp and He-Ne laser. Annealing causes the shift of the absorption edge to shelter wavelengths approximately 0.17ev, also illumination moves it to longer wavelengths about 0.05 ~ 0.07eV and it increases the refractive index maximum 0.3. Therefore the thermalbleaching(TB) and photodarkening(PD) effects have been understood by the results related to optical absorption characteristics. TB could be estimated as increasing the stabilization of amorphous chalcogenide films since absorption slope of extended regions(U) was not changed by annealing. On the other hand, PD could be understood as due to the enhancement of disorder since the slope of Urbach’s tail(1/F) around an absorption edge were decreased by illumination.ion.n.

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Numerical analysis of the coupled heat and mass transfer phenomena in a metal hydride hydrogen storage reactor(I) - Model development of analyzation for hydrogen absorption reaction using the $LaNi_5$ bed (금속수소화물 수소저장 용기 내부의 열 및 물질전달 현상에 대한 수치적 연구(I) - $LaNi_5$ 베드를 이용한 수소 흡장반응 해석 모델 개발)

  • Nam, Jinmoo;Ju, Hyunchul
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.225.1-225.1
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    • 2010
  • Within recent years attention has been focused on the method of hydrogen storage using metal hydride reactor due to its high energy density, durability, safety and low operating pressure. In this paper, a numerical study is carried out to investigate the coupled heat and mass transfer process for absorption in a cylindrical metal hydride hydrogen storage reactor using a newly developed model. The simulation results demonstrate the evolution of temperature, equilibrium pressure, H/M atomic ratio and velocity distribution as time goes by. Initially, hydrogen is absorbed earlier from near the wall which sets the cooling boundary condition owing to that absorption process is exothermic reaction. Temperature increases rapidly in entire region at the beginning stage due to the initial low temperature and enough metal surface for hydrogen absorption. As time goes by, temperature decreases slowly from the wall region due to the better heat removal. Equilibrium pressure distribution appears similarly with temperature distribution for reasons of the function of temperature. This work provides a detailed insight into the mechanism and corresponding physicochemical phenomena in the reactor during the hydrogen absorption process.

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Effect of Moisture Absorption on Dielectric Breakdown Phenomena of DGEBA/MDA/SN/Natural Zeolite System (DGEBA/MDA/SN/천연 제올라이트계의 절연파괴현상에 미쳐는 흡습의 영향)

  • Kim, You-Jeong;Lee, Hong-Ki;Kim, Sang-Wook
    • Proceedings of the KIEE Conference
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    • 1999.11d
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    • pp.994-996
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    • 1999
  • Hygrothermal aging at the elevated temperature induces the long-term degradation of the epoxy resin. We investigated the effects of hydrothermal stress on the dielectric breakdown phenomena of epoxy composite filled with natural zeolite. The cured specimens absorbed the moisture in the autoclave at $120^{\circ}C$. $T_g$ of the deteriorated composite by moisture absorption decreased. The dielectric breakdown strength decreased with the moisture absorption cycle. It was concluded that the thermal stress and the high water-vapour-pressure deteriorated the natural zeolite filled epoxy resin system, consequently and the tree growth rate increased.

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Nonuniformity of Energy Absorption Capabilities of ZnO Varistors

  • He, Jin-Liang;Han, Se-Won;Cho, Han-Goo;Kang, Hyung-Boo
    • The Korean Journal of Ceramics
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    • v.4 no.1
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    • pp.47-52
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    • 1998
  • The nonuniformity of energy absorption capability of ZnO varistor is systematically discussed in this paper. The nonuniformity of electrical characteristics and microstructure leads to decrease the energy absorption capability of ZnO varistor. The energy absorption capabilities were measured under different current waves, the experimental results stated that they have highly scattered phenomena. The influences of varistor surface area and nonuniformity of electrical characteristics to the energy absorption capability and the nonuniformity of commercial ZnO varistors were analyzed. There is a high nonuniformity existing in the energy absorption capability of commercial ZnO varistors.

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Visualization of Marangoni Convection Behavior between Two Surfactant Dropwises in the Process of Steam Absorption (증기흡수시(蒸氣吸收時) 계면활성제액적간(界面活性劑液滴間)에 발생(發生)하는 마랑고니대류거동(對流擧動)의 가시화(可視化))

  • Rie, D.H.;Choi, K.K.;Kashiwagi, T.;Seo, J.Y.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.4 no.2
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    • pp.65-71
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    • 1992
  • In most absorption machines, absorption enhancement has been achieved by adding small amount of surfactant additive, which introduced the surface tension difference between absorbent and surfactant droplets in the vapor absorption. The aim of this study is to understand a basic mechanism of Marangoni convection and its effectiveness in the vapor absorption enhancement. In this study, nonflowing aqueous solution of LiBr 60 mass% was exposed to saturated water vapor under the condition that two dropwises surfactant were fixed on the absorbent surface. Our experiments achieved to visualize the enhanced heat and mass transfer phenomena by the effect of Marangoni convection through the laser holographic interferometry. Also, Marangoni convection behavior was obtained by using tracer method.

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Polyamic Acid Alkylamine Salts(PAAS) (Langmuir-Blodgett(LB) Films의 광학적 및 전기적 특성)

  • 이승엽;강도열;김태완
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.04a
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    • pp.277-280
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    • 1997
  • It is important to investigate the molecular arrangement and the orientational distribution in the study of LB films. Polarized UV/visible absorption spectra make it possible to reveal the molecular arrangement and the orientational distribution. It is clarified that the PAAS LB films have specific directions in the molecular arrangement and the orientational distribution, which art different in intensity corresponding to the surface pressure. Unpolarized UV/visible absorption spectra reveal that the surface pressure is proportional to the finn thickness and is related to the molecular orientation. Current-Voltage(I-V) measurements provide that the current decreases as the surface pressure increases and there are certain phenomena called switching phenomena. Switching effort indicates that the current flows in high conductivity during on-state and suddenly decreases into low conductivity during off-state.

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Electromagnetically-Induced-Absorption in Multiple-V type Atomic Systems (다중-V 타입 원자계에서의 전자기 유도 흡수)

  • Park, Jong-Dae;Cho, Chang-Ho;Lee, Chul-Se
    • The Journal of Natural Sciences
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    • v.12 no.1
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    • pp.41-48
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    • 2002
  • Atomic coherences can be induced via atom-light interaction and can exhibit new interesting phenomena. Electromagnetically-induced-absorption (EIA) is one of such phenomena where the absorption of probe beam is increased due to the presence of strong coupling beam. EIA can be observed in multiple-V type atomic systems. This paper present a method to study EIA when the frequencies of probe beam and coupling beam are both near resonant to the same transition line. Time-varying interaction Hamiltonian was introduced and density matrix equations were solved and the amplitude of oscillations was used to calculate the EIA.

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