• 제목/요약/키워드: ASR reaction

검색결과 67건 처리시간 0.025초

Elasto-plastic damage modelling of beams and columns with mechanical degradation

  • Erkmen, R. Emre;Gowripalan, Nadarajah;Sirivivatnanon, Vute
    • Computers and Concrete
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    • 제19권3호
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    • pp.315-323
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    • 2017
  • Within the context of continuum mechanics, inelastic behaviours of constitutive responses are usually modelled by using phenomenological approaches. Elasto-plastic damage modelling is extensively used for concrete material in the case of progressive strength and stiffness deterioration. In this paper, a review of the main features of elasto-plastic damage modelling is presented for uniaxial stress-strain relationship. It has been reported in literature that the influence of Alkali-Silica Reaction (ASR) can lead to severe degradations in the modulus of elasticity and compression strength of the concrete material. In order to incorporate the effects of ASR related degradation, in this paper the constitutive model of concrete is based on the coupled damage-plasticity approach where degradation in concrete properties can be captured by adjusting the yield and damage criteria as well as the hardening moduli related parameters within the model. These parameters are adjusted according to results of concrete behaviour from the literature. The effect of ASR on the dynamic behaviour of a beam and a column are illustrated under moving load and cyclic load cases.

Effect of rock mineralogy on mortar expansion

  • Karaman, Kadir;Bakhytzhan, Aknur
    • Geomechanics and Engineering
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    • 제20권3호
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    • pp.233-241
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    • 2020
  • Alkali-silica reaction (ASR) is among one of the most important damaging mechanisms in concrete, depending primarily on aggregates which contain reactive minerals. However, expansion in concrete may not directly relate to the reactive minerals. This study aims to investigate the influence of ASR and the expansion of mortar bars depending on aggregate type containing various components such as quartz, clay minerals (montmorillonite and kaolinite) and micas (muscovite and biotite). In this study, the accelerated mortar bar tests (AMBT) were performed in two conditions (mortar bars in the same and sole NaOH solutions). Petrographic thin section studies, X-ray diffraction (XRD) analysis (Rietveld method), scanning electron microscopy (SEM) and chemical analyses were carried out. This study showed that quartzite bars led to increase in expansion values of mortar bars in diabase-1 and andesite when these were in the same NaOH solution. However, three samples (basalt, quartzite and claystone) were found having ASR expansion based on the AMBT when the special molds were used for each sample. SEM study revealed that samples which exhibit highest expansions according to AMBT had a generally rough surface and acicular microstructures in or around the micro-cracks. Basalt and quartzite showed more variable in major oxides than those of other samples based on the chemical analyses, SEM studies and AMBT. This study revealed that the highest expansions were observed to source not only from reactive aggregates but also from alteration products (silicification, chloritization, sericitization and argillisation), phyllosilicates (muscovite, biotite and vermiculite) and clays (montmorillonite and kaolinite).

Characteristics of Lightweight Concrete and Their Application in Structures

  • 성찬영
    • 한국농공학회지
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    • 제34권E호
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    • pp.60-69
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    • 1992
  • The research significance of the paper is to identify the major properties of synthetic lightweight concrete that are affected by ASR expansion and to determine the extent and magnitude of the loss in these properties. Emphasis is also given to the use of non-destructive testing techniques ; Such as dynamic modulus of elasticity and ultrasonic pulse velocity, to examine whether these methods could be used to identify the initiation of expansion and the internal structural damage caused by ASR.

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Mechanisms of ASR surface cracking in a massive concrete cylinder

  • Kagimoto, Hiroyuki;Yasuda, Yukihiro;Kawamura, Mitsunori
    • Advances in concrete construction
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    • 제3권1호
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    • pp.39-54
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    • 2015
  • Relative humidity and strains within a massive concrete cylinder (${\varphi}450mm{\times}900mm$) in the drying and the re-saturating process were measured for elucidating the process of ASR surface cracking in concrete. The expansion behavior of mortars in dry atmospheres with various R.H. values and the resaturating process was revealed. Non- or less-expansive layers were formed in near-surface regions in the concrete cylinder in the drying process, but ASR expansions actively progressed in inner portions. After resaturating, R.H. values of near-surface regions rapidly increased with time, but expansions in the regions were found to be very small. However, in the middle portions, of which R.H. values were kept 80% ~ 90% R.H. in the drying process, expansion actively progressed, resulting in further development of surface cracks in the re-saturating process.

공항 airside용 제설제의 기본물질에 대한 포장 영향성 평가 연구 (Pavement Impact Evaluation of Basic Materials of Airport Airside Deicers)

  • 김영웅;유광호;조창렬;조남현
    • 한국도로학회논문집
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    • 제18권6호
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    • pp.25-34
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    • 2016
  • OBJECTIVES : This is a basic research for the domestic production of airport-airside deicers. This research selected basic materials for deicers appropriate for the pavement of domestic airports by evaluating the deicing performances of basic materials used in international-standard airport deicers and their impacts on pavements. METHODS : Laboratory investigation was conducted to evaluate the asphalt surface tensile strength, concrete scaling impact, ASR impact, and deicing performances of sodium formate (NaFm), potassium formate (KFm), sodium acetate (NaAc), and potassium acetate (KAc), which are the basic de-icing materials commonly used at international airports, approved by the FAA. In addition, the analyses were also performed on the airside deicer urea, which is currently used in domestic airports. RESULTS : Laboratory investigation confirmed that sodium formate, potassium formate, sodium acetate, and potassium acetate had superior surface tensile strength, concrete scaling impact, and deicing performance compared to airside urea, but they also had greater impacts on concrete ASR. Among these materials, sodium formate had the best asphalt surface tensile strength, concrete scaling impact, and deicing performance, while also having the greatest impact on ASR; hence, mitigation plans for ASR were needed, if it were to be used as airport-airside deicer. CONCLUSIONS : It is necessary to consider additional additives to prevent ASR of concrete pavements when developing airport-airside deicers using sodium formate, potassium formate, sodium acetate, and potassium acetate.

Differential Symbiotic Response of Phage-typed Strains of Bradyrhizobium japonicum with Soybean Cultivars

  • Appunu Chinnaswamy;Dhar Banshi
    • Journal of Microbiology
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    • 제44권3호
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    • pp.363-368
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    • 2006
  • In this study, native Byadyrhizobium strains were isolated from the host plant, Glycine max, harvested from fields in Madhya Pradesh, India, and were typed by Iytic rhizobiophages. Eight indigenous (Soy2, ASR011, ASR031, ASR032, MSR091, ISR050, ISR076 and ISR078) and two exotic strains (USDA123 and CB1809), all of which evidenced a distinct reaction with six phages, were employed in this study. The symbiotic interaction of these strains was studied initially using soybean cultivar JS335 in a sand culture in a controlled environment, and the efficiency was assessed based on the nodule number, nodule dry weight, plant dry weight, nitrogenase activity, and total accumulation of N per plant. Symbiotic effectiveness was found to be highest with the native phage-sensitive isolate ASR011, whereas it was at a minimum with the phage-resistant isolates, ISR050 and ISR078. Additionally, the effectiveness of these strains was evaluated using six soybean cultivars belonging to different maturity groups; namely, Brags, Lee, Pusa20, PK416, JS33S and NRC37. Analysis of variance data evidenced significant differences due to both symbionts, for the majority of the tested parameters. The CB1809, USDA123, and ASR011 strains evidenced relatively superior symbiotic effectiveness with soybean cultivars Brags, Lee and JS335. Strain ISR078 evidenced no significant responses with any of the cultivars. The ASR031 strain performed moderately well with all tested cultivars. The symbiotic response of all the strains was quite poor with cultivar PK416. Our studies showed that a significant relationship existed between the phage sensitivity and symbiotic efficiency of the bacterial strains with the host-cultivars.

Modulation of Aqueous Extracted Angelicae sinensis Radix on Nitric Oxide Production and Pro-inflammatory Cytokine Gene Expressions in RAW 264.7 Macrophage Cells

  • Lee Young Sun;Han Ok Kyung;Shin Sang Woo;Park Jong Hyun;Kwon Young Kyu
    • 동의생리병리학회지
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    • 제17권6호
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    • pp.1514-1518
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    • 2003
  • Angelica sinensis radix, Danggui, is a traditional oriental medication, which has been used to modulate immune response. We report here that aqueous extract of Angelica sinensis radix (ASR) can induces NO production, and inhibit LPS-induced NO production in dose-dependent manner in RAW 264.7 macrophage cells. ASR also induces iNOS mRNA and iNOS protein expression, and exhibit inhibitory effect on iNOS mRNA and protein expression in a dose-dependent manner in LPS-stimulated RAW 264.7 macrophage cells. Cytokines involved in the regulation of inflammatory reaction and immune response may play a role in the pathogenesis. ASR induces. pro-inflammatory cytokine gene expression (IL-1α, IL-1β and IL-6 gene) in a dose-dependent manner, and inhibits the expressions of these cytokines in LPS-stimulated RAW 264.7 macrophage cells. These data indicate that (1) ASR may be a potential therapeutic modulator of NO synthesis in various pathological conditions, and (2) the immunomodulatory effects of ASR may be, in part, associated with the inducing or suppression of pro-inflammatory cytokine gene expressions.

중저온형 SOFC를 위한 PSCF3737(Pr0.3Sr0.7Co0.3Fe0.7O3) 공기극 물질의 특성 및 최적화께 관한 연구 (Study of Optimization and Characteristics of PSCF3737(Pr0.3Sr0.7Co0.3Fe0.7O3) for IT-SOFC)

  • 박광진;이창보;김정현;백승욱;배중면
    • 전기화학회지
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    • 제10권3호
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    • pp.207-212
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    • 2007
  • IT-SOFC(중저온형 고체산화물 연료전지)의 공기극으로 적합한 PSCF3737의 물질 특성을 파악하고 그 특성을 이용하여 낮은 ASR을 갖기 위한 소결 온도 및 두께 최적화에 관한 연구를 수행하였다. 분말 사이즈 및 상형성을 고려할 때 GNP 방법으로 합성된 분말의 하소 온도는 $1000^{\circ}C$가 적합함을 알 수 있었다. 산소 분압에 따른 ASR 변화 실험을 통하여 PSCF3737의 저항 성분을 전극 자체의 특성과 관련된 중간 주파수 대역(${\sim}10^2Hz$)과 산소의 확산에 영향 받는 낮은 주파수 대역(${\sim}10^{-1}Hz$) 2가지로 분류할 수 있었다. 공기극의 특성 실험을 통하여 소결 온도는 $1200^{\circ}C$가 가장 적합하며 공기극의 두께는 2번 스크린 프린팅 된 $27\;{\mu}m$가 가장 적합함을 알 수 있었다. 이를 토대로 EIS 측정을 하면 $700^{\circ}C$에서 $0.115\;{\Omega}cm^2$의 낮은 ASR값을 얻을 수 있었다.

국내 광물성 혼화재의 종류 및 혼입률에 따른 알칼리-실리카 반응 특성 (Characteristics of Alkali-Silica Reaction according to Types and Substitution Ratios of Mineral Admixtures in Korea)

  • 김성권;홍승호;허인;윤경구
    • 콘크리트학회논문집
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    • 제23권1호
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    • pp.49-55
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    • 2011
  • 국내에서는 알칼리-실리카 반응에 의한 피해사례가 거의 보고된 바 없었고, 골재의 품질도 양호한 것으로 알려져서 알칼리-실리카 반응에 대하여 안전하다고 평가되었다. 그러나 최근 국내 일부 고속도로 콘크리트 포장구간에서 알칼리-실리카 반응에 의한 피해 사례가 보고되어 알칼리-실리카 반응에 대한 대책과 억제방안이 요구되고 있는 실정이다. 따라서 이 논문에서는 국내 콘크리트용 굵은골재를 대상으로 ASTM C 1260 촉진 모르타르 봉 시험방법을 이용하여 광물성 혼화재인 플라이애쉬, 고로슬래그미분말, 실리카퓸의 종류 및 혼입률에 따른 알칼리-실리카 반응성을 평가하고자 하였다. 혼화재 무첨가의 경우 재령 14일에 실트암과 이암은 'potentially deleterious expansion'으로, 규장질유리질 응회암과 안산암-1은 'innocuous and deleterious'로 판정되었다. 플라이애쉬 10, 20, 30% 혼입의 경우 플라이애쉬 10%를 혼입한 이암을 제외한 모든 시험편에서 재령 14일에 'innocuous behavior'로 판정되었으며, 고로슬래그 미분말 30, 40, 50% 혼입의 경우에는 모든 시험편에서 재령 14일에 'innocuous behavior'으로, 실리카퓸 5, 7.5, 10%를 혼입한 경우에도 모든 시험편에서 재령 14일에 'innocuous behavior'로 판정되어 광물성 혼화재의 알칼리-실리카 반응 억제 효과를 확인하였다. 따라서 현장여건에 따라 선택적으로 적용 가능할 것으로 판단된다.

${\cdot}$저온형 고체 산화물 연료전지의 공기극 물질로 사용되는 $Pr_{0.3}Sr_{0.7}CO_{x}Fe_{(1-x)}O_{3-\delta}$ (x=0, 0.3, 0.5, 0.7, 1) 에 관한 연구 (Study of $Pr_{0.3}Sr_{0.7}CO_{x}Fe_{(1-x)}O_{3-\delta}$ (x=0, 0.3, 0.5, 0.7, 1) as the cathode materials for intermediate temperature SOFC)

  • 박광진;김정현;이창보;배중면
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 춘계학술대회
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    • pp.125-128
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    • 2007
  • The influence of Co substitution in B-site at perovskite PSCF($Pr_{0.3}Sr_{0.7}CO_{x}Fe_{(1-x)}O_{3}$) was investigated in this study. The PSCF series exhibits excellent MIEC(mixed ionic electronic conductor) properties. ASR(area specific resistance) of PSCF3737 was 0.137 ${\Omega}{\cdot}cm^{2}$ at $700^{\circ}C$. The activation energy of PSCF3737 was also lower than other compositions of PSCF. ASR of PSCF3737 was analysed as two parts at different part of frequency region. Responses at middle frequency part (${\sim}10^2$ Hz) were concerned with oxygen reduction reaction and those at low frequency part (${\sim}10^{-1}$ Hz) were related with oxygen diffusion.

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