• Journal of the Korean GEO-environmental Society
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• v.24 no.6
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• pp.13-20
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• 2023

This paper is aimed to evaluate the mechanical properties and durability of high-flowable retaining wall material (RWM) with different levels of steel fiber (SF) content. To produce the specimens of RWM, some chemical agents such as superplasticizer (SP), air-entrained agent (AEA) and viscosity modifying agent (VMA) were added in the fresh RWM. The compressive and split tensile strength measurements were performed on the hardened RWM specimens at the predetermined periods. Additionally, surface electric resistivity and absorption tests according to ASTM standards were carried out to examine mechanical properties of RWM mixes. The durable performances such as chloride ions penetrability and freezing-thawing resistance of RWM mixes were experimentally investigated. As resutls, it was found that the performance of RWM mix with SF were much better than that without SF, especially at the 2% addition of SF. Thus, it is noted that the proper addition of SF in the RWM mix may have a beneficial effect to improve mechanical properties and durability of RWM mixes.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.4
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• pp.299-306
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• 2023

Environmental pollution problems are occurring due to the negative treatment of basalt waste in Jeju Island. This study identifies the characteristics of permeable block with basalt with physical and chemical adsorption mechanisms and examines their applicability and functionality as building materials. This experiment is basic data for evaluating the functionality of the permeable block by analyzing flexural strength, compressive strength, permeability coefficient, carbon dioxide, and fine dust adsorption rate by producing a permeable block using a basalt waste rock. As the basalt waste stone replacement rate increased, the flexural strength and compressive strength tended to decrease, and as the replacement rate increased, the water permeability coefficient, absorption rate, carbon dioxide, and fine dust adsorption rate tended to increase. Therefore, it is judged that the permeable block using the basalt waste rock is superior to the existing permeable block.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.4
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• pp.501-508
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• 2023

Addressing urban noise problems, this study develops eco-friendly, inorganic sound-absorbing panels, overcoming the limitations of traditional PMMA and cement-based panels. These conventional panels pose safety risks due to flammability and environmental concerns due to carbon emissions. Utilizing industrial waste, the research comprises two phases: initial tests for physical and performance characteristics (fluidity, density, compressive strength, sound absorption) and subsequent development of optimized panel mixtures. This approach aims to replace existing panels with sustainable, effective alternatives, significantly contributing to safer, environmentally responsible urban infrastructure. The findings of this study have implications for the sound panel market, offering novel solutions for noise control while aligning with environmental and safety standards.

• Design & Manufacturing
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• v.17 no.3
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• pp.15-20
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• 2023

In the fine blanking process, which is a press operation known for producing parts with narrow clearances and high precision through the application of high pressure, die roll often occurs during the shearing process when the punch penetrates the material. This die roll phenomenon can significantly reduce the functional surface of the parts, leading to decreased product performance, strength, and fatigue life. In this research, we conducted an in-depth analysis of the factors influencing die roll in the curvature area of the fine blanking process and identified its root causes. Subsequently, we designed and experimentally verified a die roll reduction process specifically tailored for the door latch manufacturing process. Our findings indicate that die roll tends to increase as the curvature radius decreases, primarily due to the heightened bending moment resulting from reduced shape width-length. Additionally, die roll is triggered by the absorption of initial punch energy by scrap material during the early shearing phase, resulting in lower speed compared to the product area. To mitigate the occurrence of die roll, we strategically selected the Shaving process and carefully determined the shaving direction and clearance area length. Our experiments demonstrated a promising trend of up to 75% reduction in die roll when applying the Shaving process in the opposite direction of pre-cutting, with the minimum die roll observed at a clearance area length of 0.2 mm. Furthermore, we successfully implemented this approach in the production of door latch products, confirming a significant reduction in die roll. This research contributes valuable insights and practical solutions for addressing die roll issues in fine blanking processes.

• Journal of Korean Society of Disaster and Security
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• v.17 no.1
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• pp.27-35
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• 2024

This paper presents experimental research results to evaluate the applicability of chemical neutralization reaction and ultrasonic wave to remove cement paste and mortar attached to the surface of recycled aggregate. In order to derive optimal ultrasonic cleaning efficiency and chemical neutralization reaction, experiments were conducted using variables such as ultrasonic frequency and type of chemical solution. As a result, the optimal frequency was found to be 24 kHz, and immersion in a 15% hydrochloric acid solution for 30 minutes of stimulation showed the highest efficiency. In addition, the specific gravity, absorption rate, and wear rate of the quality-improved recycled coarse aggregate were similar to those of general aggregate and were found to satisfy all KS F 2527 standards. Therefore, it is believed that the recycled aggregate whose quality has been improved through the method proposed in this study can be used for concrete.

• Journal of the Korea institute for structural maintenance and inspection
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• v.19 no.5
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• pp.104-111
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• 2015

This study shows the mechanical properties of alkali-activated slag cement (AASC) synthesized using sulfate with NaOH solution. The used sulfates were calcium sulfate ($CaSO_4$, denoted CS) and sodium sulfate ($Na_2SO_4$, denoted SS). The replacement ratio of sulfates was 2.5, 5.0, 7.5 and 10.0% by weight of slag. NaOH solution of 2M and 4M concentration was used. A sample was activated with sulfate and activated with blended activator (blending NaOH solution with sulfate) respectively. 24 mix ratios were used and the water-binder weight ratio for the test was set 0.5. This research carried out the compressive strength, flexural strength, ultrasonic pulse velocity (UPV), absorption and X-ray diffraction (XRD). In the case of samples with CS, sample with 7.5% CS, sample with 2M NaOH+5.0% CS and sample with 4M NaOH+5.0% CS showed the good performance in the strength development. In the case of samples with SS, sample with 10.0% SS, sample with 2M NaOH+7.5% SS and sample with 4M NaOH+2.5% SS obtained good performance in strength. The results of UPV and water absorption showed a similar tendency to the strength properties. The XRD analysis of samples indicated that the hydration products formed in samples were ettringite, CSH and silicate phases. In this study, it is indicated that when compared to the use of sulfate only, the use of both sulfate and NaOH solution makes mechanical properties of AASC better.

• The Journal of Engineering Geology
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• v.33 no.1
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• pp.169-187
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• 2023

Aggregates from 84 cities and counties in Korea were tested for quality to allow analysis of the physical characteristics of aggregates from river, land, and forest environments. River and land aggregates were analyzed for 18 test items, and forest aggregates for 12 test items. They were classified according to watershed and geology, respectively. The observed physical characteristics of the river aggregates by basin were as follows: aggregates from the Geum River basin passed through 2.5, 1.2, 0.6, 0.3, 0.15, and 0.08 mm sieves; clay lumps constituted the Nakdong River basin material; aggregates from the Seomjin River basin passed through 10, 5, and 2.5 mm sieves; those from the Youngsang River basin passed through 1.2, 0.6, 0.3, 0.15, and 0.08 mm sieves; and aggregates from the Han River basin passed through 10, 5, 2.5, 1.2, 0.6, 0.3, and 0.08 mm sieves, Stability; Standard errors were analyzed for the average amount passing through 10, 0.6, and 0.08 mm silver sieves, and performance rate showed different distribution patterns from other physical characteristics. Analysis of variance found that 16 of the 18 items, excluding the absorption rate and the performance rate, had statistically significant differences in their averages by region. Considering land aggregates by basin, those from the Nakdong River basin excluding the Geum River basin had clay lumps, those from the Seomjin River basin had 10 and 5 mm sieve passage, aggregates from the Youngsang River basin had 0.08 mm sieve passage, and those from the Han River basin had 10, 0.6, and 0.08 mm sieve passage. The standard error of the mean of the quantity showed a different distribution pattern from the other physical characteristics. Analysis of variance found a statistically significant difference in the average of all 18 items by region. Analyzing forest aggregates by geology showed distributions of porosity patterns different from those of other physical characteristics in metamorphic rocks (but not igneous rocks), and distributions of wear rate and porosity were different from those of sedimentary rocks. There were statistically significant differences in the average volume mass, water absorption rate, wear rate, and Sc/Rc items by lipid.

• Korean Chemical Engineering Research
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• v.51 no.2
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• pp.240-244
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• 2013

Although forward osmosis desalination technology has drawn substantial attention as a next-generation desalination method, the energy efficiency of its draw solution treatment process should be improved for its commercialization. When ammonium bicarbonate is used as the draw solute, the system consists of forward-osmosis membrane modules, draw solution separation and recovery processes. Mixed gases of ammonia and carbon dioxide generated during the draws solution separation, need to be recovered to re-concentrate ammonium bicarbonate solution, for continuous operation as well as for the economic feasibility. The diluted ammonium bicarbonate solution has been proposed as the absorbent for the draw solution regeneration. In this study, experiments are conducted to investigate performance and features of the absorption corresponding to absorbent concentration. It is concluded that ammonium bicarbonate solution can be used to recover the generated ammonia and carbon dioxide. The results will be applied to design and operation of pilot-scale forward-osmosis desalination system.

• Journal of Electrochemical Science and Technology
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• v.10 no.4
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• pp.424-432
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• 2019

Planar BiVO₄ and 3 wt% Mo-doped BiVO₄ (abbreviated as Mo:BiVO₄) film were prepared by the facile spin-coating method on fluorine doped SnO₂(FTO) substrate in the same precursor solution including the Mo precursor in Mo:BiVO₄ film. After annealing at a high temperature of 450℃ for 30 min to improve crystallinity, the films exhibited the monoclinic crystalline phase and nanoporous architecture. Both films showed no remarkably discrepancy in crystalline or morphological properties. To investigate the effect of surface passivation exploring the Al₂O₃ layer, the ultra-thin Al₂O₃ layer with a thickness of approximately 2 nm was deposited on BiVO₄ film using the atomic layer deposition (ALD) method. No distinct morphological modification was observed for all prepared BiVO₄ and Mo:BiVO₄ films. Only slightly reduced nanopores were observed. Although both samples showed some reduction of light absorption in the visible wavelength after coating of Al₂O₃ layer, the Al₂O₃ coated BiVO₄ (Al₂O₃/BiVO₄) film exhibited enhanced photoelectrochemical performance in 0.5 M Na₂SO₄ solution (pH 6.5), having higher photocurrent density (0.91 mA/㎠ at 1.23 V vs. reversible hydrogen electrode (RHE), briefly abbreviated as V_RHE) than BiVO₄ film (0.12 mA/㎠ at 1.23 V_RHE). Moreover, Al₂O₃ coating on the Mo:BiVO₄ film exhibited more enhanced photocurrent density (1.5 mA/㎠ at 1.23 V_RHE) than the Mo:BiVO₄ film (0.86 mA/㎠ at 1.23 V_RHE). To examine the reasons, capacitance measurement and Mott-Schottky analysis were conducted, revealing that the significant degradation of capacitance value was observed in both BiVO₄ film and Al₂O₃/Mo:BiVO₄ film, probably due to degraded capacitance by surface passivation. Furthermore, the flat-band potential (V_FB) was negatively shifted to about 200 mV while the electronic conductivities were enhanced by Al₂O₃ coating in both samples, contributing to the advancement of PEC performance by ultra-thin Al₂O₃ layer.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.40 no.4
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• pp.359-364
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• 2014

In this study, we developed a HPLC method for the separation and analysis of methylparaben and p-anisic acid, which are commonly used as a synthetic preservative and natural preservative, respectively. Methylparaben and p-anisic acid have same molecular weight (152.15 g/mol), similar structure and same maximum absorption wavelength (250 nm), thus they showed same retention time (RT) value (13.3 min) in HPLC experiment. We observed that two substances are separated on C18 column after methylparaben was derivatized selectively through the acetylation reaction. Instead, RT of the acetylated methylparaben was moved to 23.9 min from 13.3 min. The average retention time was $23.9{\pm}0.1min$ and peak area values was $5042882{\pm}4778$. In addition it showed a high linearity in the calibration curve with a correlation coefficient (R2) of 0.9999658. Detection and quantitation limits were $1.47{\mu}g/mL$ and $4.44{\mu}g/mL$, respectively. In conclusion, the developed method can be useful for separation and analysis of preservatives with similar structure in cosmetic fields.