• Journal of Electrochemical Science and Technology
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• v.7 no.2
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• pp.153-160
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• 2016

The inhibition ability of N,N-bis(2,4-dihydroxyhydroxybenzaldehyde)-1,3-Propandiimine (DHBP) as a schiff base against the corrosion of API-5L-X65 steel in 1 M HCl solution was evaluated by electrochemical impedance spectroscopy, potentiodynamic polarization and scanning electron microscopy. Electrochemical impedance studies indicated that DHBP inhibited corrosion by blocking the active corrosion sites. The inhibition efficiency increased with increasing inhibitor concentrations. EIS data was analysed to equivalent circuit model and showed that the charge transfer resistance of steel increased with increasing inhibitor concentration whilst the double layer capacitance decreased. The adsorption of this compound obeyed the Langmuir adsorption isotherm. Gibbs free energy of adsorption was calculated and indicated that adsorption occurred through physical and spontaneous process. The corrosion inhibition mechanism was studied by potential of zero charge. Polarization studies indicated that DHBP retards both the cathodic and anodic reactions through adsorption on steel surface. Scanning electron microscopy was used to study the steel surface with and without inhibitor.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 2009.04a
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• pp.375-378
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• 2009

본 논문에서는 API X80 강의 대변형 비선형 거동을 모사하기 위해 비선형 유한요소해석을 수행하였다. 고강도 강재의 거동을 모사하기 위해 GTN(Gurson-Tvergaad-Needleman) 모델을 사용하였으며, 비선형 해석을 위해 범용 유한요소해석 프로그램인 ABAQUS와 User Subroutine의 사용자 재료모델(UMAT)을 연계하여 사용하였다. 해석결과와 인장실험의 결과와의 비교를 통해 GTN 모델에서 사용되는 재료모델 상수를 도출하였고, 도출된 값들은 개발된 사용자 재료모델과 함께 API X80 강의 각종 실험을 모사하고 대변형 상황의 강재 파이프의 거동을 분석하는데 유용하게 사용될 수 있다.

• Journal of Welding and Joining
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• v.32 no.5
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• pp.1-6
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• 2014

This study aims at manufacturing SA welded API-X70 line-pipe with sour gas resistance. A pipe was manufactured by JCO bending process and SA welding using the API-X70 plate guaranteed HIC resistance. SA welded pipe was expanded in order to reduce the residual stress. The evaluation of a pipe for resistance to HIC and SSCC were performed by the RS D 0004 and RS D 0005 standards. For verification that a pipe has acceptable resistance to HIC, fullscale test was carried out. Results showed no cracking for the HIC and SSCC.

• Journal of the Korean Institute of Gas
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• v.16 no.3
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• pp.54-64
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• 2012

DWTT (Drop Weigh Tearing Test) is one critical method that can exhibit the fracture properties of line pipe steel, since it estimates the properties with real pipe steel. In this study, the ductile portion, inverse fracture ratio and absorbed energy of API X65 and X70 line pipe steels were estimated with temperature variation. Both steels showed that the ratio of ductile area and absorbed energy were decreased with respect to decreasing the test temperature. However, while the ductile fracture behavior exhibited until $-40^{\circ}C$ for the X70 steel, but it showed until $-30^{\circ}C$ for the X65 steel. The fracture properties were discussed with respect to test temperatures.

• Journal of the Korean Society for Heat Treatment
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• v.35 no.4
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• pp.185-192
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• 2022

Variations in the microstructure and mechanical properties of API X70 steel processed by piping, electrical resistance welding (ERW), and post seam annealing (PSA) are investigated in this study. In the welding zone, some elongated pearlites are formed and grains coarsening occurs due to extra heat caused by the ERW and PSA processes. After the piping, the base metal shows continuous yielding behavior and a decrease in yield and impact strengths because mobile dislocation and back stress are introduced during the piping process. On the other hand, the ERW and PSA processes additionally decreased the impact strength of welding zone at room and low temperatures because some elongated pearlites easily act as crack initiation site and coarse ferrite grains facilitate crack propagation. As a result, the fracture surface of the welding zone specimen tested at low temperature revealed mostly cleavage fracture unlike the base metal specimen.

• Steel and Composite Structures
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• v.51 no.4
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• pp.351-361
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• 2024

Accurate measurement of K_IC values for gas pipeline steels is important for assessing pipe safety using failure assessment diagrams. As direct measurement of K_IC was impossible for the API X70 pipeline steel, multi-specimen fracture tests were conducted to measure J_IC using three-point bend geometry. The J values were calculated from load-displacement (F-δ) plots, and the associated crack extensions were measured from the fracture surface of test specimens. Valid data points were found for the constructed J-Δa plot resulting in J_IC=356kN/m. More data points were added analytically to the J-Δa plot to increase the number of data points without performing additional experiments for different J-Δa zones where test data was unavailable. Consequently, displacement (δ) and crack-growth (Δa) from multi-specimen tests (with small displacements) were used simultaneously, resulting in the variation of Δa-δ (crack growth law) and δ-Δa obtained for this steel. For new Δa values, corresponding δ values were first calculated from δ-Δa. Then, corresponding J values for the obtained δ values were calculated from the area under the F-δ record of a full-fractured specimen (with large displacement). Given Δa and J values for new data points, the developed J-Δa plot with extra data points yielded a satisfactory estimation of J_IC=345kN/m with only a -3.1% error. This is promising and showed that the developed technique could ease the estimation of J_IC significantly and reduce the time and cost of expensive extra fracture toughness tests.

• Journal of the Korean Institute of Gas
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• v.24 no.5
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• pp.39-46
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• 2020

This paper is considered about centerline segregation of API 5L steel used in pipeline. Mn/S, Nb and C were known as segregated elements in the centerline of pipe thickness. The Mn usually was accompanied by S consisting of long viscous shape. Microstructure of the centerline was composed of MnS and Nb/Ti indusions including oxide. The segregation effect in centerline region was analyzed by OM, SEM/EDS and micro Vickers hardness. The Mn, Nb and C are retarded elements in transformation from austenite to ferrite or martensite. These elements could derive a bainitic microstructure as a kind of martensite, which is different from difference and element segregation between in matrix and centerline derived from steel melting and heat treatment.

• Journal of Energy Engineering
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• v.18 no.1
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• pp.49-55
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• 2009

Occurrence of hydrogen embrittlement could be one of the main obstacles for using structural equipment under hydrogen environment. It is required to develop assessment methods of hydrogen embrittlement for the metals used in production, storage, transmission and application utilities of hydrogen. The most probable method of hydrogen mass transmission is using existing natural gas pipeline. Base or weld part of the pipeline can be damaged by mixed gas of hydrogen in the pipeline. In this study small punch (SP) testing was employed to evaluate the hydrogen embrittlement behavior for a line pipe steel (API X65) with electrochemically hydrogen charged specimens. Results showed that the SP test can be a good candidate test method for hydrogen damage evaluation method. Strength of steel is known to be decreased with the level of hydrogen charging. However, for API X65 steel base metal need in this study, the effect of hydrogen to strength was not significant. It can be negligible regardless of the hydrogen contents in the steel. With this test different strength levels with various hydrogen charging conditions were observed. It can also be anticipated that more sensitive evaluation of material behavior be obtainable by the SP test method.

• Corrosion Science and Technology
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• v.4 no.3
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• pp.95-99
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• 2005

Wheel test and potentiodynamic polarization methods were used to evaluate the relative effectiveness of some hydrogen sulfide corrosion inhibitors for the wet gas pipeline API 5L grade X 65 steel. Five commercially corrosion inhibitors have been studied in the deoxygenated produced water solutions containing 10 ppm and 100 ppm of hydrogen sulfide. Based on the experiment results the steel corrosion inhibition mechanism in discussed and two most effective corrosion inhibitors are selected.

• Korean Journal of Materials Research
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• v.28 no.12
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• pp.702-708
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• 2018

This study deals with the effect of microstructure factors on the strain aging properties of API X70 pipeline steels with different microstructure fractions and grain sizes. The grain size and microstructure fraction of the API pipeline steels are analyzed by optical and scanning electron microscopy and electron backscatter diffraction analysis. Tensile tests before and after 1 % pre-strain and thermal aging treatment are conducted to simulate pipe forming and coating processes. All the steels are composed mostly of polygonal ferrite, acicular ferrite, granular bainite, and bainitic ferrite. After 1 % pre-strain and thermal aging treatment, the tensile test results reveal that yield strength, tensile strength and yield ratio increase, while uniform elongation decreases with an increasing thermal aging temperature. The increment of yield and tensile strengths are affected by the fraction of bainitic ferrite with high dislocation density because the mobility of dislocations is inhibited by interaction between interstitial atoms and dislocations in bainitic ferrite. On the other hand, the variation of yield ratio and uniform elongation is the smallest in the steel with the largest grain size because of the decrease in the grain boundary area for dislocation pile-ups and the presence of many dislocations inside large grains after 1 % pre-strain.