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Electrochemical Corrosion Damage Characteristics of Aluminum Alloy Materials for Marine Environment (해양환경용 알루미늄 합금 재료의 전기화학적 부식 손상 특성)

  • Kim, Sung Jin;Hwang, Eun Hye;Park, Il-Cho;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.51 no.6
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    • pp.421-429
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    • 2018
  • In this study, various electrochemical experiments were carried out to compare the corrosion characteristics of AA5052-O, AA5083-H321 and AA6061-T6 in seawater. The electrochemical impedance and potentiostatic polarization measurements showed that the corrosion resistance is decreased in the order of AA5052-O, AA5083-H321 and AA6061-T6, with AA5052-O being the highest resistant. This is closely associated with the property of passive film formed on three tested Al alloys. Based on the slope of Mott-Schottky plots of an n-type semiconductor, the density of oxygen vacancies in the passive film formed on the alloys was determined. This revealed that the defect density is increased in the order of AA5052-O, AA5083-H321 and AA6061-T6. Considering these facts, it is implied that the addition of Mg, Si, and Cu to the Al alloys can degrade the passivity, which is characterized by a passive film structure containing more defect sites, contributing to the decrease in corrosion resistance in seawater.

Texture and Plastic Strain Ratio Changes of Hot Asymmetrically Rolled AA1050 Al Sheet (열간 비대칭 압연한 AA1050 Al 판재의 집합조직과 소성변형비 변화)

  • Hamrakulov, B.;Lee, C.W.;Kim, I.
    • Transactions of Materials Processing
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    • v.28 no.5
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    • pp.287-293
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    • 2019
  • The plastic strain ratio is one of the factors of the deep drawability of metal sheets. The plastic strain ratio of Al sheet is low value. Therefore, it is necessary to increase the plastic strain ratio in order to improve the deep drawability of the Al sheet. This study investigated the increase in the plastic strain ratio and the texture change of AA1050 Al sheet after the hot asymmetric rolling. The average plastic strain ratio of initial AA1050 Al sheets was 0.41. After 84% hot asymmetric rolling at $400^{\circ}C$, the average plastic strain ratio was 0.77. The average plastic strain ratio of 84% hot asymmetrically rolled AA1050 Al sheet at $400^{\circ}C$ is 1.9 times higher than that of initial AA1050 Al sheet. The ${\mid}{\Delta}R{\mid}$ of 84% hot asymmetrically rolled AA1050 Al sheet at $400^{\circ}C$ is 1/2 times lower than that of initial AA1050 Al sheet. This result is due to the development of the intensity of the ${\gamma}-fiber$ texture and the decrease of the intensity of {001}<100> texture after the hot asymmetric rolling of AA1050 Al sheet.

Texture and Plastic Strain Ratio Changes of Hot Asymmetrically Rolled AA3003 Sheet (열간 비대칭 압연한 AA3003 판재의 집합조직과 소성변형비 변화)

  • Hamrakulov, B.;Lee, C.W.;Kim, I.
    • Transactions of Materials Processing
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    • v.28 no.5
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    • pp.281-286
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    • 2019
  • The plastic strain ratio is one of the factors of the deep drawability of metal sheets. The plastic strain ratio of Al sheet is low value. Therefore, it is necessary to increase the plastic strain ratio in order to improve the deep draw ability of the Al sheet. This study investigated the increase of the plastic strain ratio and the texture change of AA3003 sheet after the hot asymmetric rolling. The average plastic strain ratio of the initial AA3003 sheets was 0.69. After 83% hot asymmetric rolling at $200^{\circ}C$, the average plastic strain ratio was 0.83. The average plastic strain ratio of the 83% hot asymmetrically rolled AA3003 sheet at $200^{\circ}C$ is 1.2 times higher than that of the initial AA3003 sheet. The ${\mid}{\Delta}R{\mid}$ of 83% hot asymmetrically rolled AA3003 sheet at $200^{\circ}C$ is 0.83 times lower than that of the initial AA3003 sheet. This result is due to the development of the intensity of ${\gamma}-fiber$ texture and reduces the intensity of {001}<110> and {001}<100> textures after hot asymmetric rolling of AA3003 sheet.

Microstructural Evolution of Ultrafine Grained AA1050/AA6061 Complex Aluminum Alloy Sheet with ARB Process (ARB공정에 따른 초미세립 AA1050/AA6061 복합알루미늄 합금 판재의 미세조직 발달)

  • Lee, Seong-Hee
    • Korean Journal of Materials Research
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    • v.23 no.1
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    • pp.41-46
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    • 2013
  • The microstructural evolution of AA1050/AA6061 complex aluminum alloy, which is fabricated using an accumulative roll-bonding (ARB) process, with the proceeding of ARB, was investigated by electron back scatter diffraction (EBSD) analysis. The specimen after one cycle exhibited a deformed structure in which the grains were elongated to the rolling direction for all regions in the thickness direction. With the proceeding of the ARB, the grain became finer; the average grain size of the as received material was $45{\mu}m$; however, it became $6.3{\mu}m$ after one cycle, $1.5{\mu}m$ after three cycles, and $0.95{\mu}m$ after five cycles. The deviation of the grain size distribution of the ARB processed specimens decreased with increasing number of ARB cycles. The volume fraction of the high angle grain boundary also increased with the number of ARB cycles; it was 43.7% after one cycle, 62.7% after three cycles, and 65.6% after five cycles. On the other hand, the texture development was different depending on the regions and the materials. A shear texture component {001}<110> mainly developed in the surface region, while the rolling texture components {011}<211> and {112}<111> developed in the other regions. The difference of the texture between AA1050 and AA6061 was most obvious in the surface region; {001}<110> component mainly developed in AA1050 and {111}<110> component in AA6061.

A Mechanism of Gastric Antiulceration by the Extract of Artemisiae asiatica (애엽 추출물의 항위궤양에 대한 기전)

  • Hwang Gwi-Seo;Lee Jung-Suk;Yun Yeo-Pyo
    • Journal of Society of Preventive Korean Medicine
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    • v.1 no.1
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    • pp.118-125
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    • 1997
  • In oriental medicine, Artemisiae asiatica (AA) has been used as analgesic, antiinflammatory agent, and coagulatory agent. Furthermore, eupatilin, a kind of flavonoids, is known as the active principle component of AA. This study was undertaken to determine the gastric antiulceration of AA and to elucidate its mechanism. AA showed the inhibitory effect on gastric ulceration induced by EtOH/HCl and aspirin. To elucidate its mechanism, the effect of AA on lipidperoxide level in gastric mucosa, microsome lipidperoxidation, iron -dependent lipidperoxidation, and neutrophil activation were examined. It is suggested that the antiperoxidative and antineutrophil activity of AA play important roles as a possible mechanism. These results suggest that AA might have gastric antiulceration activity due to antilipidperoxdative and antineutrophil activity.

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The Luminescent Properties of Red OLED Devices Doped with Two Dopants (2원 첨가 적색 OLED 소자의 발광특성)

  • Kim, Kyong-Min;Ju, Sung-Hoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.6
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    • pp.531-535
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    • 2007
  • To invest the luminescent characteristics of red light emitting OLED device, a dual dopant system was incorporated into the emitting layer. The multiple layer OLED device structure was $ITO(1500\;{\AA})/HIL(200\;{\AA})/a-NPD(600\;{\AA})/EML(300\;{\AA})/Alq_3(200\;{\AA})/LiF(7\;{\AA})/Al(1800\;{\AA})$. The concentrations of the rubrene dopant were tested at 0 vol.%, 3 vol.%, 6 vol.% and 9 vol.%. The maximum device efficiency and life time were obtained at the rubrene dopant concentration of 6 vol.%. Emission spectrum and color coordinate of devices showed no relationship with rubrene dopant concentration. Experiment results show that rubrene dopant absorbs energy from $Alq_3$ host and transfer it to RD1 dopant acting as an energy intermediate and influencing the device efficiency, finally the red light is emitted from the RD1 dopant.

Evaluation of surface roughness using phase-measuring interferometer for a few ten ${\AA}$ and sub ${\AA}$-rough substrates (위상측정 간섭계를 이용한 수십 ${\AA}$급 및 sub ${\AA}$급 반사경 기판 조도 평가)

  • 조민식;정태호;오문수
    • Korean Journal of Optics and Photonics
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    • v.10 no.4
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    • pp.283-288
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    • 1999
  • We investigated the characteristics of surface roughness evaluation using phase-measuring interferometer for a few ten $\AA$ and sub $\AA$-rough substrates. The influence of phase averaging and intensity averaging on the roughness measurement by phase measuring interferometer was investigated and the optimal number of phase and intensity averaging for the least measurement error was searched. For a few ten $\AA$-rough sample, roughness value did not depend so much on the data averaging. Whereas, measurement error for sub $\AA$-rough sample was significantly improved as the number of phase and intensity averaging increased. At the phase averaging of 30 and the intensity averaging of 20, roughness value that measurement error was minimized was obtained, and it was in good agreement with that by optical heterodyne interferometer. Roughness measurement at the optimal data averaging showed also good repeatability error less than 0.01$\AA$.

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The Effects of Temperature and Strain Rate on Flow Stress and Strain of AA5083 Alloy during High Temperature Deformation (AA5083 합금의 고온 변형시 유동응력 및 연신율에 미치는 온도와 변형 속도의 영향)

  • Ko, Byung-Chul;Kim, Jong-Heon;Yoo, Yeon-Chul
    • Transactions of Materials Processing
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    • v.7 no.2
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    • pp.168-176
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    • 1998
  • Hot workability of the AA5083 alloy ws investigated by torsion test at temperature ranges of $350{\sim}520^{\circ}C$ and strain rates of 0.5, 1.0, and 3.0/sec. The flow stress and hot ductility of the AA5083 alloy as a function of deformation variables such as temperature and train rate were studied. The microstructural evolution of the AA5083 alloy was studied in relation to Zener-Hollomon parameter (Z=exp( /RT) Also the hot restoration mechanism of the AA5083 alloy was small when Z val-ues were higher than $1.73{\times}1016/sec(370^{\circ}C,\;0.5/sec)$ In addition the difference microstructures during hot deformation. It was found that the increase of flow curves and deformed microstructures during hot deformation. It was found that the increase of flow stress of the AA5083 alloy was small when Z val-ues were higher than $1.73{\times}1016/sec(370^{\circ}C.\;0.5/sec)$. However under the low Z values less than $1.73{\times}1016/sec(370^{\circ}C,\;0.5/sec)$ the flow stress increase with increasing the Z values. The large dispersoid particles in the matrix grain decreased the flow strain of the AA5083 alloy because it caused the stress concentration during hot deformation.

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A study on structural characteristics of Se thin film by fabrication temperature (제작 온도에 따른 Se박막의 구조적 특성에 관한 연구)

  • 정운조;조재철;박계춘;정해덕
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.05a
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    • pp.1.1-5
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    • 1996
  • Structural characteristics in Se thin film fabricated by EBE method had been studied. Se thin film was deposited with noncrystalline until substrate temperature of 100$^{\circ}C$. But Se film was grown with monoclinic at substrate temperature of over 150$^{\circ}C$. Lattice constants of it were as follow: a=12.76[${\AA}$], b=9.15[${\AA}$], c=10.4[${\AA}$]. Finally, after heat-treatment at 150$^{\circ}C$ for 15 min with substrate temperature of 100$^{\circ}C$, noncrystalline Se was proved to be hexagonal. Lattice constants of it were as follow: a=4.27[${\AA}$], c=4.83[${\AA}$].

Fe3O4/CoFe2O4 superlattices; MBE growth and magnetic properties

  • Quang, Van Nguyen;Shin, Yooleemi;Duong, Anh Tuan;Nguyen, Thi Minh Hai;Cho, Sunglae;Meny, Christian
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.242-242
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    • 2016
  • Magnetite, Fe3O4, is a ferrimagnet with a cubic inverse spinel structure and exhibits a metal-insulator, Verwey, transition at about 120 K.[1] It is predicted to possess as half-metallic nature, 100% spin polarization, and high Curie temperature (850 K). Cobalt ferrite is one of the most important members of the ferrite family, which is characterized by its high coercivity, moderate magnetization and very high magnetocrystalline anisotropy. It has been reported that the CoFe2O4/Fe3O4 bilayers represent an unusual exchange-coupled system whose properties are due to the nature of the oxide-oxide super-exchange interactions at the interface [2]. In order to evaluate the effect of interface interactions on magnetic and transport properties of ferrite and cobalt ferrite, the CoFe2O4/Fe3O4 superlattices on MgO (100) substrate have been fabricated by molecular beam epitaxy (MBE) with the wave lengths of 50, and $200{\AA}$, called $25{\AA}/25{\AA}$ and $100{\AA}/100{\AA}$, respectively. Streaky RHEED patterns in sample $25{\AA}/25{\AA}$ indicate a very smooth surface and interface between layers. HR-TEM image show the good crystalline of sample $25{\AA}/25{\AA}$. Interestingly, magnetization curves showed a strong antiferromagnetic order, which was formed at the interfaces.

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