• 대한기계학회논문집A
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• 제24권4호
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• pp.1055-1064
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• 2000

First, various specimen geometries, namely, coupon type, waisted type and dog-bone type, were examined to determine appropriate fatigue specimen of thermoplastic composite material AS4/PEEK and the n, fatigue strength of smooth and notched specimens of AS4/PEEK [-45/0/+45/90]2s was investigated. Fatigue tests were performed under load controlled condition at a stress ratio of 0. 1 at a frequency of 5Hz. Stiffness degradation of specimens with fatigue cycling was monitored using an automated unloading compliance technique. The waisted type specimen is found appropriate for smooth fatigue specimen geometry of AS4/PEEK. As for the effect of stress concentration, it is found that fatigue strength is higher for a 2mm-diameter hole notched specimen than a 5mm-diameter one. Fatigue notch factor decreases with the increase of fatigue life. These results are far different from the trend of fatigue strength of metallic materials. The stiffness variation of smooth specimen was only 4% at maximum until final fracture. On the other hand, the stiffness of hole notched specimen was reduced by 45% at maximum. Notched fatigue strength was compared between thermoplastic composite AS4/PEEK and thermosetting composite Graphite/Epoxy. In long-life fatigue (>104), the AS4/PEEK composite shows superior fatigue strength, but in short-life fatigue, the fatigue strength of the Graphite/Epoxy composite is nearly equal or somewhat higher than that of the AS4/PEEK composite.

• Composites Research
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• 제12권4호
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• pp.8-16
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• 1999

본 연구는 인장하중의 방향변화에 따른 의사 등방성 복합재 적층판의 피로손상거동의 변화에 대하여 알아보았다. [0/-60/＋60]$_s$ 적층판과 [＋30/-30/90]$_s$ 적층판의 저 싸이클 피로시험을 행하였고, 재료계는 AS4/Epoxy와 AS4/PEEK를 사용하였다. [＋30/-30/90]$_s$ 적층판의 피로손상은 [0/-60/＋60]$_s$ 적층판에 비하여 아주 달랐다. AS4/Epoxy와 AS4/PEEK [＋30/-30/90]$_s$ 적층판에 발생한 층간분리의 위치가 모재의 종류에 따라 다르게 나타났다. 층간분리 진전시 측정된 변형률을 사용하여 임계 변형률 에너지 해방률을 계산하였다. 실험결과를 모드별 변형률 에너지 해방률의 제안된 계산법으로 얻어진 해석 결과와 비교한 결과, 잘 일치되었다.

• The Journal of Advanced Prosthodontics
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• 제14권6호
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• pp.346-359
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• 2022

PURPOSE. Four and six implant-supported fixed full-arch prostheses with various framework materials were assessed under different loading conditions. MATERIALS AND METHODS. In the edentulous maxilla, the implants were positioned in a configuration of four to six implant modalities. CoCr, Ti, ZrO₂, and PEEK materials were used to produce the prosthetic structure. Using finite element stress analysis, the first molar was subjected to a 200 N axial and 45° oblique force. Stresses were measured on the bone, implants, abutment screw, abutment, and prosthetic screw. The Von Mises, maximum, and minimum principal stress values were calculated and compared. RESULTS. The maximum and minimum principal stresses in bone were determined as CoCr < ZrO₂ < Ti < PEEK. The Von Mises stresses on the implant, implant screw, abutment, and prosthetic screws were determined as CoCr < ZrO₂ < Ti < PEEK. The highest Von Mises stress was 9584.4 Mpa in PEEK material on the prosthetic screw under 4 implant-oblique loading. The highest maximum principal stress value in bone was found to be 120.89 Mpa, for PEEK in 4 implant-oblique loading. CONCLUSION. For four and six implant-supported structures, and depending on the loading condition, the system accumulated different stresses. The distribution of stress was reduced in materials with a high elastic modulus. When choosing materials for implant-supported fixed prostheses, it is essential to consider both the number of implants and the mechanical and physical attributes of the framework material.

• 한국전기전자재료학회논문지
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• 제17권4호
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• pp.396-403
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• 2004

The dielectric properties of Y-ray irradiated and thermally aged polyetheretherketone (PEEK) have been investigated. Results of the temperature dependency of dielectric properties indicated that the glass transition temperature of aged PEEK increased as radiative and thermal ageing. The frequency dependency of dielectric properties implied that the magnitude of radiation and thermal induced dipoles, ions increased as radiative and thermal ageing. The values of relaxation intensity calculated using Cole-Cole's circular arc can be useful for evaluation of degradation level of PEEK.

• Korean Chemical Engineering Research
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• 제45권4호
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• pp.391-395
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• 2007

술폰화한 폴리에테르에테르케톤(sPEEK)과 나피온(Nafion) 아이오노머를 혼합한 새로운 전극 바인더를 제조하여 DMFC 용 음극 바인더로서 적용 가능성을 고찰하였다. 새롭게 제조한 혼합 바인더는 높은 수소 이온 전도도와 메탄올 전달 속도 및 낮은 용해도와 우수한 기계적 물성을 나타냈다. 이를 도입한 음극에서 혼합 바인더 함량에 따른 셀 성능을 고찰하였으며, 10 wt% 혼합 바인더를 도입한 음극으로 구성된 셀이 가장 우수한 성능을 나타냈다.

• 한국항공우주학회지
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• 제45권4호
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• pp.342-348
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• 2017

본 연구에서는 초음속 주유동 환경에서의 막냉각 특성에 대해 적외선 열상법을 적용한 시험을 수행하였다. 막냉각 시험은 수축형 막냉각 노즐을 갖는 쐐기형 막냉각 시편을 이용해 마하수 3.0, 단위 길이 당 레이놀즈수 $42.53{\times}10^6$ 와 $69.35{\times}10^6$ 인 조건을 구현한 자유-제트 시험 설비에서 수행하였다. 모사 탐색창에 해당하는 PEEK의 표면 온도를 계측하여 막냉각 효율을 산출하였고 받음각 및 분사율이 막냉각 효율에 미치는 영향을 분석하였다. 막냉각을 적용하지 않는 경우와 비교할 때, 막냉각을 적용할 경우 측정된 PEEK의 표면 온도가 크게 감소하였다. 막냉각의 유용성은 시간에 따른 PEEK의 표면 온도로부터 산출한 열유속 특성으로도 확인할 수 있다. 분사율이 증가할수록 보호되는 PEEK의 영역이 주유동과 막냉각 유동의 흐름 방향으로 확장되었다.

• Macromolecular Research
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• 제15권4호
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• pp.379-384
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• 2007

Sulfonation of polyetheretherketones (PEEK) was carried out in order to fabricate commercial perfluorosulfonic acid membrane alternatives, which were characterized in terms of their ion exchange capacity, ionic conductivity, water swelling, methanol crossover and electrochemical performance in their direct application as a methanol fuel cell. A high ion exchange capacity, 1.88, was achieved with a sulfonation reaction time of 8 h, with a significantly low methanol crossover low compared to that of Nafion. However, the morphological stability was found to deteriorate for membranes with sulfonation reaction times exceeding 8 h. Electrochemical cell tests suggested that the fabrication parameters of the membrane electrode assembly based on the sulfonated PEEK membranes should be optimized with respect to the physicochemical properties of the newly prepared membranes.

• The Journal of Advanced Prosthodontics
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• 제13권5호
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• pp.304-315
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• 2021

PURPOSE. Esthetic expectations have increased the use of polyetheretherketone (PEEK) clasps as alternatives to Cr-Co in removable partial dentures (RPDs). The objective of this study was to evaluate the retentive force and dimensional change of clasps with different thickness and undercut made from PEEK by the thermo-mechanical fatigue. MATERIALS AND METHODS. PEEK clasps (N = 48) with thicknesses of 1 or 1.50 mm and 48 premolar monolithic zirconia crowns with undercuts of 0.25 mm or 0.50 mm were fabricated. Samples are divided into four groups (C1-C4) and were subjected to 7200 thermal aging cycles (at 5 - 55℃). The changes in the retentive force and dimensions of the clasps were measured by micro-stress testing and micro-CT devices from five measurement points (M1 - M5). One-way ANOVA, paired t-test, two-way repeated ANOVA, and post-hoc tests were used to analyze the data (P < .05). RESULTS. The retentive forces of C1, C2, C3, and C4 groups in initial and final test were found to be 4.389-3.388 N, 4.67 - 3.396 N, 5.161 - 4.096 N, 5.459 - 4.141 N, respectively. The effects of retentive force of all PEEK clasps groups were significant decreased. Thermo-mechanical cycles caused significant dimensional changes at points with M2, M4, and M5, and abraded the clasp corners and increased the distance between the ends of the clasp, resulting in reduced retentive forces (P^* = .016, P^* = .042, P < .001, respectively). CONCLUSION. Thermo-mechanical aging decreases the retentive forces in PEEK clasps. Increasing the thickness and undercut amount of clasps decreases the amount of dimensional change. The values measured after aging are within the clinically acceptable limits.

• Journal of Korean Neurosurgical Society
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• 제60권2호
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• pp.211-219
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• 2017

Objective : This study aimed to compare the clinical and radiologic outcomes of patients with subaxial cervical injury who underwent anterior cervical discectomy and fusion (ACDF) with autologous iliac bone graft or polyetheretherketone (PEEK) cages using demineralized bone matrix (DBM). Methods : From January 2005 to December 2010, 70 patients who underwent one-level ACDF with plate fixation for post-traumatic subaxial cervical spinal injury in a single institution were retrospectively investigated. Autologous iliac crest grafts were used in 33 patients (Group I), whereas 37 patients underwent ACDF using a PEEK cage filled with DBM (Group II). Plain radiographs were used to assess bone fusion, interbody height (IBH), segmental angle (SA), overall cervical sagittal alignment (CSA, C2-7 angle), and development of adjacent segmental degeneration (ASD). Clinical outcome was assessed using a visual analog scale (VAS) for pain and Frankel grade. Results : The mean follow-up duration for patients in Group I and Group II was 28.9 and 25.4 months, respectively. All patients from both groups achieved solid fusion during the follow-up period. The IBH and SA of the fused segment and CSA in Group II were better maintained during the follow-up period. Nine patients in Group I and two patients in Group II developed radiologic ASD. There were no statistically significant differences in the VAS score and Frankel grade between the groups. Conclusion : This study showed that PEEK cage filled with DBM, and plate fixation is at least as safe and effective as ACDF using autograft, with good maintenance of cervical alignment. With advantages such as no donor site morbidity and no graft-related complications, PEEK cage filled with DBM, and plate fixation provide a promising surgical option for treating traumatic subaxial cervical spine injuries.

• Composites Research
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• 제19권1호
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• pp.15-21
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• 2006

일방향 섬유로 보강된 고성능 복합재료의 경우 모든 방향에서 곡률을 가지는 구조물의 제작에 용이하지 않다. 본 연구에서는 높은 비강성, 비강도를 가지는 일방향으로 보강된 AS4/PEEK 프리프레그 테이프를 이용한 축소 시제 복합재료 접시형 안테나 반사판의 개발 결과를 보여준다. 개발을 위해서 유한요소법을 통한 적층인자 연구를 통한 저열팽창/등방변형의 반사판 설계기법을 확립하였으며, Fiber Placement System을 통한 자동섬유적층법을 이용하여 접시형 안테나 반사판이 제작되었다. 제작된 반사판은 Full Bridge Circuit의 Strain Cage를 이용한 열변형 실험법으로 열팽창 거동에 대한 실험을 수행하였으며, 열변형 해석결과와의 비교를 통하여 제작된 구조물을 검증하였다.