• Title/Summary/Keyword: Absorption Spectroscopy

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AKARI near Infrared spectroscopy of luminous infrared galaxies

  • Lee, Jong-Chul;Hwang, Ho-Seong;Lee, Myung-Gyoon
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.1
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    • pp.50.2-50.2
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    • 2012
  • We present the results of near infrared (2.5-5 micron) spectroscopy of nearby luminous infrared galaxies (LIRGs) using AKARI. The LIRG catalog is constructed from the cross-correlation between the Infrared Astronomical Satellite and the Sloan Digital Sky Survey data, and optically non-Seyfert type LIRGs are selected for main targets. We search for optically elusive active galactic nuclei (AGNs), based on the strengths of 3.3 micron polycyclic aromatic hydrocarbon emission and dust absorption features at 3-4 micron. We investigate the hidden AGN fraction as a function of the infrared luminosity and correlation between optical and near infrared star formation indicators.

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Preparation of Highly Visible-Light Photocatalytic Active N-Doped TiO2 Microcuboids

  • Zhao, Kang;Wu, Zhiming;Tang, Rong;Jiang, Yadong
    • Journal of the Korean Chemical Society
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    • v.57 no.4
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    • pp.489-492
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    • 2013
  • N-doped $TiO_2$ microcuboids were successfully prepared by a simple one-pot hydrothermal method. The samples were characterized by X-ray diffraction, scanning electron microscopy, diffuse reflectance spectroscopy, and X-ray photoelectron spectroscopy. It was found that the N-doped $TiO_2$ microcuboids enhanced absorption in the visible light region, and exhibited higher activity for photocatalytic degradation of model dyes. Based on the experimental results, a visible light induced photocatalytic mechanism was proposed for N-doped anatase $TiO_2$ microcuboids.

HIGH RESOLUTION SPECTROSCOPY OF TITAN (타이탄의 고분산 스펙트럼)

  • KIM JOO HYEON;KIM SANG JOON;KIM KANG-MIN;SIM CHAE KYUNG;SON DONG HOON
    • Publications of The Korean Astronomical Society
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    • v.19 no.1
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    • pp.39-46
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    • 2004
  • We have carried out the high-resolution spectroscopic observations of Titan using BOES (Bohyunsan Echelle Spectrometer) to establish a standard spectral atlas of Titan. The observations were made on November 3, 4, 16 and 17, 2003 using a 300 11m fiber optics with a spectral resolving power of 30,000. The spectral atlas will be served as a reference for the future spectroscopic researches of Titan and other planetary objects. We were able to confirm $CH_4$ absorption lines of the Kuiper bands, and find unidentified lines near $7500{\AA}$.

Characteristics of Sewage sludge, Its Incineration Ash, and Sintering Pellet

  • Lee, Ki-Hwan;Lee, Tae-Ho;Cho, Heon-Young;Han, Ki-Suk
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.4 no.4
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    • pp.215-220
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    • 2000
  • This study on the incineration ash and sintering pellet from sewage sludge was carried out to evaluate the possibility of recycling in sewage sludge disposal. The samples used in this experiment were raw sewage sludge, its incineration ash, and sintering pellet. The characteristics of the three sample types were identified using X-ray diffraction(XRD), X-ray fluorescence(XRF), atomic absorption spectroscopy(AAS), and inductively coupled plasma spectroscopy(ICP). The chemical compositions of all three sample types were similar in their clay component, however, the sewage sludge had a high content of organic materials. From an analysis of the mineral content of the three sample types, the conversion of their compositions was found to be relative to temperature. Accordingly, incineration ash and sintering pellet both have potential for use as a functional construction material.

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Ag-modified BiOX (X=Cl, Br and I) Plates for Photocatalytic Dye Removal

  • Lee, Seung-Won;Choe, Yeong-In;Lee, Ju-Heon;Park, Yo-Han;Son, Yeong-Gu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.424.2-424.2
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    • 2014
  • Ag-modified BiOX (X=Cl, Br and I) nanoplates were synthesized by an ion-exchange reaction. We examined the fundamental properties by scanning electron microscopy (SEM), electron transmission microscopy (TEM), X-ray diffraction, UV-visible absorption, Fourier-transform infrared and photoluminescence spectroscopy. The adsorption and photocatalytic performances of the catalysts were tested with dyes under UV and visible light. A chemical scavenger method was employed to test the roles of active species (${\cdot}OH$, ${\cdot}O2-$ and h+) and understand photodegradation mechanism. Photoluminescence spectroscopy was used to examine ${\cdot}OH$ radical formation using terephthalic acid during photoirradiation.

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Synthesis of N,N-Diaryl-(pyridin-3-yl)pyrimidin-2-amine Derivatives and Their Photochemical Properties

  • El-Deeb, Ibrahim Mustafa;Lee, So-Ha
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.3
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    • pp.291-298
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    • 2008
  • Although the pyrimidine derivatives were obtained in low yields ranging from 8% to 20%, we reported the successful preparation of N,N-diaryl-pyrimidin-2-amine derivatives starting from the corresponding 2-aminopyrimidines (1a-1c), by direct palladium-catalyzed arylation using different arylbromides. The reasons of low yields are thought to be the electronic and steric effects by the neighboring aromatic systems. The absorption spectra and photoluminescent spectra of compounds (3a 3g and 4a-4c) were measured using dichloromethane on the concentration of 25 mM by UV vis spectroscopy and luminescent spectroscopy. Pyrimidine derivatives 4a, 4b, and 4c showed moderate emission maxima at 474 nm, 481 nm, and 367 nm, respectively, while other compounds showed very weak photoluminescence or no photoluminescence at all.

Fabrication of Conducting Polymer Thin Films Using Molecular Layer Deposition

  • Han, Gyu-Seok;Seong, Myeong-Mo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.289-289
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    • 2011
  • The conducting polymer thin films were deposited using the gas phase method which known as molecular layer deposition (MLD). Terephthalaldehyde (TPA) and p-phenylenediamine (PD) were used as monomers to deposit conducting polymer. Self-terminating nature of TPA and PD reaction were demonstrated by growth rate saturation versus precursors dosing time. Infrared spectroscopic and X-ray photoelectron spectroscopy were employed to determine the chemical composition and state of conducting polymer thin films. Layer by layer growth and polymerization of thin films can be showed by shifting of absorption edge using UV-VIS spectroscopy. This conducting polymer fabricated by using MLD method gives the opportunity to develop new hybrid materials by combining inorganic materials in nanoscale.

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Polymorphic Forms of Furosemide Characterized by THz Time Domain Spectroscopy

  • Ge, Min;Liu, Guifeng;Ma, Shihua;Wang, Wenfeng
    • Bulletin of the Korean Chemical Society
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    • v.30 no.10
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    • pp.2265-2268
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    • 2009
  • Terahertz time domain spectroscopy (THz-TDS) is applied in transmission to identify the five forms of modifications of furosemide and one commercial product from 0.3 THz to 1.6 THz at room temperature. The different absorption spectra of the different forms are sensitive to crystal structures. Density function theory (DFT) calculation was used to understand the vibrational modes of furosemide in the THz region. X-ray powder diffractometry (XRPD) was applied to confirm the different forms of modifications. The results demonstrate that THz-TDS is a potential analytical technique in investigating polymorphic forms in the pharmaceutical fields.

ESR Signal in Different Cuts of Irradiated Chicken, Pork and Beef

  • Nam, Hye-Seon;Yang, Jae-Seung;Ly, Sun-Yung
    • Nuclear Engineering and Technology
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    • v.32 no.3
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    • pp.254-260
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    • 2000
  • Electron spin resonance (ESR) spectroscopy was used to detect irradiated meat containing bones (chicken, pork and beef), to investigate the effect of irradiation dose on the ESR signal intensity and to identify the stability of radicals under 9 weeks of storage. Chicken, pork and beef were irradiated with doses 0, 1, 3, 5 and 7 kGy at room temperature using a Co-60 irradiator. Bones were pieced and dried, which were placed in a quartz tube within an Electron paramagnetic resonance (EPR) spectrometer resonator cavity. The irradiated bone presented an asymmetric absorption in shape, different from that of a non-irradiated one. The signal intensity of smaller animals are lower than larger species. Variation was observed between samples of the same species depending on the calcification status of the bone. Moreover different irradiation doses produced different signal areas that make possible to estimate the absorbed dose of treated meat. The ESR signal stability after irradiation was stable in even after a 9 week storage at room temperature.

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Structural Properties of Plasma-treated Polymer Films and Their Applications

  • Lee, Jin Young;Lee, Geon Joon;Kim, In Tae;Choi, Eun Ha
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.522-522
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    • 2013
  • Plasma can be used to various applications such as sterilization, inactivation/removal of microorganisms, wound healing, tooth bleaching, cancer treatment, surface modification and plasma polymerization. In this research, we studied the effect of plasma irradiation on the structural, optical, and biological properties of the polymer films. Several polymers were synthesized and then deposited on the glass substrates. The polymer films were treated by oxygen and nitrogen plasmas. Plasma-treated films were investigated by contact angle, infrared absorption spectroscopy, cathodoluminescence spectroscopy, and scanning electron microscopy. Functional materials were prepared on plasma-treated surface, and their performances were investigated using various techniques. Next, we discuss relationship between the performance of functional materials and the structural properties of plasma-treated polymer films.

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